DE102018115379B3 - Verbindung und Verfahren zur Bildung von selbstorganisierten Monolagen auf TCO-Substraten zur Verwendung in Perowskit-Solarzellen in invertierter Architektur - Google Patents

Verbindung und Verfahren zur Bildung von selbstorganisierten Monolagen auf TCO-Substraten zur Verwendung in Perowskit-Solarzellen in invertierter Architektur Download PDF

Info

Publication number
DE102018115379B3
DE102018115379B3 DE102018115379.1A DE102018115379A DE102018115379B3 DE 102018115379 B3 DE102018115379 B3 DE 102018115379B3 DE 102018115379 A DE102018115379 A DE 102018115379A DE 102018115379 B3 DE102018115379 B3 DE 102018115379B3
Authority
DE
Germany
Prior art keywords
group
fragment
carbon atoms
compound
hole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE102018115379.1A
Other languages
German (de)
English (en)
Inventor
Artiom Magomedov
Amran Al-Ashouri
Ernestas Kasparavicius
Steve Albrecht
Vytautas Getautis
Marko Jost
Tadas Malinauskas
Lukas Kegelmann
Eike Köhnen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Helmholtz Zentrum Berlin fuer Materialien und Energie GmbH
Kaunas Univ Of Technology
Kaunas University of Technology
Original Assignee
Helmholtz Zentrum Berlin fuer Materialien und Energie GmbH
Kaunas Univ Of Technology
Kaunas University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Helmholtz Zentrum Berlin fuer Materialien und Energie GmbH, Kaunas Univ Of Technology, Kaunas University of Technology filed Critical Helmholtz Zentrum Berlin fuer Materialien und Energie GmbH
Priority to EP19720824.2A priority Critical patent/EP3784678A1/de
Priority to US17/256,052 priority patent/US12207546B2/en
Priority to JP2020560151A priority patent/JP7663191B2/ja
Priority to CN201980042620.2A priority patent/CN112469727A/zh
Priority to PCT/EP2019/060586 priority patent/WO2019207029A1/de
Application granted granted Critical
Publication of DE102018115379B3 publication Critical patent/DE102018115379B3/de
Priority to JP2024209433A priority patent/JP2025032177A/ja
Priority to US19/032,142 priority patent/US20250185446A1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • C07F9/3873—Polyphosphonic acids containing nitrogen substituent, e.g. N.....H or N-hydrocarbon group which can be substituted by halogen or nitro(so), N.....O, N.....S, N.....C(=X)- (X =O, S), N.....N, N...C(=X)...N (X =O, S)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029—Processes of manufacture
    • H01G9/0036—Formation of the solid electrolyte layer
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
    • H01G9/2009—Solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
    • H01G9/2018—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte characterised by the ionic charge transport species, e.g. redox shuttles
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80—Constructional details
    • H10K30/81—Electrodes
    • H10K30/82—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10—Deposition of organic active material
    • H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/40—Thermal treatment, e.g. annealing in the presence of a solvent vapour
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • H10K85/633—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine comprising polycyclic condensed aromatic hydrocarbons as substituents on the nitrogen atom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • H10K85/636—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine comprising heteroaromatic hydrocarbons as substituents on the nitrogen atom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/10—Transparent electrodes, e.g. using graphene
    • H10K2102/101—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO]
    • H10K2102/103—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO] comprising indium oxides, e.g. ITO
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Power Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electromagnetism (AREA)
  • Photovoltaic Devices (AREA)
  • Electroluminescent Light Sources (AREA)
DE102018115379.1A 2018-04-25 2018-06-26 Verbindung und Verfahren zur Bildung von selbstorganisierten Monolagen auf TCO-Substraten zur Verwendung in Perowskit-Solarzellen in invertierter Architektur Active DE102018115379B3 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP19720824.2A EP3784678A1 (de) 2018-04-25 2019-04-25 Lochleitende selbstorganisierte monolage für perowskit-solarzellen
US17/256,052 US12207546B2 (en) 2018-04-25 2019-04-25 Hole-transporting self-organized monolayer for perovskite solar cells
JP2020560151A JP7663191B2 (ja) 2018-04-25 2019-04-25 ペロブスカイト太陽電池のための正孔導電性自己組織化単分子層
CN201980042620.2A CN112469727A (zh) 2018-04-25 2019-04-25 用于钙钛矿太阳能电池的空穴传输的自组织的单层
PCT/EP2019/060586 WO2019207029A1 (de) 2018-04-25 2019-04-25 Lochleitende selbstorganisierte monolage für perowskit-solarzellen
JP2024209433A JP2025032177A (ja) 2018-04-25 2024-12-02 ペロブスカイト太陽電池のための正孔導電性自己組織化単分子層
US19/032,142 US20250185446A1 (en) 2018-04-25 2025-01-20 Hole-transporting self-organised monolayer for perovskite solar cells

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP18000405 2018-04-25
EP18000405 2018-04-25

Publications (1)

Publication Number Publication Date
DE102018115379B3 true DE102018115379B3 (de) 2019-10-10

Family

ID=62222368

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102018115379.1A Active DE102018115379B3 (de) 2018-04-25 2018-06-26 Verbindung und Verfahren zur Bildung von selbstorganisierten Monolagen auf TCO-Substraten zur Verwendung in Perowskit-Solarzellen in invertierter Architektur

Country Status (6)

Country Link
US (1) US12207546B2 (https=)
EP (1) EP3784678A1 (https=)
JP (2) JP7663191B2 (https=)
CN (1) CN112469727A (https=)
DE (1) DE102018115379B3 (https=)
WO (1) WO2019207029A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019116851B3 (de) * 2019-06-21 2020-11-05 Helmholtz-Zentrum Berlin für Materialien und Energie Gesellschaft mit beschränkter Haftung Perowskit-Mehrfachsolarzelle mit Multischichtsystem als Verbindungsschicht

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021210096A1 (ja) * 2020-04-15 2021-10-21 シャープ株式会社 発光素子
KR20230163381A (ko) * 2021-03-30 2023-11-30 호도가야 가가쿠 고교 가부시키가이샤 술폰산염기를 갖는 화합물, 및 그 화합물을 사용한 광전 변환 소자
CN113161452B (zh) * 2021-04-26 2023-03-24 湖北大学 一种钙钛矿薄膜、钙钛矿led器件及其制备方法
JP7792266B2 (ja) * 2021-09-22 2025-12-25 株式会社カネカ 太陽電池及び太陽電池製造方法
CN116133497A (zh) * 2021-11-12 2023-05-16 电子科技大学 一种钙钛矿类型的太阳能电池及其制备方法
FR3131083B1 (fr) 2021-12-16 2024-09-20 Commissariat Energie Atomique Cellule photovoltaïque a contacts passives et a revêtement antireflet
JP2023147074A (ja) * 2022-03-29 2023-10-12 日本放送協会 電界発光素子、表示装置及び照明装置
EP4349808A4 (en) * 2022-05-27 2024-09-25 Contemporary Amperex Technology Co., Limited ORGANIC COMPOUND AND ITS USE, PASSIVATION FILM, SOLAR CELL AND ELECTRONIC DEVICE
CN118715886A (zh) * 2022-11-10 2024-09-27 宁德时代新能源科技股份有限公司 聚合物、钙钛矿太阳能电池、光伏组件和用电装置
CN115819457A (zh) * 2022-12-06 2023-03-21 厦门大学 一种含膦酸与甲硫基的咔唑类有机小分子空穴传输材料及其制备方法和应用
CN116731068B (zh) * 2023-05-26 2025-07-18 常州大学 一种小分子空穴传输材料及其制备方法和应用该材料的有机太阳能电池
KR102843232B1 (ko) 2023-06-26 2025-08-05 중앙대학교 산학협력단 페로브스카이트 태양전지용 자기조립층 소재 및 그 제조방법
CN116669449A (zh) * 2023-08-02 2023-08-29 宁德时代新能源科技股份有限公司 钙钛矿太阳能电池及其制备方法以及用电设备
US20250241109A1 (en) * 2024-01-18 2025-07-24 Kaunas University Of Technology Electron Transporting Self-Assembling Monolayer Compound for Use in Optoelectronic and/or Photoelectrochemical Devices and Manufacture Thereof
WO2025199279A1 (en) * 2024-03-20 2025-09-25 Northwestern University Perovskite solar cells with dual site binding ligands
CN120718061A (zh) * 2024-03-29 2025-09-30 宁德时代未来能源(上海)研究院有限公司 空穴传输材料、太阳能电池、用电设备及发电设备
CN118772199A (zh) * 2024-06-14 2024-10-15 天津大学 一种自组装单分子层空穴传输材料及其应用
CN118812594B (zh) * 2024-06-19 2025-12-02 华中科技大学 一类具有双功能化的膦酸自组装分子、其制备和应用
CN118791527B (zh) * 2024-07-11 2025-11-07 晶科能源(上饶)有限公司 空穴传输材料及其制备方法和钙钛矿太阳能电池
CN119431443A (zh) * 2024-09-06 2025-02-14 天合光能股份有限公司 分子桥类有机物、空穴传输材料、光伏器件及制备方法、光伏系统
EP4712742A1 (en) * 2024-09-16 2026-03-18 Helmholtz-Zentrum Berlin für Materialien und Energie GmbH Compounds forming hole-transporting self-assembled monolayer
CN118922003B (zh) * 2024-10-11 2024-12-24 通威太阳能（成都）有限公司 一种太阳电池及其制备方法、光伏组件
CN119698162B (zh) * 2024-11-06 2025-10-31 苏州大学 一种基于自组装单分子层的钙钛矿光伏器件及其制备方法
CN119504858B (zh) * 2024-11-20 2026-01-20 晶科能源(上饶)有限公司 磷酸咔唑类材料、其制备方法及应用
CN119504859B (zh) * 2024-11-20 2025-09-30 晶科能源(上饶)有限公司 空穴传输材料及其制备方法、钙钛矿太阳能电池
KR102921924B1 (ko) * 2024-12-26 2026-02-05 재단법인대구경북과학기술원 평면성이 확장된 자가조립 물질 및 이를 포함하는 태양전지
CN121021572B (zh) * 2025-10-29 2026-01-27 深圳市光因科技有限公司 一种二苯并呋喃基咔唑衍生物及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1889314A2 (en) 2005-06-06 2008-02-20 High Power Lithium S.A. Lithium rechargeable electrochemical cell
US8405069B2 (en) 2006-11-10 2013-03-26 Georgia Tech Research Corporation Printable thin-film transistors with high dielectric constant gate insulators and methods for producing same
GB201110565D0 (en) * 2011-06-22 2011-08-03 Cambridge Display Tech Ltd Organic optoelectronic material, device and method
EP2772956B1 (en) * 2011-10-25 2016-08-10 Dai Nippon Printing Co., Ltd. Material for positive hole injection transport layer, ink for positive hole injection transport layer, device, and production methods for same
KR101458691B1 (ko) * 2013-02-28 2014-11-05 포항공과대학교 산학협력단 고-일함수 및 고-전도도 하이브리드 전도성 박막을 포함한 유기 태양 전지
TW201517343A (zh) * 2013-08-29 2015-05-01 美國密西根州立大學 用於有機光伏打電池中緩衝層之激子障壁處理
US10586929B2 (en) * 2013-12-12 2020-03-10 Lg Chem, Ltd. Solvent-resistant hole transport layers
JP6788222B2 (ja) * 2014-11-19 2020-11-25 日産化学株式会社 架橋反応性シリコン含有膜形成組成物
KR101777779B1 (ko) * 2014-12-23 2017-09-12 광주과학기술원 P-도핑된 공액 저분자 전해질 및 이를 이용한 유기전자소자
JP6382781B2 (ja) * 2015-09-15 2018-08-29 株式会社東芝 半導体素子の製造方法および製造装置
CN107163078B (zh) 2017-04-18 2019-09-17 清华大学 有机膦酸类化合物的应用和钙钛矿太阳能电池薄膜及其制备方法

Non-Patent Citations (12)

* Cited by examiner, † Cited by third party
Title
CAN, M. [u.a.]: Electrical properties of SAM-modified ITO surface using aromatic small molecules with double bond carboxylic acid groups for OLED applications. In: Applied Surface Science, 314, 10.06.2014, S. 1082–1086. - ISSN 0169-4332 *
D. Bryant et al., J. Phys. Chem. Lett. 2015, 6, 3190 - 3194 und P. Calado, Nat. Commun. 2016, 7, 13831
GRISORIO, R.: Molecular Tailoring of Phenothiazine-Based Hole-Transporting Materials for High-Performing Perovskite Solar Cells. In: ACS Energy Letters, 2, 10.04.2017, S. 1029−1034. - ISSN 2380-8195 *
HAVARE, A. K. [u.a.]: Modification of ITO surface using aromatic small molecules with carboxylic acid. In: Synthetic Metals, 15.10.2011, S. 2397– 2404. - ISSN 0379-6779 *
J. H. Heo et al., Energy Environ. Sci. 2015, 8, 1602 - 1608
J. Zhao et al., Energy Environ. Sci. 2016, 9, 3650 - 3656
J. Zhao et al., J. Huang, Energy Environ, Sci. 2016, 9, 3650 - 3656
M. Stolterfoht et al., Energy Environ. Sci. 2017, 10, 1530 - 1539
P. Topolovsek et.al. (J. Mater. Chem. A 2017, 5, 11882 - 11893)
Stolterfoht et al., Energy Environ Sci. 2017, 10 (6), 1530
W. S. Yang et al., Science 2017, 356, 1376-1379
Y. Hou et al., Adv. Mater. Interfaces 2017, 4, 1700007, und Y. Hou et al., Science 2017, 358, 1192 - 1197

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019116851B3 (de) * 2019-06-21 2020-11-05 Helmholtz-Zentrum Berlin für Materialien und Energie Gesellschaft mit beschränkter Haftung Perowskit-Mehrfachsolarzelle mit Multischichtsystem als Verbindungsschicht

Also Published As

Publication number Publication date
JP2025032177A (ja) 2025-03-11
CN112469727A (zh) 2021-03-09
JP7663191B2 (ja) 2025-04-16
WO2019207029A1 (de) 2019-10-31
JP2021522681A (ja) 2021-08-30
US12207546B2 (en) 2025-01-21
EP3784678A1 (de) 2021-03-03
US20210234101A1 (en) 2021-07-29

Similar Documents

Publication Publication Date Title
DE102018115379B3 (de) Verbindung und Verfahren zur Bildung von selbstorganisierten Monolagen auf TCO-Substraten zur Verwendung in Perowskit-Solarzellen in invertierter Architektur
Suo et al. Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests
Wang et al. Polymeric room-temperature molten salt as a multifunctional additive toward highly efficient and stable inverted planar perovskite solar cells
Jia et al. Double-site defect passivation of perovskite film via fullerene additive engineering toward highly efficient and stable bulk heterojunction solar cells
EP3050134B9 (de) Photoaktives, organisches material für optoelektronische bauelemente
DE112020007073T5 (de) Verarbeitung von effizienten perovskit-solarzellen in feuchter luft basierend auf polymerisierbaren ionischen flüssigkeiten und salzen
US20190044080A1 (en) High efficiency large area perovskite solar cells and process for producing the same
Ali et al. Enhanced stability in cesium assisted hybrid 2D/3D-perovskite thin films and solar cells prepared in ambient humidity
EP2498315B1 (de) Organische Solarzelle
Cao et al. Reducing defects in perovskite solar cells with white light illumination-assisted synthesis
EP3223323A1 (en) High efficiency large area perovskite solar cells and process for producing the same
JP6737798B2 (ja) 光電子及び光電気化学デバイスのための小分子ホール輸送材料
Xia et al. A spiro-bifluorene based 3D electron acceptor with dicyanovinylene substitution for solution-processed non-fullerene organic solar cells
EP3575282A1 (en) Complex and method for producing same
Wang et al. Simplified pin perovskite solar cells with a multifunctional polyfullerene electron transporter
Zhao et al. Highly stable and efficient α-phase FA-based perovskite solar cells prepared in ambient air by strategically enhancing the interaction between ions in crystal lattices
Emelianov et al. Electric-field-induced aging dynamics of triple-cation lead iodide perovskite at nanoscale
JP2016063090A (ja) 太陽電池用有機−無機複合材料、太陽電池用光吸収層および太陽電池
Wang et al. A Universal Approach for Potassium‐Passivated 2D Perovskites
DE102019114456B4 (de) Bispyranilidene, Dithiobispyranilidene und Diselenobispyranilidene und deren Verwendung
Li et al. Self-Assembled Monolayers in Inverted Perovskite Solar Cells: A Rising Star with Challenges
Afraj et al. Harnessing Functionalized Thioalkylated‐Cyclopentadithiophene Monolayers on NiOx for Two‐Step Fabricated Tin Perovskite Solar Cells
EP0644907B1 (de) Polyanile
Kotta et al. Eco-friendly upgradation for the enhancement of performance and stability of perovskite solar cells
CN117425361B (zh) 一种卟啉钝化钙钛矿纳米薄膜材料及其制备和应用

Legal Events

Date Code Title Description
R086 Non-binding declaration of licensing interest
R012 Request for examination validly filed
R016 Response to examination communication
R082 Change of representative

Representative=s name: SCHULZ JUNGHANS PATENTANWAELTE PARTGMBB, DE

R016 Response to examination communication
R018 Grant decision by examination section/examining division
R020 Patent grant now final
R079 Amendment of ipc main class

Free format text: PREVIOUS MAIN CLASS: H01L0051460000

Ipc: H10K0085000000