DE2608029C2 - Verfahren zur Herstellung einer Alkaliphosphatlösung aus Naßverfahrensphosphorsäuren - Google Patents
Verfahren zur Herstellung einer Alkaliphosphatlösung aus NaßverfahrensphosphorsäurenInfo
- Publication number
- DE2608029C2 DE2608029C2 DE2608029A DE2608029A DE2608029C2 DE 2608029 C2 DE2608029 C2 DE 2608029C2 DE 2608029 A DE2608029 A DE 2608029A DE 2608029 A DE2608029 A DE 2608029A DE 2608029 C2 DE2608029 C2 DE 2608029C2
- Authority
- DE
- Germany
- Prior art keywords
- vanadium
- alkali
- ppm
- chromium
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 22
- 229910019142 PO4 Inorganic materials 0.000 title claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims description 13
- 239000010452 phosphate Substances 0.000 title claims description 13
- 239000003513 alkali Substances 0.000 title claims description 11
- 150000003016 phosphoric acids Chemical class 0.000 title claims description 10
- 235000011007 phosphoric acid Nutrition 0.000 title description 18
- 229910052720 vanadium Inorganic materials 0.000 claims description 30
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 30
- 239000011651 chromium Substances 0.000 claims description 29
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 24
- 229910052804 chromium Inorganic materials 0.000 claims description 24
- 238000006386 neutralization reaction Methods 0.000 claims description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 13
- 239000002244 precipitate Substances 0.000 claims description 11
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 244000078856 Prunus padus Species 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 239000002253 acid Substances 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000011734 sodium Substances 0.000 description 11
- 235000021317 phosphate Nutrition 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 9
- 238000001556 precipitation Methods 0.000 description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910001448 ferrous ion Inorganic materials 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910019582 Cr V Inorganic materials 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 239000005569 Iron sulphate Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- 235000011008 sodium phosphates Nutrition 0.000 description 2
- 239000001226 triphosphate Substances 0.000 description 2
- 235000011178 triphosphate Nutrition 0.000 description 2
- 125000002264 triphosphate group Chemical class [H]OP(=O)(O[H])OP(=O)(O[H])OP(=O)(O[H])O* 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/30—Alkali metal phosphates
- C01B25/301—Preparation from liquid orthophosphoric acid or from an acid solution or suspension of orthophosphates
- C01B25/303—Preparation from liquid orthophosphoric acid or from an acid solution or suspension of orthophosphates with elimination of impurities
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Removal Of Specific Substances (AREA)
- Compounds Of Iron (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2608029A DE2608029C2 (de) | 1976-02-27 | 1976-02-27 | Verfahren zur Herstellung einer Alkaliphosphatlösung aus Naßverfahrensphosphorsäuren |
| ES455855A ES455855A1 (es) | 1976-02-27 | 1977-02-11 | Procedimiento para la preparacion de soluciones de fosfatos de metales alcalinos. |
| GB6922/77A GB1543522A (en) | 1976-02-27 | 1977-02-18 | Production of pure alkali metal phosphate solutions from wet-processed phosphoric acids |
| US05/771,167 US4134962A (en) | 1976-02-27 | 1977-02-23 | Production of pure alkali metal phosphate solutions from wet-processed phosphoric acids |
| FR7705662A FR2342249A1 (fr) | 1976-02-27 | 1977-02-25 | Procede de preparation de solutions de phosphates alcalins pures a partir d'acides phosphoriques par voie humide |
| BE175255A BE851825A (fr) | 1976-02-27 | 1977-02-25 | Procede de preparation de solutions de phosphates alcalins pures a partir d'acides phosphoriques par voie humide |
| NLAANVRAGE7702068,A NL184315C (nl) | 1976-02-27 | 1977-02-25 | Werkwijze ter bereiding van zuivere alkalimetaalfosfaatoplossingen uit langs de natte weg verkregen fosforzuren. |
| IT48221/77A IT1105703B (it) | 1976-02-27 | 1977-02-25 | Procedimento per produrre soluzioni di fosfati alcalini pure da scidi fosforici da processo ad umido |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2608029A DE2608029C2 (de) | 1976-02-27 | 1976-02-27 | Verfahren zur Herstellung einer Alkaliphosphatlösung aus Naßverfahrensphosphorsäuren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2608029A1 DE2608029A1 (de) | 1977-09-01 |
| DE2608029C2 true DE2608029C2 (de) | 1984-02-23 |
Family
ID=5971047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2608029A Expired DE2608029C2 (de) | 1976-02-27 | 1976-02-27 | Verfahren zur Herstellung einer Alkaliphosphatlösung aus Naßverfahrensphosphorsäuren |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4134962A (enExample) |
| BE (1) | BE851825A (enExample) |
| DE (1) | DE2608029C2 (enExample) |
| ES (1) | ES455855A1 (enExample) |
| FR (1) | FR2342249A1 (enExample) |
| GB (1) | GB1543522A (enExample) |
| IT (1) | IT1105703B (enExample) |
| NL (1) | NL184315C (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2855922A1 (de) * | 1978-12-23 | 1980-07-10 | Hoechst Ag | Verfahren zur herstellung von zinkfreien alkaliphosphatloesungen |
| SE418845B (sv) * | 1979-05-10 | 1981-06-29 | Boliden Ab | Forfarande for rening av vatprocessfosforsyra |
| US4285920A (en) * | 1979-11-08 | 1981-08-25 | Stauffer Chemical Company | Solvent extraction process for preparing purified phosphoric acid and sodium phosphate salts |
| DE3437685C2 (de) * | 1984-10-15 | 1987-03-12 | Hoechst Ag, 6230 Frankfurt | Verfahren zur Herstellung einer vanadiumarmen Alkaliphosphatlösung |
| DE3938225A1 (de) * | 1989-11-17 | 1991-05-23 | Hoechst Ag | Verfahren zur herstellung gereinigter alkaliphosphatloesung |
| DE4327401A1 (de) * | 1993-08-14 | 1995-02-16 | Hoechst Ag | Verfahren zur Entfernung von Blei und Cadmium aus Phosphorsäure |
| RU2149825C1 (ru) * | 1999-02-09 | 2000-05-27 | Государственный научный центр Российской Федерации - Физико-энергетический институт им. акад. А.И. Лейпунского | Способ получения раствора натрия фосфата, содержащего радионуклид фосфор-32 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2174138A (en) * | 1938-04-27 | 1939-09-26 | Paul E Sage | Powder-feeding device |
| DE1117093B (de) * | 1959-01-17 | 1961-11-16 | Dr Hans Huber | Verfahren zur Herstellung gereinigter Alkaliorthophosphatloesungen durch partielle Neutralisierung roher, nach dem Nassverfahren hergestellter Phosphorsaeure |
| US3305305A (en) * | 1962-12-26 | 1967-02-21 | Hooker Chemical Corp | Purification of phosphate solutions |
| US3493336A (en) * | 1964-06-18 | 1970-02-03 | Electric Reduction Co | Manufacture of alkali metal phosphates |
| US3421845A (en) * | 1965-06-07 | 1969-01-14 | Hooker Chemical Corp | Production of sodium phosphates |
| DE1811994B2 (de) * | 1968-11-30 | 1971-02-04 | Knapsack AG. 5030 Hurth | Verfahren zur Herstellung von Alkali phosphatlosungen |
| DE2035505C3 (de) * | 1970-07-17 | 1974-06-12 | Knapsack Ag, 5033 Huerth-Knapsack | Verfahren zur Herstellung reiner Alkaliphosphatlösungen |
| DE2323292C3 (de) * | 1973-05-09 | 1981-10-29 | Kali Und Salz Ag, 3500 Kassel | Verfahren zur Herstellung von Natrium- und/oder Kaliumphosphaten |
-
1976
- 1976-02-27 DE DE2608029A patent/DE2608029C2/de not_active Expired
-
1977
- 1977-02-11 ES ES455855A patent/ES455855A1/es not_active Expired
- 1977-02-18 GB GB6922/77A patent/GB1543522A/en not_active Expired
- 1977-02-23 US US05/771,167 patent/US4134962A/en not_active Expired - Lifetime
- 1977-02-25 FR FR7705662A patent/FR2342249A1/fr active Granted
- 1977-02-25 NL NLAANVRAGE7702068,A patent/NL184315C/xx not_active IP Right Cessation
- 1977-02-25 BE BE175255A patent/BE851825A/xx not_active IP Right Cessation
- 1977-02-25 IT IT48221/77A patent/IT1105703B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| NL184315B (nl) | 1989-01-16 |
| DE2608029A1 (de) | 1977-09-01 |
| FR2342249A1 (fr) | 1977-09-23 |
| FR2342249B1 (enExample) | 1981-10-02 |
| ES455855A1 (es) | 1978-01-01 |
| NL7702068A (nl) | 1977-08-30 |
| NL184315C (nl) | 1989-06-16 |
| US4134962A (en) | 1979-01-16 |
| GB1543522A (en) | 1979-04-04 |
| IT1105703B (it) | 1985-11-04 |
| BE851825A (fr) | 1977-08-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |