DE2261378B2 - Poroese negative kobaltelektrode fuer alkalische akkumulatoren und verfahren zu ihrer herstellung - Google Patents
Poroese negative kobaltelektrode fuer alkalische akkumulatoren und verfahren zu ihrer herstellungInfo
- Publication number
- DE2261378B2 DE2261378B2 DE19722261378 DE2261378A DE2261378B2 DE 2261378 B2 DE2261378 B2 DE 2261378B2 DE 19722261378 DE19722261378 DE 19722261378 DE 2261378 A DE2261378 A DE 2261378A DE 2261378 B2 DE2261378 B2 DE 2261378B2
- Authority
- DE
- Germany
- Prior art keywords
- powder
- cobalt
- electrode
- porous
- porous negative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229910017052 cobalt Inorganic materials 0.000 title claims description 5
- 239000010941 cobalt Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title description 11
- 239000011148 porous material Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 239000002184 metal Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- -1 carbonyl metals Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009897 systematic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000001052 transient effect Effects 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 229910003307 Ni-Cd Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 210000004754 hybrid cell Anatomy 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000001272 pressureless sintering Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/76—Containers for holding the active material, e.g. tubes, capsules
- H01M4/762—Porous or perforated metallic containers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12042—Porous component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12063—Nonparticulate metal component
- Y10T428/12097—Nonparticulate component encloses particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722261378 DE2261378B2 (de) | 1972-12-15 | 1972-12-15 | Poroese negative kobaltelektrode fuer alkalische akkumulatoren und verfahren zu ihrer herstellung |
| US05/423,482 US3986892A (en) | 1972-12-15 | 1973-12-10 | Porous cobalt electrodes for alkaline accumulators and hybrid cell therewith and air electrode |
| FR7344881A FR2210833B3 (OSRAM) | 1972-12-15 | 1973-12-14 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722261378 DE2261378B2 (de) | 1972-12-15 | 1972-12-15 | Poroese negative kobaltelektrode fuer alkalische akkumulatoren und verfahren zu ihrer herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2261378A1 DE2261378A1 (de) | 1974-07-25 |
| DE2261378B2 true DE2261378B2 (de) | 1976-04-01 |
Family
ID=5864487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722261378 Pending DE2261378B2 (de) | 1972-12-15 | 1972-12-15 | Poroese negative kobaltelektrode fuer alkalische akkumulatoren und verfahren zu ihrer herstellung |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3986892A (OSRAM) |
| DE (1) | DE2261378B2 (OSRAM) |
| FR (1) | FR2210833B3 (OSRAM) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2524774C3 (de) * | 1975-06-04 | 1979-01-04 | Volkswagenwerk Ag, 3180 Wolfsburg | Negative Kobalt-Elektrode für alkalische Akkumulatoren und Verfahren zu ihrer Herstellung |
| IL50217A (en) * | 1976-08-06 | 1980-01-31 | Israel State | Electrocatalytically acitve spinel type mixed oxides |
| DE2731063C3 (de) * | 1977-07-09 | 1980-08-07 | Volkswagenwerk Ag, 3180 Wolfsburg | Verfahren zur Herstellung einer positiven Kobalt-Elektrode für alkalische Akkumulatoren |
| US5030519A (en) * | 1990-04-24 | 1991-07-09 | Amorphous Metals Technologies, Inc. | Tungsten carbide-containing hard alloy that may be processed by melting |
| AU2003213841A1 (en) * | 2002-03-11 | 2003-09-29 | Liquidmetal Technologies | Encapsulated ceramic armor |
| US7560001B2 (en) * | 2002-07-17 | 2009-07-14 | Liquidmetal Technologies, Inc. | Method of making dense composites of bulk-solidifying amorphous alloys and articles thereof |
| AU2003254123A1 (en) * | 2002-07-22 | 2004-02-09 | California Institute Of Technology | BULK AMORPHOUS REFRACTORY GLASSES BASED ON THE Ni-Nb-Sn TERNARY ALLOY SYTEM |
| US8002911B2 (en) * | 2002-08-05 | 2011-08-23 | Crucible Intellectual Property, Llc | Metallic dental prostheses and objects made of bulk-solidifying amorphhous alloys and method of making such articles |
| US7591910B2 (en) * | 2002-12-04 | 2009-09-22 | California Institute Of Technology | Bulk amorphous refractory glasses based on the Ni(-Cu-)-Ti(-Zr)-Al alloy system |
| US7896982B2 (en) * | 2002-12-20 | 2011-03-01 | Crucible Intellectual Property, Llc | Bulk solidifying amorphous alloys with improved mechanical properties |
| US8828155B2 (en) * | 2002-12-20 | 2014-09-09 | Crucible Intellectual Property, Llc | Bulk solidifying amorphous alloys with improved mechanical properties |
| WO2004059019A1 (en) * | 2002-12-20 | 2004-07-15 | Liquidmetal Technologies, Inc. | Pt-BASE BULK SOLIDIFYING AMORPHOUS ALLOYS |
| US7520944B2 (en) * | 2003-02-11 | 2009-04-21 | Johnson William L | Method of making in-situ composites comprising amorphous alloys |
| AU2003294624A1 (en) * | 2003-02-26 | 2004-09-17 | Bosch Rexroth Ag | Directly controlled pressure control valve |
| USRE47529E1 (en) | 2003-10-01 | 2019-07-23 | Apple Inc. | Fe-base in-situ composite alloys comprising amorphous phase |
| US11371108B2 (en) | 2019-02-14 | 2022-06-28 | Glassimetal Technology, Inc. | Tough iron-based glasses with high glass forming ability and high thermal stability |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US882144A (en) * | 1905-03-30 | 1908-03-17 | Edison Storage Battery Co | Storage-battery electrode. |
| LU31125A1 (OSRAM) * | 1950-12-09 | |||
| BE521719A (OSRAM) * | 1952-07-26 | |||
| LU34583A1 (OSRAM) * | 1955-09-05 | |||
| FR1370562A (fr) * | 1961-03-10 | 1964-08-28 | Accumulateurs Fixes | Procédé de fabrication de matières actives et d'électrodes pour accumulateurs alcalins, et matières actives et électrodes ainsi obtenues |
| US3341446A (en) * | 1961-11-03 | 1967-09-12 | Bbc Brown Boveri & Cie | Process for the production of a single-frame catalyzer electrode and product |
| US3288641A (en) * | 1962-06-07 | 1966-11-29 | Standard Oil Co | Electrical energy storage apparatus |
| US3311505A (en) * | 1964-09-01 | 1967-03-28 | Inst Francais Du Petrole | Gas electrodes and their fabrication |
| US3479226A (en) * | 1966-07-22 | 1969-11-18 | Leesona Corp | Method of chemically regenerating air depolarized cell with hydrogen |
| US3532548A (en) * | 1966-10-25 | 1970-10-06 | Yardney International Corp | Electrochemical cell utilizing three electrodes |
| US3418171A (en) * | 1966-12-15 | 1968-12-24 | Texas Instruments Inc | Electrochemical power supply systems |
| DE2018635A1 (de) * | 1970-04-18 | 1971-11-11 | Schilling H | Negative Kobalt-Pulver-Elektrode für alkalische Akkumulatoren und Verfahren zu ihrer Herstellung |
-
1972
- 1972-12-15 DE DE19722261378 patent/DE2261378B2/de active Pending
-
1973
- 1973-12-10 US US05/423,482 patent/US3986892A/en not_active Expired - Lifetime
- 1973-12-14 FR FR7344881A patent/FR2210833B3/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2210833A1 (OSRAM) | 1974-07-12 |
| DE2261378A1 (de) | 1974-07-25 |
| US3986892A (en) | 1976-10-19 |
| FR2210833B3 (OSRAM) | 1976-10-15 |
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