DE1496908A1 - Process for the electroplating of nickel - Google Patents

Process for the electroplating of nickel

Info

Publication number
DE1496908A1
DE1496908A1 DE19651496908 DE1496908A DE1496908A1 DE 1496908 A1 DE1496908 A1 DE 1496908A1 DE 19651496908 DE19651496908 DE 19651496908 DE 1496908 A DE1496908 A DE 1496908A DE 1496908 A1 DE1496908 A1 DE 1496908A1
Authority
DE
Germany
Prior art keywords
bad
original
nickel
primary
neon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19651496908
Other languages
German (de)
Other versions
DE1496908B2 (en
DE1496908C3 (en
Inventor
Frank Passal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
M&T Chemicals Inc
Original Assignee
M&T Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by M&T Chemicals Inc filed Critical M&T Chemicals Inc
Publication of DE1496908A1 publication Critical patent/DE1496908A1/en
Publication of DE1496908B2 publication Critical patent/DE1496908B2/en
Application granted granted Critical
Publication of DE1496908C3 publication Critical patent/DE1496908C3/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/46—Oxygen atoms
    • C07D213/50—Ketonic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/80—Acids; Esters in position 3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81—Amides; Imides
    • C07D213/82—Amides; Imides in position 3
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
    • C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
    • C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
    • C25D3/18—Heterocyclic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pyridine Compounds (AREA)

Description

PATENTANWÄLTE DR.-ING. H. FINCKE DiPL-IN G. H. BOHR DlPL-ING. S. STAEGER MÖNCHEN 5 MOLLERSTR. 31PATENT LAWYERS DR.-ING. H. FINCKE DIPL-IN G. H. BOHR DIPL-ING. S. STAEGER MÖNCHEN 5 MOLLERSTR. 31

ISS 20 012
Case 493ISS 20 012
Case 493

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der Slaaaa M&2 ChotflioeAa Jho.,
Hew Yosfc» Μ.γ«, ff. S* A«der Slaaaa M & 2 ChotflioeAa Jho.,
Hew Yosfc »Μ.γ«, ff. S * A «

«Verfahren 312» galvanischen
von«Procedure 312» galvanic
from

Prioritäten! 24· febnaar 1964 - U. S. A.Priorities! February 24, 1964 - U. S. A.

Bio Ει-fin'}ατα^ t>03ioht sich auf das Elektroplattieren Galvanisieren mit iiick©! und betrifft Um besonderen die gal-Bio Ει-fin '} ατα ^ t> 03ioht is based on electroplating Galvanizing with iiick ©! and concerns in order to special the gal-

HlederaohlaßUBg von Glansmickel bosiehungernelee das f.;en von gaXvenlsolien ulansnlc&o !Überzügen.HlederaohlaßUBg from Glansmickel bosiehungernelee das f.; en of gaXvenlsolien ulansnlc & o! coatings.

IJiclcelüberKÜgö, wie die sue Watts-Sädexn, etgric Bädern, Bluoboratbädern» usw. plattierten* sind ^änaenil, wen» sie in v?ooentlieh ßrtißoren Dicken als diejoni- -Beh% JMmQn Streich- (»atrlke«) besielwmseweiB© Sohnell-IJiclcelüberKÜgö, like the sue Watts-Sädexn, etgric baths, bluoborate baths "etc. plated * are ^ änaenil, whom" they in v? Ooentlieh ßrtißoren thicknesses as diejoni- -Beh% JMmQn prank- ("atrlke") besielwmseweiB

coatingß) plattiert werden. Des? (SLissa derartiger 9833/10 57 0^d oriqiNAL »?-"coatingß) are plated. Of? (SLissa such 9833/10 57 0 ^ d oriqi NAL »? -"

·■■- a -· ■■ - a -

Abocheiflungea beaiehungewelse tSfceratigt erhöht sieh alsfet »it «»eh- rnwtXev ittck», sondern er «trd vielaehr vtxsti&aert» M* äwwf« »att· liesiehungsweise ßlgaaloßö (matte) Abfohei&ingen beaiofcn&geiralie Öfctr-Büge erhalten »erden. TJ)B £»» derartige» Bädera dicke gSK&ae&de Ab-Scheidungen beziehungswaise tit)»irs8Uge au eraielen* 1st te aotutftdig» liestimmto Zusätze, gaTJÖSmlicli von ojganieoiior Art* weldkie dl« Brseor gang von starlc glilnBe&äen Abaohöidumgcn beaiehungsneie· ÜbeafeUgen alt einer guten Gisnafeildimgegeocliwia&lgkeit (rate of bri^itenifie) für-* öem> eussogetien· Ss äst eine üblicfee Eigeasc^iaft derartiger nannter BQlansnlckelplattiexunsel)aderM, faß dieAbocheiflungea beaiehungewelse tSfceratigt increases see alsfet »it« »eh- rnwtXev ittck», but he «trd much vtxsti & aert» M * äwwf «» att · read as ßlgaaloßö (matte) Abfohei & ingen beaiofcng received & geirdenal. TJ) B £ »» such »Bädera dicke gSK & ae & de Ab-Divorces or orphan tit)» irs8Uge au erielen * 1st te aotutftdig »reads to additions, gaTJÖSmlicli of ojganieoiior kind * weldkie dl« good Brseor gang from strong glilneagumgencian (rate of bri ^ itenifie) for- * öem> eussogetien · Ss eats a common example of such a named B Qlansnlckelplattiexunsel) ve M , grasps the

Überzüge mit ssun^mender !Dicke %v& Kc^uSumg des Ölanaea neigen. ELn besonderer Vorteil dieser "(MgasalckelMdsr* besteht -:nf daß c^f GrLT.-ißmQt allen ο weloK© aioht poliert bessi@htsig8i9@i8e ge~ glättet worden sind beziehungsweise mlch@ keinen hohen MfasgBgläae } JLnaesdi&lb aös^mösaensr B©stimßamg@ii von Hielceldioken glänsen· Absclieidungen beziehungsweise Übarsüg© erhalten werden können« BsCoatings with ssun ^ mender! Thickness % v & Kc ^ uSumg of the Ölanaea tend. There is a special advantage of this "(MgasalckelMdsr *) : n f that c ^ f GrLT.-ißmQt all ο weloK © aioht polished bessi @ htsig8i9 @ i8e have been smoothed or rather mlch @ no high MfasgBgläae } JLnaesdi & lb aös ^ stimßamg @ ii by Hielceldioken glänsen · Absclieidungen or Übarsüg © can be obtained «Bs

auch gndore begleitende Vorteile» nie Qlättung besslehungeweice lUvelllerung oder >31ό Fähigkeit der Abscheidungen besiehungsweiee UberaUge, Poren, Katzer bessiehtmgaweise Bit*© oder andere Oberflächenwelle r des Grundmet alles suozufliUen» ersielt norden. also gndore accompanying advantages »never smoothing, better luminescence or > 31ό ability of the deposits surface-white surplus, pores, scratches, bit *

Glsn?,bi*.iner in B&dern sum Flattieren mit Nickel brauchbare Zusatsmlttül worden mi Orund ihrer vorherrschenden funktion in all-SQ'UGinon in 2 Klassen eingeteilt. Primäre (äanebildner sind in sehr g-erlhger beziehtmgsigeise verhältnieoäQig geringer Konzentrat?.^, npiolswdiso in einer Kona ent ration von O0OOS bis O9 2 B/kt Materialien, welche als solche eine bezioilrosgawsise keine siclttiiare Qlansvlrknng herbsiführon können« Diesigen primäremGlsn?, Bi * .iner in B & countries sum Flat animals useful with nickel Zusatsmlttül been divided mi Orund their predominant function in all-SQ'UGinon in two classes. Primary (äanebildner are erlhger g in very beziehtmgsigeise verhältnieoäQig low concentrate?. ^, Npiolswdiso in a Kona ent ration of from 0 OOS to O 9 2 B / k t materials which can herbsiführon as such a bezioilrosgawsise no siclttiiare Qlansvlrknng "hazy primary

-9098 33 /105?-9098 33/105?

. 1496808. 1496808

weiche bti alleiniger Ves*enäaag «t«** <&eä»*irteiag fci&cß, xof en ia allgemeinen aueli schädliche 3ebsmdrkangon# wie ein® ves»i»üert« Kathodenleietung besiohaagßi*elsQ etaea veaBiaäarten «Lne schlechte fcesisirangsireies öürmge Farbe dar des t)%e»rag«e* Brüohi^ceit beslfifeaziseiie& 3celt tied ^blätter» der Aivse^ÄlSoas besl^mBgsviela« fl«e einen sehr angen Bexeiofe wa gl8&B®nde£ ?ägl1slessns oäar keine Plattler^ bei nladxigezi StTcmÄldit»iJö^öicb«nf bervxjr. Sekundäre Olesuibildner einfi Mataxlaliaii» mltäa üblichörweise la Koabination mit primären GlfinabildBem, ^edoofe In nsnnensirert höherer KonzQntration als die der pzjLn&ren OO-snabildner, beiepielew·!«© in einer Konzentration von 1 ULs 30 g/l, verwendet werden. Dieee Materialien ale solche können etwas OlcßKbüäungewirkune oder Eornrerieine-Äxingsivixicunß herbeiführen v die Abaobeidangfn bessiehuageweiae tJberctige aind jedoch la allgtaelnen nicht ea?iegelslÄni5end und die GLanablldu»ÄBßesohvyindl*keit let im allgemeinensoft bti sole Ves * enäaag «t« ** <& eä »* irteiag fci & cß, xof en ia general aueli harmful 3ebsmdrkangon # like a® ves» i »transmits« cathode lead besiohaagßi * elsQ etaea veaBiaäarten «Lne bad fcesisirangsireies of the turm )% e »rag« e * Brüohi ^ ceit beslfifeaziseiie & 3celt tied ^ leaves »der Aivse ^ ÄlSoas besl ^ mBgsviela« fl «e a very pleasant Bexeiofe wa gl8 & volumes £? «N f bervxjr. Secondary Olesuibildner einfi Mataxlaliaii "mltäa üblichörweise la Koabination with primary GlfinabildBem, ^ edoofe In nsnnensirert higher than that of KonzQntration pzjLn & ren OO snabildner, beiepielew ·!" © be used in a concentration of 1 UL 30 g / l. All of these materials can bring about a certain degree of odor or odor-éxingive effects v the Abaobeidangfn bessiehuageweiae tJberctige aind, however, the general elements are not sealed and the generality of the odor in general

Idealerweiae 1st es bei Kombination von richtig geiählten und ver txtigiichen priaSren und eekundären Olanabildnern c^^Lioh» In eines weiten S t rom dicht eb or eich biegsane beaiehungßweiee gei^hneidtge» glat to bessiehnngöceiee nivellierte Abaoheidungan besiehungeneise übaxattge m.l'u einer guten Glonzblldungssosohwlndigkeit zn erhalten· Die Qerjo.^wLndiesel'-dar Glomsbildung und dee Olättens besiehungBiieiee Sivel .τJ.GTona kssm in Abhängigkeit von den spesieH gewählten measmenvir-ZüGätrion imfl ihren tataäohlidhen und relativen Konzentrationen Eine hohe Geschwindiglceit der Glensbildung und dee QlHt-Ideally, it is with a combination of correctly assigned and ver txtigiichen primaries and secondary olana formers c ^^ Lioh "In a wide area close to eb or calibrated, flexible, flexible white accentuated" smooth to better than a good leveled Abaoheidise on a good, leveled Abaoheidisee Glonzblldungssosohlndigkeit zn get the Qerjo. ^ WLndiesel'-dar Glombildung and dee Olättens Besiee Sivel .τ J.GTona kssm depending on the selected measmenvir-ZüGätrion infl their tataäohlidhen and relative concentrations of the Glensbildung a high speed

aUgenelnen wünschenswert,desirable

909833/1057 BAD ♦ to 909833/1057 BAD ♦ to

1496S081496S08

beaonfiers wenn mit m;iai»elen Hiokeldtc&eB ein fflsociffleler (Uans er-Tiiinecht let. Die Konzentrationen fler sekundären i&eesbllfineir können im allgemeinen innerhalb zismlioh weiter Oralen variieren. I)Ie Konzentrationen der primären (Eenzblidner inueeen im allgemeinen innerhalb aiemllch enger Grenaen gehalten werden, ton die wünschenswerten Eigenschaften eiasokUsßlich d«r gntea Blessedstit beiiatowgewtie·beaonfiers if with m; iai »elen Hiokeldtc & eB a fflsociffleler (Uans er-Tiiinecht let. The concentrations of secondary i & eesbllfineir can generally vary within zismlioh further orals. I) Ie concentrations the primary (Eenzblidner inueeen in general within aiemllch narrow limits are kept, ton the desirable ones Properties eiasokUslich d «r gntea Blessedstit beiiatowgewtie ·

, der eusreidbendes Bedeckung in niedrigen Stromuew., ssu eziisdtes· Jegliches OXansniaiceleyete», nelin Böimß auf Schwmltungen <äer prla&res, the eusreidbendes covering in low Stromuew., ssu eziisdtes · Any OXansniaiceleyete », nelin Böimß auf Schwmltungen <äer prla & res

tioncn ßr!5Sore iolereasien veridohea werden Ifiönntun, h&tt· oifensichtlicho Vorteile^ besondors weil die ni*lrig« Konefntr*tlon von (Eaziabildnem und Öle ^inlgen derselben eigen« ahtnltc&e eine strenge EontroUe duräh chealeohe Äialyee ediwiexie gestaltet. Ein prUnärer QlanKbiläner, welcher In eicea weiten Eönientrationsbereich verwendot «erden kenn» let bei der $l£ienickeli>X«fctierung von groflam Wert.tioncn? Advantages ^ especially because the low level of confusion of (Eazia pictures and oils are peculiar to them a strict EontroUe designed by chealeohe aialyee ediwiexie. A prUnary QlanKbiläner, which in eicea wide range of energy Use “earth know” for the $ l £ ienickeli> X “function of great value.

EB lot din Ziel der Erfindung» eine beeeer© plattl«rung mit Hlokol. durcn Vorwenftung einer neuen K3.ae&e von Überlegenen prlofiren OlGdBbIldnern bereitzustellen, weiternln richtet eicdi die Erfindung guf ein wirlceenee Verf rfiren eur gelveniechen Niedersohlagung von ßlUnaenden und glatten Hlokelebsoheldungen, beaiehungeweiee Biokelüberaüßon. Bin weiteres Ziel der Erfindung let die Bereitstellung von Baft giuaenmona et «langen 8UBi plattleren mit nickel, suo welchen glSin «ende galvenioohe Rlokelttbersuge erhalten werden. Andere Ziele der Erfindung srgoben eich cue der folgenden Beschreibung.EB lot din the aim of the invention "a beeeer © plating" with Hlokol. by the advance of a new K3.ae & e of superior prlofiren OlGdBIldners, furthermore, eicdi directs the invention to a welceenee for your gelvenike downstroke of unsanitary and smooth hoopbe announcements, if there are no biopic reports. A further aim of the invention is to provide baffle giuaenmona et "long 8UBi plates with nickel, so which glSin" end Galvenioohe Rlokelttbersuge are obtained. Other objects of the invention are evident from the following description.

Nach bestimmten llerkmalen umfallt das crfindimgsgemäße VerfahrenAfter certain characteristics, the process according to the invention falls over

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»AfeieAt^- Di«"AfeieAt ^ - Tue"

Bitbit

ΕΕίΐ^βΙ dee mitΕΕίΐ ^ βΙ dee with

ftl··«ftl · · «

BAD ORIGINALBATH ORIGINAL

eründungegeniäß spezifisch ausgewählt, *ad©r® ßruppaaa in diesen Stellungen machen cßt weder die synthese der quaterafösen Verbinungen schwierig bessiehungaweiee unmugliah oder £Uhren sa el3 primäre Qlansbildner unwirksamen Verbindungen. ,specifically selected according to the invention, * ad © r® ßruppaaa in these positions, neither do the synthesis of the quaterafous connections difficult bessiehungaweiee unmugliah or £ clocks sa el3 primary Plan builders ineffective compounds. ,

Die primären Glansblldnor aaoh der Erfindung können in Konzentration en von 0,005 bis 0,10 g/1 verwindet norden, wobei die epeslell gewählte Konsentration von den epeslell verwände tea Typen und Konzentrationen von aeknndSren Glaa»fcilfin«rn and sekundären Hllfeglen·- bildcero und auch' von derartigen Faktoren wie den Konaentrationen von Niokelaulfat» Viofcelohlorid und Boxifinrt, dan BetriebaDeäingangen beh der Tsejperatur und des Qradea der Bewegung» den Grad deeThe primary Glansblldnor aaoh of the invention can be twisted in concentrations of 0.005 to 0.10 g / 1, with the epeslell chosen consentration of the epeslell related tea types and concentrations by aeknndSren Glaa »fcilfin« rn and secondary envelopes · - bildcero and also 'of such factors as the concentrations of Niokelaulfat »Viofcelohlorid und Boxifinrt, dan BetriebsaDeäingangen beh the Tsejperatur and the Qradea of the movement »the degree dee

oltnaee, dar erwUnaontea Geadiwlndigkeit der Glansbilteog uad des GUtte&e beeiehungewtie« Iivelli*sr*ne mud der Oberfläelianbeeoaaffeaheit da« Omnäaetallea akhlnft. Ea ist oavorsugt» 0,01 bia 0,05 bA zu verwenden.oltnaee, dar ErwUnaontea Geadiwlndigkeit der Glansbilteog uad des Gtte & e beeiehungewtie "Iivelli * sr * ne mud der Oberfläelianbeeoaaffeaheit da" Omnäaetallea akhlnft. Ea is preferred to use 0.01 to 0.05 bA.

Sekundäre Qlansbildner (beirpieleweiee In einer Menge von 1 bia 75 g/lf vonugawelaa 1 bla 20 f 1, vor lieg end \ welche in Kombination mit den prlnärea (HLansbildnexa irmohbar eind, elnd im allgemeinen aromatieohe salfönate, Balfbnc Ide beaiehungaweiae Sulflmld·, weioha subetituierte arosatiaohw VeriuA^u^^en, wie 1,5,6-Haphthalintriaulfonate, Natrium- ^alahungawelaa Caliuaaalse von Saccharin, Vatrixavb ©a loh uns er i se K^j liumaalee von oHSnliobenaaldehyd» BenBolaulfOnamid, BonKolfflonoaul. ms ^9 usw., umfaeaen· Zur Vorwendung in atark ohloridbaltigen Bädera :■ ^ Plattieren mit Iflokel eind bevoraugte cakundfire Glansbildner aaxdh SuIfonli ren von Diphenyl mit rauohender Sohwefel-Secondary planarizers (for example, in an amount of 1 to 75 g / lf vonugawelaa 1 bla 20 f 1, in this case, in combination with the preliminary (HLansbildnexa irmohbar), and generally aromatic salfönate, Balfbnc Ide beaiehungaldetweiae sulflm arosatiaohw VeriuA ^ u ^^ en, such as 1,5,6-Haphthalintriaulfonate, Sodium ^ alahungawelaa Caliuaaalse from Saccharin, Vatrixavb © a loh us he i se K ^ j liumaalee from oHSnliobenaaldehyd »BenBolaulfOnamid, BonKolfflonoaul. ms ^ 9 etc., for use in atark carbonaceous baths: ■ ^ plating with Iflokel and pre-primed cakundfire glans former aaxdh sulfonli ren of diphenyl with rough sulfur

eäure (2O# Oleum) während etwa 2 Stunden, Isolieren dea Reaktionen BADOR.Ü.NAL 909833/10S7Acid (2O # oleum) for about 2 hours, isolating the reactions BADOR.Ü.NAL 909833 / 10S7

produkten und ffeut roll aierenjberge stellte Ilatrium-KellUBSfiXic von sulfonierten DibenathiophenSloxyd. Ea iot enoimehaen, daß das voraerreoaende Reaktior agtfu&ürt die Vorbin dung rait 3 SuIf αη-säuregruppen zueeos&en mit etwas mono- und dl substituierten Komponenten let· Die sekundären Olenabildner gjlnd Im allgemeinen durc& raisidestone 1 an. ein Keraicohlenatoff atoa βΐηββ iioraocyoliflolien aronatieeten Rlrßes getnindono suldTonigruppo besiehu&geiieiee SaIf oae&tiregnappe charakterisiert.products and ffeut roll aierenjberge provided Ilatrium-KellUBSfiXic of sulfonated dibenathiophene oxide. Ea iot enoimehaen, that the pre-aerating reactor takes care of the prebinding rait 3 SuIf αη-acid groups zueeos & en with some mono- and dl-substituted components let · the secondary olena formers gjlnd generally durc & raisidestone 1 at. a keraicohlenatoff atoa βΐηββ iioraocyoliflolien aronatieeten Rlrßes getnindono suldTonigruppo besiehu & geiieiee SaIf oae & tiregnappe characterized.

P.s kunuen sekundäre EHfeglasnßbildner, «le das KetrluBiel« der 2-Prcpen-1^ulfonfläuro beaiehuasswoiae HatrIum-2-propen- 1-talitMut, d«s Natrium sol a der >■ Chlor-2-btrten-i~«ttlf ölsäure b«iiiehunse«slee Nntrl^Ä-^-chlor-^-buten-i-eolfonat und dae XeoaerseBiiaoh von dem NatriumaaXe der 2-Buten*2-hyd2t>xy-1-fnxlfoneäure besieliuie*«eiee Nntritiin-2*luton-2-tiydroiy-1-eulfoaat und den Katrltaeals der 2*Batae- -1-hydroxy-2-culföceHure beaiebon«»iieiet Notxlra^-feuten-i-tydxQjqr-'a~ßulfonat, w«lohe doroh tlneetsuae von Butadlenuonoaqrd alt Hatrlna« srilflt hargostallt wordec aela kunneea» beilelninga«elae Ph«3ylj>ropiol-P.s kunuen secondary glass formers, "le das KetrluBiel" der 2-Prcpen-1 ^ ulfonfläuro beaiehuasswoiae HatrIum-2-propen- 1-talitMut, The sodium is said to be the oleic acid chloride Nntrl ^ Ä - ^ - chlorine - ^ - buten-i-eolfonat and dae XeoaerseBiiaoh of the Sodium oxides of 2-butene * 2-hyd2t> xy-1-fnxlfonic acid are particularly common Nntritiin-2 * luton-2-thiydroiy-1-eulfoaat and the Katrltaas der 2 * Batae- -1-hydroxy-2-culföceHure beaiebon "" iieiet Notxlra ^ -feuten-i-tydxQjqr-'a ~ sulfonate, w «lohe doroh tlneetsuae from Butadlenuonoaqrd old Hatrlna« srilflt hargostallt wordec aela kunneea "beilelninga" elae Ph "3ylj> ropiol-

, In Verbindung alt den seleuadiren caanabildner den eekund&xen Olanaoildnem atmendet nexdan·, In connection old the seleuadiren caanabildner den eekund & xen Olanaoildnem breathes nexdan ·

Herkömmliche Bäder und Verfahren aom pConventional baths and procedures aom p

sind in ''Princlplee of Electroplating and electroforming", Aam baboon, Sol te 362 bis JdI, Überarbeitete dritte Anagabe, 1949, McGrait-iUll Bock Co., Ino», New YoIk1 und la "Modem Sleotroplatlng*, hsrtiUBge/seben von A» 0· Orey, eo«ie In "Tb» EXeotroohegloal Sooiety·, 1953» Seite 299 bis "555 beachrleben. SLe 8teuemng und fietzlebabe-are in '' Princlplee of Electroplating and electroforming ", Aam baboon, Sol te 362 bis JdI, Revised Third Announcement, 1949, McGrait-iUll Bock Co., Ino", New YoIk 1 and la "Modem Sleotroplatlng *, hsrtiUBge / seben von A »0 · Orey, eo« ie In "Tb» EXeotroohegloal Sooiety ·, 1953 »Pages 299 to " 555 beachrleben. SLe 8 control and fietzlebabe-

909833/10 5 ?y „u.. 909833/10 5? y " u ..

BAD ORIGINALBATH ORIGINAL

dingungen einschließlich dar Konzentration der Badb©stendteil·, de* pH-ffertea, der Temperatur, der Kathodenstromdiohte, uew· dieser bexk&enllchen BKder eind im allgemeinen auf die vorliegende Erfindung anwendbar. Prafctiach alle Ader zum 51 meniokelölektroplattleren enthalten Nie »1 sulfat, ein Chlorid, la allgemeinen Nickelchlorid, ein puffer ungsttit toi, im aUgenelnen Boraitore, und ein ,NetEiaittel, belaplalevelae Hatriaelaur/leulfet, Natri»di-(laaryl)- -Htheraulfat [sodiue üaor/l ether eulfate] bexiehungeweiee VstzSns- -T-ath^l-S-ffieth^l-^undeoanoietafat. Derartige Bäder umfaseetx die v,ohl bekenn ten Watts-Bßdor und atari chloridhaltigen Sftder. Jndere Biiüar können als Kiclcelquelle eine Koobination von Biokalflgoborat mit Niokolaulfat und Jliclcelohlorid oder eise Xoebination von Ilokel* fluoborat mit lliokelchlorid enthalten. SCypiaohe Watte-Äder end stark chloridhaltlge BÄder lind la den fabeUen II und III gestellt.Conditions including the concentration of the bathtub parts, the pH-value, the temperature, the cathode current consumption, and the like of these small cells and are generally applicable to the present invention. Practically all veins to the meniokelölektroplatteleren contain never »1 sulfate, a chloride, la general nickel chloride, a buffer ungsttit toi, in general Boraitore, and a , NetEiaittel, belaplalevelae Hatriaelaur / leulfet, Natri» di- (laaryl) - -Htherue [sodiaryl üaor / l ether eulfate] bexiehungeweiee VstzSns- -T-ath ^ lS-ffieth ^ l- ^ undeoanoietafat. Such baths include the v, ohl well-known Watts-Bßdor and atari chloride-containing baths. Other biofuels may contain a combination of biocalflgoborate with niocola sulfate and calcium chloride, or a combination of ilokelfluoborate with ilocel chloride, as the source of the calcium. Typical cotton-wool veins and baths with a high chloride content are placed in colors II and III.

Tatta-BidarTatta bidar Niokelsttlfat 200 bis 400 g/lNiokelsttlfat 200 to 400 g / l Hlckelchlorlu 30 ble 75 «AHlckelchlorlu 30 ble 75 «A Borsäure 30 ble 50 g/lBoric acid 30 ble 50 g / l Tenperatur 38 ble 650CTemperature 38 ble 65 0 C Bewegung Äechaniech und/oder left oder Fnapen der LB-Movement Äechaniech and / or left or Fnapen the LB-

eußg,uaw.eußg, etc.

pH-vert 2,5 biis 4,5 ela*tro»etrieohpH-vert 2.5 to 4.5 ela * tro »etrieoh

BAD ORIGINAUBAD ORIGINAU

- to -- to -

Hickelchlorid
nickeleulfatHickel chloride
nickel sulfate

Tempo ratur
BewegungSpeed ratur
Move

pH-WertPH value

HIHI

StarkStrong

BiidegBiideg

150 bis 300 g/1150 to 300 g / 1

40 bis 150 g/L40 to 150 g / L

3Q fcis 50 g/13Q fcis 50 g / 1

38 bis 65°C Jaeeasßiech uad/bder Iaift oder Pumpen der38 to 65 ° C Jaeeasßiech uad / bder Iaift or pumps the

SWg*SWg *

2,5 Me 4,5 elektroaetrlech2.5 Me 4.5 electroaetrlech

pde beaten PlatUeaningaersebnlaEe la e^-venieobea niedereaiaarf^uiVi3verfahren bextehuaagewaiae Übe« ugeverfahr©η «erden In nen dann erzielt» wenn eine Verfahrensweise sur Verhinderung dee armC1U9 hosichiingeweiß« SraohlSpfenB dee der Kathode urmittel^ar fcenadb barten dUnnen ?lline3 bezilglioh. des Katioaengehaltee eogewandt wird. Blue wird wUnaciienawerterwöiae duxoh Beviegen be^iehuneeweiee Rühren, wie Rühren mit Ixtftt Pumpen der 3jBmuig5 Bewagen des Kathouew., pde beaten PlatUeaningaersebnlaEe la e ^ -venieobea Niedereaiaarf ^ uiVi3verfahren bextehuaagewaiae practicing "ugeverfahr © η" grounding inside then achieved "if a procedure to prevent the armC 1 U9 hosichiingeweiß" SraohlSpfenBio barten. of the Katioaenhalte is applied. Blue will wUnaciienawerterwöiae duxoh Beviegen be ^ iehuneeweiee stirring, like stirring with Ixtft t pumps the 3jBmuig 5 wagons of the Kathouew.,

Dio Erfindung wird aß Hand der Iblgeoden nicht alsThe invention is not considered to be ate hand of the Iblgeoden

f iuf auf sä sendon Boiapiele. ztäfcar erläutert. In jedem der Beispiel« wurde ein näfiriges saures nicS»lhsItigee Bad »it den «»gegebenen pononten hsrgestallt, Die gelvaEieobe liiederaohlagang von licaceX 2iiehimgoweioe das galvanische öbersiehan nit Hiciel wurde durch BtB durchstchialcen elnea elektriiichßn Stromes dnroh einen el Ä trie oben Stromkreis mit einer iiiokelanoö^ iznd einer Kathode ma einen Met all blech beaiehungsweisö einer Metallplatte! iielohe beide in das BmA eingetaucht waren» diirohgeführt. JLo Säder murdeaa bewegt, iaf iuf auf Saendon Boiapiele. ztäfcar explains. In each of the examples, "a neat acidic bath" was designed with the "given pononts", the gelvaEieobe liiederaohlangang from licaceX 2iiehimgoweioe the galvanic overhead nit Hiciel was pierced by BtB through a btB through a dochialcen elnea electrical overhead current ^ iznd a cathode ma a metal sheet like a metal plate! iielohe both were immersed in the BmA "diirohgeführt. JLo Säder murdeaa moves, ia

90983371 0 5rf90 983 371 0 5rf

BAD ORIGINAL - H -BATHROOM ORIGINAL - H -

- ti -.- ti -.

dttroh eine alcb "bemgenäo Kathode. Eb «tirden in eilen Vereueben der Beiepiele glSnsenae galvanische Uberaüge erhalten.That is to say, an alcb "bemgenäo cathode. In hasty use of the examples of glSnsenae, galvanic coatings are obtained.

Beispiele 1 bin 14Examples 1 am 14

In den Beispielen 1 t»ia 14 cinschliee?.ioli maxu» daa folgende Stendazdbad sie GzimdllSfiiuig vemendetsIn Examples 1 »ia t 14 cinschliee? .Ioli MAXU" daa following Stendazdbad they GzimdllSfiiuig vemendets

300 g/L 6O300 g / L 6O

Borsäure
Hatrlna«iizyl8Ulfat 0,25Boric acid
Hatrlna «iizyl8Ulfat 0.25

BeaUglioh der obeolsolies Seseiöbnungen der pilnären 31ancbil&- r.or 1st die welter oben stelaende Satelle I tterensuslehen. Die sokundÄren öleisbildBer, «elobe in den Beispielen verwendet wurden, sind in der folgenden ?atolle IV sneeVBengeatellt.BeaUglioh the obeolsolies Seseiöbnung the pilnare 31ancbil & - r.or is the world-top satellite I tterensuslehen. the sokundÄren öleisbildBer, «elobe were used in the examples, are in the following? atolle IV sneeVBengeatellt.

Tabelle IVTable IV Setamflir®Setamflir®

Q.) o-BeneoeeiureeuljElaid (Heurlumaali)Q.) o-BeneoeeiureeuljElaid (Heurlumaali) H.) mbeneoleulfonaeidH.) mbeneoleulfonaeid I.) n9Nl»ble-(Phenylaiafion7l>-4f4I.) n 9 N l »ble- (Phenylaiafion7l> -4f4

j.) eulfoniertee Dibenathiojihendiojqrdj.) eulfonated Dibenathiojihendiojqrd

Dio Betunuäx^v; nilfegleusbiianer, welche in den Beispielen ver* wendot -.vurdon, elrd in der folgenden Tabelle V nie«Bmengeeteilt·Dio Betunuäx ^ v; nilfegleusbiianer, which in the examples wendot -.vurdon, elrd in the following table V never «B quantity divided ·

909833/10||909833/10 ||

- 12 -- 12 -

BAD ORIGINALBATH ORIGINAL

.. 12 -.. 12 -

«5cfcimflfire_ HjJLjfBg.l ffltsblldne r Hatrlunsal!« der j-Chlor-S-buten-i-sitlfonsifeir©«5cfcimflfire_ HjJLjfBg.l ffltsblldne r Hatrlunsal!« Der j-Chlor-S-buten-i-sitlfonsifeir ©

L > N atriums al β der ALlyleulfoanäujre besiehnngowoise Hetriua&llyl L > N atriums al β der ALlyleulfoanäujre besiehnngowoise Hetriua & llyl

su If or. atsu If or. at

In dan Beispielen bedeutetIn dan examples means

/pper© pro/ pper © pro

VIVI

Beispiel
Nr.example
No. ZuaätcoZuaätco Her«·
in g/1Her «·
in g / 1 Stromdicht©
in j/fo2 Current tight ©
in j / fo 2 Temperatur
in 0Ctemperature
in 0 C AA. 0,0200.020 11 OO 2,02.0 44th 6060 KK 5,05.0 BB. 0,OZ)0, OZ) 22 OO 2,02.0 44th 6060 KK 3,03.0 CC. 0,0200.020 33 QQ 2,02.0 44th KK 3tD3tD DD. 0,0300.030 ΛΛ 99 4,04.0 44th 6060 4,04.0 • i• i 0,0200.020 OO 2,02.0 44th 6060 EE. 3,03.0

909833/1051'909833/1051 '

- 13- 13

149690:149690:

>> 1 Γ>1 Γ> •• δδ .- 15 -.- 15 - StxoaiSiQa'teStxoaiSiQa'te II. la ula u Beispielexample κκ . Meng©. Meng © In ^/SfisIn ^ / Sfis !ir.! ir. AA. in s/Xin s / X 5050 1414th HH 0,0200.020 55 66th ICIC 2,02.0 BB. 5,05.0 6060 HH 0,0^>0.0 ^> 55 77th KK 4,04.0 BB. 4,04.0 βοβο HH 0,0300.030 44th η
«»ιη
«» Ι KK 4,04.0 εε 3,03.0 5555 00 0,0550.055 55 αα ££ 2,02.0 B ;B; 4,04.0 βοβο II. 0,0200.020 44th ;ο; ο hH 4,04.0 ] A] A 2,02.0 ■ 60 - .■ 60 -. ' J'J 0,0300.030 55 1111 KK 2,02.0 BB. 2,02.0 5050 σσ 0,0200.020 ■■ ■♦■".■■ ■ ♦ ■ ". ..J2 ..J 2 κκ 4,04.0 AA. 3,03.0 6Q "ν 6Q "ν GG 0,OS)0, OS) 55 LL. 2,02.0 3,03.0 5555 0,0200.020 44th 2,02.0 2,02.0

3AD ORIGINAL3AD ORIGINAL

BAD ORIGINALBATH ORIGINAL

COPYCOPY

-U--U-

14969061496906

in dem hoS.Bpi.olen 15 big 16 ©insohlSeHlloh r/urda das
jtandardbad sis GrumllÜBunsin the hoS.Bpi.olen 15 big 16 © insohlSeHlloh r / urda das
jtandardbad sis GrumllÜBuns

FTickelahloridFTickel arylide 250250 sAsA RlckelattlfatBacklash 4545 Borsäur©Boric acid © 4545 s/is / i HatXlialaiXrlKl**HatXlialaiXrlKl ** 00 »25»25 Vilbel le VIIVilbel le VII

1spiel1game AA. ESengeTight StzosäiobteStzosäiobte Tem ^e re türTem ^ e re door KIT.KIT. O ·
1O ·
1 in sAin sA in 0Cin 0 C KK 0,0200.020 AA. 2,02.0 66th 6060 QQ 5,05.0 LL. 0,0150.015 1616 ■■ " K ,■■ "K, 2s02 s 0 δδ 6060 αα 2*02 * 0 .' 'X" ·"". ' 'X "·" " 0,0150.015 1717th BB. 2?02 ? 0 55 6565 -- HH 3*03 * 0 LL. 0,0150.015 18 . .18th . 2.02.0 55 6060 3,03.0

obigen Beispieleabove examples

ist klar.is clear.

ßpessiell© Mder xsaä undßpessiell © Mder xsaä and

- 15 - - 15 -

BADBATH

verliert «eraes künn©n% Zwar wurden die Keliwg- uad ^ at rl us «β h&ufigaten verweiset and bevorzugt, sie können ^edooh ziaa Teil oder vollständig öuroh eolohe anders Raise «ie f es«, ersetzt «erden.loses "eraes künn © n% Admittedly the Keliwg- uad ^ at rl us" β were often relegated to and preferred, they can be replaced in part or completely in other ways.

Dlo 003 Bädern unter Vollendung aer neuenDlo 003 baths under completion of the new ones

erscogtea gslveniBcbon. HiotelUbcrxUgo sind vorteilhaft, epiejseleianaapdii saLvviieoho Ubervsüge mit eine® hchoß Or$A voi beBlefaax^BneJLse Gesolmeidigkeit in eines weiten Ketho-erscogtea gslveniBcbon. HiotelUbcrxUgo are beneficial, epiejseleianaapdii saLvviieoho Ubervsugt with a® hchoß Or $ A voi beBlefaax ^ BneJLse solubility in a wide Ketho-

ezfaaLten «erden. QLe g«lr«iiaehen Qlenmniafcel^ «erden voragewelee caf Kupfer- beiiehungenei^e EupferXtgionmgsgrantaotalle plattiert. Sie kXSnnen Jedooh «ich direkt e öl ehe Me toi le «ie Sleon, Stahl, uew. gelvanitoh fcezlehungavolae ehgeec^iedtn werden.ezfaaLten «earth. QLe g «lr« iiaehen Qlenmniafcel ^ «Earth voragewelee caf copper attachments e ^ e EupferXtgionmgsgrantaotalle plated. You can tell me directly e Öl ehe Me toi le «ie Sleon, Stahl, uew. gelvanitoh fcezlehungavolae ehgeec ^ iedtn be.

IkLe prinÄren derartstldner noch der ErflÄdong können duroh die UbootsoneIkLe principals of this kind nor can the erflÄdong through the Ubootsone

Bft B ft

-OeC-H-OeC-H

worin A und B joweüa für Wasserstoff, Cnxbonelureemld- ( - C - MBgwhere A and B joweüa for hydrogen, Cnxbonelureemld- (- C - MBg

Aoatyl- ( - ο - CH,) beciefaungeweie· Oerboouithosjgruppen ( - C - OG stehen und X ein >cilonf voreußeweio· Haloeen, bedeutet, wobei siede st ens eines vcn A und B von üaseerotoff verschieden ist, hergectcllAoatyl- (- ο - CH,) beciefaungeweie Oerboouithosjgruppen (- C - OG stand and X a> cilon f vorusseweio Haloeen, means, whereby one of A and B is different from üaseerotoff, hergectcll

C0PY BAD C0PY BATH

ntrften. so kein beleplelRvTelne die hotqrocyoliecho Vor bindung ein in der >»Steilistg enbetitulerteo Pyridin ber.lcbungoweioe «In in der eubotituiertes Pyriöin,found. so no beleplelRvTelne the hotqrocyoliecho pre-tying in the> »Steilistg enbetitulerteo pyridine ber.lcbungoweioe« In in the eubotituted pyrioin,

r.Gin.r.Gin.

Tyi'i3Che 1« Verfahren nach der Erfindung verwendbar« Rcaktlone-Tyi'i3Che 1 "method according to the invention can be used" Rcaktlone-

derthe

CrCr

uai'aaaemuai'aaaem

>Cnrbcn8fture#oidpyridln (Niootlnsäureiiald)> Cnrbcn8fture # oidpyridln (Niootlnsäureiiald)

(Klcotlnßäaree«thyleatGr besiehungsweiae(Klcotlnßäaree «thyleatGr reference white

3- Aoetylpyrldln3- Aoe tylpyrldln

Typliohe la Vertehren neoh der Erfindung verwentfbere Bealctlonctellneheer der foxaelType of defense against the invention, use Bealctlonctellneheer the foxael

909833/ U>M BAD ORIGINAL909833 / U> M BATH ORIGINAL

- 17 -- 17 -

4-Carbuaethox«pyridln (Iaonicotinsäuxemethylester beslehungsweiße4-Carbuaethox «pyridln (Iaonicotinsäuxemethylester beslehweiße

«ethyl tsont oo t; i η at)«Ethyl tsont oo t; i η at)

4- Acotylpyxidla4- Acotylpyxidla

Typlach· verwendbare ReaktionεΐβIlnehtner der Foxmel H-0"O-C-JC nnfaeaen diejenigen, in welchen X Halogen letTypplach · usable reaction εΐβIinntner of the foxmel H-0 "O-C-JC suitable for those in which X let halogen

Wogen 0er Leichtigkei t der OMetrung und dor Verfügbarkeit latWaves of ease of approach and availability lat

jpropargylbxoKld (H- CeO- O- Br) em me la ten bevorsugt.jpropargylbxoKld (H- CeO- O- Br) em mes are prevented.

H2 H 2

Ba ist klar, dad Inerte Babstituenten aufweisende Reaktion»- teilnehmer verwendet worden kennen.It is clear that the reaction has inert baby substituents »- participants have been used to know.

Sie Otaeetsung der heterocycliceheη Verbindung mit den aoetyleungee&tUgten Halogenid kann beispielsweise unter milden Be-They Otaeetsung the heterocycliceheη connection with the aoetyleungee & tUgten Halide can, for example, under mild conditions

vorsagawelee Ia Gegenwart eines Lösung emittele, durchgeführt worden. Die Utasetetmg kann leioht in hoher Ausbeute, sum Beispiel bei Rautotemperator unter schwacher gnafirnjung, die la allgemeinen «i Beginn dor Reaktion euftritt» erfolgen. Das Produkt lit im nilgemeinen ein wohl definiert er krletalliner feeter Stoff, welcher tue den Reaktionaeyaten gewonnen werden kenn, belaplelawelee doroh Filtrieren und darauffolgende« taschen mit einem pasaenden Itfsungenlttel, wie Aoeton· KLn ttokrlat all! eier en lat la allgemeinen unnUtlg und das Produkt kann leioht an dor Luft getrocknet werden.vorsagawelee Ia presence of a solution emittele, has been carried out. The use can be carried out in high yield, for example at room temperature under weak conditions, which are generally "at the beginning of the reaction". The product lit in nilgemeinen a well-defining krletalliner feeter substance which do the Reaktionaeyaten mark be won belaplelawelee doroh filtration and subsequent "bags with a pasaenden Itfsungenlttel as Aoeton · KLn ttokrlat all! Eggs en lat la generally unnecessary and the product can be dried in the air.

die Umsetzung kann in Gegenwart von inerten IiSaungaaltteln, vor-the reaction can take place in the presence of inert IiSaungaaltteln,

• BAD ORIGINAL - 18 -• ORIGINAL BATHROOM - 18 -

909833/10#tr 909833/10 # t r

von Aoeton, Dimethyl to rm/tcu id besienmgsweise AiroligofUhrfc werden.from Aoeton, Dimethyl to rm / tcu id usually AiroligofUhrfc.

Dia lnirchfUnruag <ier UEoetsimg lc on η das Ionen von 1 Mol eier hetero cy el in ehe» Verbindnns in einem tiberoahuß dos I-ö sung ntnlt tele, dar ausreicht, üb dl« Vßi*binÄBn£ cu J.Ösen,
das Iö en ng aal tt el in dar >- bis 4-faohen üfsige des Qevloiitee der cuge^en eoin. Zu dieeex Ulocnung kann mlndeetesu3 1 Mol, vox-Dia lnirchfUnruag <ier UEoetsimg lc on η the ions of 1 mole egg hetero cy el in before "connection in a tiberoahuss dos I-solution ntnlt tele, that is sufficient to the" Vßi * binÄBn £ cu J.Ösen,
das Iö en ng aal tt el in dar> - up to 4-faohen üfsige des Qevloiitee der cuge ^ en eoin. For this purpose, mlendeetesu3 1 mol, vox-

1 bie 1j3 ISoI9 AOetylünlech tm^osüttißtee Halogenid, Inebesondere Piepaxgylbroßid, sueegebon «erden. Die Mlsofaung terra bei nautnt9isper«tnr 2 Stunden bis id ohr ere Tcgo ^e nach den «pCBiell herzuntellonden Produkt stebtneelaeuen we1 bie 1j3 ISoI 9 AOetylünlech tm ^ ossüttisstee halide, in particular Piepaxgylbroßid, sueegebon «earth. The terrace sofa at night time is 2 hours to the hour before the day after the pCBiell heart-shaped product starts new

UberfUlu^ing dor ncoes Verbindungen derOverfUlu ^ ing dor ncoes compounds the

In anößre neue* Vorbindungon bei tier Durchführung d«r Erfindung keen durch tireetzen dcrcolben beispielsweise mit luellchan von βTwUnσchten /siionen, wie Ao^tston, SuIf©tea, Perahloraten» , usvr., baworfcstol.ligt warden· Bsispielsn^is® fceaaIn another new pre-commitment to the implementation of the invention by treading dcrcolben with luellchan, for example of βTwUnσchten / siionen, such as Ao ^ tston, SuIf © tea, Perahloraten » , usvr., baworfcstol.ligt warden · Examplesn ^ is® fceaa

In einem Tssißrigea Medium duroh VersiS.Eoli©n von Mengen flor Resktioagtellncitoer und ,Ab'fil tr leren d®@ . berh&lozonides, zvm BeispielIn a Tssißrigea medium duroh VersiS.Eoli © n of quantities flor Resktioagtellncitoer and, Ab'fil tr leren d® @. berh & lozonides, for example

BrBr

Ag — O - C - CH,Ag - O - C - CH,

I- H I- H

- CBC-H- CBC-H

durohgefiihrt «erden.earthed.

G-CSC-EG-CSC-E

0 -0 -

Die Herstellung «er neuen Verbindungen nach 4er Erfindung Hand der folgenden nicht al a Beaohrfcnkuns aafrcf weenden Äaiepi Idβ 21 naher erXlutert.The production of new compounds according to the invention Hand of the following not al a Beaohrfcnkuns aafrcf refer to Äaiepi Idβ 21 explained in more detail.

1919th

Ss «orden 55 β KiootanefeifreeKlä, 100 asr Dies thyIfD naeaid ccafi ca5 Propexeylbxeeld 68 staadea !«ag ^cI SesateaEperotu? laseen. Des lurlf^elline Produkt waj-äe abillirlfirt, Bit Ao*toa und en der Luft eetroelsaet· iyaebeatet 68 g (94$»)· 8e£aec2.c 1B7 Ms 1900C (SotaBttlspaa2c608Z&lttlaE$ in der Vsrricjfetezas ι Ss «orden 55 β KiootanefeifreeKlä, 100 asr Dies thyIfD naeaid ccafi ca 5 Propexeylbxeeld 68 staadea!« Ag ^ cI SesateaEperotu? read. The lurlf ^ Elline product WAJ AEE abillirlfirt, bit Ao * toa and en air eetroelsaet · iyaebeatet 68 g (94 $ ") · 8e £ aec2.c 1B7 Ms 190 0 C (SotaBttlspaa2c608Z & lttlaE $ ι in Vsrricjfetezas

vpevpe

Εε wurden to g MiootlneiiarfsaetliyifeeterΕε were to g Miootlneiiarfsaetliyifeeter

.9 09833/10 ^.9 09833/10 ^

BAD ORKSNALBAD ORKSNAL

25 oti^ Dimethyl fonacnid uad 15 om^ Propargylbromld 3 Stunden lang bei Rauatenpexaliar atefeeaeelaeeen. Paa krletelllae Produkt rurfio ab filtriert, mit /co ton gewaaohen und en der Luft getroaknot. Ausbeute ι 15»55β (β3^)· Scbmelapunltti 155 Μ.α 136 0 (flehe r- -Johns).25 oti ^ Dimethyl fonacnid uad 15 om ^ Propargylbromld 3 For hours at Rauatenpexaliar atefeeaeelaeeen. Paa krletelllae product rurfio filtered off, Gewaaohen with / co ton and en the air getroaknot. Yield ι 15 »55β (β3 ^) · Scbmelapunltti 155 Μ.α 136 0 (flehe r- -Johns).

Bei an IeI 21 B ei to IeI 21

von 4~from 4 ~

Bs wunlon 10,8 g 4-Acetylpyrldlnt 25 co·5 Dim«thylfDrBieald und 10 cn'·5 Proporgylbxomid 25,5 Stunden lao£ bei Reuateoperatur etebeegelesaen. Zur Re&fctlonsrnlqchung «urdea 100 aa5 Aceton 9U£«6«b«a und das krlotelllno Produkt wurde ab filtriert, mit Aceton E9wmab*n «DA In oinnn Rub inicator getrocknet. AOabeutet 18» 1 β (9^)· Sohatlsptaktt dunkelt l&'x 195°C> scimilzt bei et«» 2800C unter Zerseteune (Tieher- -«Tohna).For example, 10.8 g of 4-acetylpyrldln t 25 co · 5 dimethylphenol and 10 cn · 5 proporgylbxomide were etebeegelesaen for 25.5 hours at the reuate operation. For Re & fctlonsrnlqchung "Urdea 100 aa 5 acetone 9U £" 6, "b" and a krlotelllno product was filtered off, washed with acetone E9wmab * n "DA In oinnn Rub Inicator dried. AO means 18 »1 β (9 ^) · Sohatlsptaktt darkens 1 &'x 195 ° C> scimelt at et« »280 0 C under Zerseteune (Tieher-« Tohna).

909833/1 Off BAD909833/1 Off BA D

Claims (3)

~ 21 -~ 21 - i.) Ve?£ahren β um galvanischen Hiedaraohlagen von Nickel besiehungeweiae Kreeugon von galvcnisohen NlckolUberzUgen aus w&B-rlgon Btidom sun Elektroplattieren mit Nickel mit einem Qehalt an einem aetamdären (EansbllAnes: und cine· primären Ol blldner, dadurch geJcenntoiohnet, daß man ale prlttären bllöner eine Verbindung nit einem Kation der Strukturi.) The process of galvanic deposition of nickel deposits Kreeugon of galvanized plastic coatings from w & B-rlgon Btidom sun electroplating with nickel with a content on an aetamdary (EansbllAnes: and cineprimary oil Bluerdner, acknowledged by the fact that all of them were preluded but a compound with a cation of the structure 0 - C B GH0 - C B GH A und B fttx faßeeratoff, Oerbon»*ureaMio> ( - 0 - HL·)»A and B fttx faßeeratoff, Oerbon »* ureaMio> (- 0 - HL ·) » 0
Aoötyl- ( - o - CH^) beslehuflgewelee Oiirboaethoxysruppen0
Aoötyl- (- o - CH ^) beslehuflgewelee Oiirboaethoxysruppen ( - 0. - OCH,) stehen, wobei mindesten· ein·· von A und B Wasoeratoff vcrechieden ist, verwendet.(- 0. - OCH,), where at least one of A and B Wasoeratoff is used. 2.) Vermehren neon /aapraoh 1, daduroh geketm»eiohnet, dmi um (Mn primären Olcpsblldner in einer Menge von 0*005 bis O910 g/l verwendet.2.) Increase neon / aapraoh 1, daduroh ketm »eiohnet, dmi um (Mn primary olecpants in an amount of 0 * 005 to 0 9 10 g / l used. 3.) . Verfahren neon jsiepruch 1, dedurch gekenneelohoet, άβΜ mm el· prlfflärexi OlansbilAner ^CorbcmeÄureiÄiA-N^ropereylpyridiue^LWÄ3.). Procedure neon jsiekret 1, dedurch gekenneelohoet, άβΜ mm elprlfflärexi OlansbilAner ^ CorbcmeÄureiÄiA-N ^ ropereylpyridiue ^ LWÄ H^rop^eylpyiAdlniuttbxaeJLd, 5-H ^ rop ^ eylpyiAdlniuttbxaeJLd, 5- - 22 -- 22 - 9 0 9 8 3 3 / 1 0 ί 7 BAD 9 0 9 8 3 3/1 0 ί 7 BAD 14969061496906 4-Carbon© thoay-4-carbon © thoay- bromiä
verwendetbromiä
used λ .) v&ßrlgoa KLelrtrolyeenbad m galvenlvobea ÄUdexiohltgen Nlcücol mit einea o«h«Lt m 10allob«D 8altn aar des Verfahrens nach jnapsnoh 1 bla 5» dlÄarohλ.) v & ßrlgoa KLelrtrolyeenbad m galvenlvobea ÄUdexiohltgen Nlcücol with a o «h« Lt m 10allob «D 8altn aar of the procedure according to jnapsnoh 1 bla 5» dlÄaroh daß man al ο prim Urea OlaiieMldn^r «ine Vtrttnd^g Bit e±nm a dar strukturthat one al ο prim Urea OlaiieMldn ^ r «ine Vtrttnd ^ g Bit e ± nm a dar structure v.orin A und B nie Im Aieprtieh 1 ft»tgelee* sind, verwendet.v.orin A and B are never used in the Aieprtieh 1 ft »tgelee *. s.) Bad nach ^apruch 4* dadurch gelcemuelohiiet, daß der prUAre aienafbildner in oinor lien&Q von 0,005 ble 0,10 g/X See.) Bad according to April 4 * is gelcemuelohiiet that the prUAre aienafbildner in oinor lines & Q of 0.005 ble 0.10 g / X b.) Boa ntioJi ^rispruoh 4 odor 5» dadurch gelceiuiBelohnet, daß der primäre Glanrbildnor eise Verbindung derb.) Boa ntioJi ^ rispruoh 4 odor 5 »rewarded by the fact that the primary Glanrbildnor ice connection of the 0 - Ol0 - H0 - Ol0 - H irir - 23 809833/ 10 6 7 BÄD original- 23 809833/10 6 7 BÄD original -.a,- 1*96908-.a, - 1 * 96908 worin α tt&d B wie* ta .«iQpxuah 1 festgelegt sind and X ein Anion bedeutet, ist.where α tt & d B like * ta. «iQpxuah 1 are fixed and X a Anion means is. v.) Bad nach /ftapxuoh 4 bis 6, dadurch gekennzeiöhnet, d&Q dearv.) Bad according to / ftapxuoh 4 to 6, thereby marked, d & Q dear 4-I.romId bozletemßiwoleo >Afl*tyHi-pxopitrgylpyrldiniumbioiild int.4-I.romId bozletemßiwoleo> Afl * tyHi-pxopitrgylpyrldiniumbioiild int. ΜΜΝβ. a FINCtt 0ΙΗ.·«·.Η.·Ο·· WH-4MG. B. STAMMΜΜΝβ. a FINCtt 0ΙΗ. · «· .Η. · Ο ·· WH-4MG. B. TRUNK ORIGINALORIGINAL 909833/1057909833/1057
DE1496908A 1964-02-24 1965-02-23 Galvanic nickel bath. Note »M&T Chemicals Inc., New York, N.Y. (V.StA.) Expired DE1496908C3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US347046A US3296103A (en) 1964-02-24 1964-02-24 Bright nickel electroplating

Publications (3)

Publication Number Publication Date
DE1496908A1 true DE1496908A1 (en) 1969-08-14
DE1496908B2 DE1496908B2 (en) 1973-03-15
DE1496908C3 DE1496908C3 (en) 1973-10-04

Family

ID=23362091

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1496908A Expired DE1496908C3 (en) 1964-02-24 1965-02-23 Galvanic nickel bath. Note »M&T Chemicals Inc., New York, N.Y. (V.StA.)

Country Status (5)

Country Link
US (1) US3296103A (en)
CH (1) CH466662A (en)
DE (1) DE1496908C3 (en)
GB (2) GB1097723A (en)
NL (1) NL148657B (en)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2938033A (en) * 1960-05-24 Stabilization of vinylpyridines
BE511322A (en) * 1946-04-20
US2647866A (en) * 1950-07-17 1953-08-04 Udylite Corp Electroplating of nickel
US2749349A (en) * 1956-02-02 1956-06-05 Reilly Tar & Chem Corp Vinylpyridine-nu-oxides and process of making them
US3006822A (en) * 1957-05-08 1961-10-31 Langbein Pfanhauser Werke Ag Electro-deposition of nickel coatings
DE1066068B (en) * 1957-06-05 1959-09-24 Langbein-Pfanhauser Werke Aktiengesellschaft, Neuß Electrolyte for galvanic deposition of mirror-shining, leveled, ductile nickel deposits
US3218244A (en) * 1963-02-01 1965-11-16 M & T Chemicals Inc Nickel electroplating bath containing a 1, 2-dichloropropene pyridinium or quinolinium brightener
US3170855A (en) * 1963-03-18 1965-02-23 Sarki Res And Dev Corp Bright nickel plating baths
US3170854A (en) * 1963-03-18 1965-02-23 Sarki Res And Dev Corp Bright nickel plating bath containing a pyridinium or quinolinium phosphate brightener and method of electroplating therewith

Also Published As

Publication number Publication date
CH466662A (en) 1968-12-15
NL148657B (en) 1976-02-16
DE1496908B2 (en) 1973-03-15
GB1097723A (en) 1968-01-03
NL6502195A (en) 1965-08-25
GB1097724A (en) 1968-01-03
US3296103A (en) 1967-01-03
DE1496908C3 (en) 1973-10-04

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C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977