DE1767064A1 - Katalysator fuer die Herstellung von Wasserstoff aus kohlenmonoxidhaltigen Gasen - Google Patents
Katalysator fuer die Herstellung von Wasserstoff aus kohlenmonoxidhaltigen GasenInfo
- Publication number
- DE1767064A1 DE1767064A1 DE19681767064 DE1767064A DE1767064A1 DE 1767064 A1 DE1767064 A1 DE 1767064A1 DE 19681767064 DE19681767064 DE 19681767064 DE 1767064 A DE1767064 A DE 1767064A DE 1767064 A1 DE1767064 A1 DE 1767064A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- aluminum oxide
- oxide
- hydrogen
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 7
- 239000001257 hydrogen Substances 0.000 title claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 6
- 239000007789 gas Substances 0.000 title claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 title description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 12
- 239000011651 chromium Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 150000002823 nitrates Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000011872 intimate mixture Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- -1 aluminum mono- Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 150000004684 trihydrates Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 6
- 229910001593 boehmite Inorganic materials 0.000 description 5
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 229910001679 gibbsite Inorganic materials 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 239000006187 pill Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 229910001680 bayerite Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical class [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681767064 DE1767064A1 (de) | 1968-03-27 | 1968-03-27 | Katalysator fuer die Herstellung von Wasserstoff aus kohlenmonoxidhaltigen Gasen |
| DE19681812813 DE1812813B2 (de) | 1968-03-27 | 1968-12-05 | Verfahren zur herstellung von eisen, chrom und nickel enthaltenden traegerkatalysatoren |
| AT252169A AT289032B (de) | 1968-03-27 | 1969-03-14 | Katalysator für die Herstellung von Wasserstoff aus kohlenmonoxydhaltigen Gasen und Verfahren zu seiner Herstellung |
| NL6904412A NL6904412A (enrdf_load_stackoverflow) | 1968-03-27 | 1969-03-21 | |
| BE730489D BE730489A (enrdf_load_stackoverflow) | 1968-03-27 | 1969-03-26 | |
| GB1252176D GB1252176A (enrdf_load_stackoverflow) | 1968-03-27 | 1969-03-26 | |
| FR6908898A FR2004844A1 (enrdf_load_stackoverflow) | 1968-03-27 | 1969-03-26 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681767064 DE1767064A1 (de) | 1968-03-27 | 1968-03-27 | Katalysator fuer die Herstellung von Wasserstoff aus kohlenmonoxidhaltigen Gasen |
| DE19681812813 DE1812813B2 (de) | 1968-03-27 | 1968-12-05 | Verfahren zur herstellung von eisen, chrom und nickel enthaltenden traegerkatalysatoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1767064A1 true DE1767064A1 (de) | 1970-09-17 |
Family
ID=25755449
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19681767064 Pending DE1767064A1 (de) | 1968-03-27 | 1968-03-27 | Katalysator fuer die Herstellung von Wasserstoff aus kohlenmonoxidhaltigen Gasen |
| DE19681812813 Pending DE1812813B2 (de) | 1968-03-27 | 1968-12-05 | Verfahren zur herstellung von eisen, chrom und nickel enthaltenden traegerkatalysatoren |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19681812813 Pending DE1812813B2 (de) | 1968-03-27 | 1968-12-05 | Verfahren zur herstellung von eisen, chrom und nickel enthaltenden traegerkatalysatoren |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT289032B (enrdf_load_stackoverflow) |
| BE (1) | BE730489A (enrdf_load_stackoverflow) |
| DE (2) | DE1767064A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2004844A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1252176A (enrdf_load_stackoverflow) |
| NL (1) | NL6904412A (enrdf_load_stackoverflow) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2163830A6 (enrdf_load_stackoverflow) * | 1971-04-19 | 1973-07-27 | Prod Catalyse Fse | |
| US4029738A (en) * | 1971-12-02 | 1977-06-14 | Societe Francaise Des Produits Pour Catalyse | Decomposing nitrogen oxides with nickel-iron-chromium catalysts |
| DE3063818D1 (en) * | 1979-03-27 | 1983-07-28 | Ici Plc | Method for producing a solution containing nitrates of iron and chromium and making a high temperature shift catalyst from it |
| US4451578A (en) * | 1982-04-26 | 1984-05-29 | United Technologies Corporation | Iron oxide catalyst for steam reforming |
| US4410443A (en) | 1982-05-24 | 1983-10-18 | Katalco Corporation | Method of dissolving iron oxide-chrome oxide spent shift catalysts to prepare a nitrate solution suitable for use in preparing a new catalyst |
| US4482645A (en) * | 1983-05-24 | 1984-11-13 | Imperial Chemical Industries Limited | Method of making an iron oxidechromium oxide catalyst |
| US4925745A (en) * | 1985-03-29 | 1990-05-15 | Institute Of Gas Technoloy | Sulfur tolerant molten carbonate fuel cell anode and process |
| DE4405489A1 (de) * | 1994-02-21 | 1995-08-24 | Rolf Scheiwiller | Mauerstein-Bausatz |
-
1968
- 1968-03-27 DE DE19681767064 patent/DE1767064A1/de active Pending
- 1968-12-05 DE DE19681812813 patent/DE1812813B2/de active Pending
-
1969
- 1969-03-14 AT AT252169A patent/AT289032B/de not_active IP Right Cessation
- 1969-03-21 NL NL6904412A patent/NL6904412A/xx unknown
- 1969-03-26 BE BE730489D patent/BE730489A/xx unknown
- 1969-03-26 FR FR6908898A patent/FR2004844A1/fr not_active Withdrawn
- 1969-03-26 GB GB1252176D patent/GB1252176A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL6904412A (enrdf_load_stackoverflow) | 1969-09-30 |
| AT289032B (de) | 1971-03-25 |
| BE730489A (enrdf_load_stackoverflow) | 1969-09-26 |
| FR2004844A1 (enrdf_load_stackoverflow) | 1969-12-05 |
| DE1812813A1 (de) | 1970-12-10 |
| DE1812813B2 (de) | 1976-01-29 |
| GB1252176A (enrdf_load_stackoverflow) | 1971-11-03 |
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