DE3135522A1 - Verfahren zur herstellung von polymeren und copolymeren aethylenisch ungesaettigter monomerer - Google Patents
Verfahren zur herstellung von polymeren und copolymeren aethylenisch ungesaettigter monomererInfo
- Publication number
- DE3135522A1 DE3135522A1 DE19813135522 DE3135522A DE3135522A1 DE 3135522 A1 DE3135522 A1 DE 3135522A1 DE 19813135522 DE19813135522 DE 19813135522 DE 3135522 A DE3135522 A DE 3135522A DE 3135522 A1 DE3135522 A1 DE 3135522A1
- Authority
- DE
- Germany
- Prior art keywords
- polymerization
- unsaturated monomers
- copolymers
- vinyl chloride
- tert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000178 monomer Substances 0.000 title claims description 14
- 229920000642 polymer Polymers 0.000 title claims description 6
- 229920001577 copolymer Polymers 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- 239000003999 initiator Substances 0.000 claims description 15
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 7
- 238000012662 bulk polymerization Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920003091 Methocel™ Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- WPPLKRDOKPISSC-UHFFFAOYSA-N pentyl 2,2-dimethylpropaneperoxoate Chemical group CCCCCOOC(=O)C(C)(C)C WPPLKRDOKPISSC-UHFFFAOYSA-N 0.000 description 2
- -1 peroxy compound Chemical class 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- ZRZHXNCATOYMJH-UHFFFAOYSA-N 1-(chloromethyl)-4-ethenylbenzene Chemical compound ClCC1=CC=C(C=C)C=C1 ZRZHXNCATOYMJH-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 101100045694 Caenorhabditis elegans art-1 gene Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21405680A | 1980-12-08 | 1980-12-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3135522A1 true DE3135522A1 (de) | 1982-07-01 |
Family
ID=22797605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19813135522 Withdrawn DE3135522A1 (de) | 1980-12-08 | 1981-09-08 | Verfahren zur herstellung von polymeren und copolymeren aethylenisch ungesaettigter monomerer |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS57100102A (enrdf_load_stackoverflow) |
| AT (1) | AT370117B (enrdf_load_stackoverflow) |
| BE (1) | BE890018A (enrdf_load_stackoverflow) |
| BR (1) | BR8106050A (enrdf_load_stackoverflow) |
| DE (1) | DE3135522A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2495622A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2089353B (enrdf_load_stackoverflow) |
| IT (1) | IT1140257B (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5082910A (en) * | 1989-09-01 | 1992-01-21 | Isp Investments Inc. | Polymerization process using tertiary-amylperoxy pivalate as the free radical initiator |
| US7078457B2 (en) * | 2002-07-30 | 2006-07-18 | Rohm And Haas Company | Polymer composition and process for the preparation thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1558957A (enrdf_load_stackoverflow) * | 1966-12-05 | 1969-03-07 | ||
| US4063013A (en) * | 1973-02-20 | 1977-12-13 | Argus Chemical Corporation | T-Alkyl peresters of t-hydroperoxides catalysts for polymerization of unsaturated monomers |
-
1981
- 1981-08-17 AT AT0360481A patent/AT370117B/de not_active IP Right Cessation
- 1981-08-19 BE BE0/205716A patent/BE890018A/fr not_active IP Right Cessation
- 1981-08-24 FR FR8116166A patent/FR2495622A1/fr active Granted
- 1981-09-08 DE DE19813135522 patent/DE3135522A1/de not_active Withdrawn
- 1981-09-22 BR BR8106050A patent/BR8106050A/pt unknown
- 1981-10-21 JP JP56167326A patent/JPS57100102A/ja active Pending
- 1981-11-03 IT IT24833/81A patent/IT1140257B/it active
- 1981-11-17 GB GB8134611A patent/GB2089353B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2495622B1 (enrdf_load_stackoverflow) | 1985-05-03 |
| ATA360481A (de) | 1982-07-15 |
| FR2495622A1 (fr) | 1982-06-11 |
| BE890018A (fr) | 1981-12-16 |
| JPS57100102A (en) | 1982-06-22 |
| GB2089353A (en) | 1982-06-23 |
| AT370117B (de) | 1983-03-10 |
| GB2089353B (en) | 1984-11-14 |
| BR8106050A (pt) | 1982-09-08 |
| IT8124833A0 (it) | 1981-11-03 |
| IT1140257B (it) | 1986-09-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1954528A1 (de) | Verfahren zur Herstellung von perlfoermigen Polymeren | |
| DE1520310B2 (de) | Verfahren zur Herstellung einer Pfropfpolymerisatmasse | |
| US2911398A (en) | Polymer hydroperoxides | |
| DE2461083C2 (enrdf_load_stackoverflow) | ||
| DE2153886B2 (de) | Verfahren zur Herstellung von Vinylchloridpolymeren mit verbesserten Eigenschaften | |
| DD144782A5 (de) | Verfahren zur herstellung von n-vinylamid-polymeren | |
| DE2521766C2 (de) | Mischpolymere und Verfahren zu deren Herstellung | |
| DE3803036A1 (de) | Verfahren zur herstellung eines elastomerhaltigen vinylchloridpfropfcopolymerisats | |
| DE1292858B (de) | Verfahren zur Herstellung von linearen Peroxydgruppen enthaltenden Copolymeren | |
| DE3135522A1 (de) | Verfahren zur herstellung von polymeren und copolymeren aethylenisch ungesaettigter monomerer | |
| EP0052632B1 (en) | Process for preparing spherical and porous vinyl resin particles | |
| EP0016461A1 (de) | Verfahren zur Polymerisation von Vinylchlorid nach dem Mikrosuspensionsverfahren | |
| DE3323531C2 (enrdf_load_stackoverflow) | ||
| EP0534237B1 (de) | Ethylenhomopolymerisate und -copolymerisate sowie ein Verfahren zu ihrer Herstellung | |
| DE69512230T2 (de) | Verwendung von peroxysäure als kettenübertragungsmittel | |
| EP0222983B1 (de) | Verfahren zur Herstellung von Vinylchlorid-Polymeren | |
| DE3048033A1 (de) | Verfahren zur herstellung von polymeren und copolymeren aethylenisch ungesaettigter monomerer | |
| DE2807180C2 (enrdf_load_stackoverflow) | ||
| DE3505238A1 (de) | Verfahren zur herstellung von trockenen vinylchlorid-suspensionspolymerisaten | |
| EP0419951B1 (de) | Verfahren für die Festphasenpolymerisation von Acrylnitril aus der Gasphase | |
| DE2252340A1 (de) | Polyvinylchlorid von hoher schuettdichte, verfahren zu dessen herstellung und polymerisationsreaktor zur durchfuehrung des verfahrens | |
| DE2543144A1 (de) | Verfahren zur regelung der freiradikalischen blockpolymerisation von vinylchloridmonomeren | |
| DE2342560C3 (de) | Verfahren zum Polymerisieren von äthylenisch-ungesättigten Verbindungen | |
| DE3048079A1 (de) | Verfahren zur herstellung von polymeren und mischpolymeren aus vinylchlorid | |
| DE1795081C3 (de) | Verfahren zur Herstellung von Fluorolefinpolymerisaten |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |