DE2103807A1 - Umwandlung von schweren Erdöl Ausgangs materialien - Google Patents
Umwandlung von schweren Erdöl Ausgangs materialienInfo
- Publication number
- DE2103807A1 DE2103807A1 DE19712103807 DE2103807A DE2103807A1 DE 2103807 A1 DE2103807 A1 DE 2103807A1 DE 19712103807 DE19712103807 DE 19712103807 DE 2103807 A DE2103807 A DE 2103807A DE 2103807 A1 DE2103807 A1 DE 2103807A1
- Authority
- DE
- Germany
- Prior art keywords
- bed
- particles
- temperature
- oxygen
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 18
- 239000003208 petroleum Substances 0.000 title claims description 10
- 239000002994 raw material Substances 0.000 title description 4
- 239000002245 particle Substances 0.000 claims description 81
- 239000007789 gas Substances 0.000 claims description 73
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 39
- 229910052760 oxygen Inorganic materials 0.000 claims description 39
- 239000001301 oxygen Substances 0.000 claims description 39
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 31
- 229910052717 sulfur Inorganic materials 0.000 claims description 31
- 239000011593 sulfur Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 28
- 239000007858 starting material Substances 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 14
- 238000012546 transfer Methods 0.000 claims description 12
- 230000007423 decrease Effects 0.000 claims description 11
- 239000000292 calcium oxide Substances 0.000 claims description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 230000002829 reductive effect Effects 0.000 claims description 6
- 230000003068 static effect Effects 0.000 claims description 6
- 230000003247 decreasing effect Effects 0.000 claims description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 4
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000002243 precursor Substances 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 238000010790 dilution Methods 0.000 claims 1
- 239000012895 dilution Substances 0.000 claims 1
- 239000000571 coke Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 16
- 239000012535 impurity Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- 239000012808 vapor phase Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 240000007313 Tilia cordata Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000020169 heat generation Effects 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 238000012806 monitoring device Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical compound [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/16—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
- C10B55/02—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials
- C10B55/04—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials
- C10B55/08—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials in dispersed form
- C10B55/10—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials in dispersed form according to the "fluidised bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/005—Coking (in order to produce liquid products mainly)
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Treating Waste Gases (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3824/70A GB1280375A (en) | 1970-01-27 | 1970-01-27 | Conversion of heavy hydrocarbon feedstocks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2103807A1 true DE2103807A1 (de) | 1971-08-05 |
Family
ID=9765630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712103807 Withdrawn DE2103807A1 (de) | 1970-01-27 | 1971-01-27 | Umwandlung von schweren Erdöl Ausgangs materialien |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3707462A (enExample) |
| JP (1) | JPS5411321B1 (enExample) |
| BE (1) | BE762042A (enExample) |
| CA (1) | CA948582A (enExample) |
| DE (1) | DE2103807A1 (enExample) |
| FR (1) | FR2077358B1 (enExample) |
| GB (1) | GB1280375A (enExample) |
| NL (1) | NL169342C (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5139644B2 (enExample) * | 1972-11-30 | 1976-10-29 | ||
| JPS5213523B2 (enExample) * | 1973-06-05 | 1977-04-15 | ||
| US4054420A (en) * | 1974-04-11 | 1977-10-18 | Occidental Petroleum Corporation | Process for the desulfurization of carbonaceous fuels with aqueous caustic and oxygen |
| DE2508707C2 (de) * | 1975-02-28 | 1982-09-23 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zum Behandeln von bei der Schwelung von Ölschiefer entstehenden Dämpfen |
| US4007092A (en) * | 1975-03-18 | 1977-02-08 | Exxon Research And Engineering Company | Process for producing low sulfur coke |
| US4051016A (en) * | 1976-01-27 | 1977-09-27 | Exxon Research & Engineering Co. | Fluid coking with H2 S addition |
| US4058451A (en) * | 1976-08-23 | 1977-11-15 | Uop Inc. | Combination process for producing high quality metallurgical coke |
| CA1156953A (en) * | 1979-06-08 | 1983-11-15 | Michael A. Kessick | Lime addition to heavy crude oils prior to coking |
| US4309398A (en) * | 1979-10-01 | 1982-01-05 | The United States Of America As Represented By The United States Department Of Energy | Conversion of alkali metal sulfate to the carbonate |
| US4305809A (en) * | 1980-03-06 | 1981-12-15 | Mobil Oil Corporation | Fixed sulfur petroleum coke fuel and method for its production |
| US4479804A (en) * | 1980-03-06 | 1984-10-30 | Mobil Oil Corporation | Fixed sulfur petroleum coke fuel and method for its production |
| US4346064A (en) * | 1980-12-12 | 1982-08-24 | Dorr-Oliver Incorporated | Decontamination of combustion gases in fluidized bed incinerators |
| GB2096120B (en) * | 1981-03-24 | 1984-08-30 | Exxon Research Engineering Co | Process for producing co2 |
| ATE18253T1 (de) * | 1981-08-21 | 1986-03-15 | Kiyoshige Hayashi | Raffinationsprozess zur ausbeutesteigerung von destillaten aus schweren erdoeleinsaetzen. |
| US4418008A (en) * | 1982-02-24 | 1983-11-29 | Exxon Research And Engineering Co. | Process for increasing the activity of perovskite catalysts and hydrocarbon treating processes using the activated catalyst |
| US4411772A (en) * | 1982-02-24 | 1983-10-25 | Exxon Research And Engineering Co. | Fluid coking with the addition of perovskite-containing catalysts |
| US4412911A (en) * | 1982-02-24 | 1983-11-01 | Exxon Research And Engineering Co. | Process for reactivating perovskite catalysts and hydrocarbon treating processes utilizing the reactivated catalysts |
| US4414099A (en) * | 1982-09-13 | 1983-11-08 | Exxon Research And Engineering Co. | Fluid coking with the addition of alkaline earth metal ferrite-containing catalysts |
| US4497705A (en) * | 1983-08-17 | 1985-02-05 | Exxon Research & Engineering Co. | Fluid coking with solvent separation of recycle oil |
| JPS60248793A (ja) * | 1984-05-22 | 1985-12-09 | Fuji Standard Res Kk | 重質油の熱分解法 |
| US4631025A (en) * | 1985-08-20 | 1986-12-23 | Koch Carbon Inc. | Calcining process using fluid coke fuel |
| US4801402A (en) * | 1985-11-12 | 1989-01-31 | Texaco Inc. | Partial oxidation process |
| US20070031311A1 (en) * | 2003-06-23 | 2007-02-08 | Anthony Edward J | Regeneration of calcium oxide or calcium carbonate from waste calcium sulphide |
| US20040258592A1 (en) * | 2003-06-23 | 2004-12-23 | Anthony Edward J. | Regeneration of calcium oxide or calcium carbonate from waste calcium sulphide |
| US20050135997A1 (en) | 2003-12-19 | 2005-06-23 | Wellington Scott L. | Systems and methods of producing a crude product |
| US8066949B2 (en) * | 2008-09-26 | 2011-11-29 | Exxonmobil Research & Engineering Company | Scrubber for fluid coker unit |
| US20150368572A1 (en) * | 2014-06-20 | 2015-12-24 | Exxonmobil Research And Engineering Company | Fluidized bed coking with fuel gas production |
| CN106482494A (zh) * | 2016-11-15 | 2017-03-08 | 福建省古田君益佳农业开发有限公司 | 一种烘干装置 |
| WO2022241338A1 (en) | 2021-05-11 | 2022-11-17 | Exxonmobil Upstream Research Company | Polyolefin-coke composite granules as a hydraulic fracturing proppant |
| WO2023168192A1 (en) | 2022-03-04 | 2023-09-07 | Exxonmobil Research And Engineering Company | Proppants derived from crosslinking mixed aromatic resins |
| US12521764B2 (en) | 2024-06-19 | 2026-01-13 | ExxonMobil Technology and Engineering Company | Methods for preparing petroleum coke proppant particles for hydraulic fracturing |
-
1970
- 1970-01-27 GB GB3824/70A patent/GB1280375A/en not_active Expired
-
1971
- 1971-01-25 CA CA103,573A patent/CA948582A/en not_active Expired
- 1971-01-25 US US109124A patent/US3707462A/en not_active Expired - Lifetime
- 1971-01-25 NL NLAANVRAGE7100948,A patent/NL169342C/xx not_active IP Right Cessation
- 1971-01-26 BE BE762042A patent/BE762042A/xx not_active IP Right Cessation
- 1971-01-26 FR FR717102537A patent/FR2077358B1/fr not_active Expired
- 1971-01-27 JP JP279171A patent/JPS5411321B1/ja active Pending
- 1971-01-27 DE DE19712103807 patent/DE2103807A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| NL7100948A (enExample) | 1971-07-29 |
| NL169342B (nl) | 1982-02-01 |
| FR2077358A1 (enExample) | 1971-10-22 |
| CA948582A (en) | 1974-06-04 |
| US3707462A (en) | 1972-12-26 |
| FR2077358B1 (enExample) | 1974-06-21 |
| BE762042A (fr) | 1971-07-26 |
| JPS5411321B1 (enExample) | 1979-05-14 |
| GB1280375A (en) | 1972-07-05 |
| NL169342C (nl) | 1982-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8130 | Withdrawal |