DE19928741A1 - Helle Isocyanate, Verfahren zu deren Herstellung und deren Verwendung - Google Patents
Helle Isocyanate, Verfahren zu deren Herstellung und deren VerwendungInfo
- Publication number
- DE19928741A1 DE19928741A1 DE19928741A DE19928741A DE19928741A1 DE 19928741 A1 DE19928741 A1 DE 19928741A1 DE 19928741 A DE19928741 A DE 19928741A DE 19928741 A DE19928741 A DE 19928741A DE 19928741 A1 DE19928741 A1 DE 19928741A1
- Authority
- DE
- Germany
- Prior art keywords
- bromine
- phosgene
- iodine
- isocyanates
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title claims abstract description 58
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 229910052794 bromium Inorganic materials 0.000 title claims abstract description 58
- 239000012948 isocyanate Substances 0.000 title claims abstract description 48
- 150000002513 isocyanates Chemical class 0.000 title claims abstract description 47
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 title claims abstract description 44
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 229910052740 iodine Inorganic materials 0.000 title claims abstract description 40
- 239000011630 iodine Substances 0.000 title claims abstract description 40
- 150000001412 amines Chemical class 0.000 title claims abstract description 27
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 10
- 150000003673 urethanes Chemical class 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title description 17
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims description 46
- 239000002904 solvent Substances 0.000 claims description 15
- 239000004814 polyurethane Substances 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 5
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical class C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 description 22
- 239000000460 chlorine Substances 0.000 description 22
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 21
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 19
- -1 aromatic isocyanates Diphenylmethane diisocyanate series Chemical class 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 8
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 8
- 238000011282 treatment Methods 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 229920000768 polyamine Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- 229920005830 Polyurethane Foam Polymers 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 150000002497 iodine compounds Chemical class 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000005056 polyisocyanate Substances 0.000 description 3
- 229920001228 polyisocyanate Polymers 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000006103 coloring component Substances 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 201000006747 infectious mononucleosis Diseases 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- ZXVZNPQQNNZDDK-UHFFFAOYSA-N (dibromo-$l^{3}-chloranyl)formyl chloride Chemical compound ClC(=O)Cl(Br)Br ZXVZNPQQNNZDDK-UHFFFAOYSA-N 0.000 description 1
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- MGYGFNQQGAQEON-UHFFFAOYSA-N 4-tolyl isocyanate Chemical compound CC1=CC=C(N=C=O)C=C1 MGYGFNQQGAQEON-UHFFFAOYSA-N 0.000 description 1
- 229910014265 BrCl Inorganic materials 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- GPZPFPDXANIJTC-UHFFFAOYSA-N COBrF Chemical compound COBrF GPZPFPDXANIJTC-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 238000007138 Deacon process reaction Methods 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 1
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CODNYICXDISAEA-UHFFFAOYSA-N bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 description 1
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- KAFSRAJLBOFODY-UHFFFAOYSA-N carbonyl dichloride chlorobenzene Chemical compound ClC1=CC=CC=C1.C(=O)(Cl)Cl KAFSRAJLBOFODY-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Dental Preparations (AREA)
- Excavating Of Shafts Or Tunnels (AREA)
- Eye Examination Apparatus (AREA)
- Polyurethanes Or Polyureas (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19928741A DE19928741A1 (de) | 1999-06-23 | 1999-06-23 | Helle Isocyanate, Verfahren zu deren Herstellung und deren Verwendung |
| PCT/EP2000/005610 WO2001000569A1 (de) | 1999-06-23 | 2000-06-16 | Helle isocyanate, verfahren zu deren herstellung und deren verwendung |
| KR1020017016494A KR100686302B1 (ko) | 1999-06-23 | 2000-06-16 | 밝은 색상의 이소시아네이트, 그의 제조 방법 및 용도 |
| DE50003380T DE50003380D1 (de) | 1999-06-23 | 2000-06-16 | Helle isocyanate, verfahren zu deren herstellung und deren verwendung |
| PT00943828T PT1187808E (pt) | 1999-06-23 | 2000-06-16 | Isocianatos claros metodo para producao e sua utilizacao |
| CNB008093016A CN1182108C (zh) | 1999-06-23 | 2000-06-16 | 浅色异氰酸酯、其制备方法及其用途 |
| HU0201848A HU222987B1 (hu) | 1999-06-23 | 2000-06-16 | Világos színű izocianátok, előállításuk és alkalmazásuk |
| AT00943828T ATE247635T1 (de) | 1999-06-23 | 2000-06-16 | Helle isocyanate, verfahren zu deren herstellung und deren verwendung |
| JP2001506982A JP4722352B2 (ja) | 1999-06-23 | 2000-06-16 | 淡色のイソシアナート、これらの製造と使用 |
| ES00943828T ES2206268T3 (es) | 1999-06-23 | 2000-06-16 | Isocianatos claros, procedimiento para su obtencion y su empleo. |
| EP00943828A EP1187808B1 (de) | 1999-06-23 | 2000-06-16 | Helle isocyanate, verfahren zu deren herstellung und deren verwendung |
| US10/018,636 US6900348B1 (en) | 1999-06-23 | 2000-06-16 | Light isocyanates, method for producing them and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19928741A DE19928741A1 (de) | 1999-06-23 | 1999-06-23 | Helle Isocyanate, Verfahren zu deren Herstellung und deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19928741A1 true DE19928741A1 (de) | 2000-12-28 |
Family
ID=7912253
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19928741A Withdrawn DE19928741A1 (de) | 1999-06-23 | 1999-06-23 | Helle Isocyanate, Verfahren zu deren Herstellung und deren Verwendung |
| DE50003380T Expired - Lifetime DE50003380D1 (de) | 1999-06-23 | 2000-06-16 | Helle isocyanate, verfahren zu deren herstellung und deren verwendung |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE50003380T Expired - Lifetime DE50003380D1 (de) | 1999-06-23 | 2000-06-16 | Helle isocyanate, verfahren zu deren herstellung und deren verwendung |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6900348B1 (https=) |
| EP (1) | EP1187808B1 (https=) |
| JP (1) | JP4722352B2 (https=) |
| KR (1) | KR100686302B1 (https=) |
| CN (1) | CN1182108C (https=) |
| AT (1) | ATE247635T1 (https=) |
| DE (2) | DE19928741A1 (https=) |
| ES (1) | ES2206268T3 (https=) |
| HU (1) | HU222987B1 (https=) |
| PT (1) | PT1187808E (https=) |
| WO (1) | WO2001000569A1 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10235476A1 (de) | 2002-08-02 | 2004-02-12 | Basf Ag | Integriertes Verfahren zur Herstellung von Isocyanaten |
| JP4938007B2 (ja) * | 2005-05-30 | 2012-05-23 | ハンツマン・インターナショナル・エルエルシー | ジフェニルメタン系ポリイソシアネートの製造法 |
| DE102006002157A1 (de) * | 2006-01-17 | 2007-07-19 | Bayer Materialscience Ag | Verfahren zur Herstellung heller Isocyanate |
| US8030522B2 (en) * | 2006-06-07 | 2011-10-04 | Bayer Materialscience Llc | Process for the production of toluene diisocyanate |
| ES2556964T3 (es) * | 2007-01-17 | 2016-01-21 | Basf Se | Procedimiento para la preparación de isocianatos |
| ES2582173T3 (es) * | 2007-11-14 | 2016-09-09 | Covestro Deutschland Ag | Preparación de isocianatos de color claro |
| US8802890B2 (en) * | 2008-11-26 | 2014-08-12 | Huntsman International Llc | Process for manufacturing isocyanates |
| JP5416830B2 (ja) * | 2009-04-24 | 2014-02-12 | ビーエーエスエフ ソシエタス・ヨーロピア | 色の安定なｍｄａとｍｄｉの製造方法 |
| KR20120088649A (ko) * | 2009-07-14 | 2012-08-08 | 바스프 에스이 | 디페닐메탄 계열의 담색 이소시아네이트의 제조 방법 |
| CN102666371B (zh) | 2009-11-13 | 2015-01-07 | 巴斯夫欧洲公司 | 提纯氯进料的方法 |
| AU2011293662B2 (en) * | 2010-08-27 | 2014-12-04 | Inventure International (Pte) Limited | Generation of mixed diisocyanates by phosgenation of soy based methyl amino esters |
| CN103874680B (zh) | 2011-10-21 | 2016-07-06 | 拜耳知识产权有限责任公司 | 生产浅色多异氰酸酯的方法 |
| US10131641B2 (en) | 2013-03-12 | 2018-11-20 | Covestro Deutschland Ag | Method for producing TDI-trimerisates with high purity |
| ES2688697T3 (es) | 2013-03-12 | 2018-11-06 | Covestro Deutschland Ag | Procedimiento para la preparación de TDI-poliisocianatos de color claro |
| EP2896597A1 (de) | 2014-01-21 | 2015-07-22 | Bayer MaterialScience AG | Verfahren zum An- und Abfahren eines Phosgengenerators |
| CN103922969B (zh) * | 2014-04-10 | 2016-01-20 | 万华化学集团股份有限公司 | 一种制备颜色稳定的1,6-己二异氰酸酯的方法 |
| CN109761855B (zh) | 2018-12-20 | 2020-07-28 | 万华化学集团股份有限公司 | 一种制备异佛尔酮二异氰酸酯的方法 |
| WO2020216648A1 (de) | 2019-04-25 | 2020-10-29 | Basf Se | Verfahren zur herstellung von phosgen |
| CN112111044B (zh) * | 2019-06-21 | 2021-06-29 | 万华化学集团股份有限公司 | 一种聚异氰酸酯组合物及其制备方法和应用 |
| CN111635502B (zh) * | 2020-06-10 | 2022-04-22 | 万华化学集团股份有限公司 | 一种多异氰酸酯组合物及其制备方法和用途 |
| CN114349664B (zh) * | 2022-01-17 | 2023-08-11 | 万华化学（宁波）有限公司 | 一种低溴含量异氰酸酯的制备方法 |
| KR20250053185A (ko) | 2022-11-17 | 2025-04-21 | 완후아 케미컬 그룹 코., 엘티디 | 이소시아네이트 조성물과 이의 제조방법 및 용도 |
| CN119409598B (zh) * | 2024-10-31 | 2025-12-16 | 万华化学集团股份有限公司 | 一种制备浅色异氰酸酯、聚氨酯的方法 |
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| US3660261A (en) * | 1970-04-20 | 1972-05-02 | Dow Chemical Co | Method for reduction of bromine contamination of chlorine |
| DE2323299C3 (de) * | 1973-05-09 | 1983-12-08 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur kontinuierlichen Herstellung von 1-Isocyanato-3-(isocyanatomethyl)-3,5,5-trimethylcyclohexan |
| JPS5470220A (en) * | 1977-11-11 | 1979-06-05 | Mitsui Toatsu Chem Inc | Preparation of organic isocyanate |
| US4465639A (en) | 1983-01-26 | 1984-08-14 | The Upjohn Company | Process for polyisocyanates |
| DE3329124A1 (de) | 1983-08-11 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur reinigung von polyisocyanaten und die so gereinigten polyisocyanate |
| DE4006976A1 (de) | 1990-03-06 | 1991-09-12 | Basf Ag | Verfahren zur herstellung von mischungen aus diphenylmethan-diisocyanaten und polyphenyl-polymethylen-polyisocyanaten mit einer verminderten iodfarbzahl |
| DE4008074A1 (de) | 1990-03-14 | 1991-09-19 | Basf Ag | Verfahren zur qualitaetsverbesserung von rohen diaminodiphenylmethanen |
| DE4021712A1 (de) | 1990-07-07 | 1992-01-09 | Basf Ag | Verfahren zur herstellung von mischungen aus diphenylmethan-diisocyanaten und polyphenol-polymethylen-polyisocyanaten mit einer verminderten iodfarbzahl |
| DE69107212T2 (de) | 1991-10-19 | 1995-05-24 | Basf Corp | Verfahren zur Herstellung von polymerischen Methylen-dyphenylen-diisocyanaten mit verminderter Farbe und Chloridgehalt. |
| US5386059A (en) | 1991-12-10 | 1995-01-31 | Miles Inc. | Process for preparing polyamines for lighter color polyisocyanate based foam |
| DE4208359A1 (de) | 1992-03-16 | 1993-09-23 | Bayer Ag | Verfahren zur herstellung von isocyanaten oder isocyanatgemischen und deren verwendung zur herstellung von polyurethanschaumstoffen |
| KR970001071B1 (ko) | 1992-06-23 | 1997-01-25 | 미쓰이도오아쓰가가꾸 가부시끼가이샤 | 메틸렌 가교 폴리페닐렌 폴리이소시아네이트의 제조방법 |
| US5312971A (en) | 1992-07-23 | 1994-05-17 | Miles Inc. | Color reduction of polymethylene polyphenyl polyisocyanates |
| DE4300774A1 (de) * | 1993-01-14 | 1994-07-21 | Basf Ag | Verfahren zur Herstellung von Mischungen aus Diphenylmethandiisocyanaten und Polyphenyl-polymethylen-polyisocyanaten mit einer verminderten Iodfarbzahl |
| ES2123171T3 (es) * | 1994-04-07 | 1999-01-01 | Bayer Ag | Procedimiento para la fabricacion de isocianatos o mezclas de isocianatos. |
| FR2723585B1 (fr) * | 1994-08-12 | 1996-09-27 | Rhone Poulenc Chimie | Procede de preparation de composes du type polyisocyanates aromatiques en phase gazeuse. |
| IN190134B (https=) * | 1995-12-28 | 2003-06-21 | Du Pont | |
| JPH1045700A (ja) * | 1996-07-29 | 1998-02-17 | Mitsubishi Gas Chem Co Inc | ジイソシアネート化合物およびそのオリゴマー |
| DE19711447A1 (de) * | 1997-03-19 | 1998-09-24 | Basf Ag | Verfahren zur Herstellung von Isocyanaten mit heller Farbe |
| DE19817691A1 (de) | 1998-04-21 | 1999-10-28 | Basf Ag | Verfahren zur Herstellung von Mischungen aus Diphenylmehandiisocyanaten und Polyphenylen-polymethylen-polyisocyanaten mit vermindertem Gehalt an chlorierten Nebenprodukten und verminderter Jodfarbzahl |
-
1999
- 1999-06-23 DE DE19928741A patent/DE19928741A1/de not_active Withdrawn
-
2000
- 2000-06-16 PT PT00943828T patent/PT1187808E/pt unknown
- 2000-06-16 AT AT00943828T patent/ATE247635T1/de not_active IP Right Cessation
- 2000-06-16 KR KR1020017016494A patent/KR100686302B1/ko not_active Expired - Lifetime
- 2000-06-16 DE DE50003380T patent/DE50003380D1/de not_active Expired - Lifetime
- 2000-06-16 HU HU0201848A patent/HU222987B1/hu not_active IP Right Cessation
- 2000-06-16 JP JP2001506982A patent/JP4722352B2/ja not_active Expired - Fee Related
- 2000-06-16 EP EP00943828A patent/EP1187808B1/de not_active Expired - Lifetime
- 2000-06-16 US US10/018,636 patent/US6900348B1/en not_active Expired - Lifetime
- 2000-06-16 WO PCT/EP2000/005610 patent/WO2001000569A1/de not_active Ceased
- 2000-06-16 ES ES00943828T patent/ES2206268T3/es not_active Expired - Lifetime
- 2000-06-16 CN CNB008093016A patent/CN1182108C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE247635T1 (de) | 2003-09-15 |
| PT1187808E (pt) | 2003-12-31 |
| KR100686302B1 (ko) | 2007-02-23 |
| DE50003380D1 (de) | 2003-09-25 |
| HUP0201848A2 (en) | 2002-09-28 |
| KR20020010726A (ko) | 2002-02-04 |
| CN1182108C (zh) | 2004-12-29 |
| HU222987B1 (hu) | 2004-01-28 |
| US6900348B1 (en) | 2005-05-31 |
| WO2001000569A1 (de) | 2001-01-04 |
| JP2003503383A (ja) | 2003-01-28 |
| JP4722352B2 (ja) | 2011-07-13 |
| EP1187808A1 (de) | 2002-03-20 |
| CN1356980A (zh) | 2002-07-03 |
| EP1187808B1 (de) | 2003-08-20 |
| ES2206268T3 (es) | 2004-05-16 |
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