DE1593247B1 - Verfahren zur Oxychlorierung von aliphatischen Kohlenwasserstoffen mit 1 bis 4 Kohlenstoffatomen - Google Patents
Verfahren zur Oxychlorierung von aliphatischen Kohlenwasserstoffen mit 1 bis 4 KohlenstoffatomenInfo
- Publication number
- DE1593247B1 DE1593247B1 DE19661593247 DE1593247A DE1593247B1 DE 1593247 B1 DE1593247 B1 DE 1593247B1 DE 19661593247 DE19661593247 DE 19661593247 DE 1593247 A DE1593247 A DE 1593247A DE 1593247 B1 DE1593247 B1 DE 1593247B1
- Authority
- DE
- Germany
- Prior art keywords
- gas mixture
- gases
- speed
- sec
- oxychlorination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 15
- 230000008569 process Effects 0.000 title claims description 8
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 title claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 title claims description 4
- 239000007789 gas Substances 0.000 claims description 81
- 239000000203 mixture Substances 0.000 claims description 36
- 238000006243 chemical reaction Methods 0.000 claims description 32
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 20
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 12
- 239000000460 chlorine Substances 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 239000012320 chlorinating reagent Substances 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 230000002028 premature Effects 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 13
- 239000005977 Ethylene Substances 0.000 description 13
- 239000003570 air Substances 0.000 description 10
- 238000005660 chlorination reaction Methods 0.000 description 7
- 238000010944 pre-mature reactiony Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- 208000000260 Warts Diseases 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002996 emotional effect Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- SZNHAWRQQIZIBK-UHFFFAOYSA-K potassium;trichlorocopper(1-) Chemical compound [Cl-].[K+].Cl[Cu]Cl SZNHAWRQQIZIBK-UHFFFAOYSA-K 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 201000010153 skin papilloma Diseases 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47009765A | 1965-07-07 | 1965-07-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1593247B1 true DE1593247B1 (de) | 1971-03-04 |
Family
ID=23866255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661593247 Pending DE1593247B1 (de) | 1965-07-07 | 1966-07-05 | Verfahren zur Oxychlorierung von aliphatischen Kohlenwasserstoffen mit 1 bis 4 Kohlenstoffatomen |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE712418A (enrdf_load_stackoverflow) |
| CH (1) | CH475927A (enrdf_load_stackoverflow) |
| DE (1) | DE1593247B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1143736A (enrdf_load_stackoverflow) |
| NL (1) | NL6609506A (enrdf_load_stackoverflow) |
-
0
- GB GB1143736D patent/GB1143736A/en active Active
-
1966
- 1966-06-27 CH CH927066A patent/CH475927A/fr not_active IP Right Cessation
- 1966-07-05 DE DE19661593247 patent/DE1593247B1/de active Pending
- 1966-07-07 NL NL6609506A patent/NL6609506A/xx unknown
-
1968
- 1968-03-19 BE BE712418D patent/BE712418A/xx unknown
Non-Patent Citations (1)
| Title |
|---|
| None * |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1143736A (enrdf_load_stackoverflow) | |
| NL6609506A (enrdf_load_stackoverflow) | 1967-01-09 |
| BE712418A (enrdf_load_stackoverflow) | 1968-09-19 |
| CH475927A (fr) | 1969-07-31 |
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