DE2135530C3 - Verfahren zur Gewinnung von tertiär Butylhydroperoxid durch fraktionierte Destillation eines neutralisierten Isobutanoxidationsproduktes bei Atmosphärendruck in Gegenwart von Wasserdampf als Verdünnungsmittel - Google Patents
Verfahren zur Gewinnung von tertiär Butylhydroperoxid durch fraktionierte Destillation eines neutralisierten Isobutanoxidationsproduktes bei Atmosphärendruck in Gegenwart von Wasserdampf als VerdünnungsmittelInfo
- Publication number
- DE2135530C3 DE2135530C3 DE2135530A DE2135530A DE2135530C3 DE 2135530 C3 DE2135530 C3 DE 2135530C3 DE 2135530 A DE2135530 A DE 2135530A DE 2135530 A DE2135530 A DE 2135530A DE 2135530 C3 DE2135530 C3 DE 2135530C3
- Authority
- DE
- Germany
- Prior art keywords
- tertiary butyl
- butyl hydroperoxide
- diluent
- atmospheric pressure
- oxidation product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 title claims description 23
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 title claims description 16
- 230000003647 oxidation Effects 0.000 title claims description 12
- 238000007254 oxidation reaction Methods 0.000 title claims description 12
- 238000000034 method Methods 0.000 title claims description 11
- 239000003085 diluting agent Substances 0.000 title claims description 9
- 239000001282 iso-butane Substances 0.000 title claims description 8
- 238000004508 fractional distillation Methods 0.000 title claims description 3
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 238000004821 distillation Methods 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- LSRCLRQQXICZGK-UHFFFAOYSA-N O.C(CCC)OO Chemical group O.C(CCC)OO LSRCLRQQXICZGK-UHFFFAOYSA-N 0.000 description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001944 continuous distillation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/36—Azeotropic distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/42—Regulation; Control
- B01D3/4211—Regulation; Control of columns
- B01D3/4222—Head- and side stream
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6890770A | 1970-09-02 | 1970-09-02 | |
| US304278A US3864216A (en) | 1970-09-02 | 1972-11-06 | Tertiary butyl hydroperoxide purification by distillation at atmospheric pressure with an inert diluent gas |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2135530A1 DE2135530A1 (de) | 1972-03-09 |
| DE2135530B2 DE2135530B2 (de) | 1979-05-17 |
| DE2135530C3 true DE2135530C3 (de) | 1980-01-24 |
Family
ID=26749505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2135530A Expired DE2135530C3 (de) | 1970-09-02 | 1971-07-15 | Verfahren zur Gewinnung von tertiär Butylhydroperoxid durch fraktionierte Destillation eines neutralisierten Isobutanoxidationsproduktes bei Atmosphärendruck in Gegenwart von Wasserdampf als Verdünnungsmittel |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3864216A (enExample) |
| BE (1) | BE770913A (enExample) |
| DE (1) | DE2135530C3 (enExample) |
| FR (1) | FR2105840A5 (enExample) |
| GB (1) | GB1334459A (enExample) |
| NL (1) | NL177212C (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53116314A (en) * | 1977-03-19 | 1978-10-11 | Mitsui Petrochem Ind Ltd | Separation of acetic acid and water |
| US4151048A (en) * | 1977-06-06 | 1979-04-24 | Halcon Research And Development Corporation | Recovery of alkylene glycols by azeotropic distillation |
| US4257852A (en) * | 1979-01-15 | 1981-03-24 | Atlantic Richfield Company | Distillation of aqueous tertiary butyl hydroperoxide |
| DE2916572A1 (de) * | 1979-04-24 | 1980-11-13 | Peroxid Chemie Gmbh | Verfahren zur destillativen trennung von tert.-alkylhydroperoxiden und di- tert.-alkylperoxiden |
| US4584413A (en) * | 1983-09-14 | 1986-04-22 | Atlantic Richfield Company | Purification of tertiary butyl hydroperoxide containing primary and secondary alkyl hydroperoxide contaminants |
| US4891101A (en) * | 1988-11-23 | 1990-01-02 | Arco Chemical Technology, Inc. | Purification of tertiary hydroperoxides containing primary and secondary hydroperoxide contaminants |
| US5151530A (en) * | 1989-08-30 | 1992-09-29 | Texaco Chemical Company | Treatment of tertiary butyl hydroperoxide distillation fraction to remove acidic contaminants |
| US5104493B1 (en) * | 1991-01-24 | 1995-08-15 | Arco Chem Tech | Tertiary butyl hydroperoxide concentration |
| EP0514717B1 (de) * | 1991-05-21 | 1994-12-07 | Bayer Ag | Verfahren zum Trennen von Mehrstoffsystemen mit zwischensiedenden Substanzen in Trenn-kolonnen mit Seitenabzug |
| US5345008A (en) * | 1993-06-09 | 1994-09-06 | Sun Company, Inc. (R&M) | Decomposition of organic hydroperoxides with nitrated porphyrin complexes |
| US5554796A (en) * | 1994-04-29 | 1996-09-10 | Arco Chemical Technology, L.P. | Removal of primary and secondary hydroperoxide impurities from tertiary hydroperoxides |
| US5453548A (en) * | 1994-10-25 | 1995-09-26 | Arco Chemical Technology, L.P. | Purification of ditertiary butyl peroxide |
| FR2815956B1 (fr) * | 2000-10-26 | 2003-05-23 | Atofina | Procede d'obtention d'hydrazine anhydre et dispositif pour sa mise en oeuvre |
| DE102014219182A1 (de) * | 2014-09-23 | 2016-03-24 | Wacker Chemie Ag | Regelung einer Destillationskolonne |
| WO2018071272A1 (en) * | 2016-10-12 | 2018-04-19 | Lyondell Chemical Technology, L. P. | Production of tert- butyl hydroperoxide solution and process to form products therefrom |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2383919A (en) * | 1944-05-23 | 1945-08-28 | Shell Dev | Recovery of organic peroxides |
| US2845461A (en) * | 1956-04-12 | 1958-07-29 | Shell Dev | Non-catalytic liquid phase isobutane oxidation |
| US3478108A (en) * | 1966-02-21 | 1969-11-11 | Atlantic Richfield Co | Isobutane oxidation |
| US3427229A (en) * | 1967-05-22 | 1969-02-11 | Halcon International Inc | Recovery of tertiary-butyl hydroperoxide by fractionation in the presence of a refluxing agent |
| US3449217A (en) * | 1968-01-05 | 1969-06-10 | Halcon International Inc | Process of buffering a neutralized t-butyl hydroperoxide during distillation |
-
1971
- 1971-07-07 GB GB3197771A patent/GB1334459A/en not_active Expired
- 1971-07-15 DE DE2135530A patent/DE2135530C3/de not_active Expired
- 1971-08-03 FR FR7128431A patent/FR2105840A5/fr not_active Expired
- 1971-08-04 BE BE770913A patent/BE770913A/xx not_active IP Right Cessation
- 1971-08-12 NL NLAANVRAGE7111152,A patent/NL177212C/xx not_active IP Right Cessation
-
1972
- 1972-11-06 US US304278A patent/US3864216A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BE770913A (fr) | 1972-02-04 |
| NL177212C (nl) | 1985-08-16 |
| NL177212B (nl) | 1985-03-18 |
| DE2135530B2 (de) | 1979-05-17 |
| NL7111152A (enExample) | 1972-03-06 |
| DE2135530A1 (de) | 1972-03-09 |
| US3864216A (en) | 1975-02-04 |
| GB1334459A (en) | 1973-10-17 |
| FR2105840A5 (enExample) | 1972-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |