CZ351298A3 - Cleansing mixtures - Google Patents

Abstract

A cleaning composition which provides effective cleaning and shine performance, said composition comprising a surfactant system comprising an amine oxide and a betaine or sulphobetaine surfactant in a weight ratio of amine oxide to betaine or sulphobetaine of 6:1 to 100:1. Preferably, the composition comprises a solvent for enhanced cleaning and shine performance of the composition. More preferably, the composition further comprises an antimicrobial compound and/or a peroxygen bleach for enhanced disinfection performance.

Description

A cleaning composition that provides effective cleaning and an appropriate gloss, said composition comprising a surfactant system comprising an amine oxide and a betaine or sulfobetaine surfactant in a weight ratio of amine oxide to betaine or sulfobetaine of 6: 1 to 100: 1. Preferably, the composition comprises a solvent to enhance the cleaning and polishing performance of the composition. More preferably, the composition further comprises an antimicrobial compound and / or peroxy bleach for enhanced disinfectant action,

Cleaning mixtures

Technical field

The present invention relates to a cleaning composition that provides effective cleaning and glossy appearance of surfaces, especially hard surfaces.

BACKGROUND OF THE INVENTION

The composition of compositions or compositions that provide cleaned glossy surfaces is a problem known in the art to those developing the respective cleaning composition. More specifically, the problem of providing shiny surfaces is often threatened by the remnants of the compositions left on said surfaces, which appear as irregular streaks or streaks upon completion of the water evaporation. This problem of residual residue is even more noticeable where the composition is used to clean surfaces made of glossy materials such as glossy ceramic tiles, windows and mirrors, or such materials as polyurethane coated PVC, which is widely used in North America . In addition, many products are now compounded or can be used as rinse-free products. In such conditions or with such products, the problem of residualness has become even more acute.

Therefore, there is a need for a composition that provides effective cleaning performance, but also provides clean, gloss-free surfaces without any residue.

Numerous solutions have been proposed in the art to address this need, including the use of acid, magnesium ions, or the use of certain solvents, as described in WO 95/21229, EP 0 639 833 or U.S. Pat.

3,839.234.

SUMMARY OF THE INVENTION

The applicant has now surprisingly found that this need could also be met by formulating a composition comprising a surfactant system comprising an amine oxide surfactant and a betaine or sulfobetaine surfactant in specific proportions.

This finding is particularly surprising since, using amine oxide surfactants, it has been found that crystals form on drying, resulting in speckled residues on the surface to be cleaned;

whereas, on the other hand, the use of betaine or sulfobetaine surfactants. also effective cleaning components, left amorphous residues resulting in an oily film on the surface. Surprisingly, the use of a mixture of amine oxide-based surfactants and betaine or sulfobetaine in specific proportions not only provides efficient cleaning of the surfaces, but also causes said residues to appear less or even no longer occur.

The applicant further found that the addition of solvents to this surfactant system provides enhanced cleaning and polishing performance.

It is therefore an advantage of the present invention to provide a composition that provides effective cleaning and shiny appearance of the respective surfaces.

The composition of claim 1, wherein the addition of a peroxygen bleach compound, such as an antimicrobial disinfectant to the respective surface, up to a dilution of 1: 100 (mixture: water).

The applicant has also found, and / or antimicrobial essential oils, provides elevated even at large dilutions, e.g.

It is thus a further advantage of the invention to provide a composition with an effective disinfectant effect.

Yet another advantage of the present invention is that it provides a mild skin-friendly composition.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to a cleaning composition comprising a surfactant system comprising an amine oxide and a betaine or sulfobetaine surfactant in a weight ratio of amine oxide to betaine or sulfobetaine of from 6: 1 to 100: 1.

In a preferred embodiment of the invention, the composition comprises a solvent for enhanced cleaning and polishing performance of the composition.

In another preferred embodiment of the invention, the composition further comprises a peroxygen bleaching agent and / or an antimicrobial agent, such as a micronized volatile oil, its assets or mixtures thereof, to provide a composition with effective disinfectant performance.

i * o o n y description in y π δ i θ z

The main feature of the present invention is a surfactant system wherein said salt system is an amine-oxide betaine or a dry surfactant of amine-oxide to beta-new or sulfobeta-new surfactant amine oxides; a κ t i v π i 1 ark a

Amino x i u y are zd?

used, the compounds y are:

Formulas:

wherein R is a primary alkyl group containing 6-24 carbons, preferably 10-18 carbons, and wherein R 'and R' 'are each independently selected from methyl-, ethyl-2-hydroxyethyl. The arrow in the formula is a conventional representation of a semipolar bond.

Preferred amine oxides are those in which the primary alkyl group has a straight chain in most molecules, generally at least 70%, preferably at least 90% of the molecules, and amine oxides which are particularly preferred are those in which R contains 10-18 carbons and R 'and R' 'are both methyl.

Examples of preferred amine oxides are N-hexyldimethylamine oxide, N-octyl imethylamine oxide, N-dimethyldimethylamine oxide,

N-dodecyldimethylamine oxide, N-tetradecyldimethylamine oxide,

N-hexadecyldimethylamine oxide, N-octadecyldimethylamine oxide, N-eicosyldimethylamine oxide, N-docosyldimethylamine oxide N-tetracosyl-dimethylamine oxide, the corresponding amine oxides in which one or both methyl groups are replaced with ethyl or 2-hydroxyethyl groups.

Betaine or sulphobetaine surfactant

The composition of the present invention comprises a betaine or sulfobetaine surfactant or derivatives thereof or mixtures thereof. A further advantage of the invention is the mild action effect of said betaine and / or sulfobetaine surfactants. Accordingly, the surface mixtures disclosed herein, for example, with sulfobetaine foodstuffs, may particularly be comprised of delicate laundry and / or children.

In addition, betaine and / or surfactants are also very mild in their effect on the skin and thus contribute to the convenience of use of the compositions or compositions of the invention by the user.

Suitable betaine / sulfobetaine surfactants to be used in the compositions of the present invention are betaine / sulfobetaine and betaine-like detergents, wherein the molecule contains both basic and acidic groups which form an internal salt giving the molecule both cationic and anionic hydrophilic groups in a broad common example of such detergents, the ranges of H (II) are described in U.

, 082,275, 2,702,279, are the principal filings. neKttťrtť

Pat. Nose. with appropriate reference. Preferred betaine or sulfobetaine surfactants have the formula wherein R1 is an alkyl radical containing from about 1 to 24 carbon atoms, more preferably from 5 to 1S, and more preferably from 12 to 14, wherein R2 and R3 contain

R 1 --- Ν ¹ (from 1 to 3 carbon atoms and r and ai

and wherein the number is from 1 consisting of the radicals R1, R2 of its mixtures.

Examples of particularly suitable betaine surfactants include C12-C18 alkyldimethyl betaine, such as coconut betaine, and C10-C16 alkyldimethyl betaine, such as lauryl betaine.

to 10, preferably from 1 to 6, and preferably 1, Y is selected from the group of carboxylic and sulfonic radicals and wherein the sum and R 3 are from about 14 to 24 carbon atoms, or Wilson laurylbetain under the Commercial Name of Seppic, trade name Amonyl 265 % of said mixture, respectively, of at least 0.005% by weight:

Coconut betaine and resp. Albright &

Empigen BB / L.

Typically, the total compositions comprise said betaine or sulfobetaine surfactants or derivatives or mixtures thereof, more preferably from 0.01¾ to 10¾ and most preferably from 0.1¾ to 5¾.

The weight ratios of amine oxides to betaine or sulfobetaine are an important feature of the present invention. Therefore, ratios outside the following such as those where the betaine or sulphobetaine surfactant is in a higher proportion would not provide a cleaning and polishing range, an active effect, as only cleaning agents

When fat remains.

On the other hand, surfactant speckled residues with an aminox iaove κ netain or sulfobetaine bar ratio above 100: 1 would result in a surface showing:

: ypu

Thus, an important point is that the amine-oxide betaine or sulfobetaine surfactant is present in the mixture in a weight ratio of alkyl sulfates to betaine of 1

100: 1, preferably up to 30: 1.

Additional components

The composition according to the invention may optionally include components and external components, such as ρ i. Sulfurizing agents, chelating agents, antimicrobial compounds and mixtures thereof.

> d i 0: 1 to 5 0: 1, more preferably 1: 1 gives a dissolution of 1 <

Solvents When used, preferably the enhanced cleaning and performance of the composition is used. Suitable solvents for incorporation into the compositions of this invention include propylene glycol derivatives such as n-butoxypropanol or n-butoxypropoxypropanol, water-soluble solvents CARBITOL or water-soluble solvents CELLOSOLVE. CARBITOL water-soluble solvents are compounds of the 2- (2-alkoxyethoxy) ethanol class wherein the alkoxy group is derived from ethyl, propyl or butyl. A preferred water-soluble carbitol is 2- (2-butoxyethoxy) ethanol, also known as butylcarbitol.

CELLOSOLVE water-soluble solvents are compounds of the 2-alkoxyethoxyethanol class, of which 2-butoxyethoxyethanol is preferred.

benzyl alcohol, ethanol, 2-ethyl-1,3-hexanediol and mixtures. Of them they are

Other suitable solvents are isopropyl alcohol and diols, such as e.g.

2,2,4-trimethyl-1,3-pentanediol, and their preferred solvents n-butoxypropoxypropanol, butylcarbitol and mixtures thereof. Of these, butylcarbobol is the most preferred solvent.

Typically, the solvents may be present in the undiluted composition of the invention at a level of 0.01 to 10 wt%, preferably 3 to 7 wt%, based on the weight of the composition.

Peroxygen bleach

A further suitable additive component for use herein is a peroxygen bleach. A peroxygen composition, in particular hydrogen peroxide, persulfate and the like, in the disinfectant properties of the compositions of the present invention. Preferably, they contribute to this case, without being bound by theory, it can be believed that this may attack the vital function of the cells of the microorganism, e.g., it may inhibit the accumulation of ribosome units within the cytoplasm of the cells of the microorganism. The following peroxygen bleach, such as hydrogen peroxide, is a strong oxidizing radical which attacks proteins and the presence of free hydroxyl nucleic acids. In addition, the bleaching agent, in particular hydrogen peroxide, provides strong stain removal effects which are particularly noteworthy, e.g.

As used herein, the compound is contacted with an application in a conventional manner, such as from t and 5

Which water.

IU A hydrogen peroxide source for hard surface applications, hydrogen peroxide to any of the compounds in hydrogen peroxide suitable for the present case include percarbonate, percarbonate, persulphates such as monopersulfate, perborates and peroxyacids such as • hydrogen peroxide. Eg diperoxydodecanediolic acid (DPDA), magnesium salt of perphthalic acid and mixtures thereof.

A preferred peroxygen bleach is hydrogen peroxide or a water-soluble source thereof or mixtures thereof. The most preferred peroxygen bleach is hydrogen peroxide.

In addition to the peroxygen bleach, other classes of peroxides may be used as an alternative to hydrogen peroxide and its sources or in combination with hydrogen peroxide and its sources. Suitable groups include dialkyl peroxides, diacyl peroxides, preformed percarboxylic acids, organic and inorganic peroxides.

Typically, the compositions herein comprise at least 0.01¾ of said peroxygen bleach or mixtures thereof based on the weight of the total composition, preferably from 0.1 to 15%, more preferably from 0.8 to 10%, and most preferably from 1 to 5%.

Chelating agents

Chelating agents are also additional components that may be suitable for use in this case. Preferred chelating agents are those selected from the group of aminophosphonates. Suitable aminophosphonate compounds for aminoalkylene poly (alkylene phosphonate), methanethane-1-hydroxy diphosphonates, ethylenediaminetetramethylene phosphonates and diethylenetriaminepentamethylenephosphonates. The phosphonate compounds may be present either in their acid form or as salts of various cations of use containing alkali nitrile-trimethylene phosphonates, at some or all of their functional sites. A preferred aminophosphonate chelating agent is diethylenetriaminepentamethylenephosphonate. This phosphonate reagent is commercially available from Monsant under the trade name DEQUEST. said chelating agents, especially phosphonate agents such as diethylenetriaminepentamethylenephosphonates, are mainly preferred in the compositions of this invention, since they have been found to contribute intimately to the disinfecting properties of hydrogen peroxide.

Typically, the compositions of the present invention may contain up to 5% by weight of the chelating agent, or mixtures thereof, based on the total composition, preferably from 0.002 to 3% by weight, and even more preferably from 0.002 to 1.5% by weight.

Antimicrobial compounds

Another suitable additional component of the compound or mixture thereof.

Suitable antimicrobial compounds of the present invention are antimicronial as used herein, and include antimicrobial essential oils, their assets and mixtures thereof. Suitable antimicrobial essential oils used herein are those that exhibit antimicrobial activity. Essential oil assets are herein meant any additives to these oils which exhibit the antimicrobial properties of the oil as a denaturation agent and their assets are furthermore of the safety profile of the composition.

These volatile compounds (verbena plants) have antimicrobial activity. It is believed that essential oils and their assets act as proteins. Said antimicrobial oils are compounds which contribute to the present invention when used to disinfect any surface. A further advantage of said antimicrobial oils and their assets is that their presence gives the composition a pleasant fragrance, thereby avoiding the need to add the corresponding perfume.

oils include, but are not limited to, those of thyme, lemongrass, citrus, lemons, oranges, anise, and spices), cloves, cinnamon, geranium, roses, mint, lavender, citronella, eucalyptus (eucalyptus), peppermint , camphor, sandalwood and cedar wood and mixtures thereof.

The essential oils used herein include, but are not limited to, thymol (present eg in thyme), eugenol (present eg in cinnamon and clove), menthol (present eg in mint), geraniol (present eg in geranium and rose), verbena (present eg in eucalyptol and pinocarvone (present in eucalyptus), cedrol (present eg in cedar), anethole (present eg in anise), carvacro) hi nok iti ol, berber i η , ferulic acid, methylsalicylic acid, methylsilyllate, terpineol and

Preferred esters of the essential oils are thymol, eugenol, verbena, eu x and yy2, terpineol, methylsalicylic acid and / or geraniol.

: de used, are acids with acid,

Thymol may be commercially available commercially, e.g., from Sigma, Manheimer Inc.

typically a mixture present in e.g.

The systems may be of an antimicrobial invention in oil or in an amount of at least about 0.01

O. C 4.

better by 0.

ρ o the composition according to m,% of the composition, preferably from 0/006 to 10%,

0.01 to 4%, and preferably from 0.02 to 2%.

Other antimicrobial compounds can be used in mixtures in the λ * label, j and κ o n and p i. cr i u t a r a d e d y / d e d o ρ a r a d e n v e t n e r y 1 r a r ab e n u m e t 1 ρ a r a b e n u, ρ r o ρ y i ρ a r a b e n u

based on the weight of the entire composition.

Obsahují c o obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují obsahují especially essential oil or its assets or mixtures, effective disinfection is obtained against a number of different microorganisms of the anism - not Gram positive bacteria such as Staphyiococcus, or Gram negative such as Pseudomonas aeroginosa, as well as against fungi such as Candida albicans, which are present on the surface, even when used under very dilute conditions.

The following disinfection test procedure for the disinfection properties of the mixture:

can be used for measurement

Disinfection test procedure measured bacteria destroying

Disinfectant properties of the activities of the mixture.

the mixtures may be

The test procedure for evaluating the bactericidal activity of a mixture is described in European Standard, prEN 1040, CEN / TC 216 N 78, dated November 1995, published by the European Commission for Standardization in

Brussels, test disinfectant bacterial

European procedure and mixtures. The colony standard, prEN 1040, CEN / TC 216 N 78, specifies requirements for minimal bacteria destroying activity

The test is passed if the units forming (cfu) are reduced from 10 ⁷ cfu (initial level) to 10 ² cfu (final level after contact with disinfectant), ie a viability reduction of 10 ⁵ is required.

Optional compounds

Said compositions may further comprise compounds including various components of a variety of other optional buffers, bactericides, enzymes, hydrotropes, dyes, stabilizers, bleach activators, soil suspensions, colorants, brighteners, perfumes, anti-dusting agents, dispersants, dye transfer inhibitors, pigments and dyes, or mixtures thereof.

Formation of mixtures If they are prepared either as solid larvae or liquids, in the case where they are substances, these mixtures will be mixed with water for 11m. In a liquid thorn, the present invention may be washed

The compositions are formulated with an appropriate solvent, typically water. In liquid form, the compositions are preferably prepared, but are not prepared. j and κ o v o u not mixtures. The compositions and compositions are a rip aqe u r r o s r o n y s a n y o r s o n e o n o n s of use.

• I • I •

If desired, they can be spray dosed, which organic polymer invention also includes a spray dispenser. Definitely the son of this one

The compositions and compositions herein may be packaged in a variety of suitable detergent packaging known to those skilled in the art. Liquid mixtures packaged in manually operated containers are usually made of plastic materials. According to the liquid cleaning composition of the invention packaged in a preferably sprayable spray or spray type dispenser, the liquid cleaning compositions suitable for use in the present invention are uniformly applied to a relatively large area of the surface to be cleaned; this contributes to the cleaning properties of said compositions. These spray type dispensers are particularly suitable for cleaning vertical surfaces.

Suitable spray type dispensers. which are used according to the present invention include manually operated trigger type foam dispensers sold by, e.g., Specialty Packaging Products, Inc. or Continental Sprayers, Inc. These types of dispensers are disclosed, for example, in US-4,701,311 (Dunnining et al.) And US-4,646,973 and US-4,538,745 (both Focaracci). Particularly preferred for use herein are spray type dispensers, such as the T 8500, commercially available from Continental Spray International, or the T 8100, commercially available from Canyon, Northern Ireland. In such a dispenser, the liquid mixture is divided into fine liquid droplets resulting in a spray directed to the surface to be treated. Indeed, in the spray-type dispenser, the mixture contained in the body of said dispenser is directed by the spray-type dispenser head by the energy transmitted to the mechanism by the user that activates said pumping dispenser. tu) similar, eg craz ί κ at the same time or spraying (spraying) a liquid mixture, ie droplets.

The compositions of the present invention may also be wipes. Wipes herein are disposable paper towels containing the liquid composition of the present invention. Accordingly, the invention also encompasses wipes, e.g., disposable paper towels comprising, in a preferred embodiment, wetted with said liquid compositions, such as a wardrobe in a part cabinet. Win <3 o

or cone or something shaking, is: assisting the formation of liquid helps to form it in the form of a cured mixture according to the invention of wipes impregnated, preferring preferably balem • · · · η Γ, ········ · · I U

It is even more convenient to use the cleaners with the user even outside the house, i.e. it is not necessary to pour the liquid compositions of the present invention onto the surfaces to be treated and dry them with the appropriate fabric. In other words, the wipes allow surface cleaning in one step.

The present invention encompasses a surface cleaning process wherein the respective composition of the invention is applied to said surfaces.

The surface of the bathroom is meant here any surface including hard surfaces such as boards, walls, walls, kitchens, floors, table or tile, wash surfaces and the like.

In the surface cleaning process of the present invention, said compositions may be applied disinfected, in their clean or clean form; By &quot; dilute form &quot; is meant here, the purification process, whether in a liquid user, typically on a given surface to be in a &quot; diluted form &quot;.

The compositions to be used herein in solid form may be diluted up to 1000 times their weight by water, preferably 300 times, preferably 80-30 times their weight by water, and most preferably 60-40%. multiple.

In a preferred embodiment, the compositions of the invention are aqueous cleaning compositions. Said aqueous compositions preferably have a pH of not more than 12.0, more preferably from 4 to 12, and most preferably from 4 to 10. The pH of the compositions may be controlled by the use of organic or inorganic acids or alkalizing agents.

In a preferred embodiment of the process of the invention, when applied to a surface to be cleaned, such as a hard surface, in its diluted form, it is not necessary to rinse the surface after application of the composition; there is actually no visible residue on the surface.

The invention is illustrated by the following non-limiting examples, in which all percentages are by weight unless otherwise indicated.

The following test methods used to measure the cleaning and polishing performance are given below:

Cleaning test procedure

The standard enamel plates were soiled with some particles and then fired with them, applied to a sponge, and then the Garder machine measured the number of strokes or 95-99% of the clean plates. The power was measured as such and diluted to 1.5% aqueous solution.

The non-lubricated c ± test compositions were then placed on a Gardner machine.

necessary to achieve. in the undiluted race 4

Test Method Five millimeters of moistened sponge at the same pressure. The sampled product is deposited on one surface of the sponge and then applied. in one movement the tile (tile), previously cleaned with isopropyl alcohol. The applied product tile is dried for 10 minutes before being classified by qualified experts. The control test is performed by repeating said test with a moistened sponge but without the test product.

Qualified expert services were also used to evaluate the specific area where the product was applied in terms of the amount of film and / or strips applied. Each product is assigned a numerical value describing the amount of film / strips applied. A 0-4 scale is used for the test results.

= there is no difference between the test product and the control experiment, ie poor performance of the test product regarding the amount of film / strips.

= there is a clear difference between the product and the control experiment, ie no film / strips are formed with the product tested.

In the given examples the meanings:

amine oxide:

betaine:

butylcarbitol

ΏΊ 3 i 1) i r i k a c c of component π 3. s 1 e d u i i <

Coconut N-decyldimethylamine oxide available as methylbetaine available Albright & Wilson under the trade name Empigen BB / L

2- (2-butoxyethoxy) ethanol

Example 1

The following composition of the invention was formed by mixing said ingredients in the indicated proportions:

AND IT C D 3, p Ami nox i d 1 1 X / · \ and Betaine 0,0 5 0.05 0.05 0 0 5 0, 0 5 Butylcarbitol - C: 5 - _ή Eugenol - - 0 0 5 0.08 Hydrogen peroxide 1 -, and -F O

H2 S04 up to ρΗ 4

Water 3 3 A d 1 Θ j b .5 1 t o rs 1 0 0 í _ _ i ·· ·· ·· ··

Example 2

The following mixtures are those of which 1 to 3? m:

G H T J TO Am i nox i d and 1 2 8 C at Betaine 0.05 0 0 s 0.1 0., 5 0.2 Butylcarbitol 5 5 - 5 Eugenol 0.05 - - Hydrogen peroxide 1 - ¹ - 1 2 Vods s secondary components ss to i0 0 K2S04 and i do ρ n u

L M N 0 P Q Amine oxide 1 Q 1 0.9 5 O Betaine 0.05 0.1 0.05 0.05 0.2 0.5 Butylkarbi tol - 5 C: at 5 - Eucrenol - 0.05 0,0 8 - Hydrogen peroxide 1

v o d s d e g 1 e Ί s i o z κ y d z d o i 0 0

Hz 304 j to ρΗ

·· ·· • · · · ·

········ · fl 9

PATE N

U V L ·

NAROK Y

Claims (13)

1. A cleaning composition containing Άυvcππ and c11 vn i system which contains an amine-oxide and a betaine or a sulphobetaine-containing substance in a weight ratio of amine-oxide to betaine or sulphobetaine in the range of: 6: 1 to 100: 1. 2. A cleaning composition according to claim 1 wherein said amineuxide to betaine or sulfobetaine buffer is 10: 1 to 50: 1, preferably 15: 1 to 30: 1. A cleaning composition according to either of claims 1 or 2, wherein the amine oxide is of the formula R R 'R' 'N-> 0, wherein R is a primary alkyl group wherein said said 10-13 carbons, and z wherein R and R are ethyl- or containing from 6 to 24 carbons, preferably each, is independently an 2-h y drony x y y sine. The cleaning composition of any one of claims 1-3, wherein said betaine or sulfobeta surfactant is of the formula R2 AND R1-N ⁺ --- (CH2) n-Y-1 R3 wherein R1 is an alkyl radical containing from about atoms, preferably from 8 to 13, and most preferably from 12 to 14, 1 to 24 carbon where R 2 and R 3 contain from 1 to 3 uhl í k- number from 1 to 10 composed .mu.Ci se of like káá lů Rl R2 their s m e 3 i. c Η ί o u. 0 13 , £ smě with X is no more than R 3 is roughly and preferably 1 carbon atom, where n is all 6 and more preferably 1, Y is selected from the group of sulfonyl radicals and wherein the sum of from 14 to 24 carbon atoms, or narcosis: The handle is selected jd K t ΓΙΟ KO i IV contains some solvent. 6. O 1 31 i C 1 S ΓΩ e S p OQ i 6 Π and LOXU derivative. propyli ng 1 yko i ii, trid 2 í 2 s ± ko xyeho xy) els o o “2 'di Coxy 61 oxy θ i bottom 1 u. denzyiaizo io u 1, std 1 o 1 io and other mixtures, more than 3 in ^- i ρ en 1 en en 1 1 a a a 2- třídy třídy 2- 2- 2- 2- 2- 2- 2- třídy třídy třídy třídy 2- 2- třídy. 7. A cleaning kit according to any of the preceding claims, wherein the cooked mixture is dried or dried, or mixtures thereof. ρ o z k k k k k,,,,,,,, 13 13 13 ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± The groups consisting of lime oil, leniongrass oil, 4 · 99 · 4 · 4 · 9 · 1 · 4 9 9 9 9 sovehoox β, c 11 rorium vehicle 1, orange oil, anise oil, clove oil, cinnamon oil, geranium oil, rose oil, lavender oil, citronell oil, euKsiypt oils, matt essential oil, matt oil, caramel oil, sandalwood oil, cedar oil, rosemary oil, pine oil, verbene oil, fleagrass oil, rattan oil and mixtures thereof, and / or essential oil assets of the preferred choice from the group consisting of thymol, eugenol, menthol, verbenone, eucalyptol, cedrole, anethole, pinocarvone, hin okitol, berbirin, ferulic acid, methylsalicylic acid, methylsalicylate, terpineol and carvacroi, cinnamon, cinnamon , mixtures thereof. The cleaning composition of claim 8, wherein said antimicrobial essential oil, or an active agent or mixture thereof, is present at a level of at least 0.003 wt. % based on the total composition, preferably from. 0.006 to 10%, more preferably from 0.01 to 4% and most preferably from 0.02 to 2%. The cleaning composition according to any one of the preceding claims, wherein said composition further comprises a peroxygen bleach, preferably hydrogen peroxide. A wipe comprising a cleaning composition according to any one of claims 1-10, The cleaning composition of any one of claims 1-10, wherein said composition is a liquid and is preferably packaged in a spray dispenser, preferably a spray dispenser. 13. r o s t s e s e s e ni - povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch povrch z 14. A method for cleaning the surface of a poodle 13, wherein U Vedi n S í ěna ct ct ct ct ι ct ct ct ct ct ct ct ct ct ct ct Ved Ved Ved Ved E n i n e n e n e n e n e n e n e n e n e n e n e n e n e n e n e n e n e n e 15. Process of the poodle of said opiate mixture.