DE68903672T2 - Katalysator zur hydrierung eines polymers und verfahren zur katalytischen hydrierung eines polymers. - Google Patents
Katalysator zur hydrierung eines polymers und verfahren zur katalytischen hydrierung eines polymers.Info
- Publication number
- DE68903672T2 DE68903672T2 DE8989304180T DE68903672T DE68903672T2 DE 68903672 T2 DE68903672 T2 DE 68903672T2 DE 8989304180 T DE8989304180 T DE 8989304180T DE 68903672 T DE68903672 T DE 68903672T DE 68903672 T2 DE68903672 T2 DE 68903672T2
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- catalyticly
- hydrating
- hydrogenating
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/128—Mixtures of organometallic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63104256A JP2718059B2 (ja) | 1988-04-28 | 1988-04-28 | 重合体の水素添加方法および触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE68903672D1 DE68903672D1 (de) | 1993-01-14 |
DE68903672T2 true DE68903672T2 (de) | 1993-06-17 |
Family
ID=14375849
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8989304180T Expired - Lifetime DE68903672T2 (de) | 1988-04-28 | 1989-04-26 | Katalysator zur hydrierung eines polymers und verfahren zur katalytischen hydrierung eines polymers. |
Country Status (5)
Country | Link |
---|---|
US (1) | US4980421A (de) |
EP (1) | EP0339986B1 (de) |
JP (1) | JP2718059B2 (de) |
DE (1) | DE68903672T2 (de) |
FR (1) | FR2650964B1 (de) |
Families Citing this family (82)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2969771B2 (ja) * | 1989-12-22 | 1999-11-02 | ジェイエスアール株式会社 | オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物 |
US5187236A (en) * | 1990-01-16 | 1993-02-16 | Mobil Oil Corporation | Solid block and random elastomeric copolymers |
US5039755A (en) * | 1990-05-29 | 1991-08-13 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
US5141997A (en) * | 1990-08-15 | 1992-08-25 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
US5177155A (en) * | 1991-05-13 | 1993-01-05 | Shell Oil Company | Selective hydrogenation of conjugation diolefin polymers with rare earth catalysts |
US5132372A (en) * | 1991-09-09 | 1992-07-21 | Shell Oil Company | Process for selective hydrogenation of conjugated diolefin polymers |
US5206307A (en) * | 1991-09-09 | 1993-04-27 | Shell Oil Company | Process for selective hydrogenation of conjugated diolefin polymers |
US5162446A (en) * | 1991-10-30 | 1992-11-10 | Shell Oil Company | Depolymerization of conjugated diene polymers |
US5166277A (en) * | 1991-10-31 | 1992-11-24 | Shell Oil Company | Hydrogenation of unsaturation in low molecular weight diene polymers |
US5270274A (en) * | 1991-11-28 | 1993-12-14 | Japan Synthetic Rubber Co., Ltd. | Catalyst composition for hydrogenating olefinically unsaturated polymers |
ES2053363B1 (es) * | 1991-12-05 | 1995-02-16 | Repsol Quimica Sa | Procedimiento de hidrogenacion de olefinas. |
US5173537A (en) * | 1991-12-20 | 1992-12-22 | Shell Oil Company | Selective hydrogenation of conjugated diolefin poylmers |
US5242961A (en) * | 1992-05-28 | 1993-09-07 | Shell Oil Company | Color prevention in titanium catalyzed hydrogenated diene polymers |
US5242986A (en) * | 1992-08-10 | 1993-09-07 | Shell Oil Company | Selective partial hydrogenation of conjugated diolefin polymers |
US5608009A (en) * | 1992-10-28 | 1997-03-04 | Idemitsu Kosan Co., Ltd. | Olefin copolymer and process for preparing same |
ES2050620B1 (es) * | 1992-11-03 | 1994-12-16 | Repsol Quimica Sa | Procedimiento de hidrogenacion en disolucion de los dobles enlaces de polimeros de dienos conjugados y copolimero bloque hidrogenado producido. |
US5583185A (en) * | 1992-11-03 | 1996-12-10 | Repsol Quimica S.A. | Process for hydrogenation in solution of the double bonds of conjugated dienes, and hydrogenated block copolymer produced |
US5244980A (en) * | 1992-12-07 | 1993-09-14 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent |
DE69425429T2 (de) * | 1993-02-24 | 2001-01-04 | Idemitsu Kosan Co | Propylenblockcopolymer, verfahren zu dessen herstellung und daraus hergestelltes modifiziertes copolymer |
US5336726A (en) * | 1993-03-11 | 1994-08-09 | Shell Oil Company | Butadiene polymers having terminal silyl groups |
US5596041A (en) * | 1994-04-04 | 1997-01-21 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated block copolymer and hydrogenated block copolymer compositon |
AU4419496A (en) * | 1994-12-12 | 1996-07-03 | Dow Chemical Company, The | Hydrogenation of unsaturated polymers using monocyclopentadienyl group iv metal catalysts |
US5585441A (en) * | 1995-05-22 | 1996-12-17 | Mobil Oil Corporation | Elastomer - Modified thermoplastic olefin polymer compositions |
KR100201228B1 (ko) * | 1995-10-17 | 1999-06-15 | 박찬구 | 리빙중합체의 수첨방법 |
KR0182835B1 (ko) * | 1996-04-26 | 1999-05-15 | 김흥기 | 올레핀성 이중결합을 갖는 리빙중합체의 선택적 수소화 방법 |
IT1284105B1 (it) * | 1996-07-04 | 1998-05-08 | Enichem Elastomers | Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene |
JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
EP0889057B1 (de) * | 1997-06-30 | 2003-01-08 | Asahi Kasei Kabushiki Kaisha | Verfahren zur Hydrierung von konjugierten Dienpolymeren |
KR100219260B1 (ko) * | 1997-07-24 | 1999-09-01 | 박찬구 | 리빙 중합체 수첨용 신규 촉매 및 촉매를 이용한 수첨방법 |
IT1296066B1 (it) * | 1997-11-06 | 1999-06-09 | Enichem Spa | Procedimento per la idrogenazione di (co) polimeri dienici |
JP3777810B2 (ja) | 1998-07-24 | 2006-05-24 | Jsr株式会社 | オレフイン性不飽和化合物の水素添加触媒および水素添加方法 |
TW583027B (en) | 1998-10-30 | 2004-04-11 | Shell Int Research | A method for preparing a hydrogenation catalyst system |
ES2223535T3 (es) * | 1999-07-09 | 2005-03-01 | Dow Global Technologies Inc. | Hidrogenacion de polimeros insaturados usando catalizadores divalentes a base de un metal del grupo iv y bisciclopentadienilo y que contienen dieno. |
KR100348761B1 (ko) | 1999-11-26 | 2002-08-13 | 금호석유화학 주식회사 | 공액디엔을 포함하는 중합체의 선택적 수소화 방법 |
ES2257353T3 (es) | 2000-04-21 | 2006-08-01 | Jsr Corporation | Composicion de resina termoplastica. |
AU2002233185A1 (en) | 2000-07-28 | 2002-05-06 | Kraton Polymers Research B.V. | Process for preparing partially hydrogenated butadiene polymers |
EP1258498B1 (de) * | 2000-10-25 | 2014-04-02 | Asahi Kasei Kabushiki Kaisha | Hydriertes polymer |
KR100411861B1 (ko) | 2000-11-28 | 2003-12-18 | 금호석유화학 주식회사 | 유기티타늄 화합물로 선택적으로 수소화된 중합체로부터금속 촉매를 제거하는 방법 |
CZ20031622A3 (cs) | 2000-12-01 | 2003-10-15 | Kraton Polymers Research B. V. | Bitumenová kompozice se sníženou želatinační tendencí |
ATE396207T1 (de) | 2001-03-26 | 2008-06-15 | Jsr Corp | Hydriertes modifiziertes polymer, verfahren zu seiner herstellung und dieses enthaltende zusammensetzung |
EP1293535B1 (de) | 2001-09-04 | 2005-08-03 | JSR Corporation | Harzzusammensetzung und Golfball |
TW546307B (en) * | 2002-10-25 | 2003-08-11 | Tsrc Corp | Method for hydrogenating conjugated diene polymer |
KR100515452B1 (ko) * | 2003-01-04 | 2005-09-20 | 금호석유화학 주식회사 | 고속분사 노즐 장착 반응기로부터 제조된 리튬하이드라이드를 사용하여 선택적으로 수소화된 공역디엔 중합체를 제조하는 방법 |
TWI256399B (en) * | 2004-08-19 | 2006-06-11 | Tsrc Corp | Hydrogenation catalyst composition and process for hydrogenation of conjugated diene polymer |
ITMI20050860A1 (it) * | 2005-05-13 | 2006-11-14 | Polimeri Europa Spa | Procedimento per la idrogenazione selettiva di copolimeri stirene-butadiene |
US20090270525A1 (en) | 2005-12-05 | 2009-10-29 | Jsr Corporation | Thermoplastic elastomer composition, foam product, and process for production of the composition or foam product |
EP3173441B1 (de) | 2006-02-02 | 2018-10-17 | JSR Corporation | Hydrogenierte dienpolymerzusammensetzung und gegossener kautschukartikel |
US7700694B2 (en) * | 2006-04-28 | 2010-04-20 | Tsrc Corporation | Catalyst composition and method for hydrogenating a polymer having a conjugated diene |
JP4921849B2 (ja) * | 2006-05-09 | 2012-04-25 | 台橡股▲ふん▼有限公司 | 共役ジエン重合体の水素化方法 |
CN101205268B (zh) * | 2006-12-19 | 2010-09-29 | 台橡股份有限公司 | 氢化共轭二烯聚合物的方法及氢化触媒组合物 |
JP5445129B2 (ja) | 2007-03-28 | 2014-03-19 | Jsr株式会社 | 変性水添ジエン系重合体組成物 |
ITMI20071210A1 (it) * | 2007-06-15 | 2008-12-16 | Polimeri Europa Spa | Procedimento per la idrogenazione parziale di copolimeri random vinil arene-diene coniugato |
KR100910255B1 (ko) | 2007-10-08 | 2009-07-31 | 금호석유화학 주식회사 | 수소화된 공역디엔계 중합체의 제조방법 |
US20090131597A1 (en) * | 2007-11-21 | 2009-05-21 | Young Hoon Ko | Process for the preparation of a hydrogenated conjugated diene-based polymer |
US7897705B2 (en) * | 2008-08-08 | 2011-03-01 | Sumitomo Chemical Company, Limited | Process for producing olefin polymer |
TWI472544B (zh) | 2009-10-30 | 2015-02-11 | Tsrc Corp | 氫化觸媒組合物及其氫化方法 |
CA2785280A1 (en) | 2009-12-25 | 2011-06-30 | Jsr Corporation | Thermal storage medium composition and thermal storage medium |
KR101303433B1 (ko) | 2010-11-29 | 2013-09-05 | 제이에스알 가부시끼가이샤 | 전지용 결합제 조성물, 전지 전극용 슬러리, 고체 전해질 조성물, 전극 및 전고체형 전지 |
CN104245752A (zh) | 2012-04-26 | 2014-12-24 | 旭化成化学株式会社 | 聚合物的制造方法 |
SG11201501532YA (en) | 2012-09-21 | 2015-05-28 | Asahi Kasei Chemicals Corp | Catalyst composition for hydrogenation and method for hydrogenation using the same |
JP6325447B2 (ja) | 2012-09-21 | 2018-05-16 | 旭化成株式会社 | 水素添加用触媒組成物及び当該水素添加用触媒組成物を用いた水素添加方法 |
JP6240082B2 (ja) | 2012-10-24 | 2017-11-29 | 旭化成株式会社 | 水素添加用触媒組成物の製造方法 |
SG11201502915XA (en) | 2012-11-06 | 2015-06-29 | Asahi Kasei Chemicals Corp | Method for producing a polymer, polymer solution, and polymer |
BR112015019419B8 (pt) | 2013-02-14 | 2023-04-18 | Jsr Corp | Método para produzir um polímero de dieno conjugado hidrogenado, polímero de dieno conjugado hidrogenado, e, composição polimérica |
MX2015015250A (es) | 2013-04-30 | 2016-02-09 | Asahi Kasei Chemicals Corp | Composicion que contiene oxido de titanio, composicion polimerica, y articulo moldeado. |
TWI586693B (zh) | 2013-07-23 | 2017-06-11 | 財團法人工業技術研究院 | 選擇性氫化共聚物的方法 |
US10544237B2 (en) | 2015-08-26 | 2020-01-28 | Exxonmobil Chemical Patents Inc. | Method of regulating hydrogen to a polymerization reactor |
TW201714952A (zh) | 2015-09-02 | 2017-05-01 | Jsr Corp | 組成物及成形體 |
EP3381554B1 (de) * | 2015-11-27 | 2021-02-17 | Asahi Kasei Kabushiki Kaisha | Katalysatorzusammensetzung zur hydrierung, verfahren zur herstellung davon und verfahren zur herstellung von hydriertem polymer |
WO2018038796A1 (en) | 2016-08-23 | 2018-03-01 | Exxonmobil Chemical Patents Inc. | Olefin polymerization processes |
EP3504250A1 (de) | 2016-08-23 | 2019-07-03 | ExxonMobil Chemical Patents Inc. | Olefinpolymerisierungsverfahren |
JP6953841B2 (ja) | 2017-07-05 | 2021-10-27 | 住友ゴム工業株式会社 | 空気入りタイヤ |
JP6417064B1 (ja) | 2018-04-09 | 2018-10-31 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及びタイヤ |
US20210230338A1 (en) | 2018-07-24 | 2021-07-29 | Zeon Corporation | Block copolymer and method of producing same, hydrogenated block copolymer, polymer composition, and shaped product |
EP3747943A4 (de) | 2018-08-06 | 2021-06-09 | Sumitomo Rubber Industries, Ltd. | Luftreifen |
JP7224150B2 (ja) | 2018-11-12 | 2023-02-17 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
JP2020079336A (ja) | 2018-11-12 | 2020-05-28 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
JP7224149B2 (ja) | 2018-11-12 | 2023-02-17 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
JP7253897B2 (ja) | 2018-11-12 | 2023-04-07 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
JP7444166B2 (ja) | 2019-06-26 | 2024-03-06 | 住友ゴム工業株式会社 | 空気入りタイヤ |
JP2021123711A (ja) | 2020-02-05 | 2021-08-30 | Jsr株式会社 | 重合体組成物、架橋重合体、及びタイヤ |
WO2023038095A1 (ja) | 2021-09-13 | 2023-03-16 | 日本エラストマー株式会社 | 架橋ゴム組成物、架橋ゴム組成物の製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU681032A1 (ru) * | 1976-02-23 | 1979-08-25 | Грозненский филиал Охтинского научно-производственного объединения "Пластполимер" | Способ получени димеров и содимеров -олефинов |
US4204081A (en) * | 1978-08-30 | 1980-05-20 | The Goodyear Tire & Rubber Company | Selective hydrogenation of cyclopentadiene to form cyclopentene |
US4213879A (en) * | 1979-03-01 | 1980-07-22 | Phillips Petroleum Company | Catalyst composition |
US4501857A (en) * | 1983-01-20 | 1985-02-26 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for hydrogenation of polymer |
JPS60220147A (ja) | 1984-04-18 | 1985-11-02 | Asahi Chem Ind Co Ltd | オレフイン水添触媒および該触媒を用いた重合体の水添方法 |
JPS6128507A (ja) * | 1984-07-18 | 1986-02-08 | Asahi Chem Ind Co Ltd | オレフイン性不飽和ポリマ−の水添方法 |
-
1988
- 1988-04-28 JP JP63104256A patent/JP2718059B2/ja not_active Expired - Lifetime
-
1989
- 1989-04-26 DE DE8989304180T patent/DE68903672T2/de not_active Expired - Lifetime
- 1989-04-26 US US07/343,580 patent/US4980421A/en not_active Expired - Lifetime
- 1989-04-26 EP EP89304180A patent/EP0339986B1/de not_active Expired
- 1989-08-18 FR FR898911035A patent/FR2650964B1/fr not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
FR2650964A1 (fr) | 1991-02-22 |
DE68903672D1 (de) | 1993-01-14 |
JP2718059B2 (ja) | 1998-02-25 |
FR2650964B1 (fr) | 1992-03-06 |
JPH01275605A (ja) | 1989-11-06 |
US4980421A (en) | 1990-12-25 |
EP0339986B1 (de) | 1992-12-02 |
EP0339986A1 (de) | 1989-11-02 |
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