DE60103689T2 - Säurekatalysierte Polymerisation von wässrigen Epoxyharzemulsionen und deren Verwendung - Google Patents

Säurekatalysierte Polymerisation von wässrigen Epoxyharzemulsionen und deren Verwendung Download PDF

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Publication number
DE60103689T2
DE60103689T2 DE60103689T DE60103689T DE60103689T2 DE 60103689 T2 DE60103689 T2 DE 60103689T2 DE 60103689 T DE60103689 T DE 60103689T DE 60103689 T DE60103689 T DE 60103689T DE 60103689 T2 DE60103689 T2 DE 60103689T2
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DE
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Prior art keywords
acid
epoxy resin
aqueous epoxy
resin emulsions
catalyzed polymerization
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Expired - Fee Related
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DE60103689T
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DE60103689D1 (de
Inventor
Frederick Herbert Walker
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Air Products and Chemicals Inc
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Air Products and Chemicals Inc
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Publication of DE60103689D1 publication Critical patent/DE60103689D1/de
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Publication of DE60103689T2 publication Critical patent/DE60103689T2/de
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08Saturated oxiranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669Non-metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669Non-metals or compounds thereof
    • C08G65/2678Sulfur or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)
DE60103689T 2000-04-04 2001-04-02 Säurekatalysierte Polymerisation von wässrigen Epoxyharzemulsionen und deren Verwendung Expired - Fee Related DE60103689T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/542,759 US6331583B1 (en) 2000-04-04 2000-04-04 Acid catalyzed polymerization of aqueous epoxy resin emulsions and uses thereof

Publications (2)

Publication Number Publication Date
DE60103689D1 DE60103689D1 (de) 2004-07-15
DE60103689T2 true DE60103689T2 (de) 2004-10-21

Family

ID=24165168

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60103689T Expired - Fee Related DE60103689T2 (de) 2000-04-04 2001-04-02 Säurekatalysierte Polymerisation von wässrigen Epoxyharzemulsionen und deren Verwendung

Country Status (13)

Country Link
US (1) US6331583B1 (de)
EP (1) EP1142924B1 (de)
JP (1) JP3880328B2 (de)
KR (1) KR100435101B1 (de)
CN (1) CN1185275C (de)
AU (1) AU744611B2 (de)
BR (1) BR0101234A (de)
CA (1) CA2342658A1 (de)
DE (1) DE60103689T2 (de)
HK (1) HK1040525B (de)
SG (1) SG89383A1 (de)
TW (1) TW553972B (de)
ZA (1) ZA200102685B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6800717B2 (en) 2001-05-23 2004-10-05 Air Products And Chemicals, Inc. Acid catalyzed copolymerization of water and epoxy resin and uses thereof
AU2002349039A1 (en) * 2001-11-19 2003-06-10 Shell Internationale Research Maatschappij B.V. Process for the polymerisation of epoxy resins
US6777088B2 (en) 2002-04-01 2004-08-17 Air Products And Chemicals, Inc. Packaging materials having barrier coatings based on water-epoxy resin copolymers
US7615604B2 (en) * 2003-01-17 2009-11-10 The United States Of America As Represented By The Secretary Of The Navy Diols formed by ring-opening of epoxies
US7241504B2 (en) * 2003-01-17 2007-07-10 The United States Of America As Represented By The Secretary Of The Navy Diols formed by ring-opening of epoxies
US7622541B2 (en) * 2003-01-17 2009-11-24 The United States Of America As Represented By The Secretary Of The Navy Polyurethane coating
US7910223B2 (en) 2003-07-17 2011-03-22 Honeywell International Inc. Planarization films for advanced microelectronic applications and devices and methods of production thereof
US7112635B2 (en) * 2004-03-12 2006-09-26 Air Products And Chemicals, Inc. Acid catalyzed copolymerization of water, tetrahydrofuran and multifunctional epoxides and uses thereof
CN102775882B (zh) * 2012-07-20 2014-05-14 江苏科技大学 一种用于建筑的水性环氧树脂微乳液组合物及其制备方法
BR112015030200B1 (pt) * 2013-06-07 2021-12-21 Swimc Llc Composição de revestimento de uretano à base de solvente
CN103772915A (zh) * 2014-01-15 2014-05-07 芜湖市宝艺游乐科技设备有限公司 一种高性能的改性玻璃钢涂层材料及其制备方法
DE102015213535A1 (de) * 2015-07-17 2017-01-19 Siemens Aktiengesellschaft Fester Isolationswerkstoff, Verwendung dazu und damit hergestelltes Isolationssystem
CN111187587A (zh) * 2018-11-14 2020-05-22 湖北慧融创新科技研究院有限公司 一种基于环氧树脂改性的复合型墙体填缝胶
CN112979993B (zh) * 2021-02-25 2021-12-24 中国林业科学研究院林产化学工业研究所 一种两步法制备水性环氧树脂乳液的方法
EP4324863A1 (de) * 2022-07-19 2024-02-21 Permabond Engineering Adhesives Ltd Synthetische klebstoffzusammensetzungen mit verbesserter haftung, insbesondere auf polyamidsubstraten

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE541693A (de) * 1954-10-04 1900-01-01
US3305565A (en) * 1964-07-08 1967-02-21 Shell Oil Co Polyepihalohydrin preparation using fluoboric acid catalyst
US4315044A (en) 1980-11-05 1982-02-09 Celanese Corporation Stable aqueous epoxy dispersions
US4355154A (en) 1981-10-06 1982-10-19 Dow Corning Corporation Method for preparing condensation polymers by emulsion polymerization
DE3147458A1 (de) 1981-12-01 1983-07-14 Hoechst Ag, 6230 Frankfurt Stabile waessrige epoxidharzdispersion, verfahren zu deren herstellung und deren verwendung
US4374953A (en) 1982-04-19 1983-02-22 Dow Corning Corporation Method for preparing polyacetals and polyketals by emulsion polymerization
US4611026A (en) * 1983-04-04 1986-09-09 Ppg Industries, Inc. Emulsion and dispersion comprising cross-linked polymeric microgel prepared from polymerizing epoxy-containing monomer in the presence of an acid
US4540740A (en) * 1983-04-04 1985-09-10 Ppg Industries, Inc. Cross-linked polymeric microgel prepared from polymerizing epoxy-containing monomer in the presence of an acid
US4596843A (en) * 1985-03-20 1986-06-24 Insilco Corporation High solids coating compositions
US4608406A (en) 1985-04-18 1986-08-26 Celanese Corporation Stable aqueous epoxy resin dispersions
DE69332677T2 (de) 1992-10-21 2003-06-12 Air Prod & Chem Ionische emulsionspolymere und ihre herstellung
DE19520854A1 (de) * 1995-06-08 1996-12-12 Hoechst Ag Selbstemulgierende wäßrige Epoxidharzdispersionen
GB2303857B (en) 1995-07-28 1999-05-26 Gen Electric Cationic surfactant compatible anionic emulsion polymerized silicone emulsions
DE19536381A1 (de) * 1995-09-29 1997-04-03 Hoechst Ag Reaktivverdünner-haltige Epoxid- und Epoxid-Polyacrylat-Dispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung

Also Published As

Publication number Publication date
EP1142924A1 (de) 2001-10-10
CN1316448A (zh) 2001-10-10
KR100435101B1 (ko) 2004-06-09
EP1142924B1 (de) 2004-06-09
AU3138601A (en) 2001-10-25
DE60103689D1 (de) 2004-07-15
JP3880328B2 (ja) 2007-02-14
AU744611B2 (en) 2002-02-28
ZA200102685B (en) 2002-10-02
HK1040525A1 (en) 2002-06-14
BR0101234A (pt) 2001-10-30
HK1040525B (zh) 2005-05-27
SG89383A1 (en) 2002-06-18
JP2001348421A (ja) 2001-12-18
CA2342658A1 (en) 2001-10-04
KR20010095226A (ko) 2001-11-03
TW553972B (en) 2003-09-21
US6331583B1 (en) 2001-12-18
CN1185275C (zh) 2005-01-19

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