DE2101326A1 - - Google Patents

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Publication number
DE2101326A1
DE2101326A1 DE19712101326 DE2101326A DE2101326A1 DE 2101326 A1 DE2101326 A1 DE 2101326A1 DE 19712101326 DE19712101326 DE 19712101326 DE 2101326 A DE2101326 A DE 2101326A DE 2101326 A1 DE2101326 A1 DE 2101326A1
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DE
Germany
Prior art keywords
solvent
film
polymer
textile material
weight
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Pending
Application number
DE19712101326
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German (de)
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Publication date
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Publication of DE2101326A1 publication Critical patent/DE2101326A1/de
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/922—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents hydrocarbons
    • D06P1/924—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/465—Coatings containing composite materials
    • C03C25/475—Coatings containing composite materials containing colouring agents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/04—Floor or wall coverings; Carpets

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Carpets (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Treatment Of Fiber Materials (AREA)

Description

Dr. Michael HannDr. Michael Hann

Patentanwalt 635 Bad NauheimPatent attorney 635 Bad Nauheim

Burgallee 12 b Telefon (06032) 6237Burgallee 12 b Telephone (06032) 6237

11. Januar 1971January 11, 1971

H / W (291) 14,545 11B"H / W (291) 14,545 11 B "

The Dow Chemical Company, Midland, Michigan, V.St.A.The Dow Chemical Company, Midland, Michigan, V.St.A. VERFAHREN ZUM FIXIEREN VON TUFTINGTEXTILIENMETHOD OF FIXING TUFTING TEXTILES

Diese Erfindung betrifft ein Verfahren zum Fixieren von Tuftingtextilien, bei dem ein filmbildendes Material auf die Rückseite des Texti!materials aufgetragen wird.This invention relates to a method of securing tufted fabrics in which a film-forming material is applied to the back of the textile material.

Es ist bekannt, filmbildende Materialien auf die Rückseite von Textilien aufzutragen, um die Büschel bzw. Noppen bzw^ Fadenschlingen (tufts) eines Tuftinggewebes auf einem Basismaterial'(scrim) zu befestigen. In der angelsächsischen Literatur werden derartige Verfahren als "stitch-locking" oder "tuft-locking" von Textilien bezeichnet. Im allgemeinen wird als filmbildendes Material ein Latex eines synthetischen organischen Polymeren, beispielsweise eines Styrolbutadien-Mischpolymeren verwendet. Obwohl nach den bekannten Verfahren bei manchen Textilien eine befriedigende Fixierung möglich ist, treten bei anderen Textilien Schwierigkeiten auf, z.B. bei Tufting-Teppichen aus Polyamid" mit einem PolypropylenrückenνIt is known to apply film-forming materials to the back of textiles in order to remove the tufts or To fasten knobs or thread loops (tufts) of a tufted fabric on a base material '(scrim). In In the Anglo-Saxon literature, such processes are referred to as "stitch-locking" or "tuft-locking" of textiles. Generally used as film-forming Material used is a latex of a synthetic organic polymer, for example a styrene-butadiene copolymer. Although according to the known method at A satisfactory fixation is possible for some textiles, difficulties arise with other textiles, e.g. with Tufted carpets made of polyamide "with a polypropylene backing

Ausserdem ist es nachteilig, dass bei Verwendung von wässrigen Latices lange Trocknungszeiten wegen des hohen Wärmebedarfs für die Verdampfung des Wassers erforderlich sind.In addition, it is disadvantageous that when using aqueous latices, long drying times because of the high Heat demand for evaporation of the water are required.

Nach dieser Erfindung kann man in einfacher und fortschrittlicher Weise Tuftingtextilien fixieren, indem man die Rückseite des Textilmaterials mit einer Lösung eines filmbildenden Stoffes, z.B. eines synthetischen organischen Polymeren,According to this invention, tufted textiles can be fixed in a simple and advanced manner by treating the reverse side of the textile material with a solution of a film-forming substance, e.g. a synthetic organic polymer,

109835/1628109835/1628

in einem Halogenkohlenstoff- oder Halogenkohlenwasserstoff-Lösungsmittel, das bei einer Temperatur im Bereich von 5 bis 125° C siedet, benetzt und das Lösungsmittel durch Erwärmen des Textilmaterials im Dampf des Lösungsmittels, vorzugsweise im überhitzten Dampf dieses Lösungsmittels, entfernt.in a halocarbon or halocarbon solvent at a temperature in the range boils from 5 to 125 ° C, wets and the solvent is removed by heating the textile material in the vapor of the solvent, preferably in the superheated vapor of this solvent.

Gute Ergebnisse werden-erhalten, wenn man als Lösungsmittel halogenierte niedrigere Kohlenwasserstoffe verwendet, wie z.B. chlorierte, fluorierte und gemischt chlorfluorierte, bromfluorierte oder chlor-bromfluorierte Methane, Äthane, Äthylene, Propane, Propylene, Butane und Butylene. Besonders geeignet sind Methylenchlorid, 1,1,1-Trichloräthan, Trichloräthylen und Perchloräthylen.Good results have been obtained using halogenated lower hydrocarbons, such as chlorinated, fluorinated and mixed, as solvents chlorofluorinated, bromofluorinated or chlorinated bromofluorinated Methane, ethane, ethylene, propane, propylene, butane and butylene. Methylene chloride, 1,1,1-trichloroethane, trichlorethylene and perchlorethylene are particularly suitable.

Als filmbildender Stoff kann jeder filmbildende Stoff verwendet werden, der in dem Lösungsmittel löslich ist. Geeignete Beispiele schließen ein: Polyäthylen, chloriertes Polyäthylen, Polypropylen und Mischpolymere, wie Mischpolymere aus Vinylchlorid und Vinylidenchlorid, z.B. Mischpolymere aus 25 bis 80 Gew.-% Vinylchlorid und 75 bis 20 Gew,-% Vinylidenchlorid. Die Vinylchlorid/Vinylidenchlorid-Mischpolyaere sind für die Tuftingfixierung von Tuftingteppichen aus Polyamiden auf einem Substrat aus Polypropylen besonders geeignet.Any film-forming substance that is soluble in the solvent can be used as the film-forming substance. Suitable examples include: polyethylene, chlorinated Polyethylene, polypropylene and copolymers such as copolymers of vinyl chloride and vinylidene chloride, e.g. copolymers of 25 to 80% by weight of vinyl chloride and 75 to 20 % By weight vinylidene chloride. The vinyl chloride / vinylidene chloride mixed polymers are particularly suitable for tufting tufted carpets made of polyamides on a substrate made of polypropylene.

In den folgenden Beispielen wird die Erfindung noch näher erläutert.The invention is explained in more detail in the following examples.

Beispiel IiExample ii

Die Rückseite eines Tufting-Textllmaterials wird mit einer 6 Gew.-%igen Lösung eines Mischpolymeren aus 80 Gew. -% Vinylchlorid und 20 Gew.-% Vinylidenchlorid in 1,1,1-Trichloräthan besprüht. Das Textilmaterial wird dann durch eine Zone mit überhitztem Dampf von 1,1,1-Trichloräthan geführt. Man erhält ein trocknes Textilmaterial, das 2,5 Gew.-% des Mischpolymeren, bezogen auf das Gewicht des Textilmaterials, enthält. Das behandelte Gewebe zeigt eine gute Fixierung der einzelnen Büschel oder Noppen.The back of a tufted textile material is sprayed with a 6% strength by weight solution of a mixed polymer of 80% by weight vinyl chloride and 20% by weight vinylidene chloride in 1,1,1-trichloroethane. The textile material is then through a Zone with superheated steam led by 1,1,1-trichloroethane. A dry textile material is obtained which contains 2.5% by weight of the copolymer, based on the weight of the textile material, contains. The treated tissue shows good fixation of the individual tufts or knobs.

109835/1628109835/1628

210132B210132B

Beispiel 2:Example 2:

Bei diesem Beispiel wird die Rückseite eines nicht-fixierten Teppichs aus Polyamid, der ein· Rücken (scrim) aus Polypropylen besitzt, mit einer 10%igen Lösung eines Mischpolymeren aus 80 Gew.-% Vinylchlorid und 20 Gew.-% Vinylidenchlorid in 1,1,1-Trichloräthan behandelt. Nach der Entfernung des Lösungsmittels im überhitzten Lösungsmitteldampf erhält man einen Teppich, bei dem die Büschel oder Noppen fest auf dem Substrat fixiert .sind. Die Fixierung ist besser als mit den üblichen Latexzubereitungen.In this example, the back of a non-pinned Carpet made of polyamide, which has a back (scrim) made of polypropylene, with a 10% solution of a copolymer from 80 wt .-% vinyl chloride and 20 wt .-% vinylidene chloride treated in 1,1,1-trichloroethane. After removing the Solvent in the superheated solvent vapor results in a carpet in which the tufts or knobs are tight are fixed on the substrate. The fixation is better than with the usual latex preparations.

109835/162 8109835/162 8

Claims (7)

Patentansprüche tClaims t 1. Verfahren zum Fixieren von Tuftingtextilien rait einem fumbildenden Material, dadurch gekennzeichnet, dass die Rückseite des Textilmaterial mit einer Lösung eines fumbildenden Materials in einem Halogenkohlenstoff- oder Halogenkohlenwasserstoff-Lösungsmittel, das bei einer Temperatur im Bereich von 5 bis 125° C siedet, benetzt wird und das Lösungsmittel durch Erwärmen des Textilmaterial im Dampf des Lösungsmittels entfernt wird.1. Method for fixing tufted textiles in place film-forming material, characterized in that the back of the textile material with a solution of a film-forming material in a halocarbon or a halocarbon solvent which is at a temperature in the range of 5 to 125 ° C boils, is wetted and the solvent is heated by heating the textile material in the vapor of the solvent Will get removed. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der Dampf des Lösungsmittels überhitzt 1st.2. The method according to claim 1, characterized in that the vapor of the solvent is superheated. 3. Verfahren nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass als Lösungsmittel Methylenchlorid, 1,1,1-Trichloräthan, Trichlorethylen oder Perchloräthylen verwendet wird.3. The method according to any one of claims 1 or 2, characterized in that that the solvent methylene chloride, 1,1,1-trichloroethane, trichlorethylene or perchlorethylene is used. 4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass als filmbildender Stoff ein synthetisches organisches Polymeres verwendet wird.4. The method according to any one of claims 1 to 3, characterized in that that a synthetic organic polymer is used as a film-forming substance. 5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, dass als Polymeres ein Vinylchlorid/Vinylidenchlorid-Mischpolymeres verwendet wird.5. The method according to claim 4, characterized in that a vinyl chloride / vinylidene chloride mixed polymer as the polymer is used. 6. Verfahren nach einem der Ansprüche 4 oder 5, dadurch gekennzeichnet, dass als Polymeres ein Mischpolymeres aus 25 bis 80 Gew.-% Vinylchlorid und 75 bis 20 Gew.-% Vinylidenchlorid verwendet wird.6. The method according to any one of claims 4 or 5, characterized in that that the polymer is a mixed polymer of 25 to 80% by weight of vinyl chloride and 75 to 20% by weight of vinylidene chloride is used. 7. Verfahren nach einem der Ansprüche 5 oder 6, dadurch gekennzeichnet, dass das Textilmaterial ein Tuftingteppich aus Polyamid auf einem Polypropylenrücken ist.7. The method according to any one of claims 5 or 6, characterized in that that the textile material is a tufted carpet made of polyamide on a polypropylene backing. 109835/1628109835/1628
DE19712101326 1970-01-16 1971-01-13 Pending DE2101326A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US349870A 1970-01-16 1970-01-16
CH475171A CH567603B5 (en) 1970-01-16 1971-04-01

Publications (1)

Publication Number Publication Date
DE2101326A1 true DE2101326A1 (en) 1971-08-26

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ID=25696209

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DE19712101326 Pending DE2101326A1 (en) 1970-01-16 1971-01-13
DE19712101355 Pending DE2101355A1 (en) 1970-01-16 1971-01-13 Method for applying finely divided material to a substrate

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE19712101355 Pending DE2101355A1 (en) 1970-01-16 1971-01-13 Method for applying finely divided material to a substrate

Country Status (8)

Country Link
BE (2) BE761654A (en)
CH (2) CH567603B5 (en)
DE (2) DE2101326A1 (en)
FR (2) FR2076131B1 (en)
GB (2) GB1332996A (en)
LU (2) LU62409A1 (en)
NL (2) NL7100316A (en)
SE (1) SE370734B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2542338B1 (en) * 1983-03-10 1986-01-31 Inst Nat Rech Chimique CONTINUOUS IMPREGNATION PROCESS, BY SOLID POLYMERS, OF LONG LENGTH FIBERS, MACHINE FOR CARRYING OUT THIS PROCESS AND PRODUCTS THEREOF
US11358898B2 (en) 2017-10-20 2022-06-14 Corning Incorporated Methods to improve ion exchange efficiency of glasses and glass ceramics

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE504898A (en) * 1950-07-27
FR1502150A (en) * 1965-10-28 1967-11-18 Dow Chemical Co Improved method and apparatus for removing from a material a volatile liquid with which said material is wetted

Also Published As

Publication number Publication date
FR2091954B1 (en) 1973-12-07
BE761655A (en) 1971-07-15
SE370734B (en) 1974-10-28
LU62409A1 (en) 1972-08-23
LU62416A1 (en) 1972-08-23
NL7100316A (en) 1971-07-20
CH475171A4 (en) 1975-05-15
GB1338822A (en) 1973-11-28
CH567603B5 (en) 1975-10-15
FR2076131A1 (en) 1971-10-15
GB1332996A (en) 1973-10-10
FR2076131B1 (en) 1973-06-08
NL7100317A (en) 1971-07-20
DE2101355A1 (en) 1971-07-22
BE761654A (en) 1971-07-15
FR2091954A1 (en) 1971-01-21

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