DE2230227A1 - Blockcopolymere aus dienpolymerisaten und polyalkylenoxid - Google Patents
Blockcopolymere aus dienpolymerisaten und polyalkylenoxidInfo
- Publication number
- DE2230227A1 DE2230227A1 DE19722230227 DE2230227A DE2230227A1 DE 2230227 A1 DE2230227 A1 DE 2230227A1 DE 19722230227 DE19722230227 DE 19722230227 DE 2230227 A DE2230227 A DE 2230227A DE 2230227 A1 DE2230227 A1 DE 2230227A1
- Authority
- DE
- Germany
- Prior art keywords
- block
- block copolymers
- diene
- copolymers according
- polyalkylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001400 block copolymer Polymers 0.000 title claims description 24
- 229920000233 poly(alkylene oxides) Polymers 0.000 title claims description 8
- -1 diene hydrocarbon Chemical class 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000001993 dienes Chemical class 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 239000003999 initiator Substances 0.000 claims description 7
- 230000001588 bifunctional effect Effects 0.000 claims description 5
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 150000003112 potassium compounds Chemical class 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- 239000005062 Polybutadiene Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- IJJSYKQZFFGIEE-UHFFFAOYSA-N naphthalene;potassium Chemical compound [K].C1=CC=CC2=CC=CC=C21 IJJSYKQZFFGIEE-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722230227 DE2230227A1 (de) | 1972-06-21 | 1972-06-21 | Blockcopolymere aus dienpolymerisaten und polyalkylenoxid |
| NL7308061A NL7308061A (enExample) | 1972-06-21 | 1973-06-08 | |
| BE132255A BE800900A (fr) | 1972-06-21 | 1973-06-14 | Copolymeres-blocs obtenus a partir de polymere de dienes et d'oxydes de polyalkylene |
| IT5085173A IT985485B (it) | 1972-06-21 | 1973-06-18 | Copolimeri a blocchi costituiti da polimeri dienici e ossido po lialchilenico e procedimento per la loro preparazione |
| FR7322129A FR2189422A1 (enExample) | 1972-06-21 | 1973-06-18 | |
| GB2922773A GB1425870A (en) | 1972-06-21 | 1973-06-20 | Manufacture of block copolymers from conjugated diene hydrocarbons and alkylene oxides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722230227 DE2230227A1 (de) | 1972-06-21 | 1972-06-21 | Blockcopolymere aus dienpolymerisaten und polyalkylenoxid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2230227A1 true DE2230227A1 (de) | 1974-01-17 |
Family
ID=5848320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722230227 Pending DE2230227A1 (de) | 1972-06-21 | 1972-06-21 | Blockcopolymere aus dienpolymerisaten und polyalkylenoxid |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE800900A (enExample) |
| DE (1) | DE2230227A1 (enExample) |
| FR (1) | FR2189422A1 (enExample) |
| GB (1) | GB1425870A (enExample) |
| IT (1) | IT985485B (enExample) |
| NL (1) | NL7308061A (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4254238A (en) * | 1975-12-01 | 1981-03-03 | E. I. Du Pont De Nemours And Company | Hydrocarbon/ethylene oxide random graft copolymers |
| FR2558473B1 (fr) * | 1984-01-25 | 1987-05-22 | Centre Nat Rech Scient | Copolymeres reticules non ioniques, partiellement hydrophiles, et leur application a la chromatographie d'exclusion en milieu aqueux |
| FR2714386B1 (fr) * | 1993-12-23 | 1996-03-08 | Hutchinson | Film d'élastomère, son procédé de préparation et ses applications. |
-
1972
- 1972-06-21 DE DE19722230227 patent/DE2230227A1/de active Pending
-
1973
- 1973-06-08 NL NL7308061A patent/NL7308061A/xx unknown
- 1973-06-14 BE BE132255A patent/BE800900A/xx unknown
- 1973-06-18 IT IT5085173A patent/IT985485B/it active
- 1973-06-18 FR FR7322129A patent/FR2189422A1/fr not_active Withdrawn
- 1973-06-20 GB GB2922773A patent/GB1425870A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2189422A1 (enExample) | 1974-01-25 |
| IT985485B (it) | 1974-11-30 |
| BE800900A (fr) | 1973-12-14 |
| NL7308061A (enExample) | 1973-12-27 |
| GB1425870A (en) | 1976-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0026916A1 (de) | Verfahren zur Herstellung von Mischungen linearer Dreiblockcopolymerisate sowie Formteile aus diesen | |
| DE1745225B2 (de) | Verfahren zur herstellung von block- copolymerisaten | |
| DE1263002B (de) | Verfahren zur Herstellung von Lithiumaddukten konjugierter Diene | |
| DE2723905C2 (enExample) | ||
| EP0288761B1 (de) | Verfahren zur Herstellung multifunktioneller Initiatoren für die anionische Polymerisation, oligomere multifunktionelle Initiatoren, Verwendung der erhaltenen Polymeren zur Herstellung gegebenenfalls funktionalisierter Polymere und als Prepolymere für andere Harze | |
| DE2829795A1 (de) | Harzartige, radiale-lineare copolymerisatmischungen mit bloecken mit einem hetereogenitaetsindex im bereich von 2,5 - 4 | |
| EP0305909B1 (de) | Bifunktionelle Alkaliverbindungen, Verfahren zu ihrer Herstellung und Verwendung als Polymerisationsinitiatoren | |
| DE2156681C3 (de) | Polymere Massen auf der Basis von Polypropylen | |
| DE2237954C3 (de) | Verfahren zur Herstellung von niedermolekularen Blockcopolymerisaten aus Vinyl- oder Dienmonomeren undAlkylenoxiden | |
| DE1645243B1 (de) | Verfahren zur Herstellung von schlagfesten Polymeren aus vinylaromatischen Verbindungen | |
| DE1595343C3 (de) | Verfahren zum Herstellen scMagfester Styrol-Acrylnitrilmischpolymerisate | |
| DE2230227A1 (de) | Blockcopolymere aus dienpolymerisaten und polyalkylenoxid | |
| DE2239401A1 (de) | Block- bzw. pfropfcopolymere aus polyalkylenoxiden und vinylaromat- oder dienpolymerisaten | |
| EP0477679B1 (de) | Lebende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Telechele | |
| DE2301224A1 (de) | Blockcopolymere auf basis von polyalkylenoxid | |
| EP0595120B1 (de) | Thermoplastische Formmasse | |
| DE883351C (de) | Verfahren zur Herstellung perlfoermiger oder koerniger Polymerisationsprodukte | |
| DE2353314C2 (de) | Kunststoffmassen auf der Basis von hydrierten Blockcopolymeren | |
| EP0797626A1 (de) | Verfahren zur herstellung von schlagzäh modifizierten polystyrol-formmassen | |
| EP0595121B1 (de) | Verfahren zur Herstellung von schlagzähem Polystyrol | |
| EP0292714B1 (de) | Thermoplastische Formmassen auf Basis von Polyphenylenether | |
| DE3537771A1 (de) | Salze mehrwertiger kationen von block-polymerisaten von vinylaromaten und konjugierten dienen | |
| WO1998022518A1 (de) | Kontinuierliches verfahren zur herstellung thermoplastischer formmassen | |
| EP0082399A2 (de) | Verfahren zur Herstellung von Blockcopolymerisaten auf Basis von Ethylencopolymerisaten, Blockcopolymerisate und deren Verwendung als Additive für Thermoplaste und Mineralöle oder als Schmelzhaftkleber | |
| EP0049775A2 (de) | Verfahren zur kontinuierlichen Herstellung von mit Kautschuk modifizierten Polymerisaten von Vinylaromaten |