JP2617558B2 - Liquid wash bleach composition - Google Patents
Liquid wash bleach compositionInfo
- Publication number
- JP2617558B2 JP2617558B2 JP1032080A JP3208089A JP2617558B2 JP 2617558 B2 JP2617558 B2 JP 2617558B2 JP 1032080 A JP1032080 A JP 1032080A JP 3208089 A JP3208089 A JP 3208089A JP 2617558 B2 JP2617558 B2 JP 2617558B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- carbon atoms
- liquid
- alkali metal
- bleach composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は洗浄漂白力及び貯蔵安定性に優れた液体洗浄
漂白剤組成物に関するものである。Description: FIELD OF THE INVENTION The present invention relates to a liquid cleaning bleach composition having excellent cleaning bleaching power and storage stability.
従来より、次亜塩素酸アルカリ金属塩を主基剤とする
洗浄漂白剤組成物は多く知られている。それらの組成物
には、洗浄助剤となる界面活性剤として、次亜塩素酸ア
ルカリ金属塩水溶液に対する溶解性や、次亜塩素酸アル
カリ金属塩水溶液中での有効塩素の安定性等からポリオ
キシエチレンアルキルフェニルエーテル又はアルキルジ
フェニルエーテルの硫酸化物のアルカリ金属塩（例えば
特開昭52−69415）、パラフィンスルホネート（例えば
特開昭54−148006）等のアニオン性界面活性剤が使用さ
れてきた。2. Description of the Related Art Conventionally, many washing and bleaching compositions containing an alkali metal hypochlorite as a main base have been known. In these compositions, as a surfactant as a cleaning aid, polyoxychloride is considered to be soluble in an aqueous solution of an alkali metal hypochlorite and the stability of available chlorine in an aqueous solution of an alkali metal hypochlorite is used. Anionic surfactants such as alkali metal salts of sulfates of ethylene alkylphenyl ether or alkyldiphenyl ether (for example, JP-A-52-69415) and paraffin sulfonates (for example, JP-A-54-148006) have been used.
又、アニオン性界面活性剤以外のものでもカルボベタ
イン系の両性界面活性剤（例えば英国特許第1329086
号、オランダ国特許第148103号、特開昭60−33300）な
どが選択されてきた。これらの界面活性剤の添加により
洗浄液の表面活性化能が改善され、洗浄力は向上する
が、未だに充分とは言い難い。Carbobetaine-based amphoteric surfactants other than anionic surfactants (for example, British Patent No. 1329086)
No. 148103, JP-A-60-33300) and the like. The addition of these surfactants improves the surface activating ability of the cleaning liquid and improves the detergency, but is still insufficient.
また、従来の液体洗浄漂白剤組成物は粘度が低く、斜
面、垂直面での滞留性が劣るため洗浄剤の洗浄力を十分
に発揮するまでには至っていない。In addition, the conventional liquid cleaning bleach composition has a low viscosity and is inferior in retention on slopes and vertical surfaces, so that the cleaning power of the cleaning agent has not been sufficiently exerted.
斜面、垂直面での滞留性を向上させるため、次亜塩素
酸アルカリ金属塩を増粘させる種々の手段が講じられて
きた。例えば、アタパルジャイト、モンモリロナイトな
どの水和性アルミニウム、マグネシウムのシリケートを
使用する方法（例えば特開昭57−168999）、セピオライ
ト系粘土鉱物を使用する方法（例えば特公昭61−2196
9）などの無機系の増粘剤を使用する方法が挙げられる
が、前者は、有効塩素の保持及び強アルカリ下での長期
保存安定性が良くなく、後者においてはセピオライト自
体が粘土色（黄土色）を呈しており、外観の上で好まし
くなく、また、長期保存安定性も優れたものとはいえな
い。Various means have been taken to increase the viscosity of the alkali metal hypochlorite in order to improve the retention on inclined and vertical surfaces. For example, a method using a hydrated aluminum or magnesium silicate such as attapulgite or montmorillonite (for example, JP-A-57-168999), a method using a sepiolite-based clay mineral (for example, JP-B-61-2196)
9) and other methods using inorganic thickeners. The former, however, has poor retention of available chlorine and long-term storage stability under strong alkali. In the latter, sepiolite itself has a clay color (ocher). Color), which is not desirable in terms of appearance, and is not excellent in long-term storage stability.
有機系増粘剤としては、ポリビニルアルコール、メチ
ルセルロース、ポリアクリル酸塩、キサンタンガムなど
の水溶性高分子化合物が一般的に用いられるが、有効塩
素の保持及び長期保存安定性において優れたものとはい
えないのが実状である。As the organic thickener, water-soluble polymer compounds such as polyvinyl alcohol, methylcellulose, polyacrylate, and xanthan gum are generally used, although they are excellent in retention of effective chlorine and long-term storage stability. There is no actual situation.
本発明者らは、適度な粘性を有し、次亜塩素酸アルカ
リ金属塩の安定性を損なわず、しかも長期間保存におい
ても外観の安定性に優れた液体洗浄剤を見出すべく鋭意
検討を行った結果、下記の特定成分の組合せによりその
目的を達成できることを見出し、本発明を完成するに至
った。The present inventors have conducted intensive studies to find a liquid detergent having a suitable viscosity, which does not impair the stability of the alkali metal hypochlorite, and which has excellent appearance stability even during long-term storage. As a result, it has been found that the object can be achieved by a combination of the following specific components, and the present invention has been completed.
即ち本発明は、 （ａ）一般式 （式中、R1は炭素数８〜22のアルキル基、R2,R3は炭素
数１〜２のアルキル基、ｎは２〜３の整数を示す。）で
表されるスルホベタイン型両性界面活性剤を0.01〜10重
量％ （ｂ）一般式 R4R5R6N→０ （II） （式中、R4は炭素数８〜20のアルキル基、R5,R6は炭素
数１〜３のアルキル基を示す。）で表されるアミンオキ
サイド化合物を0.1〜５重量％ （ｃ）炭素数８〜18の飽和脂肪酸または炭素数10〜18の
アルキルサルコシンのアルカリ金属塩を0.1〜６重量％ （ｄ）次亜塩素酸アルカリ金属塩を0.5〜10重量％ （ｅ）アルカリ性を呈する物質を0.1〜10重量％ 含有することを特徴とする液体洗浄漂白剤組成物を提供
するものである。That is, the present invention provides: (Wherein, R 1 is an alkyl group having 8 to 22 carbon atoms, R 2 and R 3 are alkyl groups having 1 to 2 carbon atoms, and n is an integer of 2 to 3). 0.01 to 10% by weight of a surfactant (b) General formula R 4 R 5 R 6 N → 0 (II) (wherein R 4 is an alkyl group having 8 to 20 carbon atoms, and R 5 and R 6 are carbon atoms. 0.1 to 5% by weight of an amine oxide compound represented by the following formula: (c) 0.1 to 5% by weight of an alkali metal salt of a saturated fatty acid having 8 to 18 carbon atoms or an alkyl sarcosine having 10 to 18 carbon atoms. 6% by weight (d) 0.5 to 10% by weight of an alkali metal hypochlorite (e) 0.1 to 10% by weight of a substance exhibiting alkalinity is provided. is there.
上記一般式（Ｉ）において、R1は炭素数８〜22のアル
キル基であり、炭素数12〜18のアルキル基が好ましい。
R2,R3は炭素数１〜２のアルキル基であり、このうち炭
素数１のメチル基が好ましい。ｎは２〜３の整数である
が、このうち３のものが好ましい。In the above general formula (I), R 1 is an alkyl group having 8 to 22 carbon atoms, preferably an alkyl group having 12 to 18 carbon atoms.
R 2 and R 3 are an alkyl group having 1 to 2 carbon atoms, and among them, a methyl group having 1 carbon atom is preferable. n is an integer of 2 to 3, and among them, 3 is preferable.
一般式（II）において、R4の炭素数８〜20のアルキル
基としては、オクチル基、デシル基、ドデシル基、テト
ラデシル基、ヘキサデシル基、オクタデシル基などが挙
げられる。これらのうち、好ましくはドデシル基及びテ
トラデシル基であるが、天然物から誘導された炭素数の
異なるアルキル基の混合物でもかまわない。R5,R6は炭
素数１〜３のアルキル基であり、メチル基、エチル基、
プロピル基などが挙げられるが、これらのうち、好まし
くはメチル基である。In the general formula (II), examples of the alkyl group having 8 to 20 carbon atoms for R 4 include an octyl group, a decyl group, a dodecyl group, a tetradecyl group, a hexadecyl group, and an octadecyl group. Of these, a dodecyl group and a tetradecyl group are preferred, but a mixture of alkyl groups having different carbon numbers derived from natural products may be used. R 5 and R 6 are an alkyl group having 1 to 3 carbon atoms, a methyl group, an ethyl group,
Examples thereof include a propyl group, and among them, a methyl group is preferable.
一般式（II）で示されるアミンオキサイド化合物
（ｂ）の具体的な例としては、ラウリルジメチルアミン
オキサイド、ミリスチルジメチルアミンオキサイド、ヤ
シジメチルアミンオキサイドなどが挙げられる。Specific examples of the amine oxide compound (b) represented by the general formula (II) include lauryl dimethyl amine oxide, myristyl dimethyl amine oxide, and coconut dimethyl amine oxide.
炭素数８〜18の飽和脂肪酸または炭素数10〜18のアル
キルサルコシンのアルカリ金属塩（ｃ）としては、通常
ラウリン酸ナトリウム、ラウリルサルコシン酸ナトリウ
ムなど、及びそれら２種以上の混合物が用いられる。As the alkali metal salt (c) of the saturated fatty acid having 8 to 18 carbon atoms or the alkyl sarcosine having 10 to 18 carbon atoms, sodium laurate, sodium lauryl sarcosine and the like, and a mixture of two or more thereof are usually used.
次亜塩素酸アルカリ金属塩（ｄ）としては、通常次亜
塩素酸ナトリウムが用いられる。Sodium hypochlorite is usually used as the alkali metal hypochlorite (d).
アルカリ性を呈する物質（ｅ）としては、水酸化ナト
リウム、炭酸ナトリウム、メタ珪酸ナトリウム、三燐酸
ナトリウムなどが挙げられ、これらのうち、水酸化ナト
リウムが好ましい。Examples of the substance (e) exhibiting alkalinity include sodium hydroxide, sodium carbonate, sodium metasilicate, sodium triphosphate, and the like. Of these, sodium hydroxide is preferable.
本発明の液体洗浄漂白剤組成物におけるスルホベタイ
ン型両性界面活性剤（ａ）の含有量は0.01〜10重量％、
好ましくは0.03〜５重量％の範囲である。スルホベタイ
ン型両性界面活性剤の含有量が0.01重量％未満になると
組成物の保存安定性が悪くなる。また10重量％を越える
含有量は実際上必要としない。The content of the sulfobetaine type amphoteric surfactant (a) in the liquid washing bleach composition of the present invention is 0.01 to 10% by weight,
Preferably it is in the range of 0.03 to 5% by weight. When the content of the sulfobetaine-type amphoteric surfactant is less than 0.01% by weight, the storage stability of the composition becomes poor. Also, a content of more than 10% by weight is practically unnecessary.
アミンオキサイド化合物（ｂ）の含有量は0.1〜５重
量％、好ましくは0.1〜３重量％の範囲である。アミン
オキサイド化合物の含有量が0.1重量％未満になると組
成物の保存安定性が悪くなり、また５重量％を越えると
次亜塩素酸アルカリ金属塩の安定性が損なわれる。The content of the amine oxide compound (b) is in the range of 0.1 to 5% by weight, preferably 0.1 to 3% by weight. If the content of the amine oxide compound is less than 0.1% by weight, the storage stability of the composition will be poor, and if it exceeds 5% by weight, the stability of the alkali metal hypochlorite will be impaired.
炭素数８〜18の飽和脂肪酸または炭素数10〜18のアル
キルサルコシンのアルカリ金属塩（ｃ）の含有量は0.1
〜６重量％、好ましくは0.1〜４重量％の範囲である。
炭素数８〜18の飽和脂肪酸または炭素数10〜18のアルキ
ルサルコシンのアルカリ金属塩の含有量が0.1重量％未
満になると粘度が増大せず、６重量％を越えると粘度が
増大しすぎて使用感が損なわれる。The content of the saturated fatty acid having 8 to 18 carbon atoms or the alkali metal salt (c) of alkyl sarcosine having 10 to 18 carbon atoms is 0.1%.
-6% by weight, preferably 0.1-4% by weight.
When the content of the saturated fatty acid having 8 to 18 carbon atoms or the alkali metal salt of the alkyl sarcosine having 10 to 18 carbon atoms is less than 0.1% by weight, the viscosity does not increase, and when it exceeds 6% by weight, the viscosity increases too much. Feeling is impaired.
次亜塩素酸アルカリ金属塩（ｄ）の含有量は0.5〜10
重量％、好ましくは２〜７重量％の範囲である。次亜塩
素酸アルカリ金属塩の含有量が0.5重量％未満になると
漂白力が不足し、10重量％を越える含有量は実際上必要
としない。The content of the alkali metal hypochlorite (d) is 0.5 to 10
%, Preferably in the range of 2 to 7% by weight. When the content of the alkali metal hypochlorite is less than 0.5% by weight, the bleaching power is insufficient, and the content exceeding 10% by weight is practically unnecessary.
アルカリ性を呈する物質（ｅ）の含有量は0.1〜10重
量％、好ましくは0.5〜５重量％の範囲である。The content of the substance (e) exhibiting alkalinity is in the range of 0.1 to 10% by weight, preferably 0.5 to 5% by weight.
本発明の液体洗浄漂白剤組成物には、更に通常用いら
れるような添加剤、例えば他の界面活性剤、キレート
剤、香料、着色剤などの成分を配合することができる。The liquid washing / bleaching composition of the present invention may further contain additives such as commonly used additives such as surfactants, chelating agents, fragrances and coloring agents.
なお、本発明による液体洗浄漂白剤組成物の粘度は通
常５〜2000cp（Ｂ型粘度計、20℃）であり、使用目的に
応じて使い分けが可能である。The viscosity of the liquid cleaning bleach composition according to the present invention is usually 5 to 2000 cp (B-type viscometer, 20 ° C.), and can be used properly according to the purpose of use.
次に実施例を挙げて本発明を説明するが、本発明はこ
れらの実施例に限定されるものではない。Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples.
実施例１〜２及び比較例１〜７ 表−１に示す組成の各液体洗浄漂白剤組成物を調製
し、それぞれの洗浄力、仕上がり感及び低温安定性を下
記の基準に基づいて評価した。Examples 1 and 2 and Comparative Examples 1 to 7 Liquid cleaning bleach compositions having the compositions shown in Table 1 were prepared, and the detergency, finished feeling, and low-temperature stability of each composition were evaluated based on the following criteria.
洗浄力、仕上がり感の評価は、被洗浄面として、水を
流しただけでは落ちない汚れが付着している一般家庭の
水洗トイレを選定し、その水洗便器に評価用液体洗浄漂
白剤30gを塗布し、フラッシュによりすすいだ後の便器
表面の状態をみて行った。To evaluate the detergency and finished feeling, select a household flush toilet that has dirt that cannot be removed by just flushing water as the surface to be cleaned, and apply 30 g of the evaluation liquid cleaning bleach to the flush toilet. Then, the condition of the toilet bowl surface after rinsing with a flush was checked.
＜洗浄力＞ ○：汚れが８割以上落ちる △：汚れが２〜５割落ちる ×：汚れがほとんど落ちない ＜仕上がり感＞ ○：すすいだ後、水をはじく部分が２割以下 △：すすいだ後、水をはじく部分が２〜５割 ×：すすいだ後、水をはじく部分が５割以上 ＜低温安定性＞ 評価用液体洗浄漂白剤組成物を−20℃〜＋20℃（１サ
イクル／日）で30日保存した時の組成物の外観を観察し
た。<Detergency> ：: 80% or more of dirt is removed △: 20 to 50% of dirt is removed ×: Dirt is hardly removed <finish feeling> ○: After rinsing, the part that repels water is 20% or less △: Rinse After that, the part that repels water is 20 to 50%. ×: The part that repels water is 50% or more after rinsing. <Low-temperature stability> The liquid washing bleach composition for evaluation is used at -20 ° C to + 20 ° C (1 cycle / day). ) Was observed for 30 days.
○：保存前と変化がない。：: No change from before storage.
△：若干分離・沈澱がみられる。Δ: Some separation and precipitation were observed.
×：分離・沈澱がみられる。X: Separation / precipitation is observed.
これらの評価結果を表−１に示す。 Table 1 shows the evaluation results.
実施例３〜４及び比較例８〜11 表−２に示す各液体洗浄漂白剤組成物を調製し、それ
ぞれの液の粘性（液のたれにくさ）及び仕上がり感につ
いて下記の基準に基づいて評価した。 Examples 3 to 4 and Comparative Examples 8 to 11 Each liquid washing and bleaching composition shown in Table 2 was prepared, and the viscosity of each liquid (the difficulty of dripping of the liquid) and the finished feeling were evaluated based on the following criteria. did.
この時の被洗浄面としては、実施例１〜２及び比較例
１〜７と同様にして選定した水洗トイレの便器を用い
た。As the surface to be cleaned at this time, a flush toilet was selected in the same manner as in Examples 1 and 2 and Comparative Examples 1 to 7.
＜液の粘性（液のたれにくさ）＞ 評価用液体洗浄漂白剤組成物を主婦30人に使ってもら
い、垂直面での液のたれにくさについて、５段階評価を
行い、その平均値を求めた。<Viscosity of liquid (Liquid dripping)> 30 housewives used the liquid cleaning bleach composition for evaluation, and evaluated the liquid dripping resistance on a vertical surface on a five-point scale. I asked.
5:液がたれにくい 4:液がややたれにくい 3:どちらともいえない 2:液がややたれやすい 1:液がたれやすい ＜仕上がり感＞ 評価用液体洗浄漂白剤を用いて、主婦30人に便器を洗
ってもらい、すすいだ後の仕上がり感、艶について５段
階評価を行い、その平均値を求めた。5: Liquid hardly drip 4: Liquid hardly drip 3: Neither can be said 2: Liquid slightly drip 1: Liquid drip easily <Finishing feeling> Using a cleaning liquid bleach for evaluation, 30 housewives The toilet was washed, the finished feeling and the gloss after rinsing were evaluated on a 5-point scale, and the average value was determined.
5:仕上がり感が良い（艶が出る） 4:やや仕上がり感が良い（やや艶が出る） 3:どちらともいえない 2:あまり仕上がり感が良くない（あまり艶が出ない） 1:仕上がり感が良くない（艶がでない） これらの評価結果を表−２に示す。5: Good finish (glossy) 4: Good finish (slightly glossy) 3: Neither of them 2: Not very good finish (less glossy) 1: Good finish Unsatisfactory (not glossy) These evaluation results are shown in Table-2.
〔発明の効果〕 本発明によれば、汚れの除去効果はもちろん、洗浄後
の仕上がり効果に優れ、更に使用に際して適度な粘性を
有する液体洗浄漂白剤組成物が得られる。 [Effects of the Invention] According to the present invention, it is possible to obtain a liquid cleaning bleach composition which is excellent not only in the effect of removing dirt but also in the finish after cleaning, and which has an appropriate viscosity when used.
又、本発明によって得られた液体洗浄漂白剤組成物
は、貯蔵安定性にも優れている。Further, the liquid washing bleach composition obtained by the present invention has excellent storage stability.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１１Ｄ 3:04 3:20） (72)発明者 牧野 康彦 栃木県芳賀郡市貝町大字赤羽2606―６ 花王赤羽寮１―401 (56)参考文献 特開 昭61−123700（ＪＰ，Ａ) 特開 昭63−108100（ＪＰ，Ａ)──────────────────────────────────────────────────続 き Continuation of the front page (51) Int.Cl. 6 Identification number Agency reference number FI Technical display location C11D 3:04 3:20) (72) Inventor Yasuhiko Makino 2606 Akabane, Kaigamachi, Haga-gun, Tochigi Prefecture 6. Kao Akabane Ryo 1-401 (56) References JP-A-61-123700 (JP, A) JP-A-63-108100 (JP, A)
Claims (1)
数１〜２のアルキル基、ｎは２〜３の整数を示す。）で
表されるスルホベタイン型両性界面活性剤を0.01〜10重
量％ （ｂ）一般式 R4R5R6N→０ （II） （式中、R4は炭素数８〜20のアルキル基、R5,R6は炭素
数１〜３のアルキル基を示す。）で表されるアミンオキ
サイド化合物を0.1〜５重量％ （ｃ）炭素数８〜18の飽和脂肪酸または炭素数10〜18の
アルキルサルコシンのアルカリ金属塩を0.1〜６重量％ （ｄ）次亜塩素酸アルカリ金属塩を0.5〜10重量％ （ｅ）アルカリ性を呈する物質を0.1〜10重量％ 含有することを特徴とする液体洗浄漂白剤組成物。(1) General formula (Wherein, R 1 is an alkyl group having 8 to 22 carbon atoms, R 2 and R 3 are alkyl groups having 1 to 2 carbon atoms, and n is an integer of 2 to 3). 0.01 to 10% by weight of a surfactant (b) General formula R 4 R 5 R 6 N → 0 (II) (wherein R 4 is an alkyl group having 8 to 20 carbon atoms, and R 5 and R 6 are carbon atoms. 0.1 to 5% by weight of an amine oxide compound represented by the following formula: (c) 0.1 to 5% by weight of an alkali metal salt of a saturated fatty acid having 8 to 18 carbon atoms or an alkyl sarcosine having 10 to 18 carbon atoms. 6% by weight (d) 0.5 to 10% by weight of an alkali metal hypochlorite (e) 0.1 to 10% by weight of a substance exhibiting alkalinity is provided.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1032080A JP2617558B2 (en) | 1989-02-10 | 1989-02-10 | Liquid wash bleach composition |
| MYPI90000151A MY105542A (en) | 1989-02-10 | 1990-01-31 | Liquid detergent bleaching composition. |
| PH39986A PH26743A (en) | 1989-02-10 | 1990-02-02 | Liquid detergent bleaching composition |
| GB9002531A GB2229460B (en) | 1989-02-10 | 1990-02-05 | Liquid detergent bleaching composition |
| HK57394A HK57394A (en) | 1989-02-10 | 1994-06-04 | Liquid detergent bleaching composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1032080A JP2617558B2 (en) | 1989-02-10 | 1989-02-10 | Liquid wash bleach composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02212599A JPH02212599A (en) | 1990-08-23 |
| JP2617558B2 true JP2617558B2 (en) | 1997-06-04 |
Family
ID=12348902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1032080A Expired - Fee Related JP2617558B2 (en) | 1989-02-10 | 1989-02-10 | Liquid wash bleach composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2617558B2 (en) |
| GB (1) | GB2229460B (en) |
| HK (1) | HK57394A (en) |
| MY (1) | MY105542A (en) |
| PH (1) | PH26743A (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69201572T2 (en) * | 1991-01-11 | 1995-12-21 | Millipore Corp | Process for performing highly effective depositions by capillary electrophoresis. |
| US5827447A (en) * | 1991-05-15 | 1998-10-27 | Kao Corporation | Liquid bleaching agent composition |
| WO1994011484A1 (en) * | 1992-11-18 | 1994-05-26 | Kao Corporation | Liquid bleach composition |
| EP0651051A3 (en) * | 1993-10-29 | 1996-02-28 | Clorox Co | Gelled hypochlorite-based cleaner. |
| DE69534500T2 (en) * | 1994-06-07 | 2006-07-06 | Reckitt Benckiser Inc. | NICKEL CLEANING COMPOSITIONS COMPARED WITH N-ALKYL-N-ACYLAMINO ACIDS AND MYRISTYL / CETYL-DIMETHYLAMINE OXIDE |
| EP0805198A1 (en) * | 1996-05-03 | 1997-11-05 | The Procter & Gamble Company | Cleaning compositions |
| EP0842606B1 (en) * | 1996-11-13 | 2000-03-15 | The Procter & Gamble Company | Disinfecting microemulsions |
| JP2003055698A (en) * | 2001-08-10 | 2003-02-26 | Kobayashi Pharmaceut Co Ltd | Slime remover |
| EP1945850B1 (en) | 2005-09-23 | 2013-11-20 | DC Chemical Co., Ltd. | Non-aqueous liquid oxygen bleach composition |
| JP5757500B2 (en) * | 2011-04-07 | 2015-07-29 | 株式会社東企 | Hypochlorite paste composition |
| CN108467804B (en) * | 2018-03-27 | 2020-05-08 | 珠海市洁丽雅生物科技有限公司 | Medical sterilizing detergent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU519631B2 (en) * | 1977-11-18 | 1981-12-17 | Unilever Ltd. | Liquid bleach compositions |
| JPS56111300A (en) * | 1980-02-08 | 1981-09-02 | Hitachi Ltd | Jig for inncircuit tester |
| JPS61123700A (en) * | 1984-11-19 | 1986-06-11 | 株式会社 大阪製薬 | Sterilizing viscous detergent |
| DE3767603D1 (en) * | 1986-08-07 | 1991-02-28 | Clorox Co | THICKENED HYPOCHLORITE COMPOSITION AND THEIR USE. |
-
1989
- 1989-02-10 JP JP1032080A patent/JP2617558B2/en not_active Expired - Fee Related
-
1990
- 1990-01-31 MY MYPI90000151A patent/MY105542A/en unknown
- 1990-02-02 PH PH39986A patent/PH26743A/en unknown
- 1990-02-05 GB GB9002531A patent/GB2229460B/en not_active Expired - Fee Related
-
1994
- 1994-06-04 HK HK57394A patent/HK57394A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB2229460A (en) | 1990-09-26 |
| HK57394A (en) | 1994-06-17 |
| PH26743A (en) | 1992-09-28 |
| GB9002531D0 (en) | 1990-04-04 |
| GB2229460B (en) | 1992-07-15 |
| JPH02212599A (en) | 1990-08-23 |
| MY105542A (en) | 1994-10-31 |
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