DE3717928C2 - - Google Patents
Info
- Publication number
- DE3717928C2 DE3717928C2 DE3717928A DE3717928A DE3717928C2 DE 3717928 C2 DE3717928 C2 DE 3717928C2 DE 3717928 A DE3717928 A DE 3717928A DE 3717928 A DE3717928 A DE 3717928A DE 3717928 C2 DE3717928 C2 DE 3717928C2
- Authority
- DE
- Germany
- Prior art keywords
- bis
- acid
- amino
- methane
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 38
- 150000004985 diamines Chemical class 0.000 claims description 29
- 229920002647 polyamide Polymers 0.000 claims description 25
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 18
- -1 aliphatic dicarboxylic acids Chemical class 0.000 claims description 16
- 238000006068 polycondensation reaction Methods 0.000 claims description 15
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 11
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 9
- OZTBUYKEBWNOKR-UHFFFAOYSA-N 4-[(4-amino-3-ethyl-5-methylcyclohexyl)methyl]-2-ethyl-6-methylcyclohexan-1-amine Chemical class C1C(C)C(N)C(CC)CC1CC1CC(CC)C(N)C(C)C1 OZTBUYKEBWNOKR-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000299 Nylon 12 Polymers 0.000 claims description 5
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000002531 isophthalic acids Chemical class 0.000 claims description 4
- 150000003951 lactams Chemical class 0.000 claims description 4
- OZUBMBIDHPBIDL-UHFFFAOYSA-N 4-Propylcyclohexylamine Chemical compound CCCC1CCC(N)CC1 OZUBMBIDHPBIDL-UHFFFAOYSA-N 0.000 claims description 3
- 229920000571 Nylon 11 Polymers 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 claims description 3
- AXPMRSNNJUSOPB-UHFFFAOYSA-N 4-[(4-amino-3,5-diethylcyclohexyl)methyl]-2,6-diethylcyclohexan-1-amine Chemical compound C1C(CC)C(N)C(CC)CC1CC1CC(CC)C(N)C(CC)C1 AXPMRSNNJUSOPB-UHFFFAOYSA-N 0.000 claims description 2
- DJSSSLXGDJCTSI-UHFFFAOYSA-N 4-[(4-amino-3-methyl-5-propan-2-ylcyclohexyl)methyl]-2-methyl-6-propan-2-ylcyclohexan-1-amine Chemical compound C1C(C)C(N)C(C(C)C)CC1CC1CC(C(C)C)C(N)C(C)C1 DJSSSLXGDJCTSI-UHFFFAOYSA-N 0.000 claims description 2
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- OTKFKCIRTBTDKK-UHFFFAOYSA-N [3-(aminomethyl)-5-bicyclo[2.2.1]heptanyl]methanamine Chemical compound C1C(CN)C2C(CN)CC1C2 OTKFKCIRTBTDKK-UHFFFAOYSA-N 0.000 claims 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000004952 Polyamide Substances 0.000 description 23
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 12
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 11
- 238000009835 boiling Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- 150000001991 dicarboxylic acids Chemical class 0.000 description 8
- 239000000155 melt Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- TYFQFVWCELRYAO-UHFFFAOYSA-N Suberic acid Natural products OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 6
- 229920006018 co-polyamide Polymers 0.000 description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 6
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 5
- BDBZTOMUANOKRT-UHFFFAOYSA-N 4-[2-(4-aminocyclohexyl)propan-2-yl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1C(C)(C)C1CCC(N)CC1 BDBZTOMUANOKRT-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RZUDZAJRBFRQLS-UHFFFAOYSA-N 2-dodecylpropanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)C(O)=O RZUDZAJRBFRQLS-UHFFFAOYSA-N 0.000 description 2
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229920006017 homo-polyamide Polymers 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- MRERMGPPCLQIPD-NBVRZTHBSA-N (3beta,5alpha,9alpha,22E,24R)-3,5,9-Trihydroxy-23-methylergosta-7,22-dien-6-one Chemical compound C1C(O)CCC2(C)C(CCC3(C(C(C)/C=C(\C)C(C)C(C)C)CCC33)C)(O)C3=CC(=O)C21O MRERMGPPCLQIPD-NBVRZTHBSA-N 0.000 description 1
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- SVEMKBCPZYWEPH-UHFFFAOYSA-N 2,4,4-trimethylhexane Chemical compound CCC(C)(C)CC(C)C SVEMKBCPZYWEPH-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- FWQNYUYRXNWOOM-UHFFFAOYSA-N 2-nonylpropanedioic acid Chemical compound CCCCCCCCCC(C(O)=O)C(O)=O FWQNYUYRXNWOOM-UHFFFAOYSA-N 0.000 description 1
- QPGBFKDHRXJSIK-UHFFFAOYSA-N 2-tert-butylbenzene-1,3-dicarboxylic acid Chemical compound CC(C)(C)C1=C(C(O)=O)C=CC=C1C(O)=O QPGBFKDHRXJSIK-UHFFFAOYSA-N 0.000 description 1
- 241001640117 Callaeum Species 0.000 description 1
- 208000005156 Dehydration Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- CSFZOENQUCDFFR-UHFFFAOYSA-N bis(aminomethyl)tricyclo[5,2,1,02,6]decane Chemical compound C12CCCC2(CN)C2(CN)CC1CC2 CSFZOENQUCDFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- WFMPGHGAHVPFKP-UHFFFAOYSA-N dodecane;methanediamine Chemical compound NCN.CCCCCCCCCCCC WFMPGHGAHVPFKP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001007 puffing effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- BPSKTAWBYDTMAN-UHFFFAOYSA-N tridecane-1,13-diamine Chemical compound NCCCCCCCCCCCCCN BPSKTAWBYDTMAN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/105—Organic claddings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyamides (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH4513/86A CH673029A5 (en, 2012) | 1986-11-11 | 1986-11-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3717928A1 DE3717928A1 (de) | 1988-05-26 |
| DE3717928C2 true DE3717928C2 (en, 2012) | 1989-10-26 |
Family
ID=4277495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19873717928 Granted DE3717928A1 (de) | 1986-11-11 | 1987-05-27 | Transparente copolyamide und ihre verwendung |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS63170418A (en, 2012) |
| CH (1) | CH673029A5 (en, 2012) |
| DE (1) | DE3717928A1 (en, 2012) |
| FR (1) | FR2606416B1 (en, 2012) |
| GB (1) | GB2197332B (en, 2012) |
| IT (1) | IT1212046B (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10224947A1 (de) * | 2002-06-05 | 2003-12-24 | Ems Chemie Ag | Transparente Polyamid-Formmassen mit verbesserter Transparenz, Chemikalienbeständigkeit und dynamischer Belastbarkeit |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2706474B1 (fr) * | 1993-06-11 | 1995-08-25 | Atochem Elf Sa | Compositions polyamides transparentes sans déformation à chaud. |
| US6277911B1 (en) | 1995-02-01 | 2001-08-21 | Ems Inventa Ag | Transparent, colorless, amorphous copolyamides and molded articles made therefrom |
| US5773558A (en) * | 1995-02-01 | 1998-06-30 | Ems-Inventa Ag | Transparent, colorless, amorphous polyamides and molded articles |
| US6008288A (en) * | 1995-02-01 | 1999-12-28 | Ems-Inventa Ag | Transparent, colorless, amorphous polyamides and molded articles |
| CH688624A5 (de) * | 1995-02-01 | 1997-12-15 | Inventa Ag | Amorphe Polyamid-Formmassen und -Formteile. |
| CA2162430A1 (en) * | 1995-02-01 | 1996-08-02 | Ems-Inventa Ag | Transparent, colorless, amorphous polyamides and molded articles |
| US5886087A (en) * | 1995-02-01 | 1999-03-23 | Ems-Inventa Ag | Transparent, colorless, amorphous polyamides and molded articles |
| DE29514658U1 (de) * | 1995-09-12 | 1996-01-11 | Ems-Inventa AG, Zürich | Streuscheibe für Beleuchtungssysteme |
| DE19642885C2 (de) * | 1996-10-17 | 2001-08-02 | Inventa Ag | Verwendung von Polyamid-Formmassen zur Herstellung von optischen oder elektrooptischen Formteilen |
| DE60209862T2 (de) | 2001-01-26 | 2007-01-04 | Arkema | Transparente, Polyamid enthaltende Zusammensetzung |
| DE10122188B4 (de) * | 2001-05-08 | 2007-04-12 | Ems-Chemie Ag | Polyamidformmassen zur Herstellung optischer Linsen |
| DE10308226A1 (de) | 2003-02-25 | 2004-09-23 | Degussa Ag | Transparente Formmasse für optische Anwendungen |
| ATE542668T1 (de) * | 2004-06-22 | 2012-02-15 | Arkema France | Mehrschichtige struktur auf polyamidbasis zum abdecken von substraten |
| JP2008088303A (ja) | 2006-10-02 | 2008-04-17 | Sumitomo Electric Fine Polymer Inc | 透明樹脂成形体並びに光学レンズ及び光学フィルム |
| JP4681073B2 (ja) | 2007-12-28 | 2011-05-11 | 住友電工ファインポリマー株式会社 | 光学レンズ |
| EP2113535A1 (de) * | 2008-04-30 | 2009-11-04 | Ems-Patent Ag | Polyamidformmassen, enthaltend Copolyamide, zur Herstellung von transparenten Formteilen mit geringem Verzug im Klimatest |
| DE102008002599A1 (de) | 2008-06-24 | 2009-12-31 | Evonik Degussa Gmbh | Bauteil mit Deckschicht aus einer PA613-Formmasse |
| JP5769618B2 (ja) | 2008-06-26 | 2015-08-26 | エーエムエス−パテント アクチェンゲゼルシャフト | 高いノッチ付衝撃強度、低吸水性、及び、優れた耐化学性を有する、高撓み性の透明成形部品を製造するための半結晶透明コポリアミドを含むポリアミド成形物質 |
| JP5233482B2 (ja) * | 2008-07-31 | 2013-07-10 | 東レ株式会社 | 共重合ポリアミド、それよりなる微粒子および炭素繊維強化複合材料 |
| JP2010285553A (ja) * | 2009-06-12 | 2010-12-24 | Mitsubishi Gas Chemical Co Inc | 耐熱性ポリアミド樹脂 |
| EP2746340B1 (de) | 2012-12-21 | 2014-12-24 | Ems-Patent Ag | Flammgeschützte Polyamid-Formmasse und deren Verwendung |
| CN104610734B (zh) * | 2015-01-05 | 2018-06-08 | 中广核三角洲（苏州）高聚物有限公司 | 耐高低温尼龙复合材料及其制备方法 |
| CN118580488B (zh) * | 2024-08-07 | 2024-10-29 | 山东广垠新材料有限公司 | 高韧性共聚透明聚酰胺及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1541384A (fr) * | 1966-10-18 | 1968-10-04 | Basf Ag | Procédé de fabrication de polyamides transparents |
| GB1259784A (en) * | 1968-07-03 | 1972-01-12 | Ici Ltd | Method of separating salts of stereoisomers of 4,4'-diaminodicyclohexylmethane |
| US3839299A (en) * | 1972-11-27 | 1974-10-01 | Phillips Petroleum Co | Amorphous polyamide from bis(4-aminocyclohexyl)methane, bis(carboxyphenyl)methane and alkylene dicarboxylic acid |
| DE2945614A1 (de) * | 1979-11-12 | 1981-05-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4,4'diamino-3,3',5,5'-tetraalkyldicyclohexylmethanen |
| US4369305A (en) * | 1980-11-20 | 1983-01-18 | E. I. Du Pont De Nemours And Company | Polyamide molding resin from PACM having specific stereo isomer ratio |
| JPS61123803A (ja) * | 1984-11-20 | 1986-06-11 | Fujitsu Ltd | 光フアイバ |
| CH667462A5 (de) * | 1985-01-07 | 1988-10-14 | Inventa Ag | Transparente copolyamide, verfahren zu deren herstellung und deren verwendung zur herstellung von formkoerpern. |
-
1986
- 1986-11-11 CH CH4513/86A patent/CH673029A5/de not_active IP Right Cessation
- 1986-12-09 JP JP61291715A patent/JPS63170418A/ja active Pending
- 1986-12-15 GB GB8629928A patent/GB2197332B/en not_active Expired - Lifetime
-
1987
- 1987-03-03 FR FR8702867A patent/FR2606416B1/fr not_active Expired
- 1987-05-27 DE DE19873717928 patent/DE3717928A1/de active Granted
- 1987-11-09 IT IT8748596A patent/IT1212046B/it active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10224947A1 (de) * | 2002-06-05 | 2003-12-24 | Ems Chemie Ag | Transparente Polyamid-Formmassen mit verbesserter Transparenz, Chemikalienbeständigkeit und dynamischer Belastbarkeit |
| US6943231B2 (en) | 2002-06-05 | 2005-09-13 | Ems-Chemie Ag | Transparent polyamide molding materials having improved transparency, resistance to chemicals and high permanent fatigue strength |
| DE10224947B4 (de) * | 2002-06-05 | 2006-07-06 | Ems Chemie Ag | Transparente Polyamid-Formmassen mit verbesserter Transparenz, Chemikalienbeständigkeit und dynamischer Belastbarkeit |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2606416A1 (fr) | 1988-05-13 |
| GB2197332A (en) | 1988-05-18 |
| IT8748596A0 (it) | 1987-11-09 |
| DE3717928A1 (de) | 1988-05-26 |
| CH673029A5 (en, 2012) | 1990-01-31 |
| JPS63170418A (ja) | 1988-07-14 |
| GB8629928D0 (en) | 1987-01-28 |
| GB2197332B (en) | 1990-02-14 |
| FR2606416B1 (fr) | 1989-06-09 |
| IT1212046B (it) | 1989-11-08 |
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| OP8 | Request for examination as to paragraph 44 patent law | ||
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