DE101833T1 - Thermoplastische elastomere zusammensetzungen aus miteinander vertraeglichen aethylencopolymeren und halogenvinyl- oder halogenvinylidenpolymeren. - Google Patents

Thermoplastische elastomere zusammensetzungen aus miteinander vertraeglichen aethylencopolymeren und halogenvinyl- oder halogenvinylidenpolymeren.

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Publication number
DE101833T1
DE101833T1 DE198383106434T DE83106434T DE101833T1 DE 101833 T1 DE101833 T1 DE 101833T1 DE 198383106434 T DE198383106434 T DE 198383106434T DE 83106434 T DE83106434 T DE 83106434T DE 101833 T1 DE101833 T1 DE 101833T1
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Germany
Prior art keywords
copolymer
vinyl
group
carbon atoms
mixture according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE198383106434T
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English (en)
Inventor
Gary Lee Drexel Hill Pennsylvania 19026 Loomis
Robert Joseph Kennett Square Pennsylvania 19348 Statz
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EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of DE101833T1 publication Critical patent/DE101833T1/de
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/08—Homopolymers or copolymers of vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/06—Homopolymers or copolymers of esters of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L73/00—Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms

Claims (10)

European Patent Application 83 106 434.0 10.JuIi 1985 Publication Number 0 101 833 E. I. Du Pont De Nemours and Company η ι η i O O "· U '■ U I O 0 -.J Deutsche Übersetzung der veröffentlichten Ansprüche 1 bis 10
1. Teilweise vernetztes Gemisch von
(a) einem Copolymeren von Ethylen und einem oder mehreren copolymerisierbaren Comonomeren, ausgewählt aus der Gruppe von ethylenisch ungesättigten organischen Monomeren, Kohlenmonoxid und Schwefeldioxid; und
(b) zwischen 5 und 75 Gew.-%, basierend auf der Zusammensetzung, von einem Vinyl- oder Vinylidenhalogenid-Polymeren,
worin der Comonomergehalt in (a) derart ist, dass das Ethylencopolymere mit dem Vinyl- oder Vinylidenhalogenid-Polymeren verträglich ist. 25
2. Gemisch nach Anspruch 1, in das eingearbeitet ist eines oder mehrere der Mitglieder der Gruppe, bestehend aus Russ, Ton, Siliciumdioxid, Aluminiumoxid, Calciumcarbonat, Titandioxid, Dialkylphthalate, Trialkylmellitate, Polyesteroligomere und gesättigte und ungesättigte Polymere.
3. Gemisch nach Anspruch 1, bei dem die Zusammensetzung einen Gelgehalt von 5 bis 90%, bevorzugter von 10 bis 70% und am bevorzugtesten von 20 bis 40%, basierend auf dem Polymergesamtgewicht, hat.
— Ί _
4. Gemisch nach den Ansprüchen 1 bis 3, worin (b) Polyvinylchlorid ist.
5. Gemisch nach Anspruch 2, worin das Copolymere (a) von Ethylen und einem ethylenisch ungesättigten organischen Monomeren ist, das ausgewählt ist aus der Gruppe von ungesättigten Mono- oder Dicarbonsäuren mit 3-20 Kohlenstoffatomen, Estern dieser ungesättigten Mono- oder Dicarbonsäuren, Vinylestern von gesättigten Carbonsäuren, worin die Säuregruppe 2-18 Kohlenstoffatome hat, Vinylalkylethern, worin die Alkylgruppe 1-18 Kohlenstoffatome hat, Vinyl- oder Vinylidenhalogeniden, Acrylnitril, Methacrylnitril, Norbornen, oC-Olefinen mit 3-12 Kohlenstoffatomen und vinylaromatischen Verbindungen.
6. Gemisch nach Anspruch 2, worin das organische Monomere ausgewählt ist aus der Gruppe von Methylacrylat, Butylacrylat, Vinylacetat und Maleinsäuremonoethylester, und in dem Copolymeren in einer Menge grosser als etwa 40 Gew.-%, basierend auf dem Copolymeren, vorhanden ist.
7. Gemisch nach Anspruch 2, worin das Copolymere (a) ein Terpolymeres von Ethylen, einem copolymerisierbaren ethylenisch ungesättigten organischen Monomeren und einem Mitglied aus der Gruppe von Kohlenmonoxid und Schwefeldioxid ist, und das organische Monomere ausgewählt ist aus der Gruppe von ungesättigten Mono- oder Dicarbonsäuren mit 3-20 Kohlenstoffatomen, Estern dieser ungesättigten Mono- oder Dicarbonsäuren, Vinylestern von gesättigten Carbonsäuren, worin die Säuregruppe 2-18 Kohlenstoffatome hat, Vinylalkylethern, worin die Alkylgruppe 1-18 Kohlenstoffatome hat, Vinyl- oder Vinylidenhalogeniden > Acrylnitril, Methacrylnitril, Norbornen, oC -Olefinen mit 3-12 Kohlenstoffatomen und vinylaromatischen Verbindungen.
-2-
8. Gemisch nach Anspruch 2, worin das organische Monomere ausgewählt ist aus der Gruppe von Methylacrylat, Butylacrylat und Vinylacetat, und in dem Copolymeren in Mengen von 1 bis 60 Gew.-%, basierend auf dem Copolymeren, vorhanden ist, und das Kohlenmonoxid oder Schwefeldioxid in Mengen von 1 bis 30 Gew.-%, basierend auf dem Copolymeren, vorhanden ist.
9. Gemisch nach Anspruch 2, worin das Copolymere (a)
ein Copolymeres von Ethylen und einem Mitglied der. Gruppe, bestehend aus Kohlenmonoxid und Schwefeldioxid ist, wobei die Menge eines derartigen anderen Comonomeren grosser als etwa 15 Gew.-%, basierend auf dem Polymeren, ist.
10. Gegenstand in der Form eines selbsttragenden Films, einer selbsttragenden Folie, eines Formkörpers, eines strangepressten Profils, Rohres, bestehend aus einem
oder einer bzw. eines Polyester-, Polyamid-, Polyimid- oder Metall-Faser oder -Stoffes, extrusionsbeschichtet durch eine Zusammensetzung, bestehend aus einem
teilweise vernetzten Gemisch von
25
(a) einem Copolymeren von Ethylen und einem oder mehreren copolymerisierbaren Comonomeren, ausgewählt aus der Gruppe von ethylenisch ungesättigten organischen Monomeren, Kohlenmonoxid und Schwefeldioxid; und
(b) zwischen 5 und 75 Gew.-%, basierend auf der Zusammensetzung, von einem Vinyl- oder Vinylidenhalogenid-Polymeren,
worin der Comonomergehalt in (a) derart ist, dass das Ethylencopolymere mit dem Vinyl- oder Vinylidenhalogenidpolymeren verträglich ist.
-3-
DE198383106434T 1982-07-01 1983-07-01 Thermoplastische elastomere zusammensetzungen aus miteinander vertraeglichen aethylencopolymeren und halogenvinyl- oder halogenvinylidenpolymeren. Pending DE101833T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39432982A 1982-07-01 1982-07-01
US42741382A 1982-09-29 1982-09-29

Publications (1)

Publication Number Publication Date
DE101833T1 true DE101833T1 (de) 1985-09-26

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ID=27014689

Family Applications (2)

Application Number Title Priority Date Filing Date
DE8383106434T Expired DE3380631D1 (en) 1982-07-01 1983-07-01 Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer
DE198383106434T Pending DE101833T1 (de) 1982-07-01 1983-07-01 Thermoplastische elastomere zusammensetzungen aus miteinander vertraeglichen aethylencopolymeren und halogenvinyl- oder halogenvinylidenpolymeren.

Family Applications Before (1)

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DE8383106434T Expired DE3380631D1 (en) 1982-07-01 1983-07-01 Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer

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EP (1) EP0101833B1 (de)
KR (1) KR920001792B1 (de)
AU (1) AU1637383A (de)
BR (1) BR8303436A (de)
CA (1) CA1232995A (de)
DE (2) DE3380631D1 (de)
ES (1) ES523601A0 (de)
MX (1) MX163636B (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4513058A (en) * 1984-04-17 1985-04-23 Wilson Sporting Goods Co. Impact resistant high air retention bladders
FR2612118B1 (fr) * 1987-03-09 1989-06-16 Draka Polva Bv Raccord pour tuyauterie en resine a base de chlorure de vinyle comprenant un anneau d'etancheite en caoutchouc thermoplastique
US4742107A (en) * 1987-05-06 1988-05-03 E. I. Du Pont De Nemours And Company Noise reduction and damping compositions
CA1324229C (en) * 1987-09-04 1993-11-09 John R. Kastelic Mica-filled carbon monoxide unsaturated monomer copolymer
US4761449A (en) * 1987-10-22 1988-08-02 Shell Oil Company Flame retardant compositions
US4818786A (en) * 1988-06-08 1989-04-04 Shell Oil Company Polymer blend of carbon monoxide/olefin copolymer and a polyvinylidine fluoride polymer
WO1992020742A1 (en) * 1991-05-23 1992-11-26 E.I. Du Pont De Nemours And Company Free-flowing powdered polyvinyl chloride compositions
GB9403701D0 (en) * 1994-02-25 1994-04-13 Bp Chem Int Ltd Polymer composition
US5464903A (en) * 1994-10-31 1995-11-07 E. I. Du Pont De Nemours And Company Process for preparing ethylene copolymer plasticized PVC
US6048912A (en) * 1998-07-31 2000-04-11 Bayer Corporation Rubber polymerizates with a high gel content and a high swelling degree
DE19834580A1 (de) * 1998-07-31 2000-02-03 Bayer Ag Kautschuk-Polymerisate mit einem hohen Gelgehalt und einem hohen Quellgrad
KR100561336B1 (ko) * 2000-12-08 2006-03-16 주식회사 엘지화학 투명성 및 강도가 우수한 염화비닐계 열가소성탄성체 및 그의 제조방법
JP5345793B2 (ja) * 2008-02-22 2013-11-20 ポリプラスチックス株式会社 電線被覆用樹脂材料、当該電線被覆用樹脂材料を用いた電線、及び難燃ケーブル

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1019087A (en) * 1971-08-06 1977-10-11 Clarence F. Hammer Blends of ethylene/carbon monoxide copolymers with polyvinyl chloride
BE787217A (fr) * 1971-08-06 1972-12-01 Du Pont Compositions polymeres reticulees insolubles dans le tetrahydrofuranne
JPS56100815A (en) * 1980-01-18 1981-08-13 Dainippon Ink & Chem Inc Preparation of vinyl chloride resin compound with excellent thermal deformation resistance

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EP0101833B1 (de) 1989-09-27
DE3380631D1 (en) 1989-11-02
ES8503704A1 (es) 1985-03-01
AU1637383A (en) 1984-01-05
KR920001792B1 (ko) 1992-03-02
BR8303436A (pt) 1984-02-07
KR840005470A (ko) 1984-11-12
CA1232995A (en) 1988-02-16
EP0101833A2 (de) 1984-03-07
EP0101833A3 (en) 1985-11-06
ES523601A0 (es) 1985-03-01
MX163636B (es) 1992-06-09

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