CZ287910B6 - Způsob čištění spalin, obsahujících oxidy dusíku z palivové reakční zóny parního generátoru a parní generátor k provádění tohoto způsobu - Google Patents
Způsob čištění spalin, obsahujících oxidy dusíku z palivové reakční zóny parního generátoru a parní generátor k provádění tohoto způsobu Download PDFInfo
- Publication number
- CZ287910B6 CZ287910B6 CZ19962977A CZ297796A CZ287910B6 CZ 287910 B6 CZ287910 B6 CZ 287910B6 CZ 19962977 A CZ19962977 A CZ 19962977A CZ 297796 A CZ297796 A CZ 297796A CZ 287910 B6 CZ287910 B6 CZ 287910B6
- Authority
- CZ
- Czechia
- Prior art keywords
- reduction
- gases
- catalytic
- nitrogen oxides
- zone
- Prior art date
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 162
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 32
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 28
- 239000000446 fuel Substances 0.000 title claims abstract description 17
- 238000000746 purification Methods 0.000 title abstract 2
- 239000007789 gas Substances 0.000 claims abstract description 81
- 238000006722 reduction reaction Methods 0.000 claims abstract description 74
- 230000003197 catalytic effect Effects 0.000 claims abstract description 38
- 239000003054 catalyst Substances 0.000 claims abstract description 33
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 27
- 238000010531 catalytic reduction reaction Methods 0.000 claims abstract description 20
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 35
- 239000003546 flue gas Substances 0.000 claims description 25
- 229910021529 ammonia Inorganic materials 0.000 claims description 24
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 16
- 230000001603 reducing effect Effects 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 238000007599 discharging Methods 0.000 claims description 7
- 238000011144 upstream manufacturing Methods 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 238000007872 degassing Methods 0.000 claims description 2
- 239000002243 precursor Substances 0.000 claims description 2
- 239000002912 waste gas Substances 0.000 abstract 4
- 230000001276 controlling effect Effects 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000011068 loading method Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002826 coolant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
- F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
- F23C10/08—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases
- F23C10/10—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases the separation apparatus being located outside the combustion chamber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/10—Nitrogen; Compounds thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/10—Catalytic reduction devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/20—Non-catalytic reduction devices
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Treating Waste Gases (AREA)
- Chimneys And Flues (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/226,483 US5465690A (en) | 1994-04-12 | 1994-04-12 | Method of purifying gases containing nitrogen oxides and an apparatus for purifying gases in a steam generation boiler |
Publications (2)
Publication Number | Publication Date |
---|---|
CZ297796A3 CZ297796A3 (en) | 1997-03-12 |
CZ287910B6 true CZ287910B6 (cs) | 2001-03-14 |
Family
ID=22849086
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CZ19962977A CZ287910B6 (cs) | 1994-04-12 | 1995-04-12 | Způsob čištění spalin, obsahujících oxidy dusíku z palivové reakční zóny parního generátoru a parní generátor k provádění tohoto způsobu |
Country Status (13)
Families Citing this family (40)
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DE19533715A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Verfahren zum Entfernen von Stickstoffoxiden aus einem diese enthaltenden Gasstrom |
DE19600869A1 (de) * | 1996-01-12 | 1997-07-17 | Metallgesellschaft Ag | Verfahren zur Entstickung von Rauchgasen |
EP0803278B2 (en) * | 1996-04-22 | 2004-01-02 | Applied Utility Systems, Inc. | Integrated catalytic/non-catalytic process for selective reduction of nitrogen oxides |
US6000935A (en) | 1997-02-21 | 1999-12-14 | Troxler Electronic Laboratories, Inc | Adjustable apparatus for pyrolysis of a composite material and method of calibration therefor |
HUP9801342A2 (hu) * | 1997-06-20 | 1999-06-28 | Von Roll Umwelttechnik Ag | Eljárás füstgázok nitrogénmentesítésére |
FI102409B (fi) | 1997-09-16 | 1998-11-30 | Foster Wheeler Energia Oy | Menetelmä ja laite NOx päästöjen vähentämiseksi sellaisissa kiertoleij upetireaktoreissa, joita käytetään polttamaan polttoaineita, jotka sis ältävät suuren määrän haihtuvia palavia komponentteja |
US6048510A (en) * | 1997-09-30 | 2000-04-11 | Coal Tech Corporation | Method for reducing nitrogen oxides in combustion effluents |
FR2775061B1 (fr) * | 1998-02-16 | 2000-03-10 | Gec Alsthom Stein Ind | Chaudiere a lit fluidise circulant a reduction d'oxydes d'azote amelioree |
AT406126B (de) * | 1998-07-16 | 2000-02-25 | Integral Umwelt Und Anlagentec | Verfahren zum einbringen mindestens eines zweiten reaktionsmediums in mindestens ein in einem kanal strömendes, erstes reaktionsmedium und zur intensiven vermischung der reaktionsmedien miteinander |
FR2802287B1 (fr) * | 1999-12-14 | 2002-01-11 | Abb Alstom Power Comb | Procede pour l'amelioration de la combustion dans un systeme a lit fluidise circulant et systeme correspondant |
US7829033B2 (en) * | 2003-07-03 | 2010-11-09 | Fuel Tech, Inc. | Selective catalytic reduction of NOx enabled by sidestream urea decomposition |
KR20020084659A (ko) * | 2001-05-04 | 2002-11-09 | 윤만중 | 화석연료 연소 전,후 가스류 및 검뎅분해와 환원 화합물과대기 산성화 방지기술 |
FI118132B2 (fi) * | 2001-05-08 | 2015-01-30 | Metso Power Oy | Menetelmä soodakattilassa ja soodakattila |
US6944978B2 (en) * | 2001-06-11 | 2005-09-20 | Douglas Dynamics, Llc | Snowplow and mount assembly |
FI114737B (fi) * | 2002-04-24 | 2004-12-15 | Tom Blomberg | Menetelmä biomassaa polttavien höyrykattiloiden höyrytulistimien asettelemiseksi ja höyrykattila |
US7021248B2 (en) | 2002-09-06 | 2006-04-04 | The Babcock & Wilcox Company | Passive system for optimal NOx reduction via selective catalytic reduction with variable boiler load |
EP1646440A4 (en) * | 2003-05-22 | 2010-04-14 | Doosan Babcock Energy Ltd | METHOD AND DEVICE FOR ZONING INJECTION OF CHEMICALS INTO AN OVEN CONVEYING TRAIN FOR REDUCING CONTAMINATION FROM FLUE GASES |
US20050084434A1 (en) * | 2003-10-20 | 2005-04-21 | Enviroserve Associates, L.L.C. | Scrubbing systems and methods for coal fired combustion units |
DE102004051477B4 (de) * | 2004-10-22 | 2008-10-02 | Alstom Technology Ltd. | Verfahren zur Regulierung der Feststoffumlaufmenge eines zirkulierenden Wirbelschichtreaktorsystems |
DE102005005796A1 (de) * | 2005-02-09 | 2006-08-17 | Applikations- Und Technikzentrum Für Energieverfahrens-, Umwelt- Und Strömungstechnik (Atz-Evus) | Verfahren und Vorrichtung zur thermochemischen Umsetzung eines Brennstoffs |
US7578265B2 (en) * | 2006-05-09 | 2009-08-25 | Babcock & Wilcox Power Generation Group, Inc. | Multiple pass economizer and method for SCR temperature control |
US7637233B2 (en) | 2006-05-09 | 2009-12-29 | Babcock & Wilcox Power Generation Group, Inc. | Multiple pass economizer and method for SCR temperature control |
US7527776B2 (en) * | 2007-01-09 | 2009-05-05 | Catalytic Solutions, Inc. | Ammonia SCR catalyst and method of using the catalyst |
US7943097B2 (en) * | 2007-01-09 | 2011-05-17 | Catalytic Solutions, Inc. | Reactor system for reducing NOx emissions from boilers |
US8802582B2 (en) * | 2007-01-09 | 2014-08-12 | Catalytic Solutions, Inc. | High temperature ammonia SCR catalyst and method of using the catalyst |
US7767175B2 (en) * | 2007-01-09 | 2010-08-03 | Catalytic Solutions, Inc. | Ammonia SCR catalyst and method of using the catalyst |
KR100794389B1 (ko) | 2007-01-24 | 2008-01-15 | 한국에너지기술연구원 | 선택적비촉매환원법에서 질소산화물 저감을 위한 내부관통형 3중관 환원제 분사기 |
US8042497B2 (en) * | 2007-04-12 | 2011-10-25 | Babcock & Wilcox Power Generation Group, Inc. | Steam generator arrangement |
DE102007022678A1 (de) | 2007-05-11 | 2008-11-13 | Hydraulik-Ring Gmbh | Abgasnachbehandlungseinheit auf Ammoniakbasis und Verfahren zur Reinigung stickoxidhaltiger Abgase von Verbrennungskraftmaschinen |
US20090297993A1 (en) * | 2008-05-30 | 2009-12-03 | Foster Wheeler Energia Oy | Method of and System For Generating Power By Oxyfuel Combustion |
FI129360B (fi) | 2009-04-15 | 2021-12-31 | Andritz Oy | Menetelmä savukaasupäästöjen vähentämiseksi ja kattila |
US20110036279A1 (en) * | 2009-08-12 | 2011-02-17 | Jeffrey Shallcross | NOx reduction control system for boilers |
JP5399214B2 (ja) * | 2009-11-18 | 2014-01-29 | 住友重機械工業株式会社 | 循環流動床炉及び循環流動床炉の制御方法 |
US8012746B2 (en) | 2009-12-31 | 2011-09-06 | Biogas & Electric, Llc | NOx removal system for biogas engines at anaerobic digestion facilities |
US20110226195A1 (en) * | 2010-03-18 | 2011-09-22 | Foster Wheeler North America Corp. | Wall Construction for a Boiler Arrangement |
US9513000B2 (en) * | 2010-09-29 | 2016-12-06 | Mitsubishi Hitachi Power Systems, Ltd. | Oxygen combustion system and method for operating same |
EP2541144A1 (en) * | 2011-07-01 | 2013-01-02 | Tecnoborgo S.p.A. | Incinerator, particularly for waste-to-energy plants |
JP5916470B2 (ja) * | 2011-08-04 | 2016-05-11 | 三菱重工業株式会社 | 流動層処理システム及び流動層燃焼排ガスのn2o除去方法 |
WO2018077390A1 (en) * | 2016-10-25 | 2018-05-03 | Doosan Lentjes Gmbh | A cyclone with means for introducing a reducing agent |
US10653996B1 (en) * | 2019-05-13 | 2020-05-19 | The Babcock & Wilcox Company | Selective non-catalytic reduction (SNCR) of NOx in fluidized bed combustion reactors |
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US5318755A (en) * | 1992-11-30 | 1994-06-07 | A. Ahlstrom Corporation | Method and apparatus for cleaning flue gases |
US5555849A (en) * | 1994-12-22 | 1996-09-17 | Combustion Engineering, Inc. | Gas temperature control system for catalytic reduction of nitrogen oxide emissions |
-
1994
- 1994-04-12 US US08/226,483 patent/US5465690A/en not_active Expired - Lifetime
-
1995
- 1995-04-12 AT AT95915897T patent/ATE183942T1/de not_active IP Right Cessation
- 1995-04-12 PL PL95316785A patent/PL316785A1/xx unknown
- 1995-04-12 KR KR1019960705496A patent/KR970702097A/ko not_active Ceased
- 1995-04-12 CZ CZ19962977A patent/CZ287910B6/cs not_active IP Right Cessation
- 1995-04-12 DE DE69511854T patent/DE69511854T2/de not_active Expired - Fee Related
- 1995-04-12 WO PCT/FI1995/000207 patent/WO1995027554A1/en not_active Application Discontinuation
- 1995-04-12 DK DK95915897T patent/DK0755299T3/da active
- 1995-04-12 CA CA002186369A patent/CA2186369C/en not_active Expired - Fee Related
- 1995-04-12 HU HU9602805A patent/HUT76752A/hu unknown
- 1995-04-12 EP EP95915897A patent/EP0755299B1/en not_active Revoked
- 1995-04-12 JP JP7526107A patent/JPH09509474A/ja active Pending
- 1995-06-12 TW TW084103616A patent/TW260621B/zh active
-
1997
- 1997-11-26 US US08/979,308 patent/US5911956A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CZ297796A3 (en) | 1997-03-12 |
DK0755299T3 (da) | 2000-03-27 |
EP0755299B1 (en) | 1999-09-01 |
EP0755299A1 (en) | 1997-01-29 |
CA2186369A1 (en) | 1995-10-19 |
PL316785A1 (en) | 1997-02-17 |
US5911956A (en) | 1999-06-15 |
US5465690A (en) | 1995-11-14 |
ATE183942T1 (de) | 1999-09-15 |
DE69511854D1 (de) | 1999-10-07 |
CA2186369C (en) | 2000-08-08 |
JPH09509474A (ja) | 1997-09-22 |
HUT76752A (en) | 1997-11-28 |
MX9604721A (es) | 1998-05-31 |
TW260621B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1995-10-21 |
HU9602805D0 (en) | 1996-12-30 |
WO1995027554A1 (en) | 1995-10-19 |
KR970702097A (ko) | 1997-05-13 |
DE69511854T2 (de) | 2000-02-17 |
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Legal Events
Date | Code | Title | Description |
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PD00 | Pending as of 2000-06-30 in czech republic | ||
MM4A | Patent lapsed due to non-payment of fee |
Effective date: 20030412 |