DE69213866T2 - Verfahren zur Herstellung eines optischen Übertragungselements aus Plastik mit abgestiftem Brechungsindex - Google Patents
Verfahren zur Herstellung eines optischen Übertragungselements aus Plastik mit abgestiftem BrechungsindexInfo
- Publication number
- DE69213866T2 DE69213866T2 DE69213866T DE69213866T DE69213866T2 DE 69213866 T2 DE69213866 T2 DE 69213866T2 DE 69213866 T DE69213866 T DE 69213866T DE 69213866 T DE69213866 T DE 69213866T DE 69213866 T2 DE69213866 T2 DE 69213866T2
- Authority
- DE
- Germany
- Prior art keywords
- optical transmission
- refractive index
- transmission element
- preform
- index distribution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000005540 biological transmission Effects 0.000 title claims description 167
- 230000003287 optical effect Effects 0.000 title claims description 155
- 229920003023 plastic Polymers 0.000 title claims description 23
- 239000004033 plastic Substances 0.000 title claims description 23
- 238000000034 method Methods 0.000 title description 19
- 238000009826 distribution Methods 0.000 claims description 86
- 239000000126 substance Substances 0.000 claims description 37
- 238000004519 manufacturing process Methods 0.000 claims description 30
- 230000002093 peripheral effect Effects 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 25
- 239000000835 fiber Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 9
- 238000009792 diffusion process Methods 0.000 claims description 5
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 238000007790 scraping Methods 0.000 claims description 2
- -1 2,2,3,3 - tetrafluoropropyl Chemical group 0.000 description 25
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- 239000000178 monomer Substances 0.000 description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 10
- 238000001723 curing Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 8
- 239000004926 polymethyl methacrylate Substances 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000004075 alteration Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- YNSNJGRCQCDRDM-UHFFFAOYSA-N 1-chlorothioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl YNSNJGRCQCDRDM-UHFFFAOYSA-N 0.000 description 1
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- ZNJXRXXJPIFFAO-UHFFFAOYSA-N 2,2,3,3,4,4,5,5-octafluoropentyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)F ZNJXRXXJPIFFAO-UHFFFAOYSA-N 0.000 description 1
- RSVZYSKAPMBSMY-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)F RSVZYSKAPMBSMY-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- QPXVRLXJHPTCPW-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-(4-propan-2-ylphenyl)propan-1-one Chemical compound CC(C)C1=CC=C(C(=O)C(C)(C)O)C=C1 QPXVRLXJHPTCPW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OFSAUHSCHWRZKM-UHFFFAOYSA-N Padimate A Chemical compound CC(C)CCOC(=O)C1=CC=C(N(C)C)C=C1 OFSAUHSCHWRZKM-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 230000036346 tooth eruption Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
- G02B6/02038—Core or cladding made from organic material, e.g. polymeric material with core or cladding having graded refractive index
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B3/00—Simple or compound lenses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00663—Production of light guides
- B29D11/00721—Production of light guides involving preforms for the manufacture of light guides
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B3/00—Simple or compound lenses
- G02B3/0087—Simple or compound lenses with index gradient
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Mechanical Engineering (AREA)
- Light Guides In General And Applications Therefor (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Lenses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5767291 | 1991-03-01 | ||
| PCT/JP1992/000210 WO1992015901A1 (fr) | 1991-03-01 | 1992-02-26 | Module d'emission optique compose d'un plastique du type a gradient d'indice et procede de production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69213866D1 DE69213866D1 (de) | 1996-10-24 |
| DE69213866T2 true DE69213866T2 (de) | 1997-02-20 |
Family
ID=13062407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69213866T Expired - Fee Related DE69213866T2 (de) | 1991-03-01 | 1992-02-26 | Verfahren zur Herstellung eines optischen Übertragungselements aus Plastik mit abgestiftem Brechungsindex |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5287222A (enExample) |
| EP (1) | EP0527239B1 (enExample) |
| JP (1) | JP3301760B2 (enExample) |
| KR (1) | KR100260568B1 (enExample) |
| DE (1) | DE69213866T2 (enExample) |
| TW (1) | TW255016B (enExample) |
| WO (1) | WO1992015901A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10214533A1 (de) * | 2002-04-02 | 2003-10-30 | Deutsche Telekom Ag | Verfahren und Vorrichtung zum Herstellen von Kunststoff-Gradientenfasern |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6106745A (en) * | 1995-11-30 | 2000-08-22 | Akzo Nobel Nv | Method of making graded index polymeric optical fibers |
| US6200503B1 (en) | 1996-09-13 | 2001-03-13 | Mohammad W. Katoot | Graded index polymer optical fibers and process for manufacture thereof |
| EP0958254A4 (en) * | 1996-09-13 | 2001-01-10 | Mohammad W Katoot | INDEX GRADIENT POLYMERIC OPTICAL FIBERS |
| JP3728032B2 (ja) * | 1996-10-31 | 2005-12-21 | 三菱レイヨン株式会社 | 低色収差ロッドレンズアレイ及びそのユニット並びにこれらを用いたイメージスキャナ |
| TWI222978B (en) * | 1998-02-24 | 2004-11-01 | Mitsubishi Rayon Co | Process for producing methacrylate-based polymer and process for producing optical fiber |
| US6088166A (en) * | 1998-12-22 | 2000-07-11 | Dicon Fiberoptics, Inc. | Miniaturization of gradient index lens used in optical components |
| US6365072B1 (en) | 1999-03-19 | 2002-04-02 | Mk Industries, Inc. | Polymer optical fibers and process for manufacturing thereof |
| DE10226923A1 (de) * | 2002-06-17 | 2003-12-24 | Bayer Ag | Verfahren zur Enantiomerenanreicherung von cis-8-Benzyl-7,9-dioxo-2,8-diazabicyclo[4.3.0]nonan |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3626194A (en) * | 1968-08-30 | 1971-12-07 | Nippon Selfoc Co Ltd | Photoelectric converter including convergent lens with refractive index distribution |
| JPS5121594B2 (enExample) * | 1971-12-25 | 1976-07-03 | ||
| DE2756989C2 (de) * | 1977-12-21 | 1983-01-05 | Fa. Carl Zeiss, 7920 Heidenheim | Optisches System |
| JPS58159506A (ja) * | 1982-03-18 | 1983-09-21 | Nippon Sheet Glass Co Ltd | 合成樹脂光伝送体を製造する方法 |
| JPS6012509A (ja) * | 1983-07-02 | 1985-01-22 | Nippon Sheet Glass Co Ltd | 合成樹脂光伝送体の製造方法 |
| EP0130838B1 (en) * | 1983-07-02 | 1987-10-07 | Nippon Sheet Glass Co., Ltd. | Method and apparatus for producing light transmitting article of synthetic resin |
| KR950003433B1 (ko) * | 1986-03-27 | 1995-04-12 | 미쓰비시 레이욘 가부시끼가이샤 | 플라스틱 광전송체, 이의 제조방법 및 이를 사용한 렌즈 어레이 |
| JPH0264131A (ja) * | 1988-08-31 | 1990-03-05 | Mitsubishi Rayon Co Ltd | 透明円柱状組成物 |
-
1992
- 1992-02-26 KR KR1019920702704A patent/KR100260568B1/ko not_active Expired - Fee Related
- 1992-02-26 JP JP50606592A patent/JP3301760B2/ja not_active Expired - Lifetime
- 1992-02-26 WO PCT/JP1992/000210 patent/WO1992015901A1/ja not_active Ceased
- 1992-02-26 EP EP92906216A patent/EP0527239B1/en not_active Expired - Lifetime
- 1992-02-26 DE DE69213866T patent/DE69213866T2/de not_active Expired - Fee Related
- 1992-02-26 US US07/949,479 patent/US5287222A/en not_active Expired - Fee Related
- 1992-03-12 TW TW081101883A patent/TW255016B/zh active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10214533A1 (de) * | 2002-04-02 | 2003-10-30 | Deutsche Telekom Ag | Verfahren und Vorrichtung zum Herstellen von Kunststoff-Gradientenfasern |
| DE10214533B4 (de) * | 2002-04-02 | 2004-11-25 | Deutsche Telekom Ag | Verfahren und Vorrichtung zum Herstellen einer optischen Polymerfaser |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1992015901A1 (fr) | 1992-09-17 |
| KR930700857A (ko) | 1993-03-16 |
| EP0527239A1 (en) | 1993-02-17 |
| KR100260568B1 (ko) | 2000-07-01 |
| EP0527239B1 (en) | 1996-09-18 |
| JP3301760B2 (ja) | 2002-07-15 |
| TW255016B (enExample) | 1995-08-21 |
| US5287222A (en) | 1994-02-15 |
| EP0527239A4 (en) | 1993-05-05 |
| DE69213866D1 (de) | 1996-10-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |