DE3123090A1 - "feuerhemmende mischung und harzartige zubereitungen, welche diese mischung enthalten" - Google Patents
"feuerhemmende mischung und harzartige zubereitungen, welche diese mischung enthalten"Info
- Publication number
- DE3123090A1 DE3123090A1 DE19813123090 DE3123090A DE3123090A1 DE 3123090 A1 DE3123090 A1 DE 3123090A1 DE 19813123090 DE19813123090 DE 19813123090 DE 3123090 A DE3123090 A DE 3123090A DE 3123090 A1 DE3123090 A1 DE 3123090A1
- Authority
- DE
- Germany
- Prior art keywords
- phosphate
- fire
- resin
- mixture
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000203 mixture Substances 0.000 title claims description 57
- 238000002360 preparation method Methods 0.000 title claims description 33
- 230000009970 fire resistant effect Effects 0.000 title 1
- -1 aromatic Phosphates Chemical class 0.000 claims description 32
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
- 229910019142 PO4 Inorganic materials 0.000 claims description 26
- 235000021317 phosphate Nutrition 0.000 claims description 26
- 239000003063 flame retardant Substances 0.000 claims description 23
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 16
- 239000010452 phosphate Substances 0.000 claims description 16
- 229920001955 polyphenylene ether Polymers 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000004793 Polystyrene Substances 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 229920002223 polystyrene Polymers 0.000 claims description 10
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 9
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 8
- 239000012260 resinous material Substances 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 150000002989 phenols Chemical class 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 239000005060 rubber Substances 0.000 claims description 5
- 150000001555 benzenes Chemical class 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 claims description 4
- SZQAOGPCUGHBPG-UHFFFAOYSA-N (2,4,6-trimethylphenyl) dihydrogen phosphate Chemical compound CC1=CC(C)=C(OP(O)(O)=O)C(C)=C1 SZQAOGPCUGHBPG-UHFFFAOYSA-N 0.000 claims description 3
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 125000006267 biphenyl group Chemical group 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- 229920001890 Novodur Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000008033 biological extinction Effects 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 3
- GLOQRSIADGSLRX-UHFFFAOYSA-N decyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCC)OC1=CC=CC=C1 GLOQRSIADGSLRX-UHFFFAOYSA-N 0.000 description 3
- 238000007706 flame test Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- QQOMQLYQAXGHSU-UHFFFAOYSA-N 2,3,6-Trimethylphenol Chemical compound CC1=CC=C(C)C(O)=C1C QQOMQLYQAXGHSU-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- TZNDMQPVWYWNFW-UHFFFAOYSA-N diphenyl (2,4,6-trimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC(C)=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 TZNDMQPVWYWNFW-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- UETPRJJVZPVPQI-UHFFFAOYSA-N (2-propan-2-ylphenyl) dihydrogen phosphate Chemical compound CC(C)C1=CC=CC=C1OP(O)(O)=O UETPRJJVZPVPQI-UHFFFAOYSA-N 0.000 description 1
- BPRYUXCVCCNUFE-UHFFFAOYSA-N 2,4,6-trimethylphenol Chemical compound CC1=CC(C)=C(O)C(C)=C1 BPRYUXCVCCNUFE-UHFFFAOYSA-N 0.000 description 1
- 150000000345 2,6-xylenols Chemical class 0.000 description 1
- JEEZCYGSODRZFG-UHFFFAOYSA-N CC(C=C1C)=CC(C)=C1C(C=C1)=C(C)C(C)=C1OP(O)(O)=O Chemical class CC(C=C1C)=CC(C)=C1C(C=C1)=C(C)C(C)=C1OP(O)(O)=O JEEZCYGSODRZFG-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical class COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WRXFONORSZHETC-UHFFFAOYSA-N phenyl propan-2-yl hydrogen phosphate Chemical compound CC(C)OP(O)(=O)OC1=CC=CC=C1 WRXFONORSZHETC-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16163780A | 1980-06-20 | 1980-06-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3123090A1 true DE3123090A1 (de) | 1982-03-25 |
Family
ID=22582059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19813123090 Ceased DE3123090A1 (de) | 1980-06-20 | 1981-06-11 | "feuerhemmende mischung und harzartige zubereitungen, welche diese mischung enthalten" |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5730737A (enrdf_load_stackoverflow) |
| AU (1) | AU7195281A (enrdf_load_stackoverflow) |
| BR (1) | BR8103133A (enrdf_load_stackoverflow) |
| DE (1) | DE3123090A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2485027A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2078226B (enrdf_load_stackoverflow) |
| NL (1) | NL8102963A (enrdf_load_stackoverflow) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4446265A (en) * | 1982-02-01 | 1984-05-01 | Fmc Corporation | Flame retardant polyphenylene ether-styrene thermoplastic resin compositions |
| US4446062A (en) * | 1982-02-16 | 1984-05-01 | Fmc Corporation | Mixed phenyl/mesityl phosphate ester composition |
| US4511498A (en) * | 1982-02-16 | 1985-04-16 | Fmc Corporation | Mixed phenyl/mesityl phosphate ester composition |
| DE3367237D1 (en) * | 1982-03-26 | 1986-12-04 | Gen Electric | Thermal oxidation stabilizer composed of phosphite derivatives of an alcohol and ppe monomer still bottoms, and ppe compositions containing said phosphites |
| US5695850A (en) * | 1993-01-29 | 1997-12-09 | Crow; William R. | Performance enhancing athletic shoe components and methods |
| US6589630B1 (en) | 1995-03-23 | 2003-07-08 | William R. Crow | Performance enhancing shoe components and methods |
| US6120880A (en) * | 1995-03-23 | 2000-09-19 | Crow; William R. | Performance enhancing athletic shoe components and methods |
| WO2001074937A1 (en) * | 2000-03-30 | 2001-10-11 | General Electric Company | Transparent, flame retardant poly(arylene ether) blends |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2126850A (en) * | 1934-07-26 | 1938-08-16 | Celanese Corp | Conductor and filaments therefor containing organic derivative of cellulose |
| GB1218097A (en) * | 1967-05-16 | 1971-01-06 | Koppers Co Inc | Improvements in or relating to liquid triphenolic phosphate esters |
| US3639506A (en) * | 1969-05-21 | 1972-02-01 | Gen Electric | Flame retardant composition of polyphenylene ether styrene resin aromatic phosphate and aromatic halogen compound |
| US3773864A (en) * | 1970-12-16 | 1973-11-20 | Monsanto Co | Triaryl phosphates |
| DE2929099A1 (de) * | 1978-07-21 | 1980-01-31 | Ciba Geigy Ag | Triarylphosphate |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2756458A1 (de) * | 1976-12-21 | 1978-06-22 | Gen Electric | Tropfverzoegerte, plastizierte thermoplastische zusammensetzung |
| GB1413475A (en) * | 1971-11-05 | 1975-11-12 | Burmah Oil Trading Ltd | Production of cyclic esters lactones |
| DE2708447A1 (de) * | 1976-03-06 | 1977-09-08 | Ciba Geigy Ag | Flammhemmende polymerzusammensetzungen |
| JPS53137239A (en) * | 1977-04-30 | 1978-11-30 | Ciba Geigy Ag | Polymer composition |
| US4233199A (en) * | 1979-07-03 | 1980-11-11 | Visvaldis Abolins | Flame resistant thermoplastic compositions with well balanced physical properties |
-
1981
- 1981-02-20 GB GB8105509A patent/GB2078226B/en not_active Expired
- 1981-05-20 BR BR8103133A patent/BR8103133A/pt unknown
- 1981-06-11 DE DE19813123090 patent/DE3123090A1/de not_active Ceased
- 1981-06-17 FR FR8111923A patent/FR2485027A1/fr active Granted
- 1981-06-18 AU AU71952/81A patent/AU7195281A/en not_active Abandoned
- 1981-06-19 JP JP9406881A patent/JPS5730737A/ja active Pending
- 1981-06-19 NL NL8102963A patent/NL8102963A/nl not_active Application Discontinuation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2126850A (en) * | 1934-07-26 | 1938-08-16 | Celanese Corp | Conductor and filaments therefor containing organic derivative of cellulose |
| GB1218097A (en) * | 1967-05-16 | 1971-01-06 | Koppers Co Inc | Improvements in or relating to liquid triphenolic phosphate esters |
| US3639506A (en) * | 1969-05-21 | 1972-02-01 | Gen Electric | Flame retardant composition of polyphenylene ether styrene resin aromatic phosphate and aromatic halogen compound |
| US3773864A (en) * | 1970-12-16 | 1973-11-20 | Monsanto Co | Triaryl phosphates |
| DE2929099A1 (de) * | 1978-07-21 | 1980-01-31 | Ciba Geigy Ag | Triarylphosphate |
Also Published As
| Publication number | Publication date |
|---|---|
| BR8103133A (pt) | 1982-02-09 |
| FR2485027B1 (enrdf_load_stackoverflow) | 1985-05-10 |
| NL8102963A (nl) | 1982-01-18 |
| AU7195281A (en) | 1981-12-24 |
| JPS5730737A (en) | 1982-02-19 |
| FR2485027A1 (fr) | 1981-12-24 |
| GB2078226B (en) | 1984-03-07 |
| GB2078226A (en) | 1982-01-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8131 | Rejection |