DE2728865C3 - Stabilisierte Formmassen auf der Basis von Vinylchlorid-Polymerisaten - Google Patents
Stabilisierte Formmassen auf der Basis von Vinylchlorid-PolymerisatenInfo
- Publication number
- DE2728865C3 DE2728865C3 DE2728865A DE2728865A DE2728865C3 DE 2728865 C3 DE2728865 C3 DE 2728865C3 DE 2728865 A DE2728865 A DE 2728865A DE 2728865 A DE2728865 A DE 2728865A DE 2728865 C3 DE2728865 C3 DE 2728865C3
- Authority
- DE
- Germany
- Prior art keywords
- group
- groups
- molding compounds
- vinyl chloride
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000465 moulding Methods 0.000 title claims description 24
- 229920000642 polymer Polymers 0.000 title claims description 9
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 title description 27
- 239000000203 mixture Substances 0.000 claims description 18
- -1 trihydroxyethyl isocyanurate Chemical compound 0.000 claims description 17
- 229920005862 polyol Polymers 0.000 claims description 15
- 150000003077 polyols Chemical class 0.000 claims description 15
- 239000003381 stabilizer Substances 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- 239000012760 heat stabilizer Substances 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 19
- 239000004800 polyvinyl chloride Substances 0.000 description 16
- 229920000915 polyvinyl chloride Polymers 0.000 description 14
- 125000003118 aryl group Chemical group 0.000 description 10
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 8
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 8
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 8
- 229960002920 sorbitol Drugs 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 238000002845 discoloration Methods 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 235000010355 mannitol Nutrition 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000600 sorbitol Substances 0.000 description 5
- 235000010356 sorbitol Nutrition 0.000 description 5
- LRQGFQDEQPZDQC-UHFFFAOYSA-N 1-Phenyl-1,3-eicosanedione Chemical compound CCCCCCCCCCCCCCCCCC(=O)CC(=O)C1=CC=CC=C1 LRQGFQDEQPZDQC-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
- YQEMORVAKMFKLG-UHFFFAOYSA-N 2-stearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 125000002993 cycloalkylene group Chemical group 0.000 description 2
- HEBKCHPVOIAQTA-NGQZWQHPSA-N d-xylitol Chemical compound OC[C@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-NGQZWQHPSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- PXEZIKSRSYGOED-UHFFFAOYSA-N heptatriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC PXEZIKSRSYGOED-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000594 mannitol Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- IGGUPRCHHJZPBS-UHFFFAOYSA-N nonacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCC IGGUPRCHHJZPBS-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 235000010603 pastilles Nutrition 0.000 description 2
- VHQQPFLOGSTQPC-UHFFFAOYSA-N pentatriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC VHQQPFLOGSTQPC-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 125000005498 phthalate group Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Chemical class 0.000 description 2
- VVPITZPVEZFHRI-UHFFFAOYSA-N 1-(4-methoxyphenyl)icosan-1-one Chemical compound C(CCCCCCCCCCCCCCCCC)CC(C1=CC=C(C=C1)OC)=O VVPITZPVEZFHRI-UHFFFAOYSA-N 0.000 description 1
- CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 description 1
- IIOLAWJMOGLOIB-UHFFFAOYSA-N 1-phenylhexadecan-1-one Chemical compound CCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 IIOLAWJMOGLOIB-UHFFFAOYSA-N 0.000 description 1
- ARPGYWDTCNVFIR-UHFFFAOYSA-N 1-phenylicosan-1-one Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 ARPGYWDTCNVFIR-UHFFFAOYSA-N 0.000 description 1
- DBLXXVQTWJFJFI-UHFFFAOYSA-N 1-phenyloctadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 DBLXXVQTWJFJFI-UHFFFAOYSA-N 0.000 description 1
- VPPSACHDRKODSU-UHFFFAOYSA-N 1-phenyltetracosan-1-one Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 VPPSACHDRKODSU-UHFFFAOYSA-N 0.000 description 1
- LXUIUVLDNRQBQJ-UHFFFAOYSA-N 1-phenyltetradecan-1-one Chemical compound CCCCCCCCCCCCCC(=O)C1=CC=CC=C1 LXUIUVLDNRQBQJ-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical class CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- BSELJBOMYPMBNL-UHFFFAOYSA-N 2-acetyl-3,4-dihydro-2h-naphthalen-1-one Chemical compound C1=CC=C2C(=O)C(C(=O)C)CCC2=C1 BSELJBOMYPMBNL-UHFFFAOYSA-N 0.000 description 1
- QDOGDTXCIBHAMV-UHFFFAOYSA-N 2-hexadecyl-3,4-dihydro-2H-naphthalen-1-one Chemical compound C(CCCCCCCCCCCCCCC)C1C(C2=CC=CC=C2CC1)=O QDOGDTXCIBHAMV-UHFFFAOYSA-N 0.000 description 1
- VHNRAZGQKXMCSK-UHFFFAOYSA-N 2-hexadecylcyclohexan-1-one Chemical compound CCCCCCCCCCCCCCCCC1CCCCC1=O VHNRAZGQKXMCSK-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-hydroxyoctadecanoic acid Chemical class CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- UVKSTCWQLPZZSN-UHFFFAOYSA-N 2-octadecyl-3,4-dihydro-2H-naphthalen-1-one Chemical compound C1=CC=C2C(=O)C(CCCCCCCCCCCCCCCCCC)CCC2=C1 UVKSTCWQLPZZSN-UHFFFAOYSA-N 0.000 description 1
- COGQQAXXNDVWFT-UHFFFAOYSA-N 2-octadecylcyclohexan-1-one Chemical compound C(CCCCCCCCCCCCCCCCC)C1C(CCCC1)=O COGQQAXXNDVWFT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical compound [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000009750 centrifugal casting Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- IMQDQLFUWRBGGN-UHFFFAOYSA-N hentetracontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IMQDQLFUWRBGGN-UHFFFAOYSA-N 0.000 description 1
- BJQWYEJQWHSSCJ-UHFFFAOYSA-N heptacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCC BJQWYEJQWHSSCJ-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- SNXOSZZZNFRFNZ-UHFFFAOYSA-N nonatriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC SNXOSZZZNFRFNZ-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- VYRMHDHLFQRAAY-UHFFFAOYSA-N pentatetracontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC VYRMHDHLFQRAAY-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 125000000075 primary alcohol group Chemical group 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000010106 rotational casting Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- SUJUOAZFECLBOA-UHFFFAOYSA-N tritriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC SUJUOAZFECLBOA-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7620181A FR2356695A1 (fr) | 1976-06-28 | 1976-06-28 | Compositions plastifiees et stabilisees a base de poly(chlorure de vinyle) |
| FR7703086A FR2378820A2 (fr) | 1977-01-28 | 1977-01-28 | Compositions plastifiees et stabilisees a base de poly (chlorure de vinyle) |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2728865A1 DE2728865A1 (de) | 1978-01-05 |
| DE2728865B2 DE2728865B2 (de) | 1979-07-26 |
| DE2728865C3 true DE2728865C3 (de) | 1987-09-10 |
Family
ID=26219518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2728865A Expired DE2728865C3 (de) | 1976-06-28 | 1977-06-27 | Stabilisierte Formmassen auf der Basis von Vinylchlorid-Polymerisaten |
Country Status (20)
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4221687A (en) * | 1977-07-07 | 1980-09-09 | Argus Chemical Corp. | Anti-yellowing composition |
| JPS54102348A (en) * | 1978-01-31 | 1979-08-11 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| US4416797A (en) * | 1980-03-03 | 1983-11-22 | Adeka Argus Chemical Co., Ltd. | Chlorinated organic compounds having their resistance to deterioration enhanced by 1,3-dicarbonyl compounds |
| US4381360A (en) * | 1981-01-14 | 1983-04-26 | Phoenix Chemical Corporation | 1,3-Dicarbonyl compounds and polyvinyl halide resin compositions containing the same |
| DE3113442A1 (de) * | 1981-04-03 | 1982-10-21 | Henkel KGaA, 4000 Düsseldorf | "stabilisierte polyvinylchlorid-formmassen" |
| DE3207466A1 (de) * | 1982-03-02 | 1983-09-15 | Taprogge Gesellschaft mbH, 4000 Düsseldorf | Vorrichtung zum reinigen von waermetauscher-roehren und verfahren zum betrieb einer derartigen vorrichtung |
| FR2524474A1 (fr) * | 1982-03-30 | 1983-10-07 | Rhone Poulenc Spec Chim | Procede de stabilisation de polymeres a base de chlorure de vinyle, compositions stabilisantes pour la mise en oeuvre du procede et polymeres ainsi stabilises |
| US4950704A (en) * | 1988-03-01 | 1990-08-21 | Argus Chemical Corporation | Improving stability at moderate temperatures of motor vehicle components shaped from polyvinyl chloride resin compositions |
| DE68927302T2 (de) * | 1988-03-01 | 1997-03-06 | Witco Corp | Verbesserung der Stabilität bei mässigen Temperaturen von Kraftfahrzeugformteilen aus Polyvinylchlorid-Zusammensetzungen |
| EP0346279A1 (de) * | 1988-06-06 | 1989-12-13 | Ciba-Geigy Ag | Propan-1,3-dionderivate und deren Verwendung als Stabilisatoren für chlorhaltige Polymerisate |
| JP2762150B2 (ja) * | 1990-03-15 | 1998-06-04 | 旭電化工業株式会社 | 含ハロゲン樹脂組成物 |
| US5102933A (en) * | 1990-05-22 | 1992-04-07 | Witco Corporation | Polyvinylchloride composition and stabilizers therefor |
| DE4018293A1 (de) * | 1990-06-07 | 1991-12-12 | Neynaber Chemie Gmbh | Ketofettsaeureglyceride enthaltende stabilisatoren fuer ca/zn-stabilisierte pvc-formmassen |
| US5322872A (en) * | 1993-04-14 | 1994-06-21 | The Lubrizol Corporation | Stabilized compositions of mixed metal carboxylates |
| DE4426571A1 (de) * | 1994-07-27 | 1996-02-01 | Henkel Kgaa | Verwendung einer Stabilisatorkombination bei der Herstellung von Folien aus Polyvinylchlorid nach dem Kalandrierverfahren |
| US5656202A (en) * | 1995-06-20 | 1997-08-12 | Witco Corporation | Method for making overbased PVC stabilizer |
| US5872166A (en) * | 1995-06-20 | 1999-02-16 | Witco Corporation | Overbased PVC stabilizer |
| US6313203B1 (en) | 1996-12-19 | 2001-11-06 | Akcros Chemicals | Use of polyalcohols as polymer stabilizers |
| US6613723B2 (en) | 2001-12-06 | 2003-09-02 | Exxonmobil Chemical Patents Inc. | Overbased barium complexes of C8 to C10 carboxylic acids |
| JP2010180395A (ja) * | 2009-01-09 | 2010-08-19 | Sumitomo Chemical Co Ltd | ポリマー安定剤及び該安定剤を含有するポリマー組成物 |
| US9346939B2 (en) | 2013-11-01 | 2016-05-24 | Galata Chemicals Llc | Flexible PVC compounds having a low metals content |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1073201B (de) * | 1955-04-27 | 1960-01-01 | Badische Anilin- &. Soda Fabrik Aktiengesellschaft, Ludwigshafen/Rhem | Gegen die Einwirkung von Licht stabilisierte plastische Massen aus Polymerisaten des Vinylchlorids oder Vmylidenchlorids |
| US3310525A (en) * | 1963-03-22 | 1967-03-21 | Eastman Kodak Co | Ultraviolet light stabilized polyester and polyolefin compositions |
| US3373130A (en) * | 1965-02-08 | 1968-03-12 | Allied Chem | Vinyl chloride polymer insulation compositions containing ortho-hydroxybenzaldehyde |
| NL146519B (nl) * | 1965-05-21 | 1975-07-15 | Cincinnati Milacron Chem | Werkwijze voor het bereiden van een harsachtige samenstelling met een geringere lichtgevoeligheid. |
-
1977
- 1977-06-23 NL NL7706976A patent/NL7706976A/xx active Search and Examination
- 1977-06-23 NZ NZ184467A patent/NZ184467A/xx unknown
- 1977-06-23 MX MX775836U patent/MX4810E/es unknown
- 1977-06-24 LU LU77610A patent/LU77610A1/xx unknown
- 1977-06-24 GB GB26612/77A patent/GB1567257A/en not_active Expired
- 1977-06-24 PT PT66716A patent/PT66716B/pt unknown
- 1977-06-27 DE DE2728865A patent/DE2728865C3/de not_active Expired
- 1977-06-27 NO NO772264A patent/NO772264L/no unknown
- 1977-06-27 TR TR19632A patent/TR19632A/xx unknown
- 1977-06-27 FI FI771998A patent/FI771998A/fi not_active Application Discontinuation
- 1977-06-27 SE SE7707410A patent/SE417834B/xx unknown
- 1977-06-27 DD DD7700199716A patent/DD131032A5/xx unknown
- 1977-06-27 JP JP7643277A patent/JPS533443A/ja active Pending
- 1977-06-27 DK DK284077A patent/DK284077A/da unknown
- 1977-06-27 BR BR7704169A patent/BR7704169A/pt unknown
- 1977-06-28 IT IT25154/77A patent/IT1086240B/it active
- 1977-06-28 AT AT459177A patent/AT350278B/de not_active IP Right Cessation
- 1977-06-28 ES ES460176A patent/ES460176A1/es not_active Expired
- 1977-06-28 CH CH793977A patent/CH622275A5/fr not_active IP Right Cessation
- 1977-06-28 US US05/810,845 patent/US4123399A/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| DK284077A (da) | 1977-12-29 |
| DD131032A5 (de) | 1978-05-24 |
| FI771998A (fi) | 1977-12-29 |
| CH622275A5 (US20020095090A1-20020718-M00002.png) | 1981-03-31 |
| DE2728865A1 (de) | 1978-01-05 |
| PT66716A (fr) | 1977-07-01 |
| BR7704169A (pt) | 1978-03-28 |
| JPS533443A (en) | 1978-01-13 |
| NZ184467A (en) | 1979-06-08 |
| TR19632A (tr) | 1979-09-03 |
| SE417834B (sv) | 1981-04-13 |
| SE7707410L (sv) | 1977-12-29 |
| US4123399A (en) | 1978-10-31 |
| IT1086240B (it) | 1985-05-28 |
| LU77610A1 (US20020095090A1-20020718-M00002.png) | 1978-07-11 |
| ATA459177A (de) | 1978-10-15 |
| AT350278B (de) | 1979-05-25 |
| NO772264L (no) | 1977-12-29 |
| MX4810E (es) | 1982-10-15 |
| DE2728865B2 (de) | 1979-07-26 |
| ES460176A1 (es) | 1978-12-01 |
| NL7706976A (nl) | 1977-12-30 |
| GB1567257A (en) | 1980-05-14 |
| PT66716B (fr) | 1978-11-22 |
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