DE102008012516A1 - Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung - Google Patents
Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung Download PDFInfo
- Publication number
- DE102008012516A1 DE102008012516A1 DE102008012516A DE102008012516A DE102008012516A1 DE 102008012516 A1 DE102008012516 A1 DE 102008012516A1 DE 102008012516 A DE102008012516 A DE 102008012516A DE 102008012516 A DE102008012516 A DE 102008012516A DE 102008012516 A1 DE102008012516 A1 DE 102008012516A1
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- Prior art keywords
- component
- vinyl acetate
- glycol
- particularly preferably
- compositions
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 114
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 77
- 229920001577 copolymer Polymers 0.000 claims abstract description 65
- 238000000034 method Methods 0.000 claims abstract description 35
- 238000004132 cross linking Methods 0.000 claims abstract description 34
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 150000002978 peroxides Chemical class 0.000 claims abstract description 20
- 230000008569 process Effects 0.000 claims abstract description 20
- 238000002360 preparation method Methods 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 239000003999 initiator Substances 0.000 claims abstract description 13
- 229920001971 elastomer Polymers 0.000 claims description 55
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 47
- 229920001634 Copolyester Polymers 0.000 claims description 36
- -1 aliphatic Diols Chemical class 0.000 claims description 31
- 238000002844 melting Methods 0.000 claims description 30
- 230000008018 melting Effects 0.000 claims description 30
- 239000005060 rubber Substances 0.000 claims description 29
- 239000000654 additive Substances 0.000 claims description 28
- 238000002156 mixing Methods 0.000 claims description 25
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 19
- 239000004971 Cross linker Substances 0.000 claims description 17
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 15
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 14
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- 239000000945 filler Substances 0.000 claims description 11
- 239000004014 plasticizer Substances 0.000 claims description 11
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 6
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 5
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- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 claims description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 4
- 150000002334 glycols Chemical class 0.000 claims description 4
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims description 4
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 claims description 3
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
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- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 3
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- UHHKSVZZTYJVEG-UHFFFAOYSA-N oxepane Chemical compound C1CCCOCC1 UHHKSVZZTYJVEG-UHFFFAOYSA-N 0.000 claims description 3
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- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 2
- JWOACSMESNKGGJ-UHFFFAOYSA-N 2-ethenyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)C=C JWOACSMESNKGGJ-UHFFFAOYSA-N 0.000 claims description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
- 238000013037 co-molding Methods 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 claims description 2
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 150000002596 lactones Chemical class 0.000 claims description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- WMVSVUVZSYRWIY-UHFFFAOYSA-N [(4-benzoyloxyiminocyclohexa-2,5-dien-1-ylidene)amino] benzoate Chemical compound C=1C=CC=CC=1C(=O)ON=C(C=C1)C=CC1=NOC(=O)C1=CC=CC=C1 WMVSVUVZSYRWIY-UHFFFAOYSA-N 0.000 claims 1
- 239000011874 heated mixture Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 3
- 229940117958 vinyl acetate Drugs 0.000 description 65
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- 238000007906 compression Methods 0.000 description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
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- 229920001568 phenolic resin Polymers 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- DALNRYLBTOJSOH-UHFFFAOYSA-N 3,3,5,7,7-pentamethyl-1,2,4-trioxepane Chemical compound CC1CC(C)(C)OOC(C)(C)O1 DALNRYLBTOJSOH-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
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- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
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- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
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- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- 229910000423 chromium oxide Inorganic materials 0.000 description 1
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- 229920006236 copolyester elastomer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 125000005044 dihydroquinolinyl group Chemical class N1(CC=CC2=CC=CC=C12)* 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006341 elastomeric alloy Polymers 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
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- 238000002347 injection Methods 0.000 description 1
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- 238000001746 injection moulding Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 229920006030 multiblock copolymer Polymers 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
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- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
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- 230000000171 quenching effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
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- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
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- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Adhesives Or Adhesive Processes (AREA)
Priority Applications (10)
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| DE102008012516A DE102008012516A1 (de) | 2008-03-04 | 2008-03-04 | Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung |
| MX2009002086A MX2009002086A (es) | 2008-03-04 | 2009-02-25 | Composiciones reticulables, elastomeros termoplasticos obtenibles a partir de ellas y su uso. |
| BRPI0900686-9A BRPI0900686B1 (pt) | 2008-03-04 | 2009-02-26 | Composições reticuláveis, processo para a produção de composições e de elastômeros termoplásticos, elastômeros termoplásticos, uso de composições e de elastômeros termoplásticos, moldes, revestimentos de cabo, adesivos a quente ou películas |
| BRPI0900769-5A BRPI0900769B1 (pt) | 2008-03-04 | 2009-02-26 | Composições reticuláveis, processo para a produção de composições e de elastômeros termoplásticos, elastômeros termoplásticos, uso de composições e de elastômeros termoplásticos, moldes, revestimentos de cabo, adesivos a quente ou películas |
| US12/394,666 US7943694B2 (en) | 2008-03-04 | 2009-02-27 | Crosslinkable compositions, thermoplastic elastomers obtainable therefrom and their use |
| CA2656482A CA2656482C (en) | 2008-03-04 | 2009-02-27 | Crosslinkable compositions, thermoplastic elastomers obtainable therefrom and their use |
| EP20090153852 EP2098570B1 (de) | 2008-03-04 | 2009-02-27 | Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung |
| CN201510557995.6A CN105111694B (zh) | 2008-03-04 | 2009-03-02 | 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 |
| CN200910126034A CN101525471A (zh) | 2008-03-04 | 2009-03-02 | 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 |
| JP2009049267A JP5770416B2 (ja) | 2008-03-04 | 2009-03-03 | 架橋性組成物、その架橋性組成物から得られる熱可塑性エラストマー及びそれらの使用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008012516A DE102008012516A1 (de) | 2008-03-04 | 2008-03-04 | Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung |
Publications (1)
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| DE102008012516A1 true DE102008012516A1 (de) | 2009-09-10 |
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| DE102008012516A Withdrawn DE102008012516A1 (de) | 2008-03-04 | 2008-03-04 | Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7943694B2 (https=) |
| JP (1) | JP5770416B2 (https=) |
| CN (2) | CN105111694B (https=) |
| BR (2) | BRPI0900769B1 (https=) |
| CA (1) | CA2656482C (https=) |
| DE (1) | DE102008012516A1 (https=) |
| MX (1) | MX2009002086A (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009060065A1 (de) * | 2009-12-22 | 2011-06-30 | Veritas AG, 63571 | Fluidleitung |
| DE102015007200A1 (de) | 2015-05-26 | 2016-12-01 | Kraiburg Tpe Gmbh & Co. Kg | Härteeinstellung von thermoplastischen Elastomerzusammensetzungen durch Kombination von Thermoplasten und thermoplastischen Elastomeren |
| US9969880B2 (en) | 2013-06-05 | 2018-05-15 | Carl Freundenberg Kg | Thermoplastic elastomer composition and use thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2336229A1 (de) * | 2009-12-21 | 2011-06-22 | LANXESS Deutschland GmbH | Flammgeschützte Polymerzusammensetzungen |
| WO2011096477A1 (ja) * | 2010-02-08 | 2011-08-11 | 日本化成株式会社 | 架橋性エラストマー用架橋剤およびその応用 |
| US8178647B2 (en) | 2010-08-25 | 2012-05-15 | Eastman Chemical Company | Copolyester ether elastomer compositions and methods of making copolyester ether elastomer compositions |
| CN101948599B (zh) * | 2010-10-12 | 2012-08-22 | 上海交通大学 | 一种热塑性弹性体的制备方法 |
| CN102329483B (zh) * | 2011-09-26 | 2012-11-21 | 上海交通大学 | 聚丁二酸丁二醇酯/乙烯－醋酸乙烯酯共混材料制备方法 |
| US9388296B2 (en) | 2012-06-04 | 2016-07-12 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition having improved processability |
| US9617356B2 (en) | 2012-06-13 | 2017-04-11 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition |
| FR2995716B1 (fr) * | 2012-09-17 | 2014-09-05 | Silec Cable | Procede de fabrication d'un cable de transport d'energie electrique et cable fabrique par un tel procede |
| CN104540893A (zh) * | 2012-09-18 | 2015-04-22 | 提克纳有限责任公司 | 由共聚酯弹性体和α-烯烃乙酸乙烯酯共聚物的共混物制备的聚合物制品 |
| US9422428B2 (en) | 2014-04-17 | 2016-08-23 | Ticona Llc | Elastomeric composition having oil resistance |
| WO2017021800A1 (en) * | 2015-08-04 | 2017-02-09 | Aei Compounds Ltd. | Oil and mud resistant sheathing composition |
| MX2018002232A (es) | 2015-08-24 | 2018-06-22 | Aei Compounds Ltd | Composicion de aislado termoestable. |
| MX375491B (es) | 2017-03-01 | 2025-03-06 | Aei Compounds Ltd | Composiciones de aislamiento y forro de alambre |
| MX374798B (es) | 2017-03-01 | 2025-03-06 | Aei Compounds Ltd | Composición de revestimiento de cable. |
| CN110515168A (zh) * | 2019-08-30 | 2019-11-29 | 江苏中天科技股份有限公司 | 易剥离干式光纤微管和全干式微束光缆 |
| JP7432809B2 (ja) * | 2019-11-11 | 2024-02-19 | 東ソー株式会社 | 射出成形用樹脂組成物および射出成形体 |
| CN111961267A (zh) * | 2020-09-04 | 2020-11-20 | 石家庄硕若科技有限公司 | 一种耐高温的橡胶粉制作工艺 |
| CN113831855B (zh) * | 2021-09-26 | 2023-03-10 | 保定乐凯新材料股份有限公司 | 适应pla基材低温裱磁的热转移型磁条制备方法及应用 |
| KR102352074B1 (ko) * | 2021-11-08 | 2022-01-18 | 정준호 | 플랜지 접합용 가스켓 |
| CN118791796B (zh) * | 2023-04-14 | 2026-04-10 | 中国石油天然气股份有限公司 | 交联抗冲聚丙烯及其制备方法与应用 |
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| EP0327010A2 (en) | 1988-02-02 | 1989-08-09 | E.I. Du Pont De Nemours And Company | Thermoplastic elastomer blends |
| EP0341499A2 (de) | 1988-05-10 | 1989-11-15 | Bayer Ag | Lösungspolymerisation zur Herstellung von gelfreien Ethylen/Vinylacetat-Copolymerisaten |
| DE3825450A1 (de) | 1988-07-27 | 1990-02-01 | Bayer Ag | Verfahren zur herstellung von ethylen/vinylacetat-copolymerisaten mit verringerter klebeneigung, neue ethylen/vinylacetat-copolymerisate und ihre verwendung |
| EP0510478A1 (de) | 1991-04-24 | 1992-10-28 | Bayer Ag | Herstellung von Ethylen-Vinylacetat-Copolymeren |
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| JP2000351889A (ja) * | 1999-04-06 | 2000-12-19 | Yokohama Rubber Co Ltd:The | 熱可塑性エラストマー組成物及びそれを使用したジョイントブーツ |
| JP4057365B2 (ja) * | 2002-07-23 | 2008-03-05 | リケンテクノス株式会社 | 光ファイバ被覆用難燃性樹脂組成物および光ファイバコード又は光ケーブル |
| US20080161438A1 (en) * | 2006-12-28 | 2008-07-03 | Xingwang Wang | Composition comprising copolyetherester elastomer |
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2008
- 2008-03-04 DE DE102008012516A patent/DE102008012516A1/de not_active Withdrawn
-
2009
- 2009-02-25 MX MX2009002086A patent/MX2009002086A/es active IP Right Grant
- 2009-02-26 BR BRPI0900769-5A patent/BRPI0900769B1/pt not_active IP Right Cessation
- 2009-02-26 BR BRPI0900686-9A patent/BRPI0900686B1/pt not_active IP Right Cessation
- 2009-02-27 US US12/394,666 patent/US7943694B2/en active Active
- 2009-02-27 CA CA2656482A patent/CA2656482C/en not_active Expired - Fee Related
- 2009-03-02 CN CN201510557995.6A patent/CN105111694B/zh not_active Expired - Fee Related
- 2009-03-02 CN CN200910126034A patent/CN101525471A/zh active Pending
- 2009-03-03 JP JP2009049267A patent/JP5770416B2/ja not_active Expired - Fee Related
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| EP0327010A2 (en) | 1988-02-02 | 1989-08-09 | E.I. Du Pont De Nemours And Company | Thermoplastic elastomer blends |
| EP0341499A2 (de) | 1988-05-10 | 1989-11-15 | Bayer Ag | Lösungspolymerisation zur Herstellung von gelfreien Ethylen/Vinylacetat-Copolymerisaten |
| DE3825450A1 (de) | 1988-07-27 | 1990-02-01 | Bayer Ag | Verfahren zur herstellung von ethylen/vinylacetat-copolymerisaten mit verringerter klebeneigung, neue ethylen/vinylacetat-copolymerisate und ihre verwendung |
| EP0510478A1 (de) | 1991-04-24 | 1992-10-28 | Bayer Ag | Herstellung von Ethylen-Vinylacetat-Copolymeren |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009060065A1 (de) * | 2009-12-22 | 2011-06-30 | Veritas AG, 63571 | Fluidleitung |
| DE102009060065B4 (de) * | 2009-12-22 | 2018-02-01 | Veritas Ag | Fluidleitung |
| DE102009060065C5 (de) | 2009-12-22 | 2024-09-05 | Veritas Ag | Fluidleitung |
| US9969880B2 (en) | 2013-06-05 | 2018-05-15 | Carl Freundenberg Kg | Thermoplastic elastomer composition and use thereof |
| DE102015007200A1 (de) | 2015-05-26 | 2016-12-01 | Kraiburg Tpe Gmbh & Co. Kg | Härteeinstellung von thermoplastischen Elastomerzusammensetzungen durch Kombination von Thermoplasten und thermoplastischen Elastomeren |
| WO2016188517A1 (de) | 2015-05-26 | 2016-12-01 | Kraiburg Tpe Gmbh & Co. Kg | Härteeinstellung von thermoplastischen elastomerzusammensetzungen durch kombination von thermoplasten und thermoplastischen elastomeren |
Also Published As
| Publication number | Publication date |
|---|---|
| US7943694B2 (en) | 2011-05-17 |
| JP2009209370A (ja) | 2009-09-17 |
| CA2656482A1 (en) | 2009-09-04 |
| CN105111694A (zh) | 2015-12-02 |
| CN105111694B (zh) | 2018-09-14 |
| MX2009002086A (es) | 2009-09-28 |
| BRPI0900686B1 (pt) | 2019-04-24 |
| CN101525471A (zh) | 2009-09-09 |
| BRPI0900769B1 (pt) | 2019-04-24 |
| BRPI0900769A2 (pt) | 2010-04-06 |
| JP5770416B2 (ja) | 2015-08-26 |
| BRPI0900686A2 (pt) | 2010-05-04 |
| CA2656482C (en) | 2016-08-02 |
| US20090227725A1 (en) | 2009-09-10 |
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