DE2218104A1 - Verfahren zur Verringerung des Sauerstoffgehalts von Kernbrennstoffen - Google Patents
Verfahren zur Verringerung des Sauerstoffgehalts von KernbrennstoffenInfo
- Publication number
- DE2218104A1 DE2218104A1 DE19722218104 DE2218104A DE2218104A1 DE 2218104 A1 DE2218104 A1 DE 2218104A1 DE 19722218104 DE19722218104 DE 19722218104 DE 2218104 A DE2218104 A DE 2218104A DE 2218104 A1 DE2218104 A1 DE 2218104A1
- Authority
- DE
- Germany
- Prior art keywords
- oxide
- carbon
- oxygen
- reduction
- uranium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 35
- 239000001301 oxygen Substances 0.000 title claims description 34
- 229910052760 oxygen Inorganic materials 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 16
- 239000003758 nuclear fuel Substances 0.000 title description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- 229910052799 carbon Inorganic materials 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 229910000310 actinide oxide Inorganic materials 0.000 claims description 7
- SHZGCJCMOBCMKK-KGJVWPDLSA-N beta-L-fucose Chemical compound C[C@@H]1O[C@H](O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-KGJVWPDLSA-N 0.000 claims description 7
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 7
- 229910052770 Uranium Inorganic materials 0.000 claims description 6
- PSPBAKLTRUOTFX-UHFFFAOYSA-N [O-2].[Pu+4].[U+6].[O-2].[O-2].[O-2].[O-2] Chemical compound [O-2].[Pu+4].[U+6].[O-2].[O-2].[O-2].[O-2] PSPBAKLTRUOTFX-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 description 15
- 229910052739 hydrogen Inorganic materials 0.000 description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 14
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 239000000446 fuel Substances 0.000 description 8
- 229910052786 argon Inorganic materials 0.000 description 5
- 241001300080 Plutonia Species 0.000 description 4
- UTDLAEPMVCFGRJ-UHFFFAOYSA-N plutonium dihydrate Chemical compound O.O.[Pu] UTDLAEPMVCFGRJ-UHFFFAOYSA-N 0.000 description 4
- 229910000439 uranium oxide Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000011946 reduction process Methods 0.000 description 3
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 3
- 229910003452 thorium oxide Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- KLWPQZMETSOYMP-UHFFFAOYSA-N [O-2].[Pu+4].[Th+4].[O-2].[O-2].[O-2] Chemical compound [O-2].[Pu+4].[Th+4].[O-2].[O-2].[O-2] KLWPQZMETSOYMP-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- ZPTAOTXKALLEEN-UHFFFAOYSA-N plutonium thorium Chemical compound [Th].[Pu] ZPTAOTXKALLEEN-UHFFFAOYSA-N 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000002296 pyrolytic carbon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G56/00—Compounds of transuranic elements
- C01G56/004—Compounds of plutonium
- C01G56/005—Oxides; Hydroxides
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
- G21C3/623—Oxide fuels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13625471A | 1971-04-21 | 1971-04-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2218104A1 true DE2218104A1 (de) | 1972-11-02 |
Family
ID=22472036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722218104 Pending DE2218104A1 (de) | 1971-04-21 | 1972-04-14 | Verfahren zur Verringerung des Sauerstoffgehalts von Kernbrennstoffen |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3717582A (enExample) |
| AU (1) | AU457156B2 (enExample) |
| CA (1) | CA977544A (enExample) |
| DE (1) | DE2218104A1 (enExample) |
| FR (1) | FR2133903A1 (enExample) |
| GB (1) | GB1360341A (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5419886A (en) * | 1994-03-08 | 1995-05-30 | Rockwell International Corporation | Method for generation of finely divided reactive plutonium oxide powder |
| US5641435A (en) * | 1995-09-22 | 1997-06-24 | General Electric Company | Control of residual gas content of nuclear fuel |
| US8056370B2 (en) * | 2002-08-02 | 2011-11-15 | 3M Innovative Properties Company | Method of making amorphous and ceramics via melt spinning |
| US20140270041A1 (en) * | 2013-03-13 | 2014-09-18 | Idaho State University | Actinide Oxide Structures For Monitoring A Radioactive Environment Wirelessly |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL299042A (enExample) * | 1962-10-10 | |||
| US3374178A (en) * | 1965-05-03 | 1968-03-19 | Ca Atomic Energy Ltd | Doped hypostoichiometric dioxide nuclear fuel composition and method of preparation |
| US3462371A (en) * | 1967-03-09 | 1969-08-19 | Ca Atomic Energy Ltd | Nuclear reactor fuel |
-
1971
- 1971-04-21 US US00136254A patent/US3717582A/en not_active Expired - Lifetime
-
1972
- 1972-03-06 GB GB1044072A patent/GB1360341A/en not_active Expired
- 1972-03-06 CA CA136,337A patent/CA977544A/en not_active Expired
- 1972-04-14 DE DE19722218104 patent/DE2218104A1/de active Pending
- 1972-04-19 FR FR7213814A patent/FR2133903A1/fr not_active Withdrawn
- 1972-04-21 AU AU41425/72A patent/AU457156B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1360341A (en) | 1974-07-17 |
| CA977544A (en) | 1975-11-11 |
| US3717582A (en) | 1973-02-20 |
| FR2133903A1 (enExample) | 1972-12-01 |
| AU4142572A (en) | 1973-10-25 |
| AU457156B2 (en) | 1975-01-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |