DE3469178D1 - Rhodium-phosphine complexes - Google Patents
Rhodium-phosphine complexesInfo
- Publication number
- DE3469178D1 DE3469178D1 DE8484306292T DE3469178T DE3469178D1 DE 3469178 D1 DE3469178 D1 DE 3469178D1 DE 8484306292 T DE8484306292 T DE 8484306292T DE 3469178 T DE3469178 T DE 3469178T DE 3469178 D1 DE3469178 D1 DE 3469178D1
- Authority
- DE
- Germany
- Prior art keywords
- rhodium
- phosphine complexes
- phosphine
- complexes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WJIBZZVTNMAURL-UHFFFAOYSA-N phosphane;rhodium Chemical class P.[Rh] WJIBZZVTNMAURL-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
- B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/52—Antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58169283A JPS6061587A (ja) | 1983-09-16 | 1983-09-16 | ロジウム−ホスフイン錯体 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3469178D1 true DE3469178D1 (en) | 1988-03-10 |
Family
ID=15883639
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8484306292T Expired DE3469178D1 (en) | 1983-09-16 | 1984-09-14 | Rhodium-phosphine complexes |
Country Status (4)
Country | Link |
---|---|
US (1) | US4605750A (de) |
EP (1) | EP0135392B1 (de) |
JP (1) | JPS6061587A (de) |
DE (1) | DE3469178D1 (de) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60199898A (ja) * | 1984-03-22 | 1985-10-09 | Takasago Corp | ロジウム−ホスフイン錯体 |
JPS6127949A (ja) * | 1984-07-17 | 1986-02-07 | Takasago Corp | 光学活性なエナミンの製造法 |
JPS62178594A (ja) * | 1986-02-01 | 1987-08-05 | Takasago Corp | 新規ホスフイン化合物 |
ATE82745T1 (de) * | 1986-08-21 | 1992-12-15 | Hoffmann La Roche | Verfahren zur herstellung von optisch aktiven enaminen oder von den entsprechenden aldehyden. |
JPS63135397A (ja) * | 1986-11-27 | 1988-06-07 | Takasago Corp | ルテニウム−ホスフイン錯体 |
JPS63145292A (ja) * | 1986-12-09 | 1988-06-17 | Takasago Corp | ルテニウム−ホスフイン錯体 |
US4870208A (en) * | 1988-06-03 | 1989-09-26 | Monsanto Company | Asymmetric hydrogenolysis of epoxides |
JPH0692427B2 (ja) * | 1989-07-11 | 1994-11-16 | 高砂香料工業株式会社 | 2,2’―ビス(ジシクロヘキシルホスフィノ)―6,6’―ジメチル―1,1’―ビフェニルを配位子とする錯体,およびその錯体を用いた有機カルボン酸とそのエステルの製造方法 |
JPH0768260B2 (ja) * | 1990-03-01 | 1995-07-26 | 高砂香料工業株式会社 | 2,2’―ビス〔ジ―(3,5―ジアルキルフェニル)ホスフィノ〕―1,1’―ビナフチル及びこれを配位子とする遷移金属錯体 |
FR2666250A1 (fr) * | 1990-09-05 | 1992-03-06 | Rhone Poulenc Nutrition Animal | Nouveaux catalyseurs, procede de preparation et leur utilisation. |
JP2681057B2 (ja) * | 1990-10-01 | 1997-11-19 | 高砂香料工業株式会社 | 2,2’―ビス(ジフェニルホスフィノ)―5,5’,6,6’,7,7’,8,8’―オクタヒドロ―1,1’―ビナフチル及びこれを配位子とする遷移金属錯体 |
JP2733880B2 (ja) * | 1991-03-12 | 1998-03-30 | 高砂香料工業株式会社 | 光学活性三級ホスフィン化合物およびこれを配位子とする遷移金属錯体 |
US5191095A (en) * | 1991-06-17 | 1993-03-02 | Ethyl Corporation | Asymmetric hydrogenation of olefinic amides using organoruthenium catalyst |
US5187136A (en) * | 1991-06-17 | 1993-02-16 | Ethyl Corporation | Asymmetric hydrogenation of aromatic-substituted olefins using organorhenium catalyst |
US5202472A (en) * | 1991-06-17 | 1993-04-13 | Ethyl Corporation | Asymmetric hydrogenation of aromatic-substituted olefins using organonickel catalyst |
US5177231A (en) * | 1991-06-17 | 1993-01-05 | Ethyl Corporation | Asymmetric hydrogenation of aromatic-substituted olefins using cationic ruthenium(III) complexes |
US5190905A (en) * | 1991-06-17 | 1993-03-02 | Ethyl Corporation | Asymmetric hydrogenation of aromatic-substituted olefins using metal or metal alloy catalysts |
US5187281A (en) * | 1991-06-17 | 1993-02-16 | Ethyl Corporation | Asymmetric hydrogenation of aromatic-substituted olefins using organoiridium catalyst |
US5198576A (en) * | 1991-08-26 | 1993-03-30 | Ethyl Corporation | Bicyclooctyl phosphines and catalysts thereof |
US5736480A (en) * | 1994-02-22 | 1998-04-07 | California Institute Of Technology | Supported phase chiral sulfonated BINAP catalyst solubilized in alcohol and method of asymmetric hydrogenation |
US5935892A (en) * | 1994-02-22 | 1999-08-10 | California Institute Of Technology | Supported phase catalyst |
US6333435B1 (en) * | 1995-05-18 | 2001-12-25 | Merck & Co., Inc. | Process of synthesizing binaphthyl derivatives |
DE69913412T2 (de) * | 1998-04-07 | 2004-09-16 | Firmenich S.A. | Stereospezifische Isomerisierung von Allylaminen unter Verwendung von Chiralen Phospho-Liganden |
US6307087B1 (en) | 1998-07-10 | 2001-10-23 | Massachusetts Institute Of Technology | Ligands for metals and improved metal-catalyzed processes based thereon |
US7223879B2 (en) | 1998-07-10 | 2007-05-29 | Massachusetts Institute Of Technology | Ligands for metals and improved metal-catalyzed processes based thereon |
JP4275795B2 (ja) | 1999-03-30 | 2009-06-10 | 高砂香料工業株式会社 | ビニル基を有するホスフィン誘導体、それをモノマーとするポリマー及びそれらの遷移金属錯体 |
ATE297807T1 (de) * | 1999-06-17 | 2005-07-15 | Firmenich & Cie | Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden |
DE10002976A1 (de) | 2000-01-24 | 2001-07-26 | Degussa | Molekulargewichtsvergrößerte Liganden für asymmetrische homogen lösliche Hydrierkatalysatoren, Verfahren zu deren Herstellung und Verwendung |
CN102665908A (zh) * | 2009-09-28 | 2012-09-12 | 艾伯塔大学董事会 | 非均相铑金属催化剂 |
FR2952638A1 (fr) | 2009-11-17 | 2011-05-20 | Univ Strasbourg | Procede de phosphination catalytique double ou triple de composes di, tri ou tetrahalobiaryles, intermediaires employes, composes obtenus et leurs utilisations |
JP6054108B2 (ja) | 2012-09-07 | 2016-12-27 | 高砂香料工業株式会社 | 光学活性2,3−ジヒドロファルネサールの製造方法 |
CN103254047B (zh) * | 2013-05-29 | 2015-02-04 | 上海灏翔生物科技有限公司 | 制备L-薄荷醇中间体d-香茅醛的方法 |
CN111187326B (zh) * | 2020-01-14 | 2022-04-19 | 上海灏翔生物科技有限公司 | 一种醋酸诺美孕酮的制备方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2116905A5 (fr) * | 1970-12-10 | 1972-07-21 | Inst Francais Du Petrole | Nouveaux coordinats bidentes,leur fabrication et leurs applications |
US3939188A (en) * | 1972-03-24 | 1976-02-17 | Exxon Research And Engineering Company | Preparation of zerovalent phosphine substituted rhodium compounds and their use in the selective carbonylation of olefins |
FR2230654B1 (de) * | 1973-05-21 | 1975-11-21 | Rhone Poulenc Ind | |
US4008281A (en) * | 1973-12-03 | 1977-02-15 | Monsanto Company | Asymmetric catalysis |
US4152344A (en) * | 1977-08-08 | 1979-05-01 | Celanese Corporation | Phosphino-ferrocene ligands |
US4201714A (en) * | 1977-08-19 | 1980-05-06 | Celanese Corporation | Stabilized catalyst complex of rhodium metal, bidentate ligand and monodentate ligand |
US4374278A (en) * | 1980-02-28 | 1983-02-15 | Union Carbide Corporation | Hydroformylation catalyst reactivation |
US4331818A (en) * | 1980-03-19 | 1982-05-25 | The Procter & Gamble Company | Chiral phospine ligand |
US4393240A (en) * | 1981-07-06 | 1983-07-12 | Stille John K | Optically active phosphines |
-
1983
- 1983-09-16 JP JP58169283A patent/JPS6061587A/ja active Granted
-
1984
- 1984-09-14 EP EP84306292A patent/EP0135392B1/de not_active Expired
- 1984-09-14 DE DE8484306292T patent/DE3469178D1/de not_active Expired
- 1984-09-17 US US06/651,123 patent/US4605750A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0135392B1 (de) | 1988-02-03 |
EP0135392A3 (en) | 1985-06-12 |
JPS6061587A (ja) | 1985-04-09 |
EP0135392A2 (de) | 1985-03-27 |
JPH0145478B2 (de) | 1989-10-03 |
US4605750A (en) | 1986-08-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |