DE2249461C3 - Verfahren zur Herstellung von Polyphosphazenen - Google Patents
Verfahren zur Herstellung von PolyphosphazenenInfo
- Publication number
- DE2249461C3 DE2249461C3 DE2249461A DE2249461A DE2249461C3 DE 2249461 C3 DE2249461 C3 DE 2249461C3 DE 2249461 A DE2249461 A DE 2249461A DE 2249461 A DE2249461 A DE 2249461A DE 2249461 C3 DE2249461 C3 DE 2249461C3
- Authority
- DE
- Germany
- Prior art keywords
- och
- mixture
- solution
- sodium
- polyphosphazenes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002627 poly(phosphazenes) Polymers 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 150000004703 alkoxides Chemical class 0.000 claims description 5
- 239000003446 ligand Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 20
- 239000000203 mixture Substances 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- ZTGSNOLGYUVZDM-UHFFFAOYSA-N propan-2-one;1,1,2-trichloro-1,2,2-trifluoroethane Chemical compound CC(C)=O.FC(F)(Cl)C(F)(Cl)Cl ZTGSNOLGYUVZDM-UHFFFAOYSA-N 0.000 description 4
- 125000003652 trifluoroethoxy group Chemical group FC(CO*)(F)F 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- -1 sodium alkoxide Chemical class 0.000 description 2
- VRLJVDPFUDVHMJ-UHFFFAOYSA-N sodium;1,1,2,2,3,3,4-heptafluorobutan-1-olate Chemical compound [Na+].[O-]C(F)(F)C(F)(F)C(F)(F)CF VRLJVDPFUDVHMJ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000004793 2,2,2-trifluoroethoxy group Chemical group FC(CO*)(F)F 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- GZOZHLVVKGWFPK-UHFFFAOYSA-N sodium 1,1,2,2,3-pentafluoropropan-1-olate Chemical compound FCC(C([O-])(F)F)(F)F.[Na+] GZOZHLVVKGWFPK-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/025—Polyphosphazenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US188440A US3888800A (en) | 1971-10-13 | 1971-10-13 | Preparation of phosphazene polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2249461A1 DE2249461A1 (de) | 1973-04-26 |
| DE2249461B2 DE2249461B2 (de) | 1978-08-24 |
| DE2249461C3 true DE2249461C3 (de) | 1979-04-26 |
Family
ID=22693160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2249461A Expired DE2249461C3 (de) | 1971-10-13 | 1972-10-09 | Verfahren zur Herstellung von Polyphosphazenen |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3888800A (ref) |
| JP (1) | JPS5032280B2 (ref) |
| AU (1) | AU475628B2 (ref) |
| BE (1) | BE790016A (ref) |
| BR (1) | BR7207132D0 (ref) |
| CA (1) | CA983648A (ref) |
| DE (1) | DE2249461C3 (ref) |
| ES (1) | ES407597A1 (ref) |
| FR (1) | FR2156306B1 (ref) |
| GB (1) | GB1363339A (ref) |
| IT (1) | IT968876B (ref) |
| NL (1) | NL169485C (ref) |
| SE (1) | SE408904B (ref) |
| ZA (1) | ZA727267B (ref) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3943088A (en) * | 1974-01-25 | 1976-03-09 | The Firestone Tire & Rubber Company | Poly(fluoroalkoxyphosphazenes) |
| CA1105477A (en) * | 1976-03-22 | 1981-07-21 | Edwin J. Quinn | Structurally regulated polyphosphazene copolymers |
| US4129529A (en) * | 1977-08-12 | 1978-12-12 | The Firestone Tire & Rubber Company | Process for the production of phosphazene polymers |
| DE2910794A1 (de) * | 1979-03-19 | 1980-10-02 | Akzo Gmbh | Verfahren zur thermischen polymerisation von phosphazen-polymeren |
| JPS6038307A (ja) * | 1983-08-11 | 1985-02-27 | Nippon Daigaku | 充填用複合材 |
| US4593129A (en) * | 1984-04-18 | 1986-06-03 | Ethyl Corporation | Polyphosphazene process |
| US4724264A (en) * | 1985-04-30 | 1988-02-09 | Otsuka Kagaka Kabushiki Kaisha | Fluoroalkoxy cyclic phosphonitrile esters |
| US4948720A (en) * | 1987-08-20 | 1990-08-14 | Eastman Kodak Company | Photographic element containing polyphosphazene antistatic composition |
| JPH01132635A (ja) * | 1987-11-19 | 1989-05-25 | Nippon Soda Co Ltd | オルガノホスファゼンポリマーの製造法 |
| JPH0258599A (ja) * | 1988-08-23 | 1990-02-27 | Maruwa Bussan Kk | 合成潤滑剤 |
| US4870113A (en) * | 1988-12-23 | 1989-09-26 | Ethyl Corporation | Rigid polyphosphazene foam and process for making same |
| US4945140A (en) * | 1989-06-30 | 1990-07-31 | Ethyl Corporation | Process for preparation of phosphonitrilic fluoroelastomers |
| US4945139A (en) * | 1989-07-24 | 1990-07-31 | Ethyl Corporation | Process for surface treating phosphonitrilic fluoroelastomers |
| US5101002A (en) * | 1989-11-06 | 1992-03-31 | Ethyl Corporation | Cured phosphonitrilic elastomers having alkyl-substituted aryl units |
| JP4184158B2 (ja) * | 2003-06-05 | 2008-11-19 | 旭化成ケミカルズ株式会社 | ホスホニトリル酸エステルの製造法 |
| GB0421167D0 (en) * | 2004-09-23 | 2004-10-27 | Sec Dep For Defence Awe The | Novel energetic polyphosphazenes |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2875230A (en) * | 1956-02-14 | 1959-02-24 | Eastman Kodak Co | Preparation of neutral mixed phosphates from trialkyl phosphates and alcohols |
| US3083224A (en) * | 1961-12-08 | 1963-03-26 | Du Pont | Polyfluoroalkyl phosphates |
| US3271330A (en) * | 1962-01-29 | 1966-09-06 | Minnesota Mining & Mfg | High molecular weight phosphonitrile fluoroesters |
| US3515688A (en) * | 1967-08-30 | 1970-06-02 | Horizons Research Inc | Extreme service phosphonitrile elastomers |
| US3524907A (en) * | 1967-10-26 | 1970-08-18 | American Cyanamid Co | Polyfluoro alkyl esters of polymeric phosphonitrilic acid |
-
0
- BE BE790016D patent/BE790016A/xx not_active IP Right Cessation
-
1971
- 1971-10-13 US US188440A patent/US3888800A/en not_active Expired - Lifetime
-
1972
- 1972-10-09 DE DE2249461A patent/DE2249461C3/de not_active Expired
- 1972-10-11 GB GB4688972A patent/GB1363339A/en not_active Expired
- 1972-10-11 NL NLAANVRAGE7213717,A patent/NL169485C/xx not_active IP Right Cessation
- 1972-10-12 ZA ZA727267A patent/ZA727267B/xx unknown
- 1972-10-12 FR FR7236202A patent/FR2156306B1/fr not_active Expired
- 1972-10-12 SE SE7213175A patent/SE408904B/sv unknown
- 1972-10-12 AU AU47714/72A patent/AU475628B2/en not_active Expired
- 1972-10-12 IT IT30384/72A patent/IT968876B/it active
- 1972-10-12 CA CA153,778A patent/CA983648A/en not_active Expired
- 1972-10-12 BR BR007132/72A patent/BR7207132D0/pt unknown
- 1972-10-13 JP JP47103155A patent/JPS5032280B2/ja not_active Expired
- 1972-10-13 ES ES407597A patent/ES407597A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT968876B (it) | 1974-03-20 |
| FR2156306B1 (ref) | 1975-01-03 |
| ES407597A1 (es) | 1976-01-16 |
| ZA727267B (en) | 1973-06-27 |
| NL169485B (nl) | 1982-02-16 |
| DE2249461A1 (de) | 1973-04-26 |
| DE2249461B2 (de) | 1978-08-24 |
| BE790016A (fr) | 1973-04-12 |
| FR2156306A1 (ref) | 1973-05-25 |
| AU4771472A (en) | 1974-04-26 |
| BR7207132D0 (pt) | 1973-08-30 |
| CA983648A (en) | 1976-02-10 |
| GB1363339A (en) | 1974-08-14 |
| JPS5032280B2 (ref) | 1975-10-18 |
| US3888800A (en) | 1975-06-10 |
| NL169485C (nl) | 1982-07-16 |
| AU475628B2 (en) | 1976-08-26 |
| NL7213717A (ref) | 1973-04-17 |
| SE408904B (sv) | 1979-07-16 |
| JPS4875700A (ref) | 1973-10-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| EGA | New person/name/address of the applicant | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: KOHLER, M., DIPL.-CHEM. DR.RER.NAT., 8000 MUENCHEN GLAESER, J., DIPL.-ING., PAT.-ANW., 2000 HAMBURG |