DE112012001241A5 - Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen - Google Patents

Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen Download PDF

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Publication number
DE112012001241A5
DE112012001241A5 DE112012001241.0T DE112012001241T DE112012001241A5 DE 112012001241 A5 DE112012001241 A5 DE 112012001241A5 DE 112012001241 T DE112012001241 T DE 112012001241T DE 112012001241 A5 DE112012001241 A5 DE 112012001241A5
Authority
DE
Germany
Prior art keywords
oxygenates
olefins
conversion
modified catalyst
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE112012001241.0T
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English (en)
Inventor
Dr. Burgfels Götz
Dr. Klingelhöfer Stefan
Manfred Frauenrath
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant Produkte Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Produkte Deutschland GmbH filed Critical Clariant Produkte Deutschland GmbH
Publication of DE112012001241A5 publication Critical patent/DE112012001241A5/de
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE112012001241.0T 2011-03-15 2012-03-15 Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen Ceased DE112012001241A5 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102011013908.7 2011-03-15
DE102011013908A DE102011013908A1 (de) 2011-03-15 2011-03-15 Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen
PCT/EP2012/054613 WO2012123557A1 (de) 2011-03-15 2012-03-15 Modifizierter katalysator zur umwandlung von oxygenaten zu olefinen

Publications (1)

Publication Number Publication Date
DE112012001241A5 true DE112012001241A5 (de) 2014-01-09

Family

ID=45922670

Family Applications (2)

Application Number Title Priority Date Filing Date
DE102011013908A Withdrawn DE102011013908A1 (de) 2011-03-15 2011-03-15 Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen
DE112012001241.0T Ceased DE112012001241A5 (de) 2011-03-15 2012-03-15 Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE102011013908A Withdrawn DE102011013908A1 (de) 2011-03-15 2011-03-15 Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen

Country Status (6)

Country Link
US (1) US20140058180A1 (de)
CN (1) CN103561868B (de)
DE (2) DE102011013908A1 (de)
RU (1) RU2557244C2 (de)
WO (1) WO2012123557A1 (de)
ZA (1) ZA201306226B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011013911A1 (de) 2011-03-15 2012-09-20 Süd-Chemie AG Verbessertes Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine
MX2014015734A (es) 2012-06-29 2016-01-12 Basf Se Catalizador y proceso para la conversión de oxigenatos en olefinas.
US20140005455A1 (en) 2012-06-29 2014-01-02 Basf Se Process for the conversion of oxygenates to olefins
US10005702B2 (en) 2012-06-29 2018-06-26 Basf Se Catalyst coating and process for the conversion of oxygenates to olefins
US9597669B2 (en) 2012-06-29 2017-03-21 Basf Se Catalyst and process for the conversion of oxygenates to olefins
WO2015059175A1 (en) * 2013-10-23 2015-04-30 Basf Se Powder or granulate for a zeolitic material and process for its production
RU2635567C1 (ru) 2013-12-20 2017-11-14 Клариант Продукте (Дойчланд) Гмбх Фосфорсодержащий катализатор для превращения оксигенатов в олефины
EP3083045A1 (de) 2013-12-20 2016-10-26 Basf Se Katalysator und verfahren zur umwandlung von oxygenaten in olefine
RU2544241C1 (ru) 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
RU2550354C1 (ru) 2014-03-28 2015-05-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
RU2558955C1 (ru) 2014-08-12 2015-08-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления
RU2544017C1 (ru) 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
US9688587B2 (en) * 2015-03-03 2017-06-27 Uop Llc Process for oxygenate to olefin conversion using 2-D pentasil zeolite
WO2017155424A1 (en) 2016-03-09 2017-09-14 Limited Liability Company "New Gas Technologies-Synthesis" (Llc "Ngt-Synthesis") Method and plant for producing high-octane gasolines
WO2021116254A1 (en) 2019-12-11 2021-06-17 Basf Se Process for preparing a molding comprising a zeolite catalyst and method for converting oxygenates to olefins using the catalytic molding

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4058576A (en) 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
DE3838710A1 (de) 1988-11-15 1990-05-17 Sued Chemie Ag Katalysator auf der basis von kristallinen alumosilikaten
DE4009459A1 (de) 1990-03-23 1991-09-26 Metallgesellschaft Ag Verfahren zur erzeugung von niederen olefinen
EP0568913A3 (de) * 1992-05-03 1995-03-22 Dalian Chemical Physics Inst Verfahren zur Umwandlung von Methanol in leichte Olefine und dafür verwendeter Katalysator.
DE10117248A1 (de) 2000-05-31 2002-10-10 Mg Technologies Ag Verfahren zum Erzeugen von Propylen aus Methanol
US7399727B2 (en) 2004-04-23 2008-07-15 Saudi Basic Industries Corporation Zeolite catalyst and method
US7368410B2 (en) * 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
US7309679B2 (en) * 2005-08-08 2007-12-18 Uop Llc Attrition resistant MTO catalyst
US7662737B2 (en) * 2005-12-22 2010-02-16 Saudi Basic Industries Corporation Bound phosphorus-modified zeolite catalyst, method of preparing and method of using thereof
DE102006026103B4 (de) 2006-06-03 2010-05-06 Lurgi Gmbh Reaktor zur Herstellung von C2- bis C8- Olefinen aus einem Oxygenat, Wasserdampf und einen oder mehrere Kohlenwasserstoffe enthaltendem Stoffstrom
EP2025402A1 (de) * 2007-07-31 2009-02-18 Total Petrochemicals Research Feluy Phosphormodifizierte Molekularsiebe und deren Verwendung bei der Umsetzung organischer Substanzen zu Olefinen
TW200918486A (en) * 2007-09-18 2009-05-01 Asahi Kasei Chemicals Corp Process for production of propylene
CN102076636B (zh) * 2008-06-25 2014-04-16 道达尔石油化学产品研究弗吕公司 由含氧化合物制造烯烃的方法
WO2009156433A2 (en) * 2008-06-25 2009-12-30 Total Petrochemicals Research Feluy Process to make olefins from organics
US8062987B2 (en) * 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
EP2348004A1 (de) * 2010-01-25 2011-07-27 Total Petrochemicals Research Feluy Verfahren zur Herstellung eines Katalysatoren mit einem phosphormodifizierten Zeolit zur Verwendung in einem MTO- oder Dehydrierverfahren

Also Published As

Publication number Publication date
WO2012123557A1 (de) 2012-09-20
ZA201306226B (en) 2014-10-29
CN103561868A (zh) 2014-02-05
US20140058180A1 (en) 2014-02-27
DE102011013908A1 (de) 2012-09-20
RU2557244C2 (ru) 2015-07-20
CN103561868B (zh) 2017-07-04
RU2013145948A (ru) 2015-04-20

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