DE3682783D1 - Herstellung von optisch reinen organoboranen. - Google Patents
Herstellung von optisch reinen organoboranen.Info
- Publication number
- DE3682783D1 DE3682783D1 DE8686100239T DE3682783T DE3682783D1 DE 3682783 D1 DE3682783 D1 DE 3682783D1 DE 8686100239 T DE8686100239 T DE 8686100239T DE 3682783 T DE3682783 T DE 3682783T DE 3682783 D1 DE3682783 D1 DE 3682783D1
- Authority
- DE
- Germany
- Prior art keywords
- organoborane
- alkene
- organoboranes
- production
- optically pure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007787 solid Substances 0.000 abstract 2
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- MPQAQJSAYDDROO-VMAIWCPRSA-N bis[(1r,3r,4s,5r)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]boron Chemical compound C([C@H]([C@@H]1C)[B][C@@H]2C[C@@H]3C[C@@H](C3(C)C)[C@H]2C)[C@H]2C(C)(C)[C@@H]1C2 MPQAQJSAYDDROO-VMAIWCPRSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- XOKSLPVRUOBDEW-UHFFFAOYSA-N pinane of uncertain configuration Natural products CC1CCC2C(C)(C)C1C2 XOKSLPVRUOBDEW-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
- C07C35/06—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
- C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C35/22—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system
- C07C35/23—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings
- C07C35/28—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings the condensed ring system containing seven carbon atoms
- C07C35/29—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings the condensed ring system containing seven carbon atoms being a (2.2.1) system
- C07C35/30—Borneol; Isoborneol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/692,046 US4713380A (en) | 1985-01-16 | 1985-01-16 | Production of optically pure organoboranes |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3682783D1 true DE3682783D1 (de) | 1992-01-23 |
Family
ID=24779045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8686100239T Expired - Fee Related DE3682783D1 (de) | 1985-01-16 | 1986-01-10 | Herstellung von optisch reinen organoboranen. |
Country Status (6)
Country | Link |
---|---|
US (1) | US4713380A (de) |
EP (1) | EP0188235B1 (de) |
JP (1) | JPS61210089A (de) |
AT (1) | ATE70275T1 (de) |
CA (1) | CA1265536A (de) |
DE (1) | DE3682783D1 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5043479A (en) * | 1986-08-29 | 1991-08-27 | Aldrich Chemical Company, Inc. | Chemically and optically pure diisopinocampheylhaloboranes |
US4906755A (en) * | 1986-11-03 | 1990-03-06 | Merrell Dow Pharmaceuticals Inc. | Esters of hexahydro-8-hydroxy-2,6-methano-2H-quinolizin-3-(4H)-one and related compounds |
DE3842554A1 (de) * | 1988-12-17 | 1990-06-21 | Bayer Ag | Chirale verbindungen vom ss-binaphthyltyp, deren herstellung und deren verwendung |
US4978794A (en) * | 1990-03-26 | 1990-12-18 | Aldrich Chemical Company, Inc. | Novel β-(2-alkenyl)bis(2-isocaranyl)boranes |
US5103063A (en) * | 1990-08-03 | 1992-04-07 | Aldrich Chemical Company, Inc. | Intermediates useful for the chiral isoprenylation of aldehydes |
US5220072A (en) * | 1991-07-15 | 1993-06-15 | Aldrich Chemical Co., Inc. | Process of synthesizing chemically and optically pure B-halodiiso-2-ethylapopinocampheylboranes |
KR101451979B1 (ko) * | 2005-05-25 | 2014-10-21 | 메르크 파텐트 게엠베하 | 테트라하이드로피란-3-온으로부터 테트라하이드로피란의제조 방법 |
US9328126B2 (en) * | 2013-01-31 | 2016-05-03 | Promerus, Llc | Norbornenylhydrocarbylene dihydrocarbylboranes and methods of making the same |
CN113024588A (zh) * | 2021-03-22 | 2021-06-25 | 成都诺和晟泰生物科技有限公司 | 一种手性N-Boc-吡咯烷-3-硼酸类化合物的制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3254129A (en) * | 1961-01-17 | 1966-05-31 | Herbert C Brown | Optically active organoboranes |
US3337643A (en) * | 1963-10-17 | 1967-08-22 | Colgate Palmolive Co | Process for preparing optically active menthol |
US3358034A (en) * | 1964-03-12 | 1967-12-12 | Herbert C Brown | Selective hydroboration process |
US4082810A (en) * | 1971-02-09 | 1978-04-04 | Aldrich-Boranes, Inc. | Bulky trialkylborohydrides |
-
1985
- 1985-01-16 US US06/692,046 patent/US4713380A/en not_active Expired - Lifetime
-
1986
- 1986-01-10 AT AT86100239T patent/ATE70275T1/de not_active IP Right Cessation
- 1986-01-10 EP EP86100239A patent/EP0188235B1/de not_active Expired - Lifetime
- 1986-01-10 DE DE8686100239T patent/DE3682783D1/de not_active Expired - Fee Related
- 1986-01-16 JP JP61005179A patent/JPS61210089A/ja active Granted
- 1986-01-16 CA CA000499696A patent/CA1265536A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0188235B1 (de) | 1991-12-11 |
JPH0471916B2 (de) | 1992-11-16 |
JPS61210089A (ja) | 1986-09-18 |
CA1265536A (en) | 1990-02-06 |
ATE70275T1 (de) | 1991-12-15 |
US4713380A (en) | 1987-12-15 |
EP0188235A2 (de) | 1986-07-23 |
EP0188235A3 (en) | 1988-06-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |