DE2943494C2 - Verfahren zur Herstellung flüssiger Kohlenwasserstoffe aus Kohle - Google Patents
Verfahren zur Herstellung flüssiger Kohlenwasserstoffe aus KohleInfo
- Publication number
- DE2943494C2 DE2943494C2 DE2943494A DE2943494A DE2943494C2 DE 2943494 C2 DE2943494 C2 DE 2943494C2 DE 2943494 A DE2943494 A DE 2943494A DE 2943494 A DE2943494 A DE 2943494A DE 2943494 C2 DE2943494 C2 DE 2943494C2
- Authority
- DE
- Germany
- Prior art keywords
- coal
- hydrogenation
- oil
- process according
- condensates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003245 coal Substances 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 19
- 229930195733 hydrocarbon Natural products 0.000 title claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 7
- 239000007788 liquid Substances 0.000 title claims description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims description 45
- 239000003921 oil Substances 0.000 claims description 39
- 239000007789 gas Substances 0.000 claims description 34
- 239000000295 fuel oil Substances 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 239000003250 coal slurry Substances 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 15
- 239000003502 gasoline Substances 0.000 claims description 14
- 238000000227 grinding Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 238000005336 cracking Methods 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 150000003464 sulfur compounds Chemical class 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 239000012071 phase Substances 0.000 description 21
- 238000001816 cooling Methods 0.000 description 9
- 239000010802 sludge Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000003077 lignite Substances 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000004230 steam cracking Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/083—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts in the presence of a solvent
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2943494A DE2943494C2 (de) | 1979-10-27 | 1979-10-27 | Verfahren zur Herstellung flüssiger Kohlenwasserstoffe aus Kohle |
| DE8080106290T DE3069069D1 (en) | 1979-10-27 | 1980-10-16 | Process for the production of liquid hydrocarbons from coal |
| EP80106290A EP0027962B1 (de) | 1979-10-27 | 1980-10-16 | Verfahren zur Herstellung flüssiger Kohlenwasserstoffe aus Kohle |
| AU63636/80A AU538950B2 (en) | 1979-10-27 | 1980-10-23 | Production of liquid hydrocarbons from coal |
| ZA00806545A ZA806545B (en) | 1979-10-27 | 1980-10-24 | Process for the production of liquid hydrocarbons from coal |
| JP14826580A JPS5667392A (en) | 1979-10-27 | 1980-10-24 | Manufacture of liquid hydrocarbon from coal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2943494A DE2943494C2 (de) | 1979-10-27 | 1979-10-27 | Verfahren zur Herstellung flüssiger Kohlenwasserstoffe aus Kohle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2943494A1 DE2943494A1 (de) | 1981-05-07 |
| DE2943494C2 true DE2943494C2 (de) | 1987-04-16 |
Family
ID=6084545
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2943494A Expired DE2943494C2 (de) | 1979-10-27 | 1979-10-27 | Verfahren zur Herstellung flüssiger Kohlenwasserstoffe aus Kohle |
| DE8080106290T Expired DE3069069D1 (en) | 1979-10-27 | 1980-10-16 | Process for the production of liquid hydrocarbons from coal |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8080106290T Expired DE3069069D1 (en) | 1979-10-27 | 1980-10-16 | Process for the production of liquid hydrocarbons from coal |
Country Status (5)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3209143A1 (de) * | 1982-03-13 | 1983-09-22 | Veba Oel Entwicklungsgesellschaft mbH, 4660 Gelsenkirchen-Buer | Verfahren zur mehrstufigen hydrierung von kohle |
| US4472263A (en) * | 1982-07-19 | 1984-09-18 | Air Products And Chemicals, Inc. | Process for solvent refining of coal using a denitrogenated and dephenolated solvent |
| DE3311356C2 (de) * | 1983-03-29 | 1987-04-16 | GfK Gesellschaft für Kohleverflüssigung mbH, 6600 Saarbrücken | Verfahren zum Hydrieren von Kohle |
| US4569749A (en) * | 1984-08-20 | 1986-02-11 | Gulf Research & Development Company | Coal liquefaction process |
| DE3534565A1 (de) * | 1984-09-29 | 1986-04-03 | Nippon Kokan K.K., Tokio/Tokyo | Verfahren zum verfluessigen von kohle |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL29952C (US06589383-20030708-C00041.png) * | 1929-01-22 | |||
| DE2651253C2 (de) * | 1976-11-10 | 1984-03-08 | Saarbergwerke AG, 6600 Saarbrücken | Verfahren zum Hydrieren von Kohle |
| DE2936008A1 (de) * | 1979-09-06 | 1981-04-02 | Saarbergwerke AG, 6600 Saarbrücken | Verfahren zum hydrieren von kohle |
-
1979
- 1979-10-27 DE DE2943494A patent/DE2943494C2/de not_active Expired
-
1980
- 1980-10-16 EP EP80106290A patent/EP0027962B1/de not_active Expired
- 1980-10-16 DE DE8080106290T patent/DE3069069D1/de not_active Expired
- 1980-10-23 AU AU63636/80A patent/AU538950B2/en not_active Ceased
- 1980-10-24 ZA ZA00806545A patent/ZA806545B/xx unknown
- 1980-10-24 JP JP14826580A patent/JPS5667392A/ja active Pending
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA806545B (en) | 1981-11-25 |
| EP0027962A3 (en) | 1981-11-11 |
| EP0027962A2 (de) | 1981-05-06 |
| EP0027962B1 (de) | 1984-08-29 |
| DE2943494A1 (de) | 1981-05-07 |
| AU538950B2 (en) | 1984-09-06 |
| DE3069069D1 (en) | 1984-10-04 |
| JPS5667392A (en) | 1981-06-06 |
| AU6363680A (en) | 1981-04-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8127 | New person/name/address of the applicant |
Owner name: BASF AG, 6700 LUDWIGSHAFEN, DE |
|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8380 | Miscellaneous part iii |
Free format text: SALTE 2, ZEILE 59: HINTER "SUMPFPRODUKT" KOMMA STREICHEN SPALTE 6, ZEILEN 11 U. 12: CHEM. FORMEL "FE(PFEIL ABWAERTS)2(PFEIL ABWAERTS)O(PFEIL ABWAERTS)3(PFEIL ABWAERTS)" ZUSAMMEN SCHREIBEN SPALTE 6, ZEILE 14 "ESTEN" AENDERN IN "ERSTEN" SPALTE 6, ZEILE 59 "ANSTREIFER" AENDERN IN "ABSTREIFER" |
|
| 8364 | No opposition during term of opposition | ||
| 8330 | Complete renunciation |