DE60044217D1 - Poröse hybridpartikel zur chromatographischen trennung - Google Patents
Poröse hybridpartikel zur chromatographischen trennungInfo
- Publication number
- DE60044217D1 DE60044217D1 DE60044217T DE60044217T DE60044217D1 DE 60044217 D1 DE60044217 D1 DE 60044217D1 DE 60044217 T DE60044217 T DE 60044217T DE 60044217 T DE60044217 T DE 60044217T DE 60044217 D1 DE60044217 D1 DE 60044217D1
- Authority
- DE
- Germany
- Prior art keywords
- hybrid particles
- chromatographic separation
- porous hybrid
- chromatographic
- separations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28095—Shape or type of pores, voids, channels, ducts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
- B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
- B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
- B01J20/289—Phases chemically bonded to a substrate, e.g. to silica or to polymers bonded via a spacer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
- B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
- B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
- B01J20/3225—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating involving a post-treatment of the coated or impregnated product
- B01J20/3227—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating involving a post-treatment of the coated or impregnated product by end-capping, i.e. with or after the introduction of functional or ligand groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
- B01J20/3259—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
- B01J20/3261—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/26—Cation exchangers for chromatographic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/20—Anion exchangers for chromatographic processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2995—Silane, siloxane or silicone coating
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24479599A | 1999-02-05 | 1999-02-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60044217D1 true DE60044217D1 (de) | 2010-05-27 |
Family
ID=22924139
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60044217T Expired - Lifetime DE60044217D1 (de) | 1999-02-05 | 2000-02-04 | Poröse hybridpartikel zur chromatographischen trennung |
| DE60032750T Expired - Lifetime DE60032750T2 (de) | 1999-02-05 | 2000-02-04 | Verfahren zur herstellung von porösen anorganisch/organischen hybridpartikeln zur chromatographischen trennung |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60032750T Expired - Lifetime DE60032750T2 (de) | 1999-02-05 | 2000-02-04 | Verfahren zur herstellung von porösen anorganisch/organischen hybridpartikeln zur chromatographischen trennung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20010033931A1 (https=) |
| EP (2) | EP1163050B1 (https=) |
| JP (1) | JP4750280B2 (https=) |
| AT (2) | ATE464118T1 (https=) |
| AU (1) | AU2872100A (https=) |
| DE (2) | DE60044217D1 (https=) |
| WO (1) | WO2000045951A1 (https=) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6686035B2 (en) * | 1999-02-05 | 2004-02-03 | Waters Investments Limited | Porous inorganic/organic hybrid particles for chromatographic separations and process for their preparation |
| US6528167B2 (en) * | 2001-01-31 | 2003-03-04 | Waters Investments Limited | Porous hybrid particles with organic groups removed from the surface |
| US7250214B2 (en) * | 2001-08-09 | 2007-07-31 | Waters Investments Limited | Porous inorganic/organic hybrid monolith materials for chromatographic separations and process for their preparation |
| DE10393599T5 (de) | 2002-10-30 | 2005-10-27 | Waters Investments Ltd., New Castle | Poröse anorganische/organische Homogene copolymerische Hybridmaterialien für chromatographische Auftrennungen und Verfahren für deren Herstellung |
| US7887754B2 (en) | 2003-02-07 | 2011-02-15 | Waters Technologies Corporation | Polymeric solid supports for chromatography nanocolumns |
| DE112004000906T5 (de) * | 2003-05-28 | 2006-10-19 | Waters Investments Ltd., New Castle | Neue Nanoverbundstoffe und ihre Anwendung als Monolithsäulen |
| US7074491B2 (en) * | 2003-11-04 | 2006-07-11 | Dionex Corporation | Polar silanes for binding to substrates and use of the bound substrates |
| WO2005079427A2 (en) * | 2004-02-17 | 2005-09-01 | Waters Investments Limited | Porous hybrid monolith materials with organic groups removed from the surface |
| JP4538785B2 (ja) * | 2004-03-31 | 2010-09-08 | 和樹 中西 | 有機無機ハイブリッド系多孔質体の製造方法 |
| US8658277B2 (en) | 2004-07-30 | 2014-02-25 | Waters Technologies Corporation | Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation |
| US10773186B2 (en) | 2004-07-30 | 2020-09-15 | Waters Technologies Corporation | Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation |
| US7439272B2 (en) * | 2004-12-20 | 2008-10-21 | Varian, Inc. | Ultraporous sol gel monoliths |
| SE0502485L (sv) * | 2005-11-09 | 2007-05-10 | Peter Viberg | Partiklar |
| WO2008085435A1 (en) | 2007-01-12 | 2008-07-17 | Waters Investments Limited | Porous carbon-heteroatom-silicon hybrid inorganic/organic materials for chromatographic separations and process for the preparation thereof |
| CN101657325B (zh) * | 2007-02-21 | 2013-11-20 | 沃特世科技公司 | 用于色谱分离的具有高有机质含量和增进的孔几何特征的多孔无机/有机混合颗粒 |
| EP2262576B1 (en) * | 2008-04-08 | 2025-03-12 | Waters Technologies Corporation | Composite materials containing nanoparticles and their use in chromatography |
| US11439977B2 (en) | 2009-06-01 | 2022-09-13 | Waters Technologies Corporation | Hybrid material for chromatographic separations comprising a superficially porous core and a surrounding material |
| JP6151021B2 (ja) | 2009-06-01 | 2017-06-21 | ウオーターズ・テクノロジーズ・コーポレイシヨン | クロマトグラフ分離用ハイブリッド材料 |
| US10159911B2 (en) * | 2009-08-04 | 2018-12-25 | Waters Technologies Corporation | High purity chromatographic materials comprising an ionizable modifier |
| US10150098B2 (en) * | 2009-08-04 | 2018-12-11 | Waters Technologies Corporation | High purity chromatographic materials comprising an ionizable modifier |
| CN101797520B (zh) * | 2010-03-19 | 2011-11-09 | 山西大学 | 铝掺杂有机-无机杂化粘土催化剂及其制备方法和应用 |
| JP5856162B2 (ja) | 2010-07-26 | 2016-02-09 | ウオーターズ・テクノロジーズ・コーポレイシヨン | 粒度分布の狭い実質的に非多孔質のハイブリッドコアを含む表面多孔質材料 |
| WO2012166916A1 (en) * | 2011-06-03 | 2012-12-06 | Waters Technologies Corporation | Method of separation of lipid and biological molecular species using high purity chromatographic materials |
| JP2014521809A (ja) * | 2011-08-02 | 2014-08-28 | エイビーエス マテリアルズ インコーポレイテッド | ゾル−ゲル誘導組成物 |
| CN107754776B (zh) | 2012-05-15 | 2021-09-21 | 沃特世科技公司 | 色谱材料 |
| CN107106932B (zh) | 2015-01-15 | 2021-05-25 | 戴安公司 | 具有改进的pH稳定性的色谱材料、其制备方法和其用途 |
| US20190134604A1 (en) | 2016-03-06 | 2019-05-09 | Waters Technologies Corporation | Porous materials with controlled porosity; process for the preparation thereof; and use thereof for chromatographic separations |
| CN107029715B (zh) * | 2017-05-27 | 2019-12-03 | 上海应用技术大学 | 一种聚乙烯吡咯烷酮pvp改性的铑基催化剂及其制备方法和应用 |
| EP3744684A1 (en) | 2019-05-29 | 2020-12-02 | Nouryon Chemicals International B.V. | Porous silica particles |
| EP3744683A1 (en) * | 2019-05-29 | 2020-12-02 | Nouryon Chemicals International B.V. | Porous silica particles |
| EP4613370A1 (en) | 2024-03-04 | 2025-09-10 | Dionex Softron GmbH | Mixed mode chromatographic packing material |
| EP4613371A1 (en) | 2024-03-04 | 2025-09-10 | Dionex Softron GmbH | Mixed mode chromatographic packing material |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2357184A1 (de) * | 1973-11-16 | 1975-05-22 | Merck Patent Gmbh | Verfahren zur herstellung von organisch modifizierten siliciumdioxiden |
| JPS58120525A (ja) * | 1982-01-05 | 1983-07-18 | Asahi Glass Co Ltd | 珪酸塩中空球の製造方法 |
| JPS5954619A (ja) * | 1982-09-24 | 1984-03-29 | Asahi Glass Co Ltd | 珪酸塩粒状体の製造方法 |
| US4724207A (en) * | 1984-02-02 | 1988-02-09 | Cuno Incorporated | Modified siliceous chromatographic supports |
| US5565142A (en) * | 1992-04-01 | 1996-10-15 | Deshpande; Ravindra | Preparation of high porosity xerogels by chemical surface modification. |
| JP3440486B2 (ja) * | 1992-06-19 | 2003-08-25 | 旭硝子株式会社 | 球状シリカの製造方法 |
| US5378790A (en) * | 1992-09-16 | 1995-01-03 | E. I. Du Pont De Nemours & Co. | Single component inorganic/organic network materials and precursors thereof |
| JPH07113011A (ja) * | 1993-10-18 | 1995-05-02 | Nippon Sheet Glass Co Ltd | 多孔質体及びこれを充填材とするカラム及びこれらの製造方法 |
| US5637135A (en) * | 1995-06-26 | 1997-06-10 | Capillary Technology Corporation | Chromatographic stationary phases and adsorbents from hybrid organic-inorganic sol-gels |
| JP3818689B2 (ja) * | 1996-01-16 | 2006-09-06 | 富士写真フイルム株式会社 | コロイド状シリカをコアとし、有機ポリマーをシェルとするコア/シェル状複合粒子の水性分散物及びその製造方法 |
| JPH09278485A (ja) * | 1996-04-11 | 1997-10-28 | Tosoh Corp | 耐アルカリ性球状ガラスとその製造方法 |
| US5965202A (en) * | 1996-05-02 | 1999-10-12 | Lucent Technologies, Inc. | Hybrid inorganic-organic composite for use as an interlayer dielectric |
| JP3901808B2 (ja) * | 1997-09-29 | 2007-04-04 | 株式会社東芝 | キャリアブースト補正回路 |
-
2000
- 2000-02-04 AT AT06014856T patent/ATE464118T1/de not_active IP Right Cessation
- 2000-02-04 JP JP2000597060A patent/JP4750280B2/ja not_active Expired - Lifetime
- 2000-02-04 DE DE60044217T patent/DE60044217D1/de not_active Expired - Lifetime
- 2000-02-04 WO PCT/US2000/003052 patent/WO2000045951A1/en not_active Ceased
- 2000-02-04 EP EP00907186A patent/EP1163050B1/en not_active Expired - Lifetime
- 2000-02-04 DE DE60032750T patent/DE60032750T2/de not_active Expired - Lifetime
- 2000-02-04 EP EP06014856A patent/EP1733786B1/en not_active Expired - Lifetime
- 2000-02-04 AT AT00907186T patent/ATE350154T1/de not_active IP Right Cessation
- 2000-02-04 AU AU28721/00A patent/AU2872100A/en not_active Abandoned
-
2001
- 2001-05-14 US US09/858,087 patent/US20010033931A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1163050A1 (en) | 2001-12-19 |
| EP1733786B1 (en) | 2010-04-14 |
| JP4750280B2 (ja) | 2011-08-17 |
| EP1163050A4 (en) | 2003-08-06 |
| JP2002536630A (ja) | 2002-10-29 |
| DE60032750D1 (de) | 2007-02-15 |
| AU2872100A (en) | 2000-08-25 |
| EP1733786A1 (en) | 2006-12-20 |
| ATE350154T1 (de) | 2007-01-15 |
| WO2000045951A1 (en) | 2000-08-10 |
| DE60032750T2 (de) | 2007-11-08 |
| US20010033931A1 (en) | 2001-10-25 |
| EP1163050B1 (en) | 2007-01-03 |
| ATE464118T1 (de) | 2010-04-15 |
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