DE2112223B2 - Verfahren zur Herstellung von synthetischem Mordenit und dessen Verwendung - Google Patents

Verfahren zur Herstellung von synthetischem Mordenit und dessen Verwendung

Info

Publication number
DE2112223B2
DE2112223B2 DE2112223A DE2112223A DE2112223B2 DE 2112223 B2 DE2112223 B2 DE 2112223B2 DE 2112223 A DE2112223 A DE 2112223A DE 2112223 A DE2112223 A DE 2112223A DE 2112223 B2 DE2112223 B2 DE 2112223B2
Authority
DE
Germany
Prior art keywords
mordenite
sio
acid
silica
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE2112223A
Other languages
German (de)
English (en)
Other versions
DE2112223A1 (de
DE2112223C3 (enExample
Inventor
Leo Ernest Hinsdale Ill. Pollitzer (V.St.A.)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of DE2112223A1 publication Critical patent/DE2112223A1/de
Publication of DE2112223B2 publication Critical patent/DE2112223B2/de
Application granted granted Critical
Publication of DE2112223C3 publication Critical patent/DE2112223C3/de
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2861—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of mordenite type, e.g. ptilolite or dachiardite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE2112223A 1970-03-16 1971-03-13 Verfahren zur Herstellung von synthetischem Mordenit und dessen Verwendung Granted DE2112223B2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2012570A 1970-03-16 1970-03-16

Publications (3)

Publication Number Publication Date
DE2112223A1 DE2112223A1 (de) 1971-10-07
DE2112223B2 true DE2112223B2 (de) 1973-12-20
DE2112223C3 DE2112223C3 (enExample) 1974-08-15

Family

ID=21796903

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2112223A Granted DE2112223B2 (de) 1970-03-16 1971-03-13 Verfahren zur Herstellung von synthetischem Mordenit und dessen Verwendung

Country Status (3)

Country Link
DE (1) DE2112223B2 (enExample)
FR (1) FR2084704A5 (enExample)
GB (1) GB1334928A (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0040104A1 (en) * 1980-05-14 1981-11-18 Toa Nenryo Kogyo Kabushiki Kaisha Synthetic crystalline aluminosilicate composition and method for the production thereof

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ209982A (en) * 1983-11-03 1987-04-30 Mobil Oil Corp Zeolite catalyst treated with aluminium-extracting reagent to produce enhanced activity
JPS62132725A (ja) * 1985-12-04 1987-06-16 Toyo Soda Mfg Co Ltd 水素イオン交換型脱アルミニウムモルデナイトの製造方法
US5198595A (en) * 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
US4891448A (en) * 1987-11-23 1990-01-02 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers
US5243116A (en) * 1987-11-23 1993-09-07 The Dow Chemical Company Alkylation of aromatic compounds
FR2638157B1 (fr) * 1988-10-26 1991-04-19 Inst Francais Du Petrole Procede de production d'alkylbenzenes utilisant un catalyseur a base de mordenite modifiee
FR2656300B1 (fr) * 1989-12-21 1993-06-11 Inst Francais Du Petrole Procede de production de phenol.
JPH06239771A (ja) * 1989-12-22 1994-08-30 Dow Chem Co:The ベンゼンもしくは置換ベンゼンのアルキル化またはアルキル化ベンゼンのトランスアルキル化の方法および触媒組成物
FR2664264B1 (fr) * 1990-07-09 1992-09-18 Inst Francais Du Petrole Procede de production de 2- et 3-phenylalcanes utilisant un catalyseur a base de mordenite modifiee.
FR2665436B1 (fr) * 1990-07-31 1992-10-16 Inst Francais Du Petrole Procede de production de 2- et 3-phenylalcanes utilisant un catalyseur a base d'une mordenite particuliere.
CA2111101A1 (en) * 1991-06-21 1993-01-07 Guo S. J. Lee Alkylation of aromatic compounds
FR2761905B1 (fr) 1997-04-09 1999-05-14 Inst Francais Du Petrole Catalyseur a base de mordenite desaluminee contenant au moins un metal des groupes vi, vii et viii, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures aromatiques
CN112661167B (zh) * 2019-10-16 2022-11-08 中国科学院大连化学物理研究所 一种纳米丝光沸石分子筛的合成方法及分子筛
CN112591761B (zh) * 2021-02-05 2022-05-17 福州大学 一种具有贯穿梯级孔的钠菱沸石的绿色制备方法
CN113694960B (zh) * 2021-08-20 2023-05-30 常州工学院 一种用于合成5-乙氧基甲基糠醛的ZrCu-MOR沸石及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0040104A1 (en) * 1980-05-14 1981-11-18 Toa Nenryo Kogyo Kabushiki Kaisha Synthetic crystalline aluminosilicate composition and method for the production thereof

Also Published As

Publication number Publication date
DE2112223A1 (de) 1971-10-07
DE2112223C3 (enExample) 1974-08-15
GB1334928A (en) 1973-10-24
FR2084704A5 (enExample) 1971-12-17

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977
EHJ Ceased/non-payment of the annual fee