DE102010040517A1 - Verfahren zur Herstellung von Polyetherpolyolen - Google Patents

Verfahren zur Herstellung von Polyetherpolyolen Download PDF

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Publication number
DE102010040517A1
DE102010040517A1 DE102010040517A DE102010040517A DE102010040517A1 DE 102010040517 A1 DE102010040517 A1 DE 102010040517A1 DE 102010040517 A DE102010040517 A DE 102010040517A DE 102010040517 A DE102010040517 A DE 102010040517A DE 102010040517 A1 DE102010040517 A1 DE 102010040517A1
Authority
DE
Germany
Prior art keywords
methyl
metal cyanide
zinc
mixture
alkylene oxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE102010040517A
Other languages
German (de)
English (en)
Inventor
Dr. Gürtler Christoph
Joerg Hofmann
Dr. Wolf Aurel
Dr. Grasser Stefan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Priority to DE102010040517A priority Critical patent/DE102010040517A1/de
Priority to SG2013013461A priority patent/SG188278A1/en
Priority to KR1020137008882A priority patent/KR20130102588A/ko
Priority to EP11757815.3A priority patent/EP2614102B1/de
Priority to CN201180043627.XA priority patent/CN103189417B/zh
Priority to PCT/EP2011/065364 priority patent/WO2012032028A1/de
Priority to JP2013527572A priority patent/JP5792310B2/ja
Priority to BR112013005783A priority patent/BR112013005783A2/pt
Priority to CA2810559A priority patent/CA2810559A1/en
Priority to US13/821,254 priority patent/US9045592B2/en
Priority to RU2013115633/04A priority patent/RU2013115633A/ru
Priority to ES11757815.3T priority patent/ES2506440T3/es
Priority to MX2013002484A priority patent/MX2013002484A/es
Publication of DE102010040517A1 publication Critical patent/DE102010040517A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C08G64/183—Block or graft polymers containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyethers (AREA)
DE102010040517A 2010-09-09 2010-09-09 Verfahren zur Herstellung von Polyetherpolyolen Withdrawn DE102010040517A1 (de)

Priority Applications (13)

Application Number Priority Date Filing Date Title
DE102010040517A DE102010040517A1 (de) 2010-09-09 2010-09-09 Verfahren zur Herstellung von Polyetherpolyolen
SG2013013461A SG188278A1 (en) 2010-09-09 2011-09-06 Process for the preparation of polyether carbonate polyols
KR1020137008882A KR20130102588A (ko) 2010-09-09 2011-09-06 폴리에테르 카보네이트 폴리올의 제조방법
EP11757815.3A EP2614102B1 (de) 2010-09-09 2011-09-06 Verfahren zur herstellung von polyethercarbonatpolyolen
CN201180043627.XA CN103189417B (zh) 2010-09-09 2011-09-06 制备聚醚碳酸酯多元醇的方法
PCT/EP2011/065364 WO2012032028A1 (de) 2010-09-09 2011-09-06 Verfahren zur herstellung von polyethercarbonatpolyolen
JP2013527572A JP5792310B2 (ja) 2010-09-09 2011-09-06 ポリエーテルカーボネートポリオールの製造方法
BR112013005783A BR112013005783A2 (pt) 2010-09-09 2011-09-06 processo para a preparação de polióis carbonato poliéteres
CA2810559A CA2810559A1 (en) 2010-09-09 2011-09-06 Method for producing polyether carbonate polyols
US13/821,254 US9045592B2 (en) 2010-09-09 2011-09-06 Process for the preparation of polyether carbonate polyols
RU2013115633/04A RU2013115633A (ru) 2010-09-09 2011-09-06 Способ получения полиэфирных карбонатных полиолов
ES11757815.3T ES2506440T3 (es) 2010-09-09 2011-09-06 Procedimiento para la preparación de polioles de carbonato de poliéter
MX2013002484A MX2013002484A (es) 2010-09-09 2011-09-06 Procedimiento para la preparacion de polioles de carbonato de polieter.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102010040517A DE102010040517A1 (de) 2010-09-09 2010-09-09 Verfahren zur Herstellung von Polyetherpolyolen

Publications (1)

Publication Number Publication Date
DE102010040517A1 true DE102010040517A1 (de) 2012-03-15

Family

ID=44653291

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102010040517A Withdrawn DE102010040517A1 (de) 2010-09-09 2010-09-09 Verfahren zur Herstellung von Polyetherpolyolen

Country Status (13)

Country Link
US (1) US9045592B2 (https=)
EP (1) EP2614102B1 (https=)
JP (1) JP5792310B2 (https=)
KR (1) KR20130102588A (https=)
CN (1) CN103189417B (https=)
BR (1) BR112013005783A2 (https=)
CA (1) CA2810559A1 (https=)
DE (1) DE102010040517A1 (https=)
ES (1) ES2506440T3 (https=)
MX (1) MX2013002484A (https=)
RU (1) RU2013115633A (https=)
SG (1) SG188278A1 (https=)
WO (1) WO2012032028A1 (https=)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2548908A1 (de) * 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
JP2016521788A (ja) * 2013-06-13 2016-07-25 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ ポリエーテルカーボネイト−ポリオキシメチレンブロック共重合体
EP2837648A1 (en) 2013-08-12 2015-02-18 Repsol, S.A. Process for preparing polyether carbonate polyols
EP2845871A1 (de) * 2013-09-05 2015-03-11 Bayer MaterialScience AG Vernetzung von Doppelbindungen enthaltenden Polyethercarbonatpolyolen durch Addition von Mercaptanen
EP2865700A1 (de) * 2013-10-23 2015-04-29 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
US9527958B2 (en) 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
US10040901B2 (en) * 2014-07-03 2018-08-07 Covestro Deutschland Ag Method for producing polyether carbonate polyols
US10119223B2 (en) 2016-07-15 2018-11-06 Covestro Llc Carpet and synthetic turf backings prepared from a polyether carbonate polyol
US10040903B2 (en) 2016-09-13 2018-08-07 Covestro Llc Polymer polyol quality
ES2940415T3 (es) 2016-11-11 2023-05-08 Dow Global Technologies Llc Polioles basados en policarbonato
GB201703323D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyols
CN110964191B (zh) * 2018-09-29 2021-02-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法
US20220315698A1 (en) * 2019-07-31 2022-10-06 Covestro Deutschland Ag Method for producing polyether carbonate polyols
US11976165B2 (en) * 2020-01-21 2024-05-07 Covestro Deutschland Ag Method for producing double metal cyanide catalysts
KR102717144B1 (ko) * 2021-07-15 2024-10-11 아주대학교산학협력단 하이드로젠 헥사시아노코발테이트와 아연 카복실레이트의 조합으로 제조된 더블메탈시아나이드 촉매 및 이를 이용한 프로필렌 옥사이드 중합
EP4400212B1 (en) * 2021-09-08 2026-02-25 LG Chem, Ltd. Double metal cyanide catalyst, method for preparing same and method for preparing polyalkylene carbonate using the catalyst
CN114524929B (zh) * 2021-09-24 2023-07-25 山东联欣环保科技有限公司 一种二氧化碳基四元共聚物的制备方法
KR102807547B1 (ko) 2021-09-29 2025-05-16 주식회사 엘지화학 폴리알킬렌 카보네이트 수지의 제조방법
CN114381252B (zh) * 2022-01-19 2023-02-10 成都理工大学 一种超高温下耐多价金属阳离子无固相修井液的制备方法

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404109A (en) 1963-02-14 1968-10-01 Gen Tire & Rubber Co Production of polyether diols using water as a telogen
JPH04145123A (ja) 1990-10-05 1992-05-19 Asahi Glass Co Ltd ポリエーテル化合物の製造方法
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
WO2001004182A1 (en) 1999-07-09 2001-01-18 The Dow Chemical Company Complexing agent-modified hexacyanometallate hexanitrometallate catalysts
WO2001039883A1 (de) 1999-12-03 2001-06-07 Bayer Aktiengesellschaft Verfahren zur herstellung von dmc-katalysatoren
WO2001080994A1 (de) 2000-04-20 2001-11-01 Bayer Aktiengesellschaft Verfahren zur herstellung von dmc-katalysatoren
WO2003029325A1 (de) 2001-09-27 2003-04-10 Basf Aktiengesellschaft Verfahren zur herstellung aliphatischer polycarbonate
EP1359177A1 (de) 2002-04-29 2003-11-05 Bayer Aktiengesellschaft Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten
US6762278B2 (en) 2002-02-04 2004-07-13 Basf Corporation Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds
WO2004081082A1 (en) 2003-03-07 2004-09-23 Dow Global Technologies Inc. Continuous process and system of producing polyether polyols
US6852663B2 (en) 2001-05-07 2005-02-08 Bayer Aktiengesellschaft Double-metal cyanide catalysts for preparing polyether polyols
US20050143606A1 (en) 2003-11-07 2005-06-30 George Combs Process for the production of polyols using DMC catalysts having unsaturated tertiary alcohols as ligands
WO2008013731A1 (en) 2006-07-24 2008-01-31 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (dmc) catalysis

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JP2001519468A (ja) * 1997-10-13 2001-10-23 バイエル・アクチエンゲゼルシヤフト ポリエーテルポリオールを製造するための結晶質複金属シアン化物触媒
ES2400709T3 (es) 2002-11-07 2013-04-11 Dow Global Technologies Inc. Método para preparar catalizadores de cianuro metálico usando agentes complejantes polimerizables
US20060223973A1 (en) * 2005-03-29 2006-10-05 Basf Corporation Method of forming a polyethercarbonate polyol

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404109A (en) 1963-02-14 1968-10-01 Gen Tire & Rubber Co Production of polyether diols using water as a telogen
JPH04145123A (ja) 1990-10-05 1992-05-19 Asahi Glass Co Ltd ポリエーテル化合物の製造方法
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
WO2001004182A1 (en) 1999-07-09 2001-01-18 The Dow Chemical Company Complexing agent-modified hexacyanometallate hexanitrometallate catalysts
WO2001039883A1 (de) 1999-12-03 2001-06-07 Bayer Aktiengesellschaft Verfahren zur herstellung von dmc-katalysatoren
WO2001080994A1 (de) 2000-04-20 2001-11-01 Bayer Aktiengesellschaft Verfahren zur herstellung von dmc-katalysatoren
US6852663B2 (en) 2001-05-07 2005-02-08 Bayer Aktiengesellschaft Double-metal cyanide catalysts for preparing polyether polyols
WO2003029325A1 (de) 2001-09-27 2003-04-10 Basf Aktiengesellschaft Verfahren zur herstellung aliphatischer polycarbonate
US6762278B2 (en) 2002-02-04 2004-07-13 Basf Corporation Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds
EP1359177A1 (de) 2002-04-29 2003-11-05 Bayer Aktiengesellschaft Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten
WO2004081082A1 (en) 2003-03-07 2004-09-23 Dow Global Technologies Inc. Continuous process and system of producing polyether polyols
US20050143606A1 (en) 2003-11-07 2005-06-30 George Combs Process for the production of polyols using DMC catalysts having unsaturated tertiary alcohols as ligands
WO2008013731A1 (en) 2006-07-24 2008-01-31 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (dmc) catalysis

Non-Patent Citations (4)

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Title
DIN 53240-2
DIN 55672-1
I1 Kim et al. in Journal of Polymer Science 2005, Seite 4393ff
Inoue et al, Copolymerization of Carbon Dioxide and Epoxide with Organmetallic Compounds; Die Makromolekulare Chemie 130, 210-220, 1969

Also Published As

Publication number Publication date
KR20130102588A (ko) 2013-09-17
US20130184432A1 (en) 2013-07-18
CA2810559A1 (en) 2012-03-15
JP2013537245A (ja) 2013-09-30
MX2013002484A (es) 2013-04-03
RU2013115633A (ru) 2014-10-20
WO2012032028A1 (de) 2012-03-15
SG188278A1 (en) 2013-04-30
EP2614102B1 (de) 2014-07-23
JP5792310B2 (ja) 2015-10-07
ES2506440T3 (es) 2014-10-13
CN103189417A (zh) 2013-07-03
CN103189417B (zh) 2016-08-03
US9045592B2 (en) 2015-06-02
BR112013005783A2 (pt) 2017-03-21
EP2614102A1 (de) 2013-07-17

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R120 Application withdrawn or ip right abandoned

Effective date: 20130820