DE1496908B2 - GALVANIC NICKEL BATH - Google Patents
GALVANIC NICKEL BATHInfo
- Publication number
- DE1496908B2 DE1496908B2 DE19651496908 DE1496908A DE1496908B2 DE 1496908 B2 DE1496908 B2 DE 1496908B2 DE 19651496908 DE19651496908 DE 19651496908 DE 1496908 A DE1496908 A DE 1496908A DE 1496908 B2 DE1496908 B2 DE 1496908B2
- Authority
- DE
- Germany
- Prior art keywords
- nickel
- propargylpyridinium
- bromide
- brighteners
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/46—Oxygen atoms
- C07D213/50—Ketonic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/80—Acids; Esters in position 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
- C07D213/82—Amides; Imides in position 3
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
- C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
- C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
- C25D3/18—Heterocyclic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pyridine Compounds (AREA)
Description
1010
N-C-C=CH
H2 NCC = CH
H 2
in der A und B Wasserstoff, Carbonsäureamid-, Acetyl- oder Carbomethoxygruppen und X ein Halogen bedeutet und mindestens eines von A und B verschieden von Wasserstoff ist, in einer Menge von 0,005 bis 0,1 g/l enthält.in which A and B are hydrogen, carboxamide, acetyl or carbomethoxy groups and X is Is halogen and at least one of A and B is different from hydrogen, in one Contains an amount of 0.005 to 0.1 g / l.
2. Bad nach Anspruch 1, dadurch gekennzeichnet, daß es als N-Propargylpyridiniumsalz 3-Carbonsäureamid - N - propargylpyridiniumbromid, 4- Carbonsäureamid - N- propargylpyridiniumbromid, 3 - Carbomethoxy - N - propargylpyridiniumbromid, 4 - Carbomethoxy - N - propargylpyridiniumbromid, 4 -Acetyl - N - propargylpyridiniumbromid bzw. 3-Acetyl-N-propargylpyridiniumbromid enthält.2. Bath according to claim 1, characterized in that it is 3-carboxamide as the N-propargylpyridinium salt - N - propargylpyridinium bromide, 4-carboxamide - N- propargylpyridinium bromide, 3 - carbomethoxy - N - propargylpyridinium bromide, 4 - carbomethoxy - N - propargylpyridinium bromide, 4-acetyl-N-propargylpyridinium bromide or 3-acetyl-N-propargylpyridinium bromide contains.
3-Sulfo-N-propargyl-pyridinium-bromid vorgeschlagen. Es hat sich jedoch gezeigt, daß der Glanzeffekt dieser Verbindung verhältnismäßig gering ist. Aus diesem Grunde müssen sehr große Mengen dieser Verbindung verwendet werden. Dies ist nicht nur vom wirtschaftlichen Standpunkt aus unerwünscht, sondern führt auch dazu, daß das Bad schnell mit organischen Zersetzungsprodukten verunreinigt wird.3-sulfo-N-propargyl-pyridinium-bromide suggested. However, it has been shown that the gloss effect of this compound is relatively small. the end for this reason, very large amounts of this compound must be used. This is not just dated from an economic point of view undesirable, but also leads to the fact that the bath quickly with organic Decomposition products is contaminated.
Es wurde nunmehr gefunden, daß die obenerwähnten Nachteile dadurch beseitigt werden können, wenn man als primäres Glanzmittel ein spezielles N-Propargylpyridiniumsalz verwendet.It has now been found that the above-mentioned disadvantages can be eliminated if a special N-propargylpyridinium salt is used as the primary brightener.
So wird also gemäß der Erfindung ein galvanische N-Propargylpyridiniumsalze als Glanzbildner und sekundäre Glanzmittel enthaltendes Nickelbad vorgeschlagen, das dadurch gekennzeichnet ist, daß das Bad ein N-Propargylpyridiniumsalz der allgemeinen FormelThus, according to the invention, a galvanic N-propargylpyridinium salt is used as a brightener and Secondary brightening agent-containing nickel bath proposed, which is characterized in that the Bath an N-propargylpyridinium salt of the general formula
N-C-C=CH
H2 NCC = CH
H 2
3535
Die Erfindung bezieht sich auf ein galvanisches Nickelbad. Wenn man auf galvanischem Wege Nickelüberzüge herstellen will, dann muß man den Bädern sogenanntes Glanzmittel zusetzen. Man unterscheidet primäre Glanzmittel, die in sehr geringen Konzentrationen von beispielsweise 0,002 bis 0,2 g/l verwendet werden, und sekundäre Glanzmittel, welches beispielsweise in einer Konzentration von 1 bis 30 g/l verwendet werden. Die richtige Kombination dieser Materialien ergibt spiegelglänzende überzüge, wobei unter Umständen auch ein Einebnungseffekt zu verzeichnen ist.The invention relates to a galvanic nickel bath. If you have nickel plating by electroplating want to produce, then you have to add so-called brighteners to the baths. One distinguishes primary brighteners used in very low concentrations of, for example, 0.002 to 0.2 g / l and secondary brighteners, which can be used, for example, in a concentration of 1 to 30 g / l be used. The right combination of these materials results in mirror-like coatings, whereby under certain circumstances a leveling effect can also be recorded.
Es sind bereits verschiedene Glanznickelsysteme, die aus einer Kombination aus einem primären Glanzmittel und einem sekundären Glanzmittel bestehen, bekannt.There are already various bright nickel systems that consist of a combination of a primary brightening agent and a secondary brightener are known.
So ist in der deutschen Auslegeschrift 1 066 068 ein Glanznickelbad beschrieben, welches neben einem sekundären Glanzmittel, üblicherweise aromatische Sulfonsäuren, als primäres Glanzmittel ein Pyridiniumsalz enthält, das am Stickstoffatom durch eine Kette mit einer dreifachen Umsättigung substituiert ist und am Kern bis zu drei Halogenatome oder Sulfonsäuregruppen enthalten kann. Ein Beispiel für ein solches primäres Glanzmittel ist N-2-Propinpyridin-bromid. Ein Nachteil der mit solchen Bädern hergestellten Nickelüberzüge besteht darin, daß die Nickelüberzüge einen stark irisierenden Schleier innerhalb eines großen Stromdichtebereichs, der üblicherweise für die galvanische Abscheidung verwendet wird, zeigt.Thus, in the German Auslegeschrift 1 066 068, a bright nickel bath is described, which in addition to a secondary brighteners, usually aromatic sulfonic acids, as the primary brightener a pyridinium salt contains, which is substituted on the nitrogen atom by a chain with a triple unsaturation and can contain up to three halogen atoms or sulfonic acid groups on the core. An example one such primary brightener is N-2-propyne pyridine bromide. A disadvantage of the nickel coatings produced with such baths is that the Nickel coatings create a highly iridescent haze within a wide range of current densities that are commonly found used for electrodeposition shows.
Ähnliche Bäder sind aus der USA.-Patentschrift 3 006 822 bekannt. Als primäres Glanzmittel wird dort in der A und B Wasserstoff, Carbonsäureamid-, Acetyl- oder Carbomethoxygruppen und X ein Halogen bedeutet und mindestens eines von A und B verschieden von Wasserstoff ist, in einer Menge von 0,005 bis 0,1 g/l enthält.Similar baths are known from U.S. Patent 3,006,822. As the primary brightener there is in which A and B are hydrogen, carboxamide, acetyl or carbomethoxy groups and X is a halogen and at least one of A and B is other than hydrogen, in an amount of Contains 0.005 to 0.1 g / l.
Die erfindungsgemäßen Nickelbäder ergeben brillante Nickelabscheidungen mit einer vorzüglichen Duktilität und einer guten Glanzentwicklung im Bereich niedriger Stromdichte. Außerdem ist die Einebnungsgeschwindigkeit sehr hoch. Ein wesentlicher Vorteil der erfindungsgemäßen Bäder ist, daß die Glanzmittel innerhalb verhältnismäßig großer Konzentrationen enthalten sein können, so daß eine genaue Kontrolle der Konzentrationen der Glanzmittel im Bad nicht nötig ist.The nickel baths according to the invention produce brilliant nickel deposits with an excellent one Ductility and good gloss development in the area of low current density. In addition, the leveling speed is very high. A major advantage of the baths according to the invention is that the brighteners can be used within relatively large concentrations may be included, so that a precise control of the concentrations of the brighteners in the Bath is not necessary.
Ein anderer Vorteil liegt darin, daß die im erfindungsgemäßen Bad enthaltenen Glanzmittel auch bei langer Elektrolyse keine schädlichen Zersetzungsprodukte bilden. Another advantage is that the brighteners contained in the bath according to the invention are also included do not form harmful decomposition products for long periods of electrolysis.
Die primären Glanzmittel sind in einer Konzentration von 0,005 bis 0,10 g/l enthalten. Die jweils gewählte Konzentration hängt von der Badtype und auch von anderen Faktoren, wie z. B. Konzentration der Nickelsalze, den Arbeitsbedingungen, dem gewünschten Glanzgrad und dem gewünschten Einebnungsgrad ab. Konzentrationen zwischen 0,01 und 0,05 g/l werden bevorzugt verwendet.The primary brighteners are contained in a concentration of 0.005 to 0.10 g / l. The each The concentration chosen depends on the type of bath and other factors, such as B. Concentration the nickel salts, the working conditions, the desired degree of gloss and the desired level of flattening away. Concentrations between 0.01 and 0.05 g / l are preferred.
Typische Verbindungen, weiche als primäre Glanzmittel wirksam sind, sind die folgenden:Typical compounds that are effective as primary brighteners are as follows:
A. 3-Carbonsäureamid-N-propargylpyridiniumbromid, A. 3-carboxamide-N-propargylpyridinium bromide,
B. 3-Acetyl-N-propargyIpyridiniumbromid,B. 3-Acetyl-N-propargyIpyridinium bromide,
C. 3-Carbomethoxy-N-propargylpyridiniumbromid, C. 3-carbomethoxy-N-propargylpyridinium bromide,
D. 4-Carbonsäureamid-N-propargylpyridiniumbromid, D. 4-carboxamide-N-propargylpyridinium bromide,
E. 4-Acetyl-N-propargylpyridiniumbromid,E. 4-acetyl-N-propargylpyridinium bromide,
F. 4-Carbomethoxy-N-propargylpyridiniumbromid.F. 4-Carbomethoxy-N-propargylpyridinium bromide.
Sekundäre Glanzmittel, die beispielsweise in einer Menge von 1 bis 75 g/l, vorzugsweise 1 bis 20 g/l verwendet werden, sind im allgemeinen aromatische Sulfonate, Sulfonamide und Sulfimide. Spezielle Beispiele hierfür sind aromatische Verbindungen wie 1,3,6-Naphthalintrisulfonat, das Natrium- bzw. Kaliumsalz von Saccharin, das Natrium- oder Kaliumsalz von o-Sulfobenzaldehyd, Benzolsulfonamid, Benzolmonosulfonate usw. Für stark chloridhaltige Bäder wurden bevorzugt Sulfonierungsprodukte von Diphenyl verwendet.Secondary brighteners, used for example in an amount of 1 to 75 g / l, preferably 1 to 20 g / l are generally aromatic sulfonates, sulfonamides, and sulfimides. Specific examples this includes aromatic compounds such as 1,3,6-naphthalene trisulfonate, the sodium or potassium salt of saccharin, the sodium or potassium salt of o-sulfobenzaldehyde, benzenesulfonamide, benzene monosulfonates etc. For baths with a high chloride content, sulfonation products of diphenyl are preferred used.
Es können zusätzlich auch sekundäre Hilfsglanzmittel anwesend sein, z. B. das Natriumsalz der 2-Propen-1-sulfonsäure, das Natriumsalz der 3-Chloro-2-buten-l-sulfonsäure, die gemischten Isomere des Natriumsalzes von 2-Buten-2-hydroxy-l-sulfonsäure und des Natriumsalzes von 2-Buten-l-hydroxy-2-sulfonsäure, oder Phenyl-propiolamid.Secondary auxiliary gloss agents can also be present, e.g. B. the sodium salt of 2-propene-1-sulfonic acid, the sodium salt of 3-chloro-2-butene-l-sulfonic acid, the mixed isomers of the sodium salt of 2-butene-2-hydroxy-1-sulfonic acid and the sodium salt of 2-butene-1-hydroxy-2-sulfonic acid, or phenyl propiolamide.
Typische Watts-Bäder und stark chloridhaltige Bäder sind in den Tabellen II und III zusammengestellt. Typical Watts baths and baths with a high chloride content are listed in Tables II and III.
Tabelle II
Watts-BäderTable II
Watts baths
Nickelsulfat 200 bis 400 g/lNickel sulfate 200 to 400 g / l
Nickelchlorid 30 bis 75 g/lNickel chloride 30 to 75 g / l
Borsäure 30 bis 50 g/lBoric acid 30 to 50 g / l
Temperatur 38 bis 65° CTemperature 38 to 65 ° C
Bewegung mechanischMechanical movement
und/oder Luft oder Pumpen der Lösung usw.and / or air or pumping the solution, etc.
pH-Wert 2,5 bis 4,5pH 2.5 to 4.5
elektrometrischelectrometric
Tabelle III
Stark chloridhaltige BäderTable III
Baths with a high concentration of chloride
Nickelchlorid 150 bis 300 g/lNickel chloride 150 to 300 g / l
Nickelsulfat 40 bis 150 g/lNickel sulfate 40 to 150 g / l
Borsäure 30 bis 50 g/lBoric acid 30 to 50 g / l
Temperatur 38 bis 65°CTemperature 38 to 65 ° C
Bewegung mechanischMechanical movement
und/oder Luft oder Pumpen der Lösung usw.and / or air or pumping the solution, etc.
pH-Wert 2,5 bis 4,5pH 2.5 to 4.5
elektrometrischelectrometric
Die Erfindung wird an Hand der folgenden Beispiele näher erläutert. In jedem der Beispiele wurde ein Nickelbad mit den angegebenen Komponenten hergestellt. Während der Abscheidung wurden die Bäder bewegt. In allen Beispielen wurden glänzende galvanische überzüge erhalten.The invention is explained in more detail with reference to the following examples. In each of the examples there was a Nickel bath made with the specified components. During the deposition, the baths were emotional. In all examples shiny electroplated coatings were obtained.
Beispiele 1 bis 14Examples 1 to 14
In den Beispielen 1 bis 14 einschließlich wurde das folgende Standardbad als Grundlösung verwendet:In Examples 1 to 14 inclusive, the following standard bath was used as the base solution:
Nickelsulfat 300 g/lNickel sulfate 300 g / l
Nickelchlorid 60 g/lNickel chloride 60 g / l
Borsäure 45 g/lBoric acid 45 g / l
Natriumlaurylsulfat 0,25 g/lSodium Lauryl Sulphate 0.25 g / l
Bezüglich der chemischen Bezeichnungen der primären Glanzmittel wird auf die weiter oben stehende Tabelle I hingewiesen. Die sekundären Glanzmittel, welche in den Beispielen verwendet wurden, sind in der folgenden Tabelle IV zusammengestellt.Regarding the chemical names of the primary brighteners, see above Table I noted. The secondary brighteners used in the examples are shown in FIG compiled below Table IV.
Sekundäre GlanzmittelSecondary brighteners
G. o-Benzoesäuresulfimid (Natriumsalz), H. Dibenzolsulfonamid, I. N,N'-Bis-(phenylsulfonyl)-4,4'-diphenyl-G. o-Benzoesäuresulfimid (sodium salt), H. Dibenzenesulfonamid, I. N, N'-bis (phenylsulfonyl) -4,4'-diphenyl-
disulfonamid,
J. sulfoniertes Dibenzthiophendioxyd.disulfonamide,
J. Sulphonated Dibenzothiophene Dioxide.
Die sekundären Hilfsglanzmittel, welche in den Beispielen verwendet wurden, sind in der folgenden Tabelle V zusammengestellt.The secondary gloss agents used in the examples are in the following table V compiled.
Sekundäre HilfsglanzmittelSecondary auxiliary gloss agents
K. Natriumsalz der 3-Chlor-2-buten-l-sulfonsäure, L. Natriumsalz der Allylsulfonsäure.K. sodium salt of 3-chloro-2-butene-1-sulfonic acid, L. sodium salt of allylsulfonic acid.
Fortsetzungcontinuation
Beispiele 15 bis 18 Die aus Bädern unter Verwendung der neuen GlanzExamples 15-18 Die from baths using the new gloss
mittelkombination abgeschiedenen NickelüberzügeMedium combination of deposited nickel coatings
In den Beispielen 15 bis 18 wurde das folgende 25 sind vorteilhaft, indem spiegelglänzende galvanische Standardbad als Grundlösung verwendet: überzüge mit einem hohen Grad von BiegsamkeitIn Examples 15 to 18, the following 25 are advantageous by using mirror-finish galvanic Standard bath used as the basic solution: coatings with a high degree of flexibility
bzw. Geschmeidigkeit in einem weiten Kathoden-Nickelchlorid 250 g/l Stromdichtebereich erhalten wecden. Die galvanischenor flexibility in a wide cathode nickel chloride 250 g / l current density range was obtained. The galvanic
Nickelsulfat 45 g/l Glanznickelüberzüge werden vorzugsweise auf Kup- Nickel sulfate 45 g / l bright nickel coatings are preferably applied to copper
Borsäure 45 g/l 30 fer- bzw. Kupferlegierungsgrundmetalle oder auchBoric acid 45 g / l 30 ferrous or copper alloy base metals or also
Natriumlaurylsulfat 0,25 g/l direkt auf Eisen oder Stahl abgeschieden.Sodium lauryl sulfate 0.25 g / l deposited directly on iron or steel.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US347046A US3296103A (en) | 1964-02-24 | 1964-02-24 | Bright nickel electroplating |
Publications (3)
Publication Number | Publication Date |
---|---|
DE1496908A1 DE1496908A1 (en) | 1969-08-14 |
DE1496908B2 true DE1496908B2 (en) | 1973-03-15 |
DE1496908C3 DE1496908C3 (en) | 1973-10-04 |
Family
ID=23362091
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1496908A Expired DE1496908C3 (en) | 1964-02-24 | 1965-02-23 | Galvanic nickel bath. Note »M&T Chemicals Inc., New York, N.Y. (V.StA.) |
Country Status (5)
Country | Link |
---|---|
US (1) | US3296103A (en) |
CH (1) | CH466662A (en) |
DE (1) | DE1496908C3 (en) |
GB (2) | GB1097723A (en) |
NL (1) | NL148657B (en) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2938033A (en) * | 1960-05-24 | Stabilization of vinylpyridines | ||
BE511322A (en) * | 1946-04-20 | |||
US2647866A (en) * | 1950-07-17 | 1953-08-04 | Udylite Corp | Electroplating of nickel |
US2749349A (en) * | 1956-02-02 | 1956-06-05 | Reilly Tar & Chem Corp | Vinylpyridine-nu-oxides and process of making them |
US3006822A (en) * | 1957-05-08 | 1961-10-31 | Langbein Pfanhauser Werke Ag | Electro-deposition of nickel coatings |
DE1066068B (en) * | 1957-06-05 | 1959-09-24 | Langbein-Pfanhauser Werke Aktiengesellschaft, Neuß | Electrolyte for galvanic deposition of mirror-shining, leveled, ductile nickel deposits |
US3218244A (en) * | 1963-02-01 | 1965-11-16 | M & T Chemicals Inc | Nickel electroplating bath containing a 1, 2-dichloropropene pyridinium or quinolinium brightener |
US3170854A (en) * | 1963-03-18 | 1965-02-23 | Sarki Res And Dev Corp | Bright nickel plating bath containing a pyridinium or quinolinium phosphate brightener and method of electroplating therewith |
US3170855A (en) * | 1963-03-18 | 1965-02-23 | Sarki Res And Dev Corp | Bright nickel plating baths |
-
1964
- 1964-02-24 US US347046A patent/US3296103A/en not_active Expired - Lifetime
-
1965
- 1965-01-28 GB GB3849/65A patent/GB1097723A/en not_active Expired
- 1965-01-28 GB GB34038/67A patent/GB1097724A/en not_active Expired
- 1965-02-22 NL NL656502195A patent/NL148657B/en not_active IP Right Cessation
- 1965-02-22 CH CH238065A patent/CH466662A/en unknown
- 1965-02-23 DE DE1496908A patent/DE1496908C3/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL6502195A (en) | 1965-08-25 |
GB1097724A (en) | 1968-01-03 |
GB1097723A (en) | 1968-01-03 |
CH466662A (en) | 1968-12-15 |
DE1496908A1 (en) | 1969-08-14 |
DE1496908C3 (en) | 1973-10-04 |
NL148657B (en) | 1976-02-16 |
US3296103A (en) | 1967-01-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE971806C (en) | Electroplated nickel plating | |
DE1007592B (en) | Bath for the production of galvanic metal coatings | |
DE832982C (en) | Electrolyte and process for the electrodeposition of copper | |
DE2630980C2 (en) | ||
DE2537065C2 (en) | ||
DE1071439B (en) | Acid bath for the galvanic deposition of nickel coatings | |
DE1106139B (en) | Bath and process for the galvanic deposition of nickel coatings | |
DE1496908C3 (en) | Galvanic nickel bath. Note »M&T Chemicals Inc., New York, N.Y. (V.StA.) | |
CH640888A5 (en) | METHOD FOR THE GALVANIC DEPOSITION OF AN IRON AND NICKEL AND / OR COBALT CONTAINING RAIN AND A SUITABLE BATH FOR THIS. | |
DE2366419C2 (en) | ||
DE1621186B1 (en) | Galvanic chrome bath with additives that prevent spray mist | |
DE1237870B (en) | Acid galvanic nickel bath | |
DE1621116C3 (en) | Bright nickel bath | |
DE888191C (en) | Bath and process for galvanic nickel plating | |
DE2450133A1 (en) | PROCESS AND GALVANIC BATH FOR DEPOSITING NICKEL / IRON AND NICKEL / COBALT / IRON ALLOYS | |
DE1496919C3 (en) | Aqueous galvanic nickel bath | |
DE2541304A1 (en) | METHOD AND BATH FOR GALVANIC DEPOSITION OF IRON ALLOYS | |
DE1151706B (en) | Acid galvanic nickel bath | |
DE2020840A1 (en) | Bath for the galvanic deposition of nickel and nickel alloys | |
DE1208593B (en) | Acid galvanic nickel bath for the deposition of semi-glossy coatings | |
DE971335C (en) | Bright nickel plating | |
DE1470061B2 (en) | SHINY NICKEL BATH | |
DE1190287B (en) | Aqueous bath for galvanic nickel plating | |
DE2743847A1 (en) | METHOD FOR GALVANIC DEPOSITION OF NICKEL AND COBALT ALONE OR AS BINARY OR TERNAIRE ALLOYS | |
DE2948999C2 (en) | Aqueous, acidic bath for the electrodeposition of gold and method for the electrodeposition of hard gold with its use |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C3 | Grant after two publication steps (3rd publication) | ||
E77 | Valid patent as to the heymanns-index 1977 |