DE3029958A1 - Verfahren zur herstellung eines photochromen, silberhalogenidhaltigen glases - Google Patents
Verfahren zur herstellung eines photochromen, silberhalogenidhaltigen glasesInfo
- Publication number
- DE3029958A1 DE3029958A1 DE19803029958 DE3029958A DE3029958A1 DE 3029958 A1 DE3029958 A1 DE 3029958A1 DE 19803029958 DE19803029958 DE 19803029958 DE 3029958 A DE3029958 A DE 3029958A DE 3029958 A1 DE3029958 A1 DE 3029958A1
- Authority
- DE
- Germany
- Prior art keywords
- glass
- photochromic
- tin
- components
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011521 glass Substances 0.000 title claims description 179
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 56
- 238000000034 method Methods 0.000 claims description 38
- 229910052709 silver Inorganic materials 0.000 claims description 36
- 150000003606 tin compounds Chemical class 0.000 claims description 36
- 239000004332 silver Substances 0.000 claims description 35
- 238000010438 heat treatment Methods 0.000 claims description 30
- 238000002360 preparation method Methods 0.000 claims description 30
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 20
- -1 silver halide Chemical class 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 15
- 238000013459 approach Methods 0.000 claims description 13
- 238000007496 glass forming Methods 0.000 claims description 11
- 239000006060 molten glass Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 8
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims description 8
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 7
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- 239000005365 phosphate glass Substances 0.000 claims description 4
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 238000011282 treatment Methods 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 235000016337 monopotassium tartrate Nutrition 0.000 claims description 2
- KYKNRZGSIGMXFH-ZVGUSBNCSA-M potassium bitartrate Chemical compound [K+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O KYKNRZGSIGMXFH-ZVGUSBNCSA-M 0.000 claims description 2
- 229940086065 potassium hydrogentartrate Drugs 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims 1
- 230000003287 optical effect Effects 0.000 description 11
- 238000002844 melting Methods 0.000 description 10
- 230000008018 melting Effects 0.000 description 10
- 230000008859 change Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- OFQCQIGMURIECL-UHFFFAOYSA-N 2-[2-(diethylamino)ethyl]-2',6'-dimethylspiro[isoquinoline-4,4'-oxane]-1,3-dione;phosphoric acid Chemical compound OP(O)(O)=O.O=C1N(CCN(CC)CC)C(=O)C2=CC=CC=C2C21CC(C)OC(C)C2 OFQCQIGMURIECL-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 239000006121 base glass Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000010979 ruby Substances 0.000 description 2
- 229910001750 ruby Inorganic materials 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 101100189378 Caenorhabditis elegans pat-3 gene Proteins 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000006066 glass batch Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
- C03C4/06—Compositions for glass with special properties for photosensitive glass for phototropic or photochromic glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B1/00—Preparing the batches
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7927751 | 1979-08-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3029958A1 true DE3029958A1 (de) | 1981-03-26 |
Family
ID=10507085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803029958 Withdrawn DE3029958A1 (de) | 1979-08-09 | 1980-08-07 | Verfahren zur herstellung eines photochromen, silberhalogenidhaltigen glases |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4349634A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS5632348A (cg-RX-API-DMAC10.html) |
| KR (1) | KR840001395B1 (cg-RX-API-DMAC10.html) |
| AR (1) | AR231961A1 (cg-RX-API-DMAC10.html) |
| BR (1) | BR8004828A (cg-RX-API-DMAC10.html) |
| DE (1) | DE3029958A1 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2463102A1 (cg-RX-API-DMAC10.html) |
| HK (1) | HK13784A (cg-RX-API-DMAC10.html) |
| IT (1) | IT1132373B (cg-RX-API-DMAC10.html) |
| MY (1) | MY8500013A (cg-RX-API-DMAC10.html) |
| PH (1) | PH16693A (cg-RX-API-DMAC10.html) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3020357A1 (de) * | 1980-05-29 | 1981-12-03 | Jenaer Glaswerk Schott & Gen., 6500 Mainz | Verfahren zur verstaerkung des phototropen effekts in phototropen glaesern |
| DE3220367A1 (de) * | 1982-05-29 | 1983-12-01 | Schott Glaswerke, 6500 Mainz | Phototropes glas mit brauntoenung im belichteten zustand |
| US4576920A (en) * | 1985-05-23 | 1986-03-18 | Corning Glass Works | B2 O3 --P2 O5 --SiO2 glass-ceramics |
| CN117447079A (zh) * | 2023-10-23 | 2024-01-26 | 天津包钢稀土研究院有限责任公司 | 利用包钢含铁尘泥制备变色吸热玻璃 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3022181A (en) * | 1961-02-01 | 1962-02-20 | Corning Glass Works | Glass color filter |
| NL272816A (cg-RX-API-DMAC10.html) * | 1961-12-27 | |||
| NL125550C (cg-RX-API-DMAC10.html) * | 1963-05-06 | |||
| FR2085970A1 (en) | 1970-04-10 | 1971-12-31 | Jenaer Glaswerk Schott & Gen | Photochromatic colour glass with borosili-ca |
| GB1367903A (en) | 1971-07-12 | 1974-09-25 | Pilkington Brothers Ltd | Photochromic glasses |
| US3892582A (en) * | 1974-02-01 | 1975-07-01 | Robert A Simms | Process for changing the tint of a photochromic material and material formed thereby |
| US3920463A (en) * | 1974-02-01 | 1975-11-18 | Robert A Simms | Process for changing the tint of a photochromic material and material formed thereby |
| US4043781A (en) * | 1974-11-04 | 1977-08-23 | Corning Glass Works | Method for making a brown photochromic glass |
| FR2289458A1 (fr) * | 1975-11-03 | 1976-05-28 | Corning Glass Works | Procede de fabrication de verre photochromique |
| US4017318A (en) * | 1976-01-02 | 1977-04-12 | Corning Glass Works | Photosensitive colored glasses |
| CA1092876A (en) * | 1976-01-30 | 1981-01-06 | Edric Ellis | Photochromic alumino-phosphate glass having dispersed silver halide crystals |
| GB1515642A (en) | 1976-01-30 | 1978-06-28 | Pilkington Brothers Ltd | Photochromic glasses |
| US4118214A (en) * | 1977-06-22 | 1978-10-03 | Corning Glass Works | Treating polychromatic glass in reducing atmospheres |
| US4166745A (en) * | 1977-12-16 | 1979-09-04 | Corning Glass Works | Refractive index-corrected copper-cadmium halide photochromic glasses |
-
1980
- 1980-07-31 BR BR8004828A patent/BR8004828A/pt unknown
- 1980-08-01 PH PH24384A patent/PH16693A/en unknown
- 1980-08-01 FR FR8017045A patent/FR2463102A1/fr active Granted
- 1980-08-07 DE DE19803029958 patent/DE3029958A1/de not_active Withdrawn
- 1980-08-08 JP JP10839980A patent/JPS5632348A/ja active Pending
- 1980-08-08 IT IT24081/80A patent/IT1132373B/it active
- 1980-08-08 AR AR282097A patent/AR231961A1/es active
- 1980-08-08 KR KR1019800003149A patent/KR840001395B1/ko not_active Expired
- 1980-08-11 US US06/176,838 patent/US4349634A/en not_active Expired - Lifetime
-
1984
- 1984-02-16 HK HK137/84A patent/HK13784A/xx not_active IP Right Cessation
-
1985
- 1985-12-30 MY MY13/85A patent/MY8500013A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MY8500013A (en) | 1985-12-31 |
| JPS5632348A (en) | 1981-04-01 |
| FR2463102B1 (cg-RX-API-DMAC10.html) | 1984-10-12 |
| AR231961A1 (es) | 1985-04-30 |
| US4349634A (en) | 1982-09-14 |
| PH16693A (en) | 1984-01-06 |
| BR8004828A (pt) | 1981-02-10 |
| HK13784A (en) | 1984-02-24 |
| IT8024081A0 (it) | 1980-08-08 |
| IT1132373B (it) | 1986-07-02 |
| KR840001395B1 (ko) | 1984-09-24 |
| KR830003378A (ko) | 1983-06-20 |
| FR2463102A1 (fr) | 1981-02-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8128 | New person/name/address of the agent |
Representative=s name: DANNENBERG, G., DIPL.-ING., 6000 FRANKFURT WEINHOL |
|
| 8141 | Disposal/no request for examination |