JP2608338B2 - Liquid cleaning composition for floors - Google Patents
Liquid cleaning composition for floorsInfo
- Publication number
- JP2608338B2 JP2608338B2 JP1322877A JP32287789A JP2608338B2 JP 2608338 B2 JP2608338 B2 JP 2608338B2 JP 1322877 A JP1322877 A JP 1322877A JP 32287789 A JP32287789 A JP 32287789A JP 2608338 B2 JP2608338 B2 JP 2608338B2
- Authority
- JP
- Japan
- Prior art keywords
- floors
- weight
- quaternary ammonium
- ammonium salt
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明はフロアー用液体洗浄剤組成物、更に詳しくは
特にテラゾー、大理石等の石製の床表面の汚れを洗浄す
るのに適した液体洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention relates to a liquid cleaning composition for floors, and more particularly to a liquid cleaning composition suitable for cleaning dirt on a stone floor surface such as terrazzo or marble. Agent composition.
〔従来の技術及びその課題〕 床表面の洗浄にはアニオン、ノニオン等の界面活性剤
を配合した中性液体洗浄剤或いはこれに溶剤類を配合し
た洗浄剤が広く使われている。[Prior Art and Its Problems] For cleaning the floor surface, a neutral liquid detergent containing a surfactant such as anion or nonion or a detergent containing a solvent is widely used.
これらの洗浄剤は木、ビニールタイル等の床の汚れの
除去に適している。しかし、近年普及しつつあるテラゾ
ー、大理石等の石製の床表面の汚れに対する洗浄性能は
未だ十分でない。These cleaning agents are suitable for removing floor dirt such as wood and vinyl tiles. However, the cleaning performance against the stain on the floor surface made of stone, such as terrazzo and marble, which has been spreading in recent years, is not yet sufficient.
本発明者らは前記課題を解決すべく鋭意研究した結
果、ノニオン、カチオン界面活性剤系にヒドロキシアル
キルセルロースを配合した洗剤が石製表面の汚れの除去
効果に優れており、しかも洗浄後の表面に好ましい仕上
がり感（艶）を与え、べたつきも少ないことを見出し本
発明を完成するに至った。As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that a detergent containing hydroxyalkyl cellulose in a nonionic or cationic surfactant system has an excellent effect of removing stains on a stone surface, and the surface after washing is also excellent. The present invention has been completed by finding that a favorable finish feeling (gloss) is provided and that the stickiness is small.
すなわち本発明は、 （ａ） ノニオン界面活性剤 ２〜10重量％ （ｂ） モノ長鎖アルキル型第４級アンモニウム塩カチ
オン界面活性剤 0.1〜５重量％ （ｃ） ヒドロキシアルキルセルロース 0.1〜２重量％ を含有してなることを特徴とするフロアー用液体洗浄剤
組成物を提供するものである。That is, the present invention provides: (a) 2 to 10% by weight of a nonionic surfactant; (b) 0.1 to 5% by weight of a mono long chain alkyl type quaternary ammonium salt cationic surfactant; (c) 0.1 to 2% by weight of a hydroxyalkyl cellulose. The present invention provides a liquid detergent composition for floors, which comprises:
本発明に用いられる（ａ）成分のノニオン界面活性剤
としてはポリオキシエチレンアルキルエーテル、ポリオ
キシエチレンアルキルフェニルエーテル等が特に有用で
ある。ノニオン界面活性剤はHLBが９以上、好ましくは1
1〜13の範囲にあるものが洗浄性能の面で望ましい。ノ
ニオン界面活性剤は組成物中に２〜10重量％配合され
る。As the nonionic surfactant as the component (a) used in the present invention, polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether and the like are particularly useful. The nonionic surfactant has an HLB of 9 or more, preferably 1
Those in the range of 1 to 13 are desirable in terms of cleaning performance. The nonionic surfactant is incorporated in the composition in an amount of 2 to 10% by weight.
本発明において（ｂ）成分のモノ長鎖アルキル型第４
級アンモニウム塩としては下記の構造を有するものが好
適に使用される。In the present invention, the mono-long-chain alkyl type fourth component (b) is used.
As the quaternary ammonium salt, those having the following structures are preferably used.
（式中、R1は炭素数８〜14のアルキル基、R2,R3はそれ
ぞれ炭素数１〜３のアルキル基、R4は炭素数１〜３のア
ルキル基又はベンジル基を表し、X-は塩素、臭素等の陰
イオンを表す。） 第４級アンモニウム塩は洗浄効果を向上させ、べたつ
き性を低減させる効果を有する。第４級アンモニウム塩
は組成物中に0.1〜５重量％、好ましくは0.3〜２重量％
配合される。 (In the formula, R 1 represents an alkyl group having 8 to 14 carbon atoms, R 2 and R 3 each represent an alkyl group having 1 to 3 carbon atoms, R 4 represents an alkyl group having 1 to 3 carbon atoms or a benzyl group, X - has chlorine, represents) quaternary ammonium salt anion such as bromine improves the cleaning effect, the effect of reducing the stickiness.. The quaternary ammonium salt is present in the composition in an amount of 0.1 to 5% by weight, preferably 0.3 to 2% by weight.
Be compounded.
本発明に用いられる（ｃ）成分のヒドロキシアルキル
セルロースとしてはヒドロキシメチルセルロース、ヒド
ロキシエチルセルロース等が挙げられる。ヒドロキシア
ルキルセルロースは25℃、１％濃度の水溶液が約100〜5
000センチポイズの粘度を有し、アルキル置換度（DS）
が0.8〜1.5の範囲にあるものが好適に用いられる。これ
らヒドロキシアルキルセルロースは洗浄性能を向上さ
せ、石製の床表面に艶を与える効果を有する。かかるヒ
ドロキシアルキルセルロースは組成物中に0.1〜２重量
％配合される。Examples of the hydroxyalkyl cellulose as the component (c) used in the present invention include hydroxymethyl cellulose and hydroxyethyl cellulose. Hydroxyalkyl cellulose is a 100% solution of 1% aqueous solution at 25 ℃.
With a viscosity of 000 centipoise and a degree of alkyl substitution (DS)
Is preferably used in the range of 0.8 to 1.5. These hydroxyalkyl celluloses have the effects of improving the cleaning performance and imparting luster to the stone floor surface. Such hydroxyalkyl cellulose is incorporated in the composition in an amount of 0.1 to 2% by weight.
本発明のフロアー用液体洗浄剤組成物には必要に応じ
てエチレンジアミン四酢酸塩等のキレート剤、低級アル
コール等のハイドロトロープ、アルカノールアミン等の
アルカリ剤、香料、色素等を配合することができる。If necessary, a chelating agent such as ethylenediaminetetraacetate, a hydrotrope such as a lower alcohol, an alkali agent such as an alkanolamine, a fragrance, a dye, and the like can be added to the floor detergent composition of the present invention.
以下実施例にて本発明を説明するが、本発明はこれら
の実施例に限定されるものではない。Hereinafter, the present invention will be described with reference to examples, but the present invention is not limited to these examples.
表１に示す組成のフロアー用液体洗浄剤組成物（pHは
いずれも7.1）を調製し、以下の方法により洗浄力及び
実用性の評価を行なった。A liquid cleaning composition for floors having a composition shown in Table 1 (pH is 7.1) was prepared and the cleaning power and practicality were evaluated by the following methods.
〈洗浄力評価方法〉 ナタネ油に油溶性色素スダンIIIを微量加えたもの0.5
gを30×30cmのテラゾー片にハケで薄く塗布した。この
テラゾー片に表１に示す組成のフロアー用液体洗浄剤組
成物の0.3％水溶液を10ml滴下し、テラゾー片表面を布
でこすり、洗浄力を肉眼で判定する。<Evaluation method for detergency> A small amount of oil-soluble dye Sudan III added to rapeseed oil 0.5
g was thinly applied to a 30 × 30 cm terrazzo piece with a brush. To this terrazzo piece, 10 ml of a 0.3% aqueous solution of the liquid detergent composition for floors having the composition shown in Table 1 was dropped, and the surface of the terrazzo piece was rubbed with a cloth, and the detergency was visually determined.
この時の判定基準は以下の通りである。 The criteria at this time are as follows.
○：きれいに落ちている △：少しピンク色が残っている ×：ピンク色がまだらに残る 〈実用性評価方法〉 テラゾー製の床のある家庭40軒で表１に示す組成のフ
ロアー用液体洗浄剤組成物を使用してもらい、洗浄時の
汚れの落ちやすさ、洗浄後のテラゾー面の光沢及び洗浄
後のテラゾー面に素足で乗った時のべたつき感を評価し
てもらった。○: Beautifully dropped △: A little pink color remains ×: Pink color remains mottled <Practicality evaluation method> Forty households with terrazzo floors were asked to use the liquid cleaning composition for floors having the composition shown in Table 1 to easily remove stains during washing, and to clean the terrazzo surface after washing. The glossiness and the sticky feeling when the bare thighs were put on the washed terrazzo surface were evaluated.
これらの評価結果を表２に示す。 Table 2 shows the evaluation results.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 牧野 康彦 栃木県芳賀郡市貝町大字赤羽2606―６ 花王赤羽寮 (56)参考文献 特開 昭63−35699（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Yasuhiko Makino 2606-6 Akabane, Kaigai-cho, Haga-gun, Tochigi Prefecture Kao Akabane Ryo (56) References JP-A-63-35699
Claims (2)
％ （ｂ） モノ長鎖アルキル型第４級アンモニウム塩カチ
オン界面活性剤 0.1〜５重量％ （ｃ） ヒドロキシアルキルセルロース 0.1〜２重量
％ を含有してなることを特徴とするフロアー用液体洗浄剤
組成物。1. A nonionic surfactant 2 to 10% by weight (b) Mono long-chain alkyl type quaternary ammonium salt cationic surfactant 0.1 to 5% by weight (c) Hydroxyalkyl cellulose 0.1 to 2% by weight A liquid detergent composition for floors, comprising:
カチオン界面活性剤が下記一般式で表されるモノ長鎖ア
ルキル型第４級アンモニウム塩カチオン界面活性剤であ
る請求項１記載のフロアー用液体洗浄剤組成物。 （式中、R1は炭素数８〜14のアルキル基、R2,R3はそれ
ぞれ炭素数１〜３のアルキル基、R4は炭素数１〜３のア
ルキル基又はベンジル基を表し、X-は陰イオンを表
す。）2. The floor according to claim 1, wherein the mono long-chain alkyl quaternary ammonium salt cationic surfactant is a mono long-chain alkyl quaternary ammonium salt cationic surfactant represented by the following general formula. Liquid detergent composition. (Wherein, R 1 represents an alkyl group having 8 to 14 carbon atoms, R 2 and R 3 each represent an alkyl group having 1 to 3 carbon atoms, R 4 represents an alkyl group having 1 to 3 carbon atoms or a benzyl group; - represents an anion).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1322877A JP2608338B2 (en) | 1989-12-12 | 1989-12-12 | Liquid cleaning composition for floors |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1322877A JP2608338B2 (en) | 1989-12-12 | 1989-12-12 | Liquid cleaning composition for floors |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03182597A JPH03182597A (en) | 1991-08-08 |
| JP2608338B2 true JP2608338B2 (en) | 1997-05-07 |
Family
ID=18148612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1322877A Expired - Fee Related JP2608338B2 (en) | 1989-12-12 | 1989-12-12 | Liquid cleaning composition for floors |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2608338B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5295548B2 (en) * | 2006-12-01 | 2013-09-18 | 花王株式会社 | Floor water wiping aid |
| JP5419799B2 (en) * | 2010-05-21 | 2014-02-19 | 花王株式会社 | Liquid detergent composition for floors |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8519047D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent composition |
-
1989
- 1989-12-12 JP JP1322877A patent/JP2608338B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03182597A (en) | 1991-08-08 |
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