DE68908624T2 - Verfahren zur Herstellung von alpha-(4-Isobutyl)propionsäure oder ihres Vorläufers. - Google Patents

Verfahren zur Herstellung von alpha-(4-Isobutyl)propionsäure oder ihres Vorläufers.

Info

Publication number
DE68908624T2
DE68908624T2 DE89111484T DE68908624T DE68908624T2 DE 68908624 T2 DE68908624 T2 DE 68908624T2 DE 89111484 T DE89111484 T DE 89111484T DE 68908624 T DE68908624 T DE 68908624T DE 68908624 T2 DE68908624 T2 DE 68908624T2
Authority
DE
Germany
Prior art keywords
isobutyl
precursor
alpha
preparation
propionic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE89111484T
Other languages
English (en)
Other versions
DE68908624D1 (de
Inventor
Isoo Shimizu
Yasuo Matsumura
Yuuichi Tokumoto
Kazumichi Uchida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Petrochemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP63156331A external-priority patent/JPH0798758B2/ja
Priority claimed from JP63156332A external-priority patent/JPH0798759B2/ja
Priority claimed from JP31415288A external-priority patent/JPH0819013B2/ja
Priority claimed from JP63314155A external-priority patent/JPH0791215B2/ja
Application filed by Nippon Petrochemicals Co Ltd filed Critical Nippon Petrochemicals Co Ltd
Publication of DE68908624D1 publication Critical patent/DE68908624D1/de
Application granted granted Critical
Publication of DE68908624T2 publication Critical patent/DE68908624T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/72—Addition to a non-aromatic carbon atom of hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85—Chromium, molybdenum or tungsten
    • C07C2523/86—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1206—Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE89111484T 1988-06-24 1989-06-23 Verfahren zur Herstellung von alpha-(4-Isobutyl)propionsäure oder ihres Vorläufers. Expired - Fee Related DE68908624T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP63156331A JPH0798758B2 (ja) 1988-06-24 1988-06-24 ｐ−イソブチルスチレンの製造方法
JP63156332A JPH0798759B2 (ja) 1988-06-24 1988-06-24 ｐ−イソブチルスチレンの製造方法
JP31415288A JPH0819013B2 (ja) 1988-12-13 1988-12-13 ｏ−イソブチルエチルベンゼンおよびｍ−イソブチルエチルベンゼン
JP63314155A JPH0791215B2 (ja) 1988-12-13 1988-12-13 α−（４−イソブチルフェニル）プロピオン酸またはそのアルキルエステルの製造方法

Publications (2)

Publication Number Publication Date
DE68908624D1 DE68908624D1 (de) 1993-09-30
DE68908624T2 true DE68908624T2 (de) 1994-03-24

Family

ID=27473405

Family Applications (1)

Application Number Title Priority Date Filing Date
DE89111484T Expired - Fee Related DE68908624T2 (de) 1988-06-24 1989-06-23 Verfahren zur Herstellung von alpha-(4-Isobutyl)propionsäure oder ihres Vorläufers.

Country Status (4)

Country Link
US (1) US5097061A (de)
EP (1) EP0347939B1 (de)
CA (1) CA1334103C (de)
DE (1) DE68908624T2 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2782363B2 (ja) * 1989-08-25 1998-07-30 日本石油化学株式会社 α−（４−イソブチルフェニル）プロピオン酸またはそのエステルの製造方法
US5254766A (en) * 1990-10-16 1993-10-19 Mitsui Petrochemical Industries, Ltd. Process for producing alkyl-substituted aromatic hydrocarbon using heteropolyacid salts
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
US5223640A (en) * 1992-12-23 1993-06-29 Hoechst Celanese Corporation Preparation of optically active α-aryl propionic acids
US5254720A (en) * 1992-12-28 1993-10-19 Ethyl Corporation Process for preparing aryl-substituted aliphatic carboxylic acids and their alkyl esters
WO1996020154A1 (en) * 1994-12-28 1996-07-04 Exxon Chemical Patents Inc. Production of trialkylacetic acids using a solid cationic resin catalyst system
US5849965A (en) * 1997-05-22 1998-12-15 Amoco Corporation Multistage alkylation process

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2407373A (en) * 1943-03-27 1946-09-10 Standard Oil Dev Co Dehydrogenation of hydrocarbons
US2864859A (en) * 1956-01-23 1958-12-16 Sun Oil Co Preparation of organic acids having a tertiary or quaternary alpha carbon atom
US2888499A (en) * 1956-08-29 1959-05-26 Phillips Petroleum Co Dehydrogenation catalyst and process
US2995610A (en) * 1959-03-24 1961-08-08 Standard Oil Co Isobutylbenzene preparation
US3291847A (en) * 1964-01-02 1966-12-13 Phillips Petroleum Co Catalytic alkylation of alkyl-substituted aromatics with monoolefins
US3437703A (en) * 1966-05-05 1969-04-08 Foster Grant Co Inc Catalytic dehydrogenation process and compositions
US3631213A (en) * 1970-05-07 1971-12-28 Foster Grant Co Inc Process for the preparation of meta-and para-tertiarybutylstyrenes
JPS5323823B2 (de) * 1973-01-22 1978-07-17
DE2646792C2 (de) * 1975-10-23 1985-05-09 Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben
US4902845A (en) * 1982-02-04 1990-02-20 Amoco Corporation Method to extend life of iron oxide-containing catalysts using low levels of oxygen
US4463207A (en) * 1983-09-23 1984-07-31 Shell Oil Company Arene alkylation with metal oxide-tantalum halide/oxide catalysts
US4694100A (en) * 1984-07-14 1987-09-15 Nippon Petrochemicals Company, Ltd. Method for producing α-(p-isobutylphenyl)propionic acid or its alkyl esters
US4827065A (en) * 1984-07-14 1989-05-02 Nippon Petrochemicals Company, Limited Method of producing p-isobutylstyrene and a starting compound therefor
JPS62149641A (ja) * 1985-11-25 1987-07-03 モンサント　コンパニ− ２−アリ−ルプロピオン酸の製造方法
US4914250A (en) * 1988-06-17 1990-04-03 Ethyl Corporation Coupling process

Also Published As

Publication number Publication date
US5097061A (en) 1992-03-17
CA1334103C (en) 1995-01-24
DE68908624D1 (de) 1993-09-30
EP0347939A1 (de) 1989-12-27
EP0347939B1 (de) 1993-08-25

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Legal Events

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8339 Ceased/non-payment of the annual fee