DE2519236A1 - Verfahren zum reinigen von gasfoermigen mischungen - Google Patents

Verfahren zum reinigen von gasfoermigen mischungen

Info

Publication number
DE2519236A1
DE2519236A1 DE19752519236 DE2519236A DE2519236A1 DE 2519236 A1 DE2519236 A1 DE 2519236A1 DE 19752519236 DE19752519236 DE 19752519236 DE 2519236 A DE2519236 A DE 2519236A DE 2519236 A1 DE2519236 A1 DE 2519236A1
Authority
DE
Germany
Prior art keywords
adsorbent
earth metal
rare earth
metal component
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19752519236
Other languages
German (de)
English (en)
Inventor
Clyde L Aldridge
Geoffrey R Say
Kenneth S Wheelock
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of DE2519236A1 publication Critical patent/DE2519236A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/402—Further details for adsorption processes and devices using two beds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
DE19752519236 1974-05-07 1975-04-30 Verfahren zum reinigen von gasfoermigen mischungen Withdrawn DE2519236A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/467,716 US3974256A (en) 1974-05-07 1974-05-07 Sulfide removal process
US05/536,164 US4002720A (en) 1974-05-07 1974-12-24 Gas desulfurization

Publications (1)

Publication Number Publication Date
DE2519236A1 true DE2519236A1 (de) 1975-11-27

Family

ID=27042153

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19752519236 Withdrawn DE2519236A1 (de) 1974-05-07 1975-04-30 Verfahren zum reinigen von gasfoermigen mischungen

Country Status (5)

Country Link
US (2) US3974256A (cg-RX-API-DMAC10.html)
JP (1) JPS50150686A (cg-RX-API-DMAC10.html)
CA (1) CA1069678A (cg-RX-API-DMAC10.html)
DE (1) DE2519236A1 (cg-RX-API-DMAC10.html)
GB (1) GB1500811A (cg-RX-API-DMAC10.html)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
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DE2708035C2 (de) * 1976-02-27 1986-08-28 Hitachi, Ltd., Tokio/Tokyo Verfahren zur Entfernung von Schwefelwasserstoff und Ammoniak aus einem heißen Gas
US4885145A (en) * 1979-04-19 1989-12-05 Kay D Alan R Method for providing oxygen ion vacancies in lanthanide oxides
US4857280A (en) * 1979-04-19 1989-08-15 Kay D Alan R Method for the regeneration of sulfided cerium oxide back to a form that is again capable of removing sulfur from fluid materials
US4604268A (en) * 1979-04-19 1986-08-05 Kay Alan R Methods of desulfurizing gases
US4826664A (en) * 1980-07-31 1989-05-02 Kay D Alan R Methods of desulfurizing gases
US4714598A (en) * 1979-04-19 1987-12-22 Kay D Alan R Methods of desulfurizing gases
US4330307A (en) * 1980-04-07 1982-05-18 Coury Glenn E Method of separating a noncondensable gas from a condensable vapor
US4321242A (en) * 1980-09-30 1982-03-23 United States Steel Corporation Low sulfur content hot reducing gas production using calcium oxide desulfurization with water recycle
US5326737A (en) * 1980-07-31 1994-07-05 Gas Desulfurization Corporation Cerium oxide solutions for the desulfurization of gases
US4382469A (en) * 1981-03-10 1983-05-10 Electro-Petroleum, Inc. Method of in situ gasification
US4346063A (en) * 1981-03-16 1982-08-24 Exxon Research & Engineering Co. Desulfurization of hot gas with cerium oxide
CA1134596A (en) * 1981-07-06 1982-11-02 Leo A. Behie Process for producing hydrogen from hydrogen sulphide in a gas fluidized bed reactor
US4556547A (en) * 1982-02-01 1985-12-03 Takeda Chemical Industries, Ltd. Process for treatment of gases
US4425312A (en) 1982-07-02 1984-01-10 Exxon Research And Engineering Co. Removal of sulfur from process streams
US4442078A (en) * 1982-07-07 1984-04-10 The United States Of America As Represented By The United States Department Of Energy Method of removing hydrogen sulfide from gases utilizing a zinc oxide sorbent and regenerating the sorbent
US4455286A (en) * 1982-07-07 1984-06-19 The United States Of America As Represented By The United States Department Of Energy High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures
US5002742A (en) * 1983-05-16 1991-03-26 W. R. Grace & Co.-Conn. Inorganic oxide sorbents for sulfur oxides
US4533529A (en) * 1983-10-21 1985-08-06 Standard Oil Company Sulfur recovery process
US4600702A (en) * 1984-11-14 1986-07-15 Monsanto Company Vapor phase nitration catalysts
US4757043A (en) * 1984-11-14 1988-07-12 Monsanto Company Process for preparing vapor phase nitration catalysts
US4746642A (en) * 1984-11-14 1988-05-24 Monsanto Company Vapor phase nitration catalysts
AU596604B2 (en) * 1985-07-01 1990-05-10 Texaco Development Corporation Control of sox emission
US4798819A (en) * 1985-07-01 1989-01-17 Texaco Inc. Catalyst for control of emission of sulfur oxides
US4668655A (en) * 1985-07-08 1987-05-26 Texaco Inc. Catalyst composition for catalytic cracking
DE3525241A1 (de) * 1985-07-15 1987-01-15 Peter Siegfried Verfahren zur entfernung von organischen schwefelverbindungen oder schwefeloxiden und stickoxiden aus solche enthaltenden gasen
US5171551A (en) * 1986-04-30 1992-12-15 Rhone-Poulenc Chimie Zirconium dioxide gas desulfurization catalyst
FR2608458B1 (fr) * 1986-12-23 1989-03-10 Rhone Poulenc Chimie Catalyseur a base d'oxyde de cerium et procede pour le traitement de gaz industriels contenant des composes du soufre
US4937059A (en) * 1988-09-26 1990-06-26 Phillips Petroleum Company Absorption and desorption of carbon dioxide
US5023224A (en) * 1989-08-31 1991-06-11 Shell Oil Company Alkoxylation process catalyzed by lanthanum silicates and metasilicates
JPH0593519A (ja) * 1991-04-02 1993-04-16 Mitsubishi Heavy Ind Ltd ガス化複合発電プラント
US5180703A (en) * 1991-04-24 1993-01-19 W. R. Grace & Co.-Conn. Sox/nox sorbent and process of use
WO1996020906A1 (en) * 1994-12-30 1996-07-11 Albert Calderon Method for upgrading a gas
JP2000515807A (ja) * 1996-07-26 2000-11-28 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 触媒組成物、その調製、及び接触灰化におけるその使用
WO1999037389A1 (en) * 1998-01-26 1999-07-29 Tda Research, Inc. Catalysts for the selective oxidation of hydrogen sulfide to sulfur
AU4406799A (en) * 1998-05-30 1999-12-20 Kansas State University Research Foundation Porous pellet adsorbents fabricated from nanocrystals
ATE321895T1 (de) * 2001-06-08 2006-04-15 Mspl Ltd Neue poröse schwefelschwamm-eisenverbindung, verfahren zu ihrer herstellung und verfahren zur entschwefelung von erdgas mit der verbindung
US20030118495A1 (en) * 2001-12-20 2003-06-26 Khare Gyanesh P. Desulfurization and novel sorbent for same
WO2003082455A2 (en) * 2002-03-25 2003-10-09 Tda Research, Inc. Catalysts and process for oxidizing hydrogen sulfide to sulfur dioxide and sulfur
US7060233B1 (en) * 2002-03-25 2006-06-13 Tda Research, Inc. Process for the simultaneous removal of sulfur and mercury
WO2004035196A2 (en) * 2002-10-16 2004-04-29 Conocophillips Company A stabilized transition alumina catalyst support from boehmite and catalysts made therefrom
MY140997A (en) * 2004-07-22 2010-02-12 Shell Int Research Process for the removal of cos from a synthesis gas stream comprising h2s and cos
US20060110308A1 (en) * 2004-09-17 2006-05-25 Puneet Gupta Silicon carbides, silicon carbide based sorbents, and uses thereof
WO2006052997A1 (en) * 2004-11-08 2006-05-18 Trustees Of Tufts College Apparatus and methods for non-regenerative and regenerative hot gas desulfurization
EP1973841A1 (en) * 2006-01-18 2008-10-01 Shell Internationale Research Maatschappij B.V. Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream
CN101588855B (zh) 2006-11-30 2013-08-28 普拉菲尔有限公司 干式净化用介质组合物及其制备方法和使用方法
WO2009120744A1 (en) * 2008-03-25 2009-10-01 Purafil, Inc. Dry-scrubbing media compositions and methods of production and use
NL1036224C2 (en) * 2008-11-21 2010-05-25 Stichting Energie Water gas shift process.
US8465712B2 (en) * 2009-11-12 2013-06-18 The United States Of America As Represented By The Secretary Of The Army Desulfurization apparatus and method
US8308848B1 (en) * 2009-11-27 2012-11-13 Tda Research, Inc. High temperature gas desulfurization sorbents
MY160346A (en) * 2010-03-02 2017-02-28 Japan Oil Gas & Metals Jogmec Method for removing sulfur compounds in castable
US9611198B2 (en) * 2011-04-18 2017-04-04 M-I L.L.C. Method for catalyst regeneration
NL2008313C2 (en) 2012-02-17 2013-09-02 Stichting Energie Water gas shift process.
US9289714B1 (en) 2014-10-17 2016-03-22 JuvanCo Industries, LLC Device for adsorbing the hydrogen sulfide component of exhausted calibration gases
WO2020033500A1 (en) * 2018-08-09 2020-02-13 Ohio State Innovation Foundation Systems, methods and materials for hydrogen sulfide conversion
EP4314200A1 (en) * 2021-03-31 2024-02-07 ExxonMobil Chemical Patents Inc. Processes and systems for upgrading a hydrocarbon
CN116422321B (zh) * 2023-04-20 2024-10-29 南京工业大学 一种碱性簇状微米棒催化剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1900751A (en) * 1928-02-27 1933-03-07 Ig Farbenindustrie Ag Purification of gases
US3864459A (en) * 1969-04-21 1975-02-04 Alvin B Stiles Process for the economical use of refractory reducing gases for the reduction of sulfur dioxide
CA996472A (en) * 1972-07-13 1976-09-07 W.R. Grace And Co. Method for the selective removal of hydrogen sulfide from a carbon dioxide containing stream
NL190227C (nl) * 1974-01-10 1993-12-16 Rhone Poulenc Ind Werkwijze voor de bereiding van aluminiumoxydelichamen alsmede dergelijke lichamen.

Also Published As

Publication number Publication date
CA1069678A (en) 1980-01-15
GB1500811A (en) 1978-02-15
US4002720A (en) 1977-01-11
JPS50150686A (cg-RX-API-DMAC10.html) 1975-12-03
US3974256A (en) 1976-08-10

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Legal Events

Date Code Title Description
8141 Disposal/no request for examination