CS271345B2 - Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath - Google Patents
Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath Download PDFInfo
- Publication number
- CS271345B2 CS271345B2 CS88287A CS28788A CS271345B2 CS 271345 B2 CS271345 B2 CS 271345B2 CS 88287 A CS88287 A CS 88287A CS 28788 A CS28788 A CS 28788A CS 271345 B2 CS271345 B2 CS 271345B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- pickling
- bath
- scale
- alloys
- pickled
- Prior art date
Links
- 238000005554 pickling Methods 0.000 title claims description 73
- 238000000034 method Methods 0.000 title claims description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 18
- 229910045601 alloy Inorganic materials 0.000 title claims description 13
- 239000000956 alloy Substances 0.000 title claims description 13
- 229910052742 iron Inorganic materials 0.000 title claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 title claims description 4
- 150000004706 metal oxides Chemical class 0.000 title claims description 4
- 239000000243 solution Substances 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 10
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 5
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 4
- 229910001447 ferric ion Inorganic materials 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- -1 iron ion Chemical class 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 20
- 150000002500 ions Chemical class 0.000 description 14
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 239000000155 melt Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910000975 Carbon steel Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- IGUSRGSVTUAUKM-UHFFFAOYSA-N [N+][O-].O[N+]([O-])=O Chemical class [N+][O-].O[N+]([O-])=O IGUSRGSVTUAUKM-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000027939 micturition Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU87135A HUT53398A (en) | 1987-01-19 | 1987-01-19 | Process for descaling and deoxidating metals and metal alloys, particularly alloyed steels, high-alloyed steels and carbon steels, in pickling bath containing iron(iii)ion active ingredient |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS28788A2 CS28788A2 (en) | 1989-12-13 |
| CS271345B2 true CS271345B2 (en) | 1990-09-12 |
Family
ID=10948099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS88287A CS271345B2 (en) | 1987-01-19 | 1988-01-15 | Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath |
Country Status (8)
| Country | Link |
|---|---|
| CN (1) | CN1039850A (de) |
| CS (1) | CS271345B2 (de) |
| DD (1) | DD267265A5 (de) |
| DE (1) | DE3801018A1 (de) |
| FR (1) | FR2633946A1 (de) |
| HU (1) | HUT53398A (de) |
| NO (1) | NO882844L (de) |
| PL (1) | PL270198A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HUT53398A (en) * | 1987-01-19 | 1990-10-28 | Borsodi Vegyi Komb | Process for descaling and deoxidating metals and metal alloys, particularly alloyed steels, high-alloyed steels and carbon steels, in pickling bath containing iron(iii)ion active ingredient |
| EP0346510A1 (de) * | 1988-06-15 | 1989-12-20 | Chema Chemiemaschinen Gmbh | Beizen von Halbzeugen |
| AT406486B (de) * | 1998-12-22 | 2000-05-25 | Andritz Patentverwaltung | Verfahren zum beizen von edelstahl |
| CN102660747A (zh) * | 2012-04-13 | 2012-09-12 | 中国文化遗产研究院 | 用于银器与鎏金银器保护的硫脲类复配除锈剂和除锈膏 |
| CN103498164A (zh) * | 2013-09-04 | 2014-01-08 | 大连理工大学 | 一种热轧钢板氧化层的环保清洗液及清洗方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS545829A (en) * | 1977-06-15 | 1979-01-17 | Nishiyama Sutenresu Kemikaru K | Acid cleaning agent for marageing steel |
| DE2736255A1 (de) * | 1977-08-11 | 1979-03-01 | Beugin Procedes Sa | Verfahren zum beizen von staehlen |
| JPS6043920B2 (ja) * | 1978-09-13 | 1985-10-01 | 旭電化工業株式会社 | 新規な酸洗剤 |
| JPS5550468A (en) * | 1978-10-11 | 1980-04-12 | Kawasaki Steel Corp | Pickling method for cr base stainless steel |
| JPS5920752B2 (ja) * | 1980-08-07 | 1984-05-15 | 川崎製鉄株式会社 | オ−ステナイト系ステンレス鋼板の酸洗方法 |
| HUT53398A (en) * | 1987-01-19 | 1990-10-28 | Borsodi Vegyi Komb | Process for descaling and deoxidating metals and metal alloys, particularly alloyed steels, high-alloyed steels and carbon steels, in pickling bath containing iron(iii)ion active ingredient |
-
1987
- 1987-01-19 HU HU87135A patent/HUT53398A/hu unknown
-
1988
- 1988-01-15 DE DE3801018A patent/DE3801018A1/de not_active Withdrawn
- 1988-01-15 CS CS88287A patent/CS271345B2/cs unknown
- 1988-01-18 DD DD88312282A patent/DD267265A5/de unknown
- 1988-01-18 PL PL27019888A patent/PL270198A1/xx unknown
- 1988-06-27 NO NO88882844A patent/NO882844L/no unknown
- 1988-07-07 FR FR8809226A patent/FR2633946A1/fr active Pending
- 1988-07-22 CN CN88104461A patent/CN1039850A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DD267265A5 (de) | 1989-04-26 |
| FR2633946A1 (fr) | 1990-01-12 |
| CS28788A2 (en) | 1989-12-13 |
| NO882844L (no) | 1990-01-22 |
| HUT53398A (en) | 1990-10-28 |
| PL270198A1 (en) | 1988-12-08 |
| DE3801018A1 (de) | 1988-07-28 |
| NO882844D0 (no) | 1988-06-27 |
| CN1039850A (zh) | 1990-02-21 |
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