DE102009047848A1 - Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen - Google Patents

Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen Download PDF

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Publication number
DE102009047848A1
DE102009047848A1 DE102009047848A DE102009047848A DE102009047848A1 DE 102009047848 A1 DE102009047848 A1 DE 102009047848A1 DE 102009047848 A DE102009047848 A DE 102009047848A DE 102009047848 A DE102009047848 A DE 102009047848A DE 102009047848 A1 DE102009047848 A1 DE 102009047848A1
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DE
Germany
Prior art keywords
metals
calcium
use according
bead polymer
alkaline earth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE102009047848A
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German (de)
English (en)
Inventor
Reinhold Dr. Klipper
Stefan Dr. Neumann
Jens Stoll
Michael Dr. Schelhaas
Pierre Dr. Vanhoorne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Deutschland GmbH
Original Assignee
Lanxess Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland GmbH filed Critical Lanxess Deutschland GmbH
Priority to DE102009047848A priority Critical patent/DE102009047848A1/de
Priority to EP10176509A priority patent/EP2305381A3/de
Priority to US12/890,794 priority patent/US8440730B2/en
Priority to JP2010218848A priority patent/JP5600541B2/ja
Priority to CN2010105021754A priority patent/CN102029201A/zh
Publication of DE102009047848A1 publication Critical patent/DE102009047848A1/de
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/40Introducing phosphorus atoms or phosphorus-containing groups
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/34Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/425Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/12Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36Divinylbenzene

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
DE102009047848A 2009-09-30 2009-09-30 Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen Withdrawn DE102009047848A1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE102009047848A DE102009047848A1 (de) 2009-09-30 2009-09-30 Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen
EP10176509A EP2305381A3 (de) 2009-09-30 2010-09-14 Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen
US12/890,794 US8440730B2 (en) 2009-09-30 2010-09-27 Method for improved removal of cations by means of chelating resins
JP2010218848A JP5600541B2 (ja) 2009-09-30 2010-09-29 キレート樹脂を用いるカチオンの改善された除去方法
CN2010105021754A CN102029201A (zh) 2009-09-30 2010-09-29 通过螯合树脂改进阳离子去除的方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102009047848A DE102009047848A1 (de) 2009-09-30 2009-09-30 Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen

Publications (1)

Publication Number Publication Date
DE102009047848A1 true DE102009047848A1 (de) 2011-03-31

Family

ID=43525178

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102009047848A Withdrawn DE102009047848A1 (de) 2009-09-30 2009-09-30 Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen

Country Status (5)

Country Link
US (1) US8440730B2 (https=)
EP (1) EP2305381A3 (https=)
JP (1) JP5600541B2 (https=)
CN (1) CN102029201A (https=)
DE (1) DE102009047848A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014221241A1 (de) * 2014-10-20 2016-04-21 Volkswagen Aktiengesellschaft Befeuchtungseinrichtung für ein Brennstoffzellensystem sowie Brennstoffzellensystem
WO2022069389A1 (de) 2020-09-30 2022-04-07 Lanxess Deutschland Gmbh Neue chelatharze

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013105177A1 (de) 2013-05-21 2014-11-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Gewinnung metallischer Anteile sowie von metallabgereichertem Material aus metallhaltigen Materialien
RU2676705C2 (ru) * 2014-08-20 2019-01-10 ЛЕНКСЕСС Дойчланд ГмбХ Сульфированные, аминометилированные хелатные смолы
DE112015005452B4 (de) * 2014-12-05 2025-02-13 Blue Cube Ip Llc Laugenreinigungsverfahren
JP6738145B2 (ja) * 2015-12-22 2020-08-12 学校法人福岡大学 次亜塩素酸ソーダの製造方法及び次亜塩素酸ソーダの製造装置
CN110003376B (zh) * 2019-03-11 2021-09-28 西安蓝晓科技新材料股份有限公司 一种从含镍溶液中制备硫酸镍的螯合树脂制备方法
CN110980876A (zh) * 2019-11-21 2020-04-10 武汉百富环保工程有限公司 一种从钝化液中回收铜并回用铬的处理工艺
MX2024011516A (es) * 2022-03-22 2024-09-24 Lanxess Deutschland Gmbh Metodo para la elucion de iones de aluminio y/o iones de zinc.
CN117361766B (zh) * 2022-06-28 2026-04-10 宝山钢铁股份有限公司 硅钢反渗透浓缩液的零排放工艺、设备及其滤料、吸附剂及制备方法
WO2025181142A1 (de) * 2024-02-29 2025-09-04 Lanxess Deutschland Gmbh Herstellung von calciumreduziertem lithiumcarbonat

Citations (9)

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Publication number Priority date Publication date Assignee Title
EP0046535A2 (de) 1980-08-22 1982-03-03 Bayer Ag Verfahren zur Herstellung von Perlpolymerisaten einheitlicher Teilchengrösse
US4382124A (en) 1958-07-18 1983-05-03 Rohm And Haas Company Process for preparing macroreticular resins, copolymers and products of said process
US4419245A (en) 1982-06-30 1983-12-06 Rohm And Haas Company Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer
US4444961A (en) 1980-10-30 1984-04-24 The Dow Chemical Company Process and apparatus for preparing uniform size polymer beads
DE3704307A1 (de) 1987-02-12 1988-08-25 Dow Chemical Gmbh Komplexbildendes harz des geltyps und seine verwendung zur verringerung der konzentration mehrwertiger erdalkali- und/oder schwermetallionen in loesungen
US4818773A (en) 1983-02-24 1989-04-04 Rohm And Haas Company Alkylaminophosphonic chelating resins, their preparation and use in purifying brines
WO1993012167A1 (en) 1991-12-19 1993-06-24 The Dow Chemical Company Seeded porous copolymers and ion-exchange resins prepared therefrom
EP0785690A2 (en) 1996-01-22 1997-07-23 Tektronix, Inc. SCH phase adjustment for digitally synthesized video test signals
EP1078690A2 (de) 1999-08-27 2001-02-28 Bayer Ag Verfahren zur Herstellung von monodispersen Ionenaustauschern mit chelatisierenden Gruppen und ihre Verwendung

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2418976C3 (de) * 1974-04-19 1978-10-26 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von wasserunlöslichen Kunstharzen mit Anionenaustauscher-Eigenschaften
DE4328075A1 (de) * 1993-08-20 1995-02-23 Bayer Ag Verfahren zur Herstellung schwachbasischer Anionenaustauscher und dafür geeigneter Reagenzien
DE10121163A1 (de) * 2001-04-30 2002-10-31 Bayer Ag Verfahren zur Herstellung heterodisperser Chelatharze
DE10353534A1 (de) * 2003-11-14 2005-06-16 Bayer Chemicals Ag Chelataustauscher
DE102006034659A1 (de) * 2006-07-24 2008-02-21 Lanxess Deutschland Gmbh Ionenaustauscher zur Gewinnung von Wertmetallen
DE102007034733A1 (de) * 2007-07-23 2009-01-29 Lanxess Deutschland Gmbh Verfahren zur Herstellung monodisperser Chelatharze
DE102007034732A1 (de) * 2007-07-23 2009-01-29 Lanxess Deutschland Gmbh Verfahren zur Herstellung von Chelatharzen

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4382124A (en) 1958-07-18 1983-05-03 Rohm And Haas Company Process for preparing macroreticular resins, copolymers and products of said process
US4382124B1 (en) 1958-07-18 1994-10-04 Rohm & Haas Process for preparing macroreticular resins, copolymers and products of said process
EP0046535A2 (de) 1980-08-22 1982-03-03 Bayer Ag Verfahren zur Herstellung von Perlpolymerisaten einheitlicher Teilchengrösse
US4444961A (en) 1980-10-30 1984-04-24 The Dow Chemical Company Process and apparatus for preparing uniform size polymer beads
US4419245A (en) 1982-06-30 1983-12-06 Rohm And Haas Company Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer
US4818773A (en) 1983-02-24 1989-04-04 Rohm And Haas Company Alkylaminophosphonic chelating resins, their preparation and use in purifying brines
DE3704307A1 (de) 1987-02-12 1988-08-25 Dow Chemical Gmbh Komplexbildendes harz des geltyps und seine verwendung zur verringerung der konzentration mehrwertiger erdalkali- und/oder schwermetallionen in loesungen
WO1993012167A1 (en) 1991-12-19 1993-06-24 The Dow Chemical Company Seeded porous copolymers and ion-exchange resins prepared therefrom
EP0785690A2 (en) 1996-01-22 1997-07-23 Tektronix, Inc. SCH phase adjustment for digitally synthesized video test signals
EP1078690A2 (de) 1999-08-27 2001-02-28 Bayer Ag Verfahren zur Herstellung von monodispersen Ionenaustauschern mit chelatisierenden Gruppen und ihre Verwendung

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DIN 66133
R. M. Klipper, H. Hoffmann, T. Augustin, Ion Exchange Advances, Proceedings of IEX 92, Seite 414 ff.; Elsevier Applied Science, London, 1992

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014221241A1 (de) * 2014-10-20 2016-04-21 Volkswagen Aktiengesellschaft Befeuchtungseinrichtung für ein Brennstoffzellensystem sowie Brennstoffzellensystem
WO2022069389A1 (de) 2020-09-30 2022-04-07 Lanxess Deutschland Gmbh Neue chelatharze

Also Published As

Publication number Publication date
CN102029201A (zh) 2011-04-27
JP5600541B2 (ja) 2014-10-01
US8440730B2 (en) 2013-05-14
JP2011116944A (ja) 2011-06-16
EP2305381A2 (de) 2011-04-06
EP2305381A3 (de) 2011-09-14
US20110089116A1 (en) 2011-04-21

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R119 Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee

Effective date: 20140401