DE1116408B - Verfahren zur Polymerisation von ungesaettigten organischen Verbindungen - Google Patents
Verfahren zur Polymerisation von ungesaettigten organischen VerbindungenInfo
- Publication number
- DE1116408B DE1116408B DEI18552A DEI0018552A DE1116408B DE 1116408 B DE1116408 B DE 1116408B DE I18552 A DEI18552 A DE I18552A DE I0018552 A DEI0018552 A DE I0018552A DE 1116408 B DE1116408 B DE 1116408B
- Authority
- DE
- Germany
- Prior art keywords
- parts
- polymerization
- organic compounds
- mixed
- unsaturated organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 12
- 238000006116 polymerization reaction Methods 0.000 title claims description 8
- 150000002894 organic compounds Chemical class 0.000 title claims description 3
- KFGFVPMRLOQXNB-UHFFFAOYSA-N 3,5,5-trimethylhexanoyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(=O)CC(C)CC(C)(C)C KFGFVPMRLOQXNB-UHFFFAOYSA-N 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000012299 nitrogen atmosphere Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- BODRLKRKPXBDBN-UHFFFAOYSA-N 3,5,5-Trimethyl-1-hexanol Chemical compound OCCC(C)CC(C)(C)C BODRLKRKPXBDBN-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000012933 diacyl peroxide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 1
- GEKPNPPFAYJZRD-UHFFFAOYSA-N 3,5,5-trimethylhexanoyl chloride Chemical compound ClC(=O)CC(C)CC(C)(C)C GEKPNPPFAYJZRD-UHFFFAOYSA-N 0.000 description 1
- XJFFUXNWVUZUIF-UHFFFAOYSA-N 4-ethenylisoindole-1,3-dione Chemical compound C=CC1=CC=CC2=C1C(=O)NC2=O XJFFUXNWVUZUIF-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- -1 diallyl ester Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2756859A GB879625A (en) | 1959-08-12 | 1959-08-12 | Polymerisation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1116408B true DE1116408B (de) | 1961-11-02 |
Family
ID=10261733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI18552A Pending DE1116408B (de) | 1959-08-12 | 1960-08-10 | Verfahren zur Polymerisation von ungesaettigten organischen Verbindungen |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE593999A (enrdf_load_stackoverflow) |
| DE (1) | DE1116408B (enrdf_load_stackoverflow) |
| ES (1) | ES260324A1 (enrdf_load_stackoverflow) |
| FR (1) | FR1274493A (enrdf_load_stackoverflow) |
| GB (1) | GB879625A (enrdf_load_stackoverflow) |
| NL (2) | NL110684C (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1301514B (de) * | 1966-02-15 | 1969-08-21 | Elektrochem Werke Muenchen Ag | Verfahren zur Polymerisation und Copolymerisation olefinischer Verbindungen |
-
0
- NL NL254725D patent/NL254725A/xx unknown
- NL NL110684D patent/NL110684C/xx active
- BE BE593999D patent/BE593999A/xx unknown
-
1959
- 1959-08-12 GB GB2756859A patent/GB879625A/en not_active Expired
-
1960
- 1960-08-10 DE DEI18552A patent/DE1116408B/de active Pending
- 1960-08-11 ES ES0260324A patent/ES260324A1/es not_active Expired
- 1960-08-12 FR FR835843A patent/FR1274493A/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1301514B (de) * | 1966-02-15 | 1969-08-21 | Elektrochem Werke Muenchen Ag | Verfahren zur Polymerisation und Copolymerisation olefinischer Verbindungen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1274493A (fr) | 1961-10-27 |
| NL254725A (enrdf_load_stackoverflow) | |
| BE593999A (enrdf_load_stackoverflow) | |
| NL110684C (enrdf_load_stackoverflow) | |
| ES260324A1 (es) | 1960-11-16 |
| GB879625A (en) | 1961-10-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE955634C (de) | Verfahren zur Herstellung von Polymerisaten und Mischpolymerisaten | |
| DE938038C (de) | Verfahren zur Herstellung von Mischpolymerisaten mit niedrigem Molekulargewicht aus Vinylverbindungen und polymerisierbaren Dicarbonsaeureverbindungen | |
| DE2432759C2 (enrdf_load_stackoverflow) | ||
| EP0114394A2 (de) | Verfahren zur Herstellung von Polymerisaten der Vinylphosphonsäure in protischen Lösungsmitteln | |
| DE1180132B (de) | Verfahren zur Polymerisation von ungesaettigten Verbindungen | |
| DE1234992B (de) | Verfahren zur Herstellung von zinnhaltigen Polymeren | |
| DE1116408B (de) | Verfahren zur Polymerisation von ungesaettigten organischen Verbindungen | |
| DE888172C (de) | Verfahren zur Herstellung sich absetzender Polymerisate von Vinyl- oder Vinylidenverbindungen | |
| DE947024C (de) | Verfahren zur Herstellung von Mischpolymerisaten auf Grundlage von Vinylidencyanid | |
| DE2230561A1 (de) | Maleinsaeureanhydridmischpolymere | |
| AT230093B (de) | Polymerisationsverfahren | |
| DE69106299T2 (de) | Peroxyester und seine Verwendung als Polymerisationsinitiator und Härtungsmittel. | |
| DE2033910A1 (de) | Verfahren zur Durchfuhrung radikalisch initiierter chemischer Reaktionen | |
| US3129206A (en) | Polymerization process | |
| DE1178854B (de) | Verfahren zur Herstellung von Carbonsaeure-estern, AEthern oder Acetalen des 2, 5-Dimethyl-hexan-2, 5-dihydroperoxyds | |
| DE1795467A1 (de) | Verfahren zur Herstellung von Polyamiden durch Polymerisieren von epsilon-Caprolactam | |
| DE2034922C3 (de) | hexyl)-peroxydicarbonat und mindestens 70% cis-Isomeres enthaltende Di-(3.3.5trimethyl-cyclohexyO-peroxydiarbonat-Isomerengemische | |
| DE1170641B (de) | Verfahren zur Polymerisation von olefinisch ungesaettigten Verbindungen | |
| DE1131407B (de) | Verfahren zur Polymerisation ungesaettigter Verbindungen | |
| DE2154510A1 (de) | Verfahren zur herstellung von polymaleinsaeureanhydrid | |
| DE3048081A1 (de) | Verfahren zur herstellung von polymeren und mischpolymeren aethylenisch ungesaettigter monomerer | |
| DE1301516B (de) | Verfahren zur Herstellung von Homo- und Co-Polymerisaten aus olefinisch ungesaettigten Monomeren | |
| DE2330518A1 (de) | Organische peroxyde | |
| DE1520278A1 (de) | Verfahren zur Herstellung von Mischpolymerisaten niedrigen Molekulargewichts | |
| DE3807564C2 (de) | Diisopropylbenzol-bisperneoalkanoate, Verfahren zu ihrer Herstellung und ihre Verwendung als Polymerisationsinitiatoren |