DE277222T1 - Modifizierte succinimide. - Google Patents

Modifizierte succinimide.

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Publication number
DE277222T1
DE277222T1 DE198787905836T DE87905836T DE277222T1 DE 277222 T1 DE277222 T1 DE 277222T1 DE 198787905836 T DE198787905836 T DE 198787905836T DE 87905836 T DE87905836 T DE 87905836T DE 277222 T1 DE277222 T1 DE 277222T1
Authority
DE
Germany
Prior art keywords
alkenyl
alkyl
multiply adducted
group
multiply
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE198787905836T
Other languages
English (en)
Inventor
Frank Novato Ca 94947 Plavac
H. Robert San Rafael Ca 94903 Wollenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron Research Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Research Co filed Critical Chevron Research Co
Publication of DE277222T1 publication Critical patent/DE277222T1/de
Pending legal-status Critical Current

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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C07D207/408—Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
    • C07D207/412—Acyclic radicals containing more than six carbon atoms
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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Claims (25)

übersetzung der Patentansprüche
1. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid, wobei eines oder mehrere der Stickstoffatome des vielfach adduktierten Alkenyl- oder Alkylsuccinimids mit einem Hydroxyhydrocarbyloxycarbonyl substituiert ist (sind), und wobei die Hydroxyhydrocarbylgruppe des Hydroxyhydrocarbyloxycarbonyls 2 bis 20 Kohlenstoffatome und 1 bis 6 Hydroxygruppen enthält, unter der Voraussetzung, daß keine Hydroxysubstitution an dem Hydrocarbylatom vorliegt, welches die Hydroxyhydrocarbylgruppe mit dem Oxyatom oder Oxycarbonylgruppe ver·
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bindet, und unter der weiteren Voraussetzung, daß dann, wenn mehr als eine Hydroxygruppe in der Hydroxyhydrocarbylgruppe enthalten ist, nicht mehr als eine Hydroxygruppe mit dem gleichen Kohlenstoffatom verknüpft ist und die Anzahl der Kohlenstoffatome in der Hydroxyhydrocarbylgruppe minimal um 1 großer ist als die Zahl der Hydroxygruppen, und wobei das vielfach adduktierte Alkenyl- oder Alkylsuccinimid auf ein vielfach adduktiertes Alkenyl- oder Alkylbernsteinsäureanhydrid zurückgeht, gekennzeichnet durch das Vorliegen von durchschnittlich mehr als 1,3 Bexnsteinsäuregruppen pro Äquivalent Alkenyl- oder Alkylgruppe in seiner Struktur.
1^
2. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid gemäß Anspruch 1, wobei die Hydrocarbylgruppe des Hydroxyhydrocarbyloxycarbonyls 2 bis 20 Kohlenstoffatome enthält.
3. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid nach Anspruch 2, wobei die Hydroxyhydrocarbylgruppe des Hydroxyhydrocarbyloxycarbonyls 1 bis 6 Hydroxygruppen enthält.
4. vielfach adduktiertes Alkenyl- oder Alkylsuccinimid gemäß Anspruch 3, wobei die Hydroxyhydrocarbylgruppe des Hydroxyhydrocarbyloxycarbonyls aus 2-Hydroxyethylcarbamat besteht.
5. Vielfach adduktiertes Alkenyl- oder Alkysuccinimid, wobei eines oder mehrere der Stickstoffe des vielfach adduktierten Alkenyl- oder Alkylsuccinimids mit Hydrocarbyloxycarbonyl substituiert ist (sind) und wobei das
vielfach adduktierte Alkenyl- oder Alkylsuccinimid auf ein vielfach adduktiertes Alkenyl- oder Alkylbernsteinsäureanhydrid zurückgeht, gekennzeichnet durch das Vorliegen von durchschnittlich mehr als 1,3 Bernsteinsäuregruppen pro Äquivalent Alkenyl- oder Alkylgruppe in seiner Struktur.
6. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid gemäß Anspruch 5, wobei die Hydrocarbylgruppe des Hydrocarbyloxycarbonyls 1 bis 20 Kohlenstoffatome enthalt.
7. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid, wobei eines oder mehrere der Stickstoffe des vielfach
1^ adduktierten Alkenyl- oder Alkylsuccinimids mit einem Hydroxypolyoxyalkylenoxycarbonyl substituiert ist (sind), und wobei das vielfach adduktierte Alkenyl- oder Alkylsuccinimid auf ein vielfach adduktiertes Alkenyl- oder Alkylbernsteinsäureanhydrid zurückgeht, gekennzeichnet durch das Vorliegen von durchschnittlich mehr als 1,3 Bernsteinsäuregruppen pro Äquivalent Alkenyl- oder Alkylgruppe in seiner Struktur.
8. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid
2^ gemäß Anspruch 7, wobei das Polyoxyalkylen des Hydroxypolyoxyalkylenoxycarbonyls 2 bis 30 C2-C5-Oxyalkyleneinheiten enthält.
9. Vielfach adduktiertes Alkenyl- oder Alkylsuccinimid gemäß Anspruch 1, 5 oder 7, wobei der Alkenyl- oder Alkylanteil eine C70-C,5„-Alkenyl- oder -alkylgruppe ist.
10. Produkt, hergestellt nach einem Verfahren, welches darin besteht, bei einer Temperatur, die zur Bewirkung einer Reaktion ausreicht, ein vielfach adduktiertes Alkenyl- oder Alkylsuccinimid, das wenigstens ein
primäres oder sekundäres Amin enthält, mit einem
zyklischen Carbonat umzusetzen, wobei das vielfach adduktiertes Alkenyl- oder Alkylsuccinimid auf ein vielfach adduktiertes Alkenyl- oder
Alkylbernsteinsäureanhydrid zurückgeht, gekennzeichnet durch das Vorliegen von duxchschnittlich mehr als 1,3 Bernsteinsäuregruppen pro Äquivalent Alkenyl- oder Alkylgruppen in seiner Struktur, und wobei das Molverhältnis des zyklischen Carbonats zu dem basischen Stickstoff des vielfach adduktierten Alkenyl- oder Alkylsuccinimids ungefähr 0,2 : 1 bis ungefähr 10 :1 beträgt.
11. Produkt, hergestellt nach dem Verfahren des Anspruchs 10, wobei das zyklische Carbonat ausgewählt ist aus der Gruppe bestehend aus
O O
Il »
0'- "0 0 0 CT ^O
I Ii I I ;
R4HC CR5 CH2 CH2
CH2OH / \
Ri r\H&ogr;L- C-HoOH
N / n
/1&lgr; (2) (3)
I I ; und I I
R4HC CHRc H9C CH0
I H0C CH0
OH Il
io Il
O (4) (5)
15 worin R47 R5, R-, R7, R„ und Rg unabhängig voneinander ausgewählt sind aus Wasserstoff oder Alkyl mit 1 bis 2 Kohlenstoffatomen, R,Q Hydroxy oder Wasserstoff ist und &eegr; eine ganze Zahl von 0 bis 1 ist.
2^
12. Produkt, hergestellt nach dem Verfahren gemäß Anspruch 11, wobei das zyklische Carbonat aus
O
25 Il
&ogr; &ogr;
• C ^-V^"1 ">&kgr;- C &ngr;
^ R
besteht.
13. Produkt, hergestellt nach dem Verfahren von Anspruch
12, wobei &eegr; 0 ist und R-, R5, Rg Wasserstoff sind und Rq Wasserstoff oder Methyl ist.
14. Produkt, hergestellt nach dem Verfahren von Anspruch
13, wobei das vielfach adduktierte Alkenyl- oder Alkylsuccinimid ungefähr 1,3 bis 3,5 Bernsteinsäuregruppen pro Alkenyl- oder Alkylgruppe enthält.
15. Produkt nach Anspruch 14, wobei das Molverhältnis des zyklischen Carbonate zu den basischen Stickstoffen des vielfach adduktierten Alkenyl- oder Alkylsuccinimids ungefähr 0,5 : 1 bis ungefähr 5 : 1 beträgt.
16. Produkt nach Anspruch 15, wobei das Molverhältnis des zyklischen Carbonats zu den basischen Stickstoffen des
Alkenyl- oder Alkylsuccinimids ungefähr 2 : 1 beträgt. 20
17. Produkt nach Anspruch 16, wobei der Alkenyl- oder Alkylanteil eine C70-C, ^-Alkenyl- oder -alkylgruppe ist.
2^
18. Produkt hergestellt nach einem Verfahren, welches darin besteht, ein vielfach adduktiertes Alkenyl- oder Alkylsuccinimid mit einem Polycarbonat bei einer Temperatur zu kontaktieren, die dazu ausreicht, eine Reaktion zu bewirken, wobei die Molverhältnisse der einzelnen Carbonateinheiten des linearen Polycarbonats zu den basischen Aminstickstoffen des vielfach adduktierten Alkenyl- oder Alkylsuccinimids ungefähr 0,1 : 1 bis ungefähr 5 : 1 betragen, und wobei das
vielfach adduktierte Alkenyl- oder Alkylsuccinimid 35
—7—
auf ein vielfach adduktiertes Alkenyl- oder Alkylbernsteinsaureanhydrid zurückgeht, gekennzeichnet durch das Vorliegen von mehr als 1,3 Bernsteinsäuregruppen pro Äquivalent Alkenyl- oder Alkylgruppen in seiner Struktur.
19. Produkt, hergestellt nach dem Verfahren gemäß Anspruch 18, wobei das lineare Polycarbonat aus
O O
I! 1
R15^OCOR16(OR16)JnOCOR15
besteht, wobei R,- ein Hydroxyhydrocarbyl mit 2 bis 20 Kohlenstoffatomen ist, R1, eine divalente Hydrocarbylgruppe mit 2 bis 20 Kohlenstoffatomen ist, m eine ganze zahl von 1 bis 10 ist und &eegr; eine ganze Zahl von 1 bis 300 ist.
20. Produkt, hergestellt nach dem Verfahren von Anspruch 19, wobei die Reaktion bei 00C bis 2500C durchgeführt wird.
21. Produkt, hergestellt nach einem Verfahren, welches darin besteht, eine Verbindung gemäß einem der
Ansprüche 1, 5, 7, 10 und 18 mit Borsäure umzusetzen. 30
22. Schmierölzubereitung aus einem öl mit Schmierviskosität und ungefähr 0,2 bis 10 Gew.-% einer Verbindung gemäß einem der Ansprüche 1, 5, 7, 10, 18 und 21.
23. Schmierölkonzentrat aus ungefähr 10 bis 90 Gew.-% eines Öls mit Schmierviskosität und ungefähr 90 bis 10 Gew.-% einer Verbindung gemäß einem der Ansprüche 1, 5, 7, 10,
18 und 5
24. TreibstoffZubereitung aus einem Kohlenwasserstoff, der im Benzinbereich siedet, und 10 bis 10000 Teilen pro Million einer Verbindung gemäß einem der Ansprüche 1,
5, 7, 10, 18 und 10
25. Treibstoffkonzentrat aus 30 bis 90 Gew.-% eines inerten stabilen oleofilen organischen Lösungsmittels und bis 70 Gew.-% einer Verbindung gemäß einem der
Ansprüche 1, 5, 7, 10, 18 und 15
DE198787905836T 1986-08-15 1987-08-13 Modifizierte succinimide. Pending DE277222T1 (de)

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US06/897,190 US4747965A (en) 1985-04-12 1986-08-15 Modified succinimides
PCT/US1987/002004 WO1988001290A1 (en) 1986-08-15 1987-08-13 Modified succinimides

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EP (1) EP0277222B1 (de)
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WO (1) WO1988001290A1 (de)

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Publication number Publication date
US4747965A (en) 1988-05-31
EP0277222A1 (de) 1988-08-10
DE3784157D1 (de) 1993-03-25
CA1324385C (en) 1993-11-16
EP0277222B1 (de) 1993-02-10
WO1988001290A1 (en) 1988-02-25
EP0277222A4 (de) 1988-12-22
DE3784157T2 (de) 1993-09-23

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