DE60318903T3 - 4,4'-biphenol-polysulfon-zusammensetzungen, herstellungsverfahren dafür und gegenstände daraus - Google Patents
4,4'-biphenol-polysulfon-zusammensetzungen, herstellungsverfahren dafür und gegenstände daraus Download PDFInfo
- Publication number
- DE60318903T3 DE60318903T3 DE60318903T DE60318903T DE60318903T3 DE 60318903 T3 DE60318903 T3 DE 60318903T3 DE 60318903 T DE60318903 T DE 60318903T DE 60318903 T DE60318903 T DE 60318903T DE 60318903 T3 DE60318903 T3 DE 60318903T3
- Authority
- DE
- Germany
- Prior art keywords
- psu
- composition
- weight
- biphenol
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 121
- 229920002492 poly(sulfone) Polymers 0.000 title claims abstract description 95
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 23
- 239000011574 phosphorus Substances 0.000 claims abstract description 23
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 20
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000155 melt Substances 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 14
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000003457 sulfones Chemical class 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims description 17
- -1 phosphorus compound Chemical class 0.000 claims description 9
- 238000001746 injection moulding Methods 0.000 claims description 7
- 239000000470 constituent Substances 0.000 claims description 6
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 14
- 239000002075 main ingredient Substances 0.000 abstract 1
- 229920000491 Polyphenylsulfone Polymers 0.000 description 17
- 125000003118 aryl group Chemical group 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 229920013655 poly(bisphenol-A sulfone) Polymers 0.000 description 4
- 229920003295 Radel® Polymers 0.000 description 3
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000006224 matting agent Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- GQJDFTIOKVGUOF-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)C(CO)(CO)CO Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)C(CO)(CO)CO GQJDFTIOKVGUOF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229920006020 amorphous polyamide Polymers 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000009428 plumbing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5393—Phosphonous compounds, e.g. R—P(OR')2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43377102P | 2002-12-17 | 2002-12-17 | |
| US433771P | 2002-12-17 | ||
| PCT/US2003/040117 WO2004058870A1 (en) | 2002-12-17 | 2003-12-17 | 4,4’-biphenol polysulfone compositions, process to prepare them, and articles made thereof |
| EP03814067A EP1581585B2 (en) | 2002-12-17 | 2003-12-17 | 4,4'-biphenol polysulfone compositions, process to prepare them, and articles made thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE60318903D1 DE60318903D1 (de) | 2008-03-13 |
| DE60318903T2 DE60318903T2 (de) | 2009-02-12 |
| DE60318903T3 true DE60318903T3 (de) | 2013-06-20 |
Family
ID=32681968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60318903T Expired - Lifetime DE60318903T3 (de) | 2002-12-17 | 2003-12-17 | 4,4'-biphenol-polysulfon-zusammensetzungen, herstellungsverfahren dafür und gegenstände daraus |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7691926B2 (enExample) |
| EP (1) | EP1581585B2 (enExample) |
| JP (1) | JP4865230B2 (enExample) |
| CN (1) | CN100368468C (enExample) |
| AT (1) | ATE384761T1 (enExample) |
| AU (1) | AU2003297221A1 (enExample) |
| DE (1) | DE60318903T3 (enExample) |
| ES (1) | ES2299764T5 (enExample) |
| IN (2) | IN222216B (enExample) |
| WO (1) | WO2004058870A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003297221A1 (en) * | 2002-12-17 | 2004-07-22 | Solvay Advanced Polymers, L.L.C. | 4,4'-biphenol polysulfone compositions, process to prepare them, and articles made thereof |
| CN107254171A (zh) * | 2017-06-15 | 2017-10-17 | 金发科技股份有限公司 | 一种砜聚合物组合物及其应用 |
| CN112194896B (zh) * | 2020-09-08 | 2023-03-28 | 威海金泓管材有限公司 | 一种用于制备分集水器的聚砜树脂及其制备方法 |
| CN114196206A (zh) * | 2021-12-29 | 2022-03-18 | 苏州建发塑料制品有限公司 | 一种ppsu耐高温鼠笼及其制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1365503A (en) * | 1971-03-10 | 1974-09-04 | Imterial Chemical Ind Ltd | Aromatic olymers |
| US3755266A (en) * | 1971-11-11 | 1973-08-28 | Union Carbide Corp | Lactam polymerization with amide initiators |
| GB1398133A (en) * | 1972-09-20 | 1975-06-18 | Ici Ltd | Aromatic polymers |
| SU952923A1 (ru) | 1980-03-06 | 1982-08-23 | Предприятие П/Я М-5885 | Композици на основе полиэфирсульфона |
| DE3419376A1 (de) † | 1984-05-24 | 1985-11-28 | Basf Ag, 6700 Ludwigshafen | Gegen thermooxidation geschuetzte, aromatische polyether enthaltende mischungen und deren verwendung zur herstellung von formteilen |
| US5164466A (en) * | 1988-03-03 | 1992-11-17 | Amoco Corporation | Poly(aryl ether sulfone) compositions |
| US5086130A (en) | 1988-03-03 | 1992-02-04 | Amoco Corporation | Poly(aryl ether sulfone) compositions comprising poly(phenylene ether sulfone) |
| US4902836A (en) | 1988-07-11 | 1990-02-20 | General Electric Company | Process for inhibiting dihydric phenol degradation and color formation and composition thereof |
| GB2283490A (en) † | 1993-11-03 | 1995-05-10 | Sandoz Ltd | Processing stabilizers for polymers |
| JPH07179758A (ja) * | 1993-12-22 | 1995-07-18 | Mitsui Toatsu Chem Inc | 芳香族ポリスルホン樹脂成形材料 |
| US6593485B1 (en) | 1994-10-06 | 2003-07-15 | Clariant Finance (Bvi) Limited | Stabilizer composition |
| US5910560A (en) | 1996-11-29 | 1999-06-08 | Sumitomo Chemical Company, Ltd. | Thermoplastic resin composition and molded article |
| JPH10212403A (ja) * | 1996-11-29 | 1998-08-11 | Sumitomo Chem Co Ltd | 熱可塑性樹脂組成物および成形体 |
| JPH1135705A (ja) * | 1997-07-25 | 1999-02-09 | Sumitomo Chem Co Ltd | ポリエーテルスルホン系樹脂フィルムの製造方法 |
| US6329493B1 (en) * | 1998-10-06 | 2001-12-11 | Bp Corporation North America Inc. | Plumbing articles from poly(aryl ether sulfones) |
| US6645412B2 (en) | 1999-04-20 | 2003-11-11 | Stratasys, Inc. | Process of making a three-dimensional object |
| USH1975H1 (en) | 1999-09-23 | 2001-07-03 | General Electric Co. | Thermoplastic article having a metallic flake appearance |
| ES2298514T3 (es) | 2002-04-15 | 2008-05-16 | Solvay Advanced Polymers, Llc | Composiciones de polisulfona que presentan muy poco color y propiedades de transmitancia de luz elevada y articulos obtenidos a partir de ellas. |
| EP1497376B1 (en) | 2002-04-15 | 2007-12-26 | Solvay Advanced Polymers, LLC | Polyarylethersulfone compositions exhibiting reduced yellowness and high light transmittance properties and articles made therefrom |
| AU2003297221A1 (en) * | 2002-12-17 | 2004-07-22 | Solvay Advanced Polymers, L.L.C. | 4,4'-biphenol polysulfone compositions, process to prepare them, and articles made thereof |
-
2003
- 2003-12-17 AU AU2003297221A patent/AU2003297221A1/en not_active Abandoned
- 2003-12-17 WO PCT/US2003/040117 patent/WO2004058870A1/en not_active Ceased
- 2003-12-17 AT AT03814067T patent/ATE384761T1/de not_active IP Right Cessation
- 2003-12-17 ES ES03814067T patent/ES2299764T5/es not_active Expired - Lifetime
- 2003-12-17 EP EP03814067A patent/EP1581585B2/en not_active Expired - Lifetime
- 2003-12-17 JP JP2004563636A patent/JP4865230B2/ja not_active Expired - Fee Related
- 2003-12-17 CN CNB2003801066114A patent/CN100368468C/zh not_active Expired - Fee Related
- 2003-12-17 US US10/539,060 patent/US7691926B2/en not_active Expired - Fee Related
- 2003-12-17 IN IN2475DE2005 patent/IN222216B/en unknown
- 2003-12-17 DE DE60318903T patent/DE60318903T3/de not_active Expired - Lifetime
-
2008
- 2008-03-25 IN IN2476DE2008 patent/IN2008DE02476A/en unknown
-
2010
- 2010-02-04 US US12/700,015 patent/US8048945B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006510791A (ja) | 2006-03-30 |
| JP4865230B2 (ja) | 2012-02-01 |
| US20100168294A1 (en) | 2010-07-01 |
| AU2003297221A1 (en) | 2004-07-22 |
| DE60318903T2 (de) | 2009-02-12 |
| EP1581585B1 (en) | 2008-01-23 |
| ES2299764T5 (es) | 2013-03-22 |
| WO2004058870A1 (en) | 2004-07-15 |
| US7691926B2 (en) | 2010-04-06 |
| US8048945B2 (en) | 2011-11-01 |
| IN2005DE02475A (enExample) | 2007-01-05 |
| US20070155871A1 (en) | 2007-07-05 |
| ES2299764T3 (es) | 2008-06-01 |
| EP1581585A1 (en) | 2005-10-05 |
| IN222216B (enExample) | 2008-08-15 |
| ATE384761T1 (de) | 2008-02-15 |
| DE60318903D1 (de) | 2008-03-13 |
| EP1581585B2 (en) | 2012-10-31 |
| IN2008DE02476A (enExample) | 2008-06-27 |
| EP1581585A4 (en) | 2006-10-18 |
| CN100368468C (zh) | 2008-02-13 |
| CN1729244A (zh) | 2006-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| R102 | Epo decision maintaining patent in amended form now final |
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