DE3029188C2 - Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen - Google Patents

Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen

Info

Publication number
DE3029188C2
DE3029188C2 DE3029188A DE3029188A DE3029188C2 DE 3029188 C2 DE3029188 C2 DE 3029188C2 DE 3029188 A DE3029188 A DE 3029188A DE 3029188 A DE3029188 A DE 3029188A DE 3029188 C2 DE3029188 C2 DE 3029188C2
Authority
DE
Germany
Prior art keywords
activated carbon
gas
cmvg
pore volume
adsorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE3029188A
Other languages
German (de)
English (en)
Other versions
DE3029188A1 (de
Inventor
Klaus-Dirk Ing.(Grad.) Henning
Harald Prof. Dipl.-Chem. Dr. 4300 Essen Jüntgen
Jürgen Dipl.-Phys. Dr. Klein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bergwerksverband GmbH
Original Assignee
Bergwerksverband GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6108647&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE3029188(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bergwerksverband GmbH filed Critical Bergwerksverband GmbH
Priority to DE3029188A priority Critical patent/DE3029188C2/de
Priority to EP81105649A priority patent/EP0045865B1/de
Priority to JP56119433A priority patent/JPS5757792A/ja
Priority to AU73608/81A priority patent/AU542194B2/en
Priority to ZA815314A priority patent/ZA815314B/xx
Publication of DE3029188A1 publication Critical patent/DE3029188A1/de
Application granted granted Critical
Publication of DE3029188C2 publication Critical patent/DE3029188C2/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • B01D53/12—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents according to the "fluidised technique"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
    • C01B17/0469—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide at least one catalyst bed operating below the dew-point of sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/402—Further details for adsorption processes and devices using two beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/404—Further details for adsorption processes and devices using four beds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Industrial Gases (AREA)
DE3029188A 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen Expired DE3029188C2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE3029188A DE3029188C2 (de) 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen
EP81105649A EP0045865B1 (de) 1980-08-01 1981-07-18 Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen
JP56119433A JPS5757792A (en) 1980-08-01 1981-07-31 Removal of hydrogen sulfide from gas mixture containing hydrocarbons
AU73608/81A AU542194B2 (en) 1980-08-01 1981-07-31 Removing hydrogen sulphide from gaseous hydrocarbons using active carbon
ZA815314A ZA815314B (en) 1980-08-01 1981-08-03 Process for the removal of hydrogen sulphide from gas mixtures containing hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3029188A DE3029188C2 (de) 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen

Publications (2)

Publication Number Publication Date
DE3029188A1 DE3029188A1 (de) 1982-04-01
DE3029188C2 true DE3029188C2 (de) 1986-04-24

Family

ID=6108647

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3029188A Expired DE3029188C2 (de) 1980-08-01 1980-08-01 Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen

Country Status (5)

Country Link
EP (1) EP0045865B1 (en:Method)
JP (1) JPS5757792A (en:Method)
AU (1) AU542194B2 (en:Method)
DE (1) DE3029188C2 (en:Method)
ZA (1) ZA815314B (en:Method)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2688215B1 (fr) * 1992-03-06 1994-06-03 Inst Francais Du Petrole Procede de purification d'un hydrocarbure ou d'une coupe d'hydrocarbures par adsorption selective des impuretes.
DE19722569A1 (de) 1997-05-28 1998-12-03 Basf Ag Statistische Propylencopolymerisate
WO1999041010A1 (fr) * 1998-02-17 1999-08-19 Kanebo, Limited Carbone active pour adsorption et stockage d'un compose gazeux
US6387159B1 (en) * 2000-06-26 2002-05-14 Engelhard Corporation Claus feed gas hydrocarbon removal
US7780846B2 (en) 2004-09-01 2010-08-24 Sud-Chemie Inc. Sulfur adsorbent, desulfurization system and method for desulfurizing
US8323603B2 (en) 2004-09-01 2012-12-04 Sud-Chemie Inc. Desulfurization system and method for desulfurizing a fuel stream
AR066573A1 (es) 2007-05-18 2009-08-26 Shell Int Research Un sistema reactor un absorbente y un proceso para la reaccion de una fuente
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
DE102007031680A1 (de) * 2007-07-06 2009-01-08 Thermo Fisher Scientific (Bremen) Gmbh Einrichtung zur Bereitstellung von Gasen, insbesondere für die Isotopenverhältnisanalyse
EP2285795B1 (en) 2008-05-15 2017-03-22 Shell Internationale Research Maatschappij B.V. Process for the preparation of alkylene carbonate and/or alkylene glycol
KR101633523B1 (ko) 2008-05-15 2016-06-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 알킬렌 카보네이트 및 알킬렌 글리콜의 제조방법
DE102010003880A1 (de) 2010-04-12 2011-10-13 Durtec Gmbh Mineralische Gasadsorber zur Beseitigung von Ozon aus Abluft/Abgas, Verfahren zu deren Herstellung und Regenerierung

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2771964A (en) * 1953-04-13 1956-11-27 Jefferson Lake Sulphur Co Method of recovering h2s from natural gas
DE1952346C3 (de) * 1969-10-17 1974-11-14 Metallgesellschaft Ag, 6000 Frankfurt Vorrichtung zur Abscheidung von Schwefelwasserstoff und Schwefelkohlenstoff aus Sauerstoff enthaltenden Gasen
DE2652099C2 (de) * 1976-11-16 1986-03-27 Bergwerksverband Gmbh, 4300 Essen Verfahren zum Abscheiden von Schwefelwasserstoff aus Gasgemischen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NICHTS-ERMITTELT

Also Published As

Publication number Publication date
AU7360881A (en) 1982-02-04
ZA815314B (en) 1982-08-25
JPS5757792A (en) 1982-04-07
JPH0218360B2 (en:Method) 1990-04-25
AU542194B2 (en) 1985-02-14
DE3029188A1 (de) 1982-04-01
EP0045865B1 (de) 1983-10-12
EP0045865A1 (de) 1982-02-17

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
D2 Grant after examination
8363 Opposition against the patent
8365 Fully valid after opposition proceedings
8339 Ceased/non-payment of the annual fee