DE60327802D1 - Bimetallische indenoindolyl katalysatoren - Google Patents
Bimetallische indenoindolyl katalysatorenInfo
- Publication number
- DE60327802D1 DE60327802D1 DE60327802T DE60327802T DE60327802D1 DE 60327802 D1 DE60327802 D1 DE 60327802D1 DE 60327802 T DE60327802 T DE 60327802T DE 60327802 T DE60327802 T DE 60327802T DE 60327802 D1 DE60327802 D1 DE 60327802D1
- Authority
- DE
- Germany
- Prior art keywords
- indenoindolyl
- bimetallic
- complexes
- bimetalic
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Indole Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/308,842 US6841500B2 (en) | 2002-12-03 | 2002-12-03 | Bimetallic indenoindolyl catalysts |
PCT/US2003/028209 WO2004050718A1 (en) | 2002-12-03 | 2003-09-10 | Bimetallic indenoindolyl catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60327802D1 true DE60327802D1 (de) | 2009-07-09 |
Family
ID=32392850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60327802T Expired - Fee Related DE60327802D1 (de) | 2002-12-03 | 2003-09-10 | Bimetallische indenoindolyl katalysatoren |
Country Status (12)
Country | Link |
---|---|
US (1) | US6841500B2 (de) |
EP (1) | EP1567561B1 (de) |
JP (1) | JP2006509071A (de) |
KR (1) | KR20050085300A (de) |
CN (1) | CN1308354C (de) |
AT (1) | ATE432296T1 (de) |
AU (1) | AU2003272296A1 (de) |
BR (1) | BR0316966A (de) |
CA (1) | CA2505685A1 (de) |
DE (1) | DE60327802D1 (de) |
MX (1) | MXPA05005910A (de) |
WO (1) | WO2004050718A1 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7473745B2 (en) * | 2005-09-02 | 2009-01-06 | Equistar Chemicals, Lp | Preparation of multimodal polyethylene |
JP4825648B2 (ja) * | 2006-11-28 | 2011-11-30 | 三菱電機株式会社 | 開閉器制御装置 |
US8012900B2 (en) * | 2007-12-28 | 2011-09-06 | Chevron Phillips Chemical Company, L.P. | Nano-linked metallocene catalyst compositions and their polymer products |
US7863210B2 (en) | 2007-12-28 | 2011-01-04 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
US8080681B2 (en) | 2007-12-28 | 2011-12-20 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
US7919639B2 (en) * | 2009-06-23 | 2011-04-05 | Chevron Phillips Chemical Company Lp | Nano-linked heteronuclear metallocene catalyst compositions and their polymer products |
US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
KR101894023B1 (ko) * | 2011-05-11 | 2018-10-05 | 삼성디스플레이 주식회사 | 축합환 화합물, 이를 포함하는 유기 발광 소자 및 평판 표시 장치 |
WO2013040276A1 (en) * | 2011-09-13 | 2013-03-21 | California Institute Of Technology | Multi-metallic organometallic complexes, and related polymers, compositions, methods and systems |
KR20140075589A (ko) | 2012-12-11 | 2014-06-19 | 주식회사 엘지화학 | 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법 |
JP5959131B2 (ja) | 2012-12-11 | 2016-08-02 | エルジー・ケム・リミテッド | 新規なリガンド化合物、その製造方法および前記リガンド化合物を含む遷移金属化合物、およびその製造方法 |
KR101703274B1 (ko) * | 2014-08-12 | 2017-02-22 | 주식회사 엘지화학 | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법 |
EP3510060A1 (de) * | 2016-09-08 | 2019-07-17 | Total Research & Technology Feluy | Verfahren zur herstellung von polypropylen |
WO2018046567A1 (en) * | 2016-09-08 | 2018-03-15 | Total Research & Technology Feluy | Process for preparing polyethylene |
KR102586857B1 (ko) * | 2017-06-20 | 2023-10-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 바이아릴 페녹시 4족 전이 금속 촉매 |
CN108341903B (zh) * | 2018-02-08 | 2020-07-14 | 中国石油天然气股份有限公司 | 一种烯烃聚合催化剂 |
EP3755705A1 (de) * | 2018-02-19 | 2020-12-30 | ExxonMobil Chemical Patents Inc. | Katalysatoren, katalysatorsysteme und verfahren zu ihrer verwendung |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3232260A (en) * | 1962-03-01 | 1966-02-01 | Reynolds Metals Co | End former and flanger |
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5241025A (en) * | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5449650A (en) * | 1992-12-08 | 1995-09-12 | Mitsubishi Petrochemical Company Limited | Catalyst components for polymerization of olefins and use thereof |
US5414180A (en) * | 1993-07-14 | 1995-05-09 | Phillips Petroleum Company | Organo-aluminoxy product and use |
US5495035A (en) * | 1994-06-01 | 1996-02-27 | University Of Iowa Research Foundation | Synthesis of ANSA-metallocene catalysts |
US6140432A (en) * | 1995-07-13 | 2000-10-31 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US5539124A (en) * | 1994-12-19 | 1996-07-23 | Occidental Chemical Corporation | Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring |
US5554775A (en) * | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
RU2167879C2 (ru) * | 1995-04-25 | 2001-05-27 | Эквистар Кэмиклз, эЛПи | КАТАЛИЗАТОР ПОЛИМЕРИЗАЦИИ ОЛЕФИНОВ В ВИДЕ АЗАБОРОЛИНИЛЬНЫХ КОМПЛЕКСОВ МЕТАЛЛОВ И СПОСОБ ПОЛУЧЕНИЯ ПОЛИ-α-ОЛЕФИНА (ВАРИАНТЫ) |
EP0739897A1 (de) * | 1995-04-27 | 1996-10-30 | Hoechst Aktiengesellschaft | Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator |
US5892079A (en) * | 1997-10-17 | 1999-04-06 | Sri International | Metallocene catalysts and associated methods of preparation and use |
US6451724B1 (en) * | 1997-11-12 | 2002-09-17 | Basell Technology Company Bv | Metallocenes and catalysts for olefin-polymerisation |
US6211311B1 (en) * | 1999-05-25 | 2001-04-03 | Equistar Chemicals, L.P. | Supported olefin polymerization catalysts |
US6232260B1 (en) | 1999-10-14 | 2001-05-15 | Equistar Chemicals, L.P. | Single-site catalysts for olefin polymerization |
JP2003520869A (ja) | 2000-01-18 | 2003-07-08 | バセル テクノロジー カンパニー ビー.ブイ. | 実質的に非晶質のプロピレンベースのポリマーの製造方法 |
US6414162B1 (en) * | 2001-04-05 | 2002-07-02 | Equistar Chemicals, Lp | Bimetallic catalysts for olefin polymerization |
EP1399491B1 (de) * | 2001-04-30 | 2006-08-23 | W.R. Grace & Co.-Conn. | Geträgerte dualübergangsmetallkatalysatorsysteme |
US6541583B2 (en) * | 2001-05-17 | 2003-04-01 | Equistar Chemicals, Lp | Polypropylene preparation |
US6440889B1 (en) * | 2001-08-15 | 2002-08-27 | Equistar Chemicals, Lp | Amine elimination process for making single-site catalysts |
US6642400B2 (en) * | 2001-09-26 | 2003-11-04 | Univation Technologies, Llc | Linked metallocene complexes, catalyst systems, and olefin polymerization processes using same |
-
2002
- 2002-12-03 US US10/308,842 patent/US6841500B2/en not_active Expired - Fee Related
-
2003
- 2003-09-10 AU AU2003272296A patent/AU2003272296A1/en not_active Abandoned
- 2003-09-10 EP EP03754472A patent/EP1567561B1/de not_active Expired - Lifetime
- 2003-09-10 KR KR1020057009995A patent/KR20050085300A/ko not_active Application Discontinuation
- 2003-09-10 CA CA002505685A patent/CA2505685A1/en not_active Abandoned
- 2003-09-10 JP JP2004557119A patent/JP2006509071A/ja not_active Withdrawn
- 2003-09-10 CN CNB038255243A patent/CN1308354C/zh not_active Expired - Fee Related
- 2003-09-10 BR BR0316966-9A patent/BR0316966A/pt not_active IP Right Cessation
- 2003-09-10 WO PCT/US2003/028209 patent/WO2004050718A1/en active Application Filing
- 2003-09-10 AT AT03754472T patent/ATE432296T1/de not_active IP Right Cessation
- 2003-09-10 DE DE60327802T patent/DE60327802D1/de not_active Expired - Fee Related
- 2003-09-10 MX MXPA05005910A patent/MXPA05005910A/es active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
US6841500B2 (en) | 2005-01-11 |
ATE432296T1 (de) | 2009-06-15 |
KR20050085300A (ko) | 2005-08-29 |
CN1708517A (zh) | 2005-12-14 |
WO2004050718A1 (en) | 2004-06-17 |
AU2003272296A1 (en) | 2004-06-23 |
EP1567561A1 (de) | 2005-08-31 |
BR0316966A (pt) | 2005-10-25 |
MXPA05005910A (es) | 2005-08-26 |
CA2505685A1 (en) | 2004-06-17 |
US20040106514A1 (en) | 2004-06-03 |
CN1308354C (zh) | 2007-04-04 |
EP1567561B1 (de) | 2009-05-27 |
JP2006509071A (ja) | 2006-03-16 |
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