DE60305500D1 - Katalysatoren mit späten übergangsmetallen zur olefinpolymerisierung und oligomerisierung - Google Patents
Katalysatoren mit späten übergangsmetallen zur olefinpolymerisierung und oligomerisierungInfo
- Publication number
- DE60305500D1 DE60305500D1 DE60305500T DE60305500T DE60305500D1 DE 60305500 D1 DE60305500 D1 DE 60305500D1 DE 60305500 T DE60305500 T DE 60305500T DE 60305500 T DE60305500 T DE 60305500T DE 60305500 D1 DE60305500 D1 DE 60305500D1
- Authority
- DE
- Germany
- Prior art keywords
- oligomerization
- catalysts
- transition metals
- olefin polymerization
- late transition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 101100020619 Arabidopsis thaliana LATE gene Proteins 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006384 oligomerization reaction Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 229910052723 transition metal Inorganic materials 0.000 title 1
- 150000003624 transition metals Chemical class 0.000 title 1
- 239000003446 ligand Substances 0.000 abstract 3
- YCIMNLLNPGFGHC-UHFFFAOYSA-L catecholate(2-) Chemical class [O-]C1=CC=CC=C1[O-] YCIMNLLNPGFGHC-UHFFFAOYSA-L 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
- C07F15/0066—Palladium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39637002P | 2002-07-17 | 2002-07-17 | |
| US396370P | 2002-07-17 | ||
| PCT/US2003/022356 WO2004007509A1 (en) | 2002-07-17 | 2003-07-17 | Late transition metal catalysts for olefin polymerization and oligomerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60305500D1 true DE60305500D1 (de) | 2006-06-29 |
| DE60305500T2 DE60305500T2 (de) | 2006-11-23 |
Family
ID=30116018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60305500T Expired - Lifetime DE60305500T2 (de) | 2002-07-17 | 2003-07-17 | Katalysatoren mit späten übergangsmetallen zur olefinpolymerisierung und oligomerisierung |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7247687B2 (de) |
| EP (1) | EP1521758B1 (de) |
| AT (1) | ATE327243T1 (de) |
| AU (1) | AU2003259148A1 (de) |
| DE (1) | DE60305500T2 (de) |
| WO (1) | WO2004007509A1 (de) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1267525C (zh) * | 2001-03-08 | 2006-08-02 | 香港大学 | 有机金属光发射材料 |
| WO2003102005A1 (en) | 2002-05-30 | 2003-12-11 | Exxonmobil Chemical Patents Inc. | Soluble late transition metal catalysts for olefin oligomerizations |
| US7871953B2 (en) * | 2002-10-25 | 2011-01-18 | Exxonmobil Chemical Patents Inc. | Late transition metal catalysts for olefin oligomerizations |
| US7160834B2 (en) | 2003-03-18 | 2007-01-09 | Exxonmobil Chemical Patents Inc. | Soluble group-10 α-diimine catalyst precursors, catalysts and methods for dimerizing and oligomerizing olefins |
| DE10356567A1 (de) * | 2003-12-04 | 2005-07-07 | Christian-Albrechts-Universität Zu Kiel | Radiosensibilisatoren und Herstellungsverfahren |
| US7767773B2 (en) | 2004-03-17 | 2010-08-03 | Exxonmobile Chemical Patents Inc. | Catalyst compounds are use thereof |
| DE602005012066D1 (de) | 2004-03-17 | 2009-02-12 | Exxonmobil Chem Patents Inc | Katalysatorzusammensetzung und verwendung davon |
| US7358410B2 (en) | 2004-12-30 | 2008-04-15 | Exxonmobil Chemical Patents Inc. | Processes for forming polypropylene from an oxygenate-contaminated monomer feedstock |
| US20070292991A1 (en) * | 2006-06-20 | 2007-12-20 | Lisa Edith Helberg | Method for quantification of analytes in a titanium, tin or silcon tetrachloride sample |
| US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| CN102039182B (zh) * | 2009-10-19 | 2012-07-25 | 中国石油化工股份有限公司 | 烯烃齐聚用铁系催化剂及其制备方法和应用 |
| CN101962382B (zh) * | 2010-09-03 | 2012-10-31 | 浙江工业大学 | 一种对称型三吩嗪镍配合物及其应用 |
| US9315755B2 (en) | 2011-05-16 | 2016-04-19 | Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences | Catalytic system for preparation of high branched alkane from olefins |
| US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| US10164284B2 (en) | 2012-07-27 | 2018-12-25 | Lockheed Martin Energy, Llc | Aqueous redox flow batteries featuring improved cell design characteristics |
| US9382274B2 (en) | 2012-07-27 | 2016-07-05 | Lockheed Martin Advanced Energy Storage, Llc | Aqueous redox flow batteries featuring improved cell design characteristics |
| US9768463B2 (en) * | 2012-07-27 | 2017-09-19 | Lockheed Martin Advanced Energy Storage, Llc | Aqueous redox flow batteries comprising metal ligand coordination compounds |
| US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| EP2767542A1 (de) * | 2013-02-18 | 2014-08-20 | Basell Polyolefine GmbH | Oligomerisierungskatalysator |
| US9890182B2 (en) | 2013-05-06 | 2018-02-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| WO2014186513A1 (en) | 2013-05-15 | 2014-11-20 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
| TW201524602A (zh) | 2013-11-19 | 2015-07-01 | Momentive Performance Mat Inc | 鈷觸媒及其於矽氫化與脫氫甲矽烷化之用途 |
| EP3071585B1 (de) | 2013-11-19 | 2018-11-07 | Momentive Performance Materials Inc. | Kobaltkatalysatoren und deren verwendung zur hydrosilylierung und dehydrogenativen silylierung |
| US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| CN107108669A (zh) | 2014-11-26 | 2017-08-29 | 洛克希德马丁尖端能量存储有限公司 | 取代的儿茶酚盐的金属络合物及含有其的氧化还原液流电池 |
| US10253051B2 (en) | 2015-03-16 | 2019-04-09 | Lockheed Martin Energy, Llc | Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride |
| US10316047B2 (en) | 2016-03-03 | 2019-06-11 | Lockheed Martin Energy, Llc | Processes for forming coordination complexes containing monosulfonated catecholate ligands |
| US10644342B2 (en) | 2016-03-03 | 2020-05-05 | Lockheed Martin Energy, Llc | Coordination complexes containing monosulfonated catecholate ligands and methods for producing the same |
| US9938308B2 (en) | 2016-04-07 | 2018-04-10 | Lockheed Martin Energy, Llc | Coordination compounds having redox non-innocent ligands and flow batteries containing the same |
| US9803037B1 (en) | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
| KR20190003835A (ko) | 2016-06-30 | 2019-01-09 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 퀴놀리닐디아미도 전이 금속 착물, 제조 및 이의 용도 |
| US10377687B2 (en) | 2016-07-26 | 2019-08-13 | Lockheed Martin Energy, Llc | Processes for forming titanium catechol complexes |
| US10343964B2 (en) | 2016-07-26 | 2019-07-09 | Lockheed Martin Energy, Llc | Processes for forming titanium catechol complexes |
| US10065977B2 (en) | 2016-10-19 | 2018-09-04 | Lockheed Martin Advanced Energy Storage, Llc | Concerted processes for forming 1,2,4-trihydroxybenzene from hydroquinone |
| US10930937B2 (en) | 2016-11-23 | 2021-02-23 | Lockheed Martin Energy, Llc | Flow batteries incorporating active materials containing doubly bridged aromatic groups |
| US10497958B2 (en) | 2016-12-14 | 2019-12-03 | Lockheed Martin Energy, Llc | Coordinatively unsaturated titanium catecholate complexes and processes associated therewith |
| US10741864B2 (en) | 2016-12-30 | 2020-08-11 | Lockheed Martin Energy, Llc | Aqueous methods for forming titanium catecholate complexes and associated compositions |
| US10320023B2 (en) | 2017-02-16 | 2019-06-11 | Lockheed Martin Energy, Llc | Neat methods for forming titanium catecholate complexes and associated compositions |
| CN108344719B (zh) * | 2018-01-03 | 2020-05-05 | 江西理工大学 | 一种基于铱配合物的用于卤代烷烃检测的传感器及其应用 |
| US11440979B2 (en) | 2018-02-19 | 2022-09-13 | Exxonmobil Chemical Patents Inc. | Catalysts, catalyst systems, and methods for using the same |
| CN111902435A (zh) | 2018-03-19 | 2020-11-06 | 埃克森美孚化学专利公司 | 弹性体丙烯-α-烯烃-二烯三元共聚物组合物 |
| EP3841188A1 (de) | 2018-08-22 | 2021-06-30 | ExxonMobil Research and Engineering Company | Herstellung eines grundstoffes aus ethanol |
| WO2020041096A1 (en) | 2018-08-22 | 2020-02-27 | Exxonmobil Research And Engineering Company | Manufacturing hydrocarbons |
| WO2020069086A2 (en) | 2018-09-27 | 2020-04-02 | Exxonmobil Chemical Patents Inc. | C1,c2-bridged ligands and catalysts |
| EP3999563A1 (de) | 2019-07-17 | 2022-05-25 | ExxonMobil Chemical Patents Inc. | Ep mit hohem propylengehalt und niedrigen glasübergangstemperaturen |
| WO2021025977A1 (en) | 2019-08-05 | 2021-02-11 | Exxonmobil Chemical Patents Inc. | Propylene-alpha-olefin-diene terpolymer additive for improving rubber tack |
| JP7363214B2 (ja) * | 2019-09-02 | 2023-10-18 | 株式会社レゾナック | イオン性化合物、有機エレクトロニクス材料、インク組成物、及び有機エレクトロニクス素子 |
| WO2021188361A1 (en) | 2020-03-20 | 2021-09-23 | Exxonmobil Chemical Patents Inc. | Linear alpha-olefin copolymers and impact copolymers thereof |
| CN112210031B (zh) * | 2020-10-22 | 2023-02-24 | 华东理工大学 | 一种后过渡金属配合物催化的乙烯与α-烯烃共聚合方法 |
| CN117377703A (zh) | 2021-05-24 | 2024-01-09 | 埃克森美孚化学专利公司 | 两相聚合方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2514217A (en) * | 1947-10-29 | 1950-07-04 | Firestone Tire & Rubber Co | Rubber compositions and process of producing same |
| EP0454231A3 (en) | 1990-04-20 | 1992-01-15 | The University Of North Carolina At Chapel Hill | Late transition metal catalysts for olefin polymerization |
| EP1287891A3 (de) | 1996-06-17 | 2003-11-26 | ExxonMobil Chemical Company | Spätübergangsmetall-Trägerkatalysatorsysteme |
| US6242623B1 (en) | 1997-07-22 | 2001-06-05 | Symyx Technologies, Inc. | Compositions and metal complexes having ancillary ligands |
| AU5490099A (en) * | 1998-08-18 | 2000-03-14 | E.I. Du Pont De Nemours And Company | Manufacture of alpha-olefins |
| ATE273312T1 (de) * | 2000-03-13 | 2004-08-15 | Repsol Quimica Sa | Diiminverbindungen |
| DE60005640T2 (de) | 2000-03-13 | 2004-07-29 | Repsol Quimica S.A. | Zweizähnige Nickel- und Palladium-komplexe und Polymerisationskatalysatoren |
| WO2003102005A1 (en) * | 2002-05-30 | 2003-12-11 | Exxonmobil Chemical Patents Inc. | Soluble late transition metal catalysts for olefin oligomerizations |
-
2003
- 2003-07-17 EP EP03764785A patent/EP1521758B1/de not_active Expired - Lifetime
- 2003-07-17 WO PCT/US2003/022356 patent/WO2004007509A1/en not_active Application Discontinuation
- 2003-07-17 AT AT03764785T patent/ATE327243T1/de not_active IP Right Cessation
- 2003-07-17 DE DE60305500T patent/DE60305500T2/de not_active Expired - Lifetime
- 2003-07-17 AU AU2003259148A patent/AU2003259148A1/en not_active Abandoned
- 2003-07-17 US US10/517,104 patent/US7247687B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003259148A8 (en) | 2004-02-02 |
| ATE327243T1 (de) | 2006-06-15 |
| EP1521758B1 (de) | 2006-05-24 |
| WO2004007509A8 (en) | 2007-09-07 |
| WO2004007509A1 (en) | 2004-01-22 |
| EP1521758A1 (de) | 2005-04-13 |
| AU2003259148A1 (en) | 2004-02-02 |
| DE60305500T2 (de) | 2006-11-23 |
| US7247687B2 (en) | 2007-07-24 |
| US20060047094A1 (en) | 2006-03-02 |
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