DD106861A5 - - Google Patents

Info

Publication number
DD106861A5
DD106861A5 DD172614A DD17261473A DD106861A5 DD 106861 A5 DD106861 A5 DD 106861A5 DD 172614 A DD172614 A DD 172614A DD 17261473 A DD17261473 A DD 17261473A DD 106861 A5 DD106861 A5 DD 106861A5
Authority
DD
German Democratic Republic
Application number
DD172614A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH1135472A external-priority patent/CH572082A5/de
Priority claimed from CH1782472A external-priority patent/CH572086A5/de
Application filed filed Critical
Publication of DD106861A5 publication Critical patent/DD106861A5/xx

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/91Dibenzofurans; Hydrogenated dibenzofurans
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D209/00Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04Indoles; Hydrogenated indoles
    • C07D209/10Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
    • C07D209/14Radicals substituted by nitrogen atoms, not forming part of a nitro radical
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C07D249/101,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D249/14Nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D277/00Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62Benzothiazoles
    • C07D277/68Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/82Nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/50Amino-hydroxy-anthraquinones; Ethers and esters thereof
    • C09B1/503Amino-hydroxy-anthraquinones; Ethers and esters thereof unsubstituted amino-hydroxy anthraquinone
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/50Amino-hydroxy-anthraquinones; Ethers and esters thereof
    • C09B1/54Amino-hydroxy-anthraquinones; Ethers and esters thereof etherified
    • C09B1/545Anthraquinones with aliphatic, cycloaliphatic or araliphatic ether groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/10The polymethine chain containing an even number of >CH- groups
    • C09B23/105The polymethine chain containing an even number of >CH- groups two >CH- groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14Styryl dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14Styryl dyes
    • C09B23/145Styryl dyes the ethylene chain carrying an heterocyclic residue, e.g. heterocycle-CH=CH-C6H5
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/16Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing hetero atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/16Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing hetero atoms
    • C09B23/162Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing hetero atoms only nitrogen atoms
    • C09B23/164Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing hetero atoms only nitrogen atoms containing one nitrogen atom
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00Monoazo dyes prepared by diazotising and coupling
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00Monoazo dyes prepared by diazotising and coupling
    • C09B29/34Monoazo dyes prepared by diazotising and coupling from other coupling components
    • C09B29/36Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
    • C09B29/3604Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
    • C09B29/3617Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom
    • C09B29/3621Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a six-membered heterocyclic with only one nitrogen as heteroatom from a pyridine ring
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B44/00Azo dyes containing onium groups
    • C09B44/02Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B44/00Azo dyes containing onium groups
    • C09B44/10Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B44/00Azo dyes containing onium groups
    • C09B44/10Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
    • C09B44/101Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system characterised by the coupling component having an amino directing group
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B44/00Azo dyes containing onium groups
    • C09B44/10Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
    • C09B44/18Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system having three nitrogen atoms as the only ring hetero atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/78Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with other reactive groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00Dyes not provided for by a single group of this subclass
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00Dyes not provided for by a single group of this subclass
    • C09B69/001Dyes containing an onium group attached to the dye skeleton via a bridge

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
DD172614A 1972-07-31 1973-07-30 DD106861A5 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH1135472A CH572082A5 (en) 1972-07-31 1972-07-31 Sulphonic acid-free basic dyes - for dyeing and printing acrylonitrile or vinylidene cyanide polymer-contg textiles polyesters and polyamides
CH1782472A CH572086A5 (en) 1972-12-07 1972-12-07 Sulphonic acid-free basic dyes - for dyeing or printing textiles contg acrylo-nitrile polymers, polyamides or polyesters
CH161873 1973-02-05

Publications (1)

Publication Number Publication Date
DD106861A5 true DD106861A5 (de) 1974-07-05

Family

ID=27173120

Family Applications (1)

Application Number Title Priority Date Filing Date
DD172614A DD106861A5 (de) 1972-07-31 1973-07-30

Country Status (12)

Country Link
US (2) US4085098A (de)
JP (2) JPS4950286A (de)
AR (2) AR207435A1 (de)
AU (1) AU5874873A (de)
CA (1) CA1010852A (de)
DD (1) DD106861A5 (de)
DE (2) DE2338682A1 (de)
ES (3) ES417382A1 (de)
FR (2) FR2194710B1 (de)
GB (2) GB1443722A (de)
IT (2) IT990078B (de)
NL (2) NL7310512A (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55136383A (en) * 1979-04-11 1980-10-24 Kumahira Safe Co Remote controller for safeedeposit box for rent
JPS6139819Y2 (de) * 1979-06-30 1986-11-14
JPS6123179Y2 (de) * 1979-08-24 1986-07-11
JPS6120931Y2 (de) * 1980-04-21 1986-06-23
US4910299A (en) * 1986-12-09 1990-03-20 Ciba-Geigy Corporation Disperse azo dyes containing N-phenoxyalkyleneanilines as coupling components
DE4314787A1 (de) * 1993-05-05 1994-11-10 Oekologische Sanierungs Und En N-benzylierte Triazolazofarbstoffe und Verfahren zu ihrer Herstellung

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA657908A (en) * 1963-02-19 E. Lewis Charles Polyacrylonitriles dyed with quaternized heterocyclic azo dyes
FR1144237A (fr) * 1954-12-15 1957-10-10 Geigy Ag J R Sels de colorants solubles dans l'eau et leur procédé de préparation
US3078137A (en) * 1955-06-14 1963-02-19 Basf Ag Process of dyeing structures of cellulose acetates and polyesters
US3148935A (en) * 1955-06-25 1964-09-15 Basf Ag Dyeing textile material consisting of polyacrylonitrile and its copolymers
US2913303A (en) * 1956-08-14 1959-11-17 Basf Ag Dyeing of polyacrylonitrile and copolymers of acrylonitrile
US3133052A (en) * 1959-01-08 1964-05-12 Sandoz Ltd Quaternated disazo dyestuffs
US3102878A (en) * 1960-04-11 1963-09-03 Basf Ag Production of water-soluble dyestuffs salts
US3132132A (en) * 1960-06-02 1964-05-05 Hodogaya Chemical Co Ltd Cationic thiazole dyes and process for manufacturing the same
US3245981A (en) * 1963-02-28 1966-04-12 Allied Chem 6-alkoxy-2-benzothiazole monoazo dyestuffs
NL128007C (de) * 1963-12-14
DE1544506A1 (de) * 1965-01-02 1970-04-16 Hoechst Ag Verfahren zur Herstellung von basischen Azofarbstoffen
US3438963A (en) * 1966-02-07 1969-04-15 American Cyanamid Co Alkylation process for cationic triazole dye
US3515715A (en) * 1967-01-23 1970-06-02 Eastman Kodak Co Quaternized pyrazolylazo dyes
CH502419A (de) * 1968-02-13 1971-01-31 Sandoz Ag Verfahren zur Herstellung von basischen Verbindungen der Monoazoreihe
US3585182A (en) * 1968-02-28 1971-06-15 Eastman Kodak Co Quaternized triazoliumazo - 4 - phenyl-thiomorpholino-1,1-dioxide dyestuffs
CH643868A4 (de) * 1968-04-30 1972-10-31
US3679656A (en) * 1968-05-20 1972-07-25 Hodogaya Chemical Co Ltd Quaternized 1,2,4-triazolium-3-azo dyestuffs
DE1795227A1 (de) * 1968-08-24 1971-11-04 Basf Ag Neue basische Azofarbstoffe der Indazolreihe
DE1943799B2 (de) * 1968-09-18 1976-07-01 Toms River Chemical Corp., Toms River, NJ. (V.St.A.) Verfahren zur herstellung von benzthiazoliumazoverbindungen
DE1943800A1 (de) * 1968-09-18 1970-04-09 Toms River Chemical Corp Verfahren zur Alkylierung von Triazolazoverbindungen
US3707532A (en) * 1969-01-03 1972-12-26 Ciba Geigy Ag Azo dyestuffs containing a benzthiazolyl group
GB1298021A (en) * 1969-03-04 1972-11-29 Sandoz Ltd Basic monoazo dyes, their production and use
BE759551A (fr) * 1969-12-01 1971-04-30 Sumitomo Chemical Co Nouveaux colorants cationiques
JPS4823330B1 (de) * 1970-02-02 1973-07-12
DE2040872C3 (de) * 1970-08-18 1978-04-20 Bayer Ag, 5090 Leverkusen Hydrazonfarbstoffe
DE2044823A1 (de) * 1970-09-10 1972-03-16 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Basische Azofarbstoffe der Indazolreihe
CH562292A5 (de) * 1970-11-11 1975-05-30 Ciba Geigy Ag
DE2232542A1 (de) * 1972-07-03 1974-01-24 Bayer Ag Kationische azofarbstoffe
DE2355076A1 (de) * 1973-11-03 1975-05-07 Bayer Ag Kationische farbstoffe

Also Published As

Publication number Publication date
GB1443722A (en) 1976-07-21
US4085098A (en) 1978-04-18
FR2194710A1 (de) 1974-03-01
ES417381A1 (es) 1976-06-01
DE2338681C2 (de) 1983-01-13
IT990077B (it) 1975-06-20
DE2338681A1 (de) 1974-02-28
JPS5035480A (de) 1975-04-04
NL7310511A (de) 1974-02-04
AR207435A1 (es) 1976-10-08
ES417382A1 (es) 1976-06-01
DE2338682A1 (de) 1974-02-21
FR2194710B1 (de) 1979-01-26
ES417383A1 (es) 1976-06-01
IT990078B (it) 1975-06-20
GB1444190A (en) 1976-07-28
NL7310512A (de) 1974-02-04
JPS4950286A (de) 1974-05-15
US4289693A (en) 1981-09-15
AR197997A1 (es) 1974-05-24
AU5874873A (en) 1975-02-06
CA1010852A (en) 1977-05-24
FR2194709A1 (de) 1974-03-01
FR2194709B1 (de) 1978-02-10

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