DE102008060888A1 - Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase - Google Patents
Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase Download PDFInfo
- Publication number
- DE102008060888A1 DE102008060888A1 DE102008060888A DE102008060888A DE102008060888A1 DE 102008060888 A1 DE102008060888 A1 DE 102008060888A1 DE 102008060888 A DE102008060888 A DE 102008060888A DE 102008060888 A DE102008060888 A DE 102008060888A DE 102008060888 A1 DE102008060888 A1 DE 102008060888A1
- Authority
- DE
- Germany
- Prior art keywords
- phase
- glycerol
- acrolein
- acrylic acid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 74
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- LKPFBGKZCCBZDK-UHFFFAOYSA-N n-hydroxypiperidine Chemical compound ON1CCCCC1 LKPFBGKZCCBZDK-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000090 poly(aryl ether) Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000414 polyfuran Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- ZKWPMZVVAJSYNI-UHFFFAOYSA-N prop-2-enal Chemical compound C=CC=O.C=CC=O ZKWPMZVVAJSYNI-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003930 superacid Substances 0.000 description 1
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 1
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008060888A DE102008060888A1 (de) | 2008-12-09 | 2008-12-09 | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
| CN2009801492265A CN102245551A (zh) | 2008-12-09 | 2009-11-03 | 包括粗甘油相再生的制备丙烯醛的方法 |
| PCT/EP2009/064500 WO2010066513A1 (de) | 2008-12-09 | 2009-11-03 | Verfahren zur herstellung von acrolein umfassend die aufarbeitung einer rohglycerin-phase |
| BRPI0919647-1A BRPI0919647B1 (pt) | 2008-12-09 | 2009-11-03 | processo para preparação de acroleína, de ácido acrílico e de um polímero |
| EP09745047.2A EP2356088B1 (de) | 2008-12-09 | 2009-11-03 | Verfahren zur herstellung von acrolein umfassend die aufarbeitung einer rohglycerin-phase |
| US13/128,538 US8524945B2 (en) | 2008-12-09 | 2009-11-03 | Method for producing acrolein comprising the regeneration of a raw glycerin phase |
| JP2011538921A JP2012511505A (ja) | 2008-12-09 | 2009-11-03 | 粗製グリセリン相の処理を含むアクロレインの製造方法 |
| ZA2011/02268A ZA201102268B (en) | 2008-12-09 | 2011-03-28 | Method for producing acrolein comprising the regeneration of a raw glycerin phase |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008060888A DE102008060888A1 (de) | 2008-12-09 | 2008-12-09 | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102008060888A1 true DE102008060888A1 (de) | 2010-06-10 |
Family
ID=41668419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102008060888A Ceased DE102008060888A1 (de) | 2008-12-09 | 2008-12-09 | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8524945B2 (https=) |
| EP (1) | EP2356088B1 (https=) |
| JP (1) | JP2012511505A (https=) |
| CN (1) | CN102245551A (https=) |
| BR (1) | BRPI0919647B1 (https=) |
| DE (1) | DE102008060888A1 (https=) |
| WO (1) | WO2010066513A1 (https=) |
| ZA (1) | ZA201102268B (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006039203B4 (de) | 2006-08-22 | 2014-06-18 | Evonik Degussa Gmbh | Verfahren zur Herstellung von durch Kristallisation gereinigter Acrylsäure aus Hydroxypropionsäure sowie Vorrichtung dazu |
| FR2953829B1 (fr) | 2009-12-14 | 2011-12-09 | Arkema France | Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol |
| US9725641B2 (en) * | 2012-03-29 | 2017-08-08 | Axel R. Johnson | Methods fluids by producing and employing oil and gas well drilling and completion fluids as well as hydraulic fracturing fluids employing triglyceride processing by products and propylene glycol recovered from aircraft deicing operations |
| US10676664B2 (en) * | 2012-03-29 | 2020-06-09 | Axel R. Johnson | Increased availability and reduced costs for viscoelastic surfactants used in hydrofracturing fluids |
| DE102013000602A1 (de) | 2013-01-16 | 2014-07-17 | Evonik Industries Ag | Verfahren zur Herstellung von Acrylsäure |
| DE102013217386A1 (de) | 2013-09-02 | 2015-03-05 | Evonik Industries Ag | Verfahren zur Herstellung von Acrylsäure |
| JP6228246B2 (ja) | 2015-03-03 | 2017-11-08 | エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ | エテンのオリゴマー化に使用される不均一系触媒の再生 |
| PL3255029T3 (pl) | 2016-06-10 | 2019-04-30 | Evonik Degussa Gmbh | Oligomeryzacja etenu w warunkach nadkrytycznych |
| EP3266757B1 (de) | 2016-07-08 | 2019-12-25 | Evonik Operations GmbH | Herstellung von zumindest 1-hexen und octen aus ethen |
| US10227279B2 (en) | 2016-09-12 | 2019-03-12 | Evonik Degussa Gmbh | Dehydrogenation of LPG or NGL and flexible utilization of the olefins thus obtained |
| US11253844B2 (en) | 2018-03-14 | 2022-02-22 | Evonik Operations Gmbh | Oligomerization catalyst and process for the production thereof |
| US10882028B2 (en) | 2018-03-14 | 2021-01-05 | Evonik Operations Gmbh | Ni-containing catalyst for the oligomerization of olefins |
| US10882027B2 (en) | 2018-03-14 | 2021-01-05 | Evonik Operations Gmbh | Process for producing an oligomerization catalyst |
| US10850261B2 (en) | 2018-03-14 | 2020-12-01 | Evonik Operations Gmbh | Oligomerization catalyst and process for the production thereof |
| CA3049521C (en) | 2018-07-25 | 2025-05-27 | Evonik Oxeno Gmbh & Co. Kg | PROCESS FOR OLIGOMERIZING BUTENE AND DETERMINING THE PROPORTION OF ACID CATALYSIS |
| US11186782B2 (en) | 2019-01-08 | 2021-11-30 | Evonik Operations Gmbh | Catalyst and process for removing mercaptans from hydrocarbon streams |
| EP3680224B1 (de) | 2019-01-08 | 2023-05-24 | Evonik Operations GmbH | Verfahren zur entfernung mehrfach ungesättigter kohlenwasserstoffe aus c4-kohlenwasserstoffströmen in anwesenheit von mercaptanen, disulfiden und c5-kohlenwasserstoffen |
| CN110642674B (zh) * | 2019-10-15 | 2022-04-26 | 宁波环洋新材料股份有限公司 | 一种在生物柴油副产粗甘油的精制过程中联产丙烯醛的方法 |
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| DE4238493C1 (de) | 1992-11-14 | 1994-04-21 | Degussa | Verfahren zur Herstellung von Acrolein und dessen Verwendung |
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| DE102007004351A1 (de) * | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin |
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2009
- 2009-11-03 US US13/128,538 patent/US8524945B2/en not_active Expired - Fee Related
- 2009-11-03 JP JP2011538921A patent/JP2012511505A/ja active Pending
- 2009-11-03 WO PCT/EP2009/064500 patent/WO2010066513A1/de not_active Ceased
- 2009-11-03 EP EP09745047.2A patent/EP2356088B1/de not_active Not-in-force
- 2009-11-03 BR BRPI0919647-1A patent/BRPI0919647B1/pt not_active IP Right Cessation
- 2009-11-03 CN CN2009801492265A patent/CN102245551A/zh active Pending
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2011
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Also Published As
| Publication number | Publication date |
|---|---|
| US8524945B2 (en) | 2013-09-03 |
| EP2356088A1 (de) | 2011-08-17 |
| BRPI0919647A2 (pt) | 2015-12-08 |
| CN102245551A (zh) | 2011-11-16 |
| BRPI0919647B1 (pt) | 2018-11-06 |
| WO2010066513A1 (de) | 2010-06-17 |
| ZA201102268B (en) | 2011-12-28 |
| JP2012511505A (ja) | 2012-05-24 |
| US20110275777A1 (en) | 2011-11-10 |
| EP2356088B1 (de) | 2018-09-26 |
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