DE2223186A1 - Verbesserte ABS-Kunststoffe,schlagzaehmachende Vormischungen dafuer und ihre Herstellung - Google Patents
Verbesserte ABS-Kunststoffe,schlagzaehmachende Vormischungen dafuer und ihre HerstellungInfo
- Publication number
- DE2223186A1 DE2223186A1 DE19722223186 DE2223186A DE2223186A1 DE 2223186 A1 DE2223186 A1 DE 2223186A1 DE 19722223186 DE19722223186 DE 19722223186 DE 2223186 A DE2223186 A DE 2223186A DE 2223186 A1 DE2223186 A1 DE 2223186A1
- Authority
- DE
- Germany
- Prior art keywords
- latex
- rubber
- particles
- weight
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 238000004519 manufacturing process Methods 0.000 title claims description 19
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- 239000005060 rubber Substances 0.000 claims description 169
- 229920000126 latex Polymers 0.000 claims description 151
- 239000004816 latex Substances 0.000 claims description 137
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- 239000011145 styrene acrylonitrile resin Substances 0.000 claims description 90
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 86
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- 238000006116 polymerization reaction Methods 0.000 claims description 44
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 17
- -1 vinyl aromatic hydrocarbon Chemical class 0.000 claims description 16
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
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- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims 7
- 150000004808 allyl alcohols Chemical class 0.000 claims 1
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- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 26
- 239000000344 soap Substances 0.000 description 22
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 21
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- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 14
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- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
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- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
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- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 3
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- 239000005720 sucrose Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 229920006328 Styrofoam Polymers 0.000 description 2
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- 229940117913 acrylamide Drugs 0.000 description 2
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- 239000012298 atmosphere Substances 0.000 description 2
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- 125000005605 benzo group Chemical group 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
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- 125000004386 diacrylate group Chemical group 0.000 description 2
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- 239000003792 electrolyte Substances 0.000 description 2
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 2
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- 125000005395 methacrylic acid group Chemical group 0.000 description 2
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- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 229940096992 potassium oleate Drugs 0.000 description 2
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 2
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- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- SDRZFSPCVYEJTP-UHFFFAOYSA-N 1-ethenylcyclohexene Chemical class C=CC1=CCCCC1 SDRZFSPCVYEJTP-UHFFFAOYSA-N 0.000 description 1
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- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
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- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 101100346656 Drosophila melanogaster strat gene Proteins 0.000 description 1
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- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 230000002792 vascular Effects 0.000 description 1
- 230000009278 visceral effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/942—Polymer derived from nitrile, conjugated diene and aromatic co-monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14274071A | 1971-05-12 | 1971-05-12 | |
| US241063A US3879496A (en) | 1971-05-12 | 1972-04-13 | Low rubber, high-flow and high impact ABS plastics, improved rubber toughener for producing same, and method of manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2223186A1 true DE2223186A1 (de) | 1972-12-07 |
Family
ID=26840388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722223186 Withdrawn DE2223186A1 (de) | 1971-05-12 | 1972-05-12 | Verbesserte ABS-Kunststoffe,schlagzaehmachende Vormischungen dafuer und ihre Herstellung |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3879496A (cg-RX-API-DMAC10.html) |
| AU (1) | AU475587B2 (cg-RX-API-DMAC10.html) |
| BE (1) | BE783364A (cg-RX-API-DMAC10.html) |
| CA (1) | CA989990A (cg-RX-API-DMAC10.html) |
| DE (1) | DE2223186A1 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2139458A5 (cg-RX-API-DMAC10.html) |
| GB (1) | GB1396144A (cg-RX-API-DMAC10.html) |
| NL (1) | NL7206407A (cg-RX-API-DMAC10.html) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022733A (en) * | 1975-06-25 | 1977-05-10 | Monsanto Company | Graft polymerization process |
| DE2927572A1 (de) * | 1979-07-07 | 1981-01-22 | Basf Ag | Themoplastische formmassen |
| DE3843371A1 (de) * | 1988-12-23 | 1990-07-05 | Basf Ag | Pfropfpolymerisate |
| DE3901448A1 (de) * | 1989-01-19 | 1990-07-26 | Basf Ag | Emulsionscopolymerisate |
| EP0562088B1 (en) * | 1991-10-11 | 1998-03-25 | Ansell Perry Inc. | Rubber articles having a modified polymer layer of ether and ester units |
| US5570475A (en) * | 1991-10-11 | 1996-11-05 | Ansell Perry Inc. | Surgeon's glove having improved donning properties |
| BR9609295A (pt) | 1995-06-28 | 1999-05-18 | Kimberly Clark Co | Novas substâncias corantes e modificadores de substância corante |
| US6072002A (en) * | 1997-10-21 | 2000-06-06 | Bayer Corporation | Weatherable resinous composition |
| DE10003511A1 (de) * | 2000-01-27 | 2001-08-02 | Basf Ag | Verfahren zur Herstellung schlagzäher Kunststoffe |
| US7638559B2 (en) * | 2005-05-10 | 2009-12-29 | Nova Chemicals Inc. | Expandable resins |
| KR102592891B1 (ko) * | 2017-12-19 | 2023-10-20 | 이네오스 스티롤루션 그룹 게엠베하 | 높은 피로 저항성 abs |
| CN112876609B (zh) * | 2021-01-18 | 2023-04-07 | 万华化学(四川)有限公司 | 一种聚丁二烯胶乳的制备方法、聚丁二烯胶乳及abs |
| CN113831679A (zh) * | 2021-11-01 | 2021-12-24 | 东莞市帝泰新材料有限公司 | 一种高强度abs塑胶颗粒及其制备方法 |
| CN116159968B (zh) * | 2022-12-13 | 2025-04-22 | 沈阳铸研科技有限公司 | 一种防变形工程塑料填充物骨架结构及其应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2614093A (en) * | 1946-05-23 | 1952-10-14 | Goodrich Co B F | Preparation of synthetic polymeric materials |
| US2677674A (en) * | 1953-02-13 | 1954-05-04 | Us Rubber Co | Blends of (1) copolymers of styrene with small amounts of divinylbenzene, (2) high styrene-low butadiene resinous copolymers, and (3) rubbery copolymers of 35-60 per cent butadiene and 65-40 per cent styrene |
| NL222760A (cg-RX-API-DMAC10.html) * | 1956-11-28 | |||
| US3661994A (en) * | 1969-11-14 | 1972-05-09 | Stauffer Chemical Co | Graft polymers of rubber for reinforcing plastics |
| US3657172A (en) * | 1970-02-16 | 1972-04-18 | Stauffer Chemical Co | Suspension emulsion core-shell interpolymers containing vinyl chloride |
| US3663656A (en) * | 1970-06-22 | 1972-05-16 | Monsanto Co | Process for making novel graft copolymer blends |
-
1972
- 1972-04-13 US US241063A patent/US3879496A/en not_active Expired - Lifetime
- 1972-05-03 CA CA141,252A patent/CA989990A/en not_active Expired
- 1972-05-08 AU AU42046/72A patent/AU475587B2/en not_active Expired
- 1972-05-11 GB GB2201572A patent/GB1396144A/en not_active Expired
- 1972-05-12 NL NL7206407A patent/NL7206407A/xx not_active Application Discontinuation
- 1972-05-12 FR FR7216951A patent/FR2139458A5/fr not_active Expired
- 1972-05-12 DE DE19722223186 patent/DE2223186A1/de not_active Withdrawn
- 1972-05-12 BE BE783364A patent/BE783364A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL7206407A (cg-RX-API-DMAC10.html) | 1972-11-14 |
| US3879496A (en) | 1975-04-22 |
| FR2139458A5 (cg-RX-API-DMAC10.html) | 1973-01-05 |
| CA989990A (en) | 1976-05-25 |
| GB1396144A (en) | 1975-06-04 |
| AU475587B2 (en) | 1976-08-26 |
| BE783364A (fr) | 1972-09-01 |
| AU4204672A (en) | 1973-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8130 | Withdrawal |