ATE70275T1 - Herstellung von optisch reinen organoboranen. - Google Patents

Herstellung von optisch reinen organoboranen.

Info

Publication number
ATE70275T1
ATE70275T1 AT86100239T AT86100239T ATE70275T1 AT E70275 T1 ATE70275 T1 AT E70275T1 AT 86100239 T AT86100239 T AT 86100239T AT 86100239 T AT86100239 T AT 86100239T AT E70275 T1 ATE70275 T1 AT E70275T1
Authority
AT
Austria
Prior art keywords
organoborane
alkene
organoboranes
preparation
optically pure
Prior art date
Application number
AT86100239T
Other languages
English (en)
Inventor
Herbert C Brown Ph D
Original Assignee
Aldrich Chem Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aldrich Chem Co Inc filed Critical Aldrich Chem Co Inc
Application granted granted Critical
Publication of ATE70275T1 publication Critical patent/ATE70275T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/06—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/22—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system
    • C07C35/23—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings
    • C07C35/28—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings the condensed ring system containing seven carbon atoms
    • C07C35/29—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings the condensed ring system containing seven carbon atoms being a (2.2.1) system
    • C07C35/30—Borneol; Isoborneol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT86100239T 1985-01-16 1986-01-10 Herstellung von optisch reinen organoboranen. ATE70275T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/692,046 US4713380A (en) 1985-01-16 1985-01-16 Production of optically pure organoboranes
EP86100239A EP0188235B1 (de) 1985-01-16 1986-01-10 Herstellung von optisch reinen Organoboranen

Publications (1)

Publication Number Publication Date
ATE70275T1 true ATE70275T1 (de) 1991-12-15

Family

ID=24779045

Family Applications (1)

Application Number Title Priority Date Filing Date
AT86100239T ATE70275T1 (de) 1985-01-16 1986-01-10 Herstellung von optisch reinen organoboranen.

Country Status (6)

Country Link
US (1) US4713380A (de)
EP (1) EP0188235B1 (de)
JP (1) JPS61210089A (de)
AT (1) ATE70275T1 (de)
CA (1) CA1265536A (de)
DE (1) DE3682783D1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5043479A (en) * 1986-08-29 1991-08-27 Aldrich Chemical Company, Inc. Chemically and optically pure diisopinocampheylhaloboranes
US4906755A (en) * 1986-11-03 1990-03-06 Merrell Dow Pharmaceuticals Inc. Esters of hexahydro-8-hydroxy-2,6-methano-2H-quinolizin-3-(4H)-one and related compounds
DE3842554A1 (de) * 1988-12-17 1990-06-21 Bayer Ag Chirale verbindungen vom ss-binaphthyltyp, deren herstellung und deren verwendung
US4978794A (en) * 1990-03-26 1990-12-18 Aldrich Chemical Company, Inc. Novel β-(2-alkenyl)bis(2-isocaranyl)boranes
US5103063A (en) * 1990-08-03 1992-04-07 Aldrich Chemical Company, Inc. Intermediates useful for the chiral isoprenylation of aldehydes
US5220072A (en) * 1991-07-15 1993-06-15 Aldrich Chemical Co., Inc. Process of synthesizing chemically and optically pure B-halodiiso-2-ethylapopinocampheylboranes
KR101451979B1 (ko) * 2005-05-25 2014-10-21 메르크 파텐트 게엠베하 테트라하이드로피란-3-온으로부터 테트라하이드로피란의제조 방법
WO2014121008A1 (en) * 2013-01-31 2014-08-07 Promerus, Llc Norbornenylhydrocarbylene dihydrocarbylboranes and methods of making the same
CN113024588A (zh) * 2021-03-22 2021-06-25 成都诺和晟泰生物科技有限公司 一种手性N-Boc-吡咯烷-3-硼酸类化合物的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3254129A (en) * 1961-01-17 1966-05-31 Herbert C Brown Optically active organoboranes
US3337643A (en) * 1963-10-17 1967-08-22 Colgate Palmolive Co Process for preparing optically active menthol
US3358034A (en) * 1964-03-12 1967-12-12 Herbert C Brown Selective hydroboration process
US4082810A (en) * 1971-02-09 1978-04-04 Aldrich-Boranes, Inc. Bulky trialkylborohydrides

Also Published As

Publication number Publication date
US4713380A (en) 1987-12-15
JPS61210089A (ja) 1986-09-18
EP0188235A2 (de) 1986-07-23
DE3682783D1 (de) 1992-01-23
CA1265536A (en) 1990-02-06
EP0188235B1 (de) 1991-12-11
EP0188235A3 (en) 1988-06-01
JPH0471916B2 (de) 1992-11-16

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Legal Events

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UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee