CS254146B1 - Method of glue production - Google Patents

Method of glue production Download PDF

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Publication number
CS254146B1
CS254146B1 CS848906A CS890684A CS254146B1 CS 254146 B1 CS254146 B1 CS 254146B1 CS 848906 A CS848906 A CS 848906A CS 890684 A CS890684 A CS 890684A CS 254146 B1 CS254146 B1 CS 254146B1
Authority
CS
Czechoslovakia
Prior art keywords
diene
diglycidileter
dithiol
bisphenol
concentration
Prior art date
Application number
CS848906A
Other languages
English (en)
Inventor
Elisabeth Klemm
Rolf Maertin
Hans-Heinrich Hoerhold
Steffi Sensfass
Hans-Juergen Flammersheim
Horst Wolf
Original Assignee
Elisabeth Klemm
Rolf Maertin
Hoerhold Hans Heinrich
Steffi Sensfass
Flammersheim Hans Juergen
Horst Wolf
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Publication date
Application filed by Elisabeth Klemm, Rolf Maertin, Hoerhold Hans Heinrich, Steffi Sensfass, Flammersheim Hans Juergen, Horst Wolf filed Critical Elisabeth Klemm
Publication of CS254146B1 publication Critical patent/CS254146B1/cs

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/0275—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with dithiol or polysulfide compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J181/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Adhesives based on polysulfones; Adhesives based on derivatives of such polymers
    • C09J181/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Description

1
HaaBaHHe n3o6peTeHHH:
Cnoco6 nojiyqeHHH xneeB , OSnaCTb ΠρΗΜΒΗβΗΗΗ Η3θ6ρβΤβΗΗΗ: lÍ3o6peTeHHe othochtch k cnocoĎy nonyweHHH KJieeB Ha ocHOBe cfcoTooTBepjimaioineňcHeHOBOň flHTHOJIBHOň nonHMepH3aUHOHHOň CHCTeMbl. nojiyueHHbie cornacHo Η3ο6ρβτβΗΗκ> κηβΗ ocofieHHo noflxoflHT flnn CKjienBanHH οπτη-uecKHx fleTajieň fljia oepaaoBaHHH οπτΗΜβοκΗΧ chctcm coSjnoflaflt BbicoKHe TpeSoBáHHHHa TOMHOCTb Η B KBHeCTBe ΙΑΠβΗ flJIH OnpaB. ITo.3TOMy OHH HaXOflHT πρΗΜβΗβΗΗβnpeHMymecTBeHHO b oSnacTH οπτΗκο-MexaHHMecKoň npoMHmneHHocTH.
XapaKTepncTHKa H3BecTHMx TexHHMecxHx pemeHHň: y«e H3BecTHbi cnocoSbi nonyMeHHH OTBepxflarauiHXCH Ha xono«y KJieeB, npn KOTopbixnofleepraiOT nonHMepH3anHH ceeTOM roMoreHHbie cmsch H3 πολητηολοβ, coaepxanwxMHHHMajlbHO flBe THOJIbHbie rpyTHIM ΠΟ MOJiexyjie, Η H3 ΠΟΠΗβΗΟΒ C MHHHMajlbHO flByMHpeaKIÍHOHHOCnOCO6HbIMH HeHaCbímeHHblMH yrJiepOfl^yrnepOflHblMH CBH3HMH ΠΟ MOJiexyneB npHcyTCTBHH φοτοΗΗΗΐίΜ3τοροΒ (DE-OS 2 734 076, 1978). φΐΗ ΤΟΓΟ MTpSbJ flOCTHrHyTb «OCTaTOMHO BblCOKHX CKOpOCTeĎ ΟΤΒβρ»ΗβΗΗΗ, flJIH hc-nonbsoBaHHH nponeccoB Φοτοοπιηββηηη 4>yHKUHOHanbHocTb nojiHTHOjia h/hjih nojineHab cMecH MOHOMepoB noBbmtaeTCH MHHHMajlbHO, Ha onny $yHKuinoHajibHyK) rpynny(DE-OS 2 622 126, <1977). Taxwe CHCTeMbl onncbieaioTCH b xanecTBe npo3paMHbix,otjihmho npHJiHnaiomHX MaTepHanoB «jih nojiyneHHH noxpbiTHň Ha CTéxjie η MeTajuie.OHH ΗΜβΙΟΤ BblflatOmHeCH CBOňCTBa OTHOCHTejlbHO (JíOpMOyCTOflHHBOCTH H CTOŇKOCTHκ bjihhhhhm pacTBopHTejjeň.
OflHaxo TaxHe nojiHMepw H3-3a CTpyKTypbi HepacTBopuMbi, mto orpaHHMHBaeT hx πρκ-ΜβΗβΗΗβ B oSjíaCTH npeUH3HOHHOň ΟΠΤΗΚΗ. ΠρΗ ΠΡΗΜΘΗΘΗΗΗ SKBHMOJIHpHblX CMeceň6H<}>yHKUHOHajibHbix THonbHbJx eHOBbix coeflHHeHHň nonywaioT pacTBopHMbie nojiHMepw,OflHaxo Heo6xoflHMM oneHb flonrae BpeMeHa o6jiyMeHHH λπη φοτοοτΒβρκ/ιβΗΗΗ. ykopa-nHBaHHe ΒρβΜβΗ oCnyneHHH 6bino 6bi atejiaTejibHo ujih τογο, hto6m oco6eHHo πρπ H3roTOBJíeHHH 6ojibinHx MHceji H3fleJinň BbicoKOTOHHbnc onTHnecKiix neTajieň narb bo3-MOJKHOCTb 3φφβΚΤΗΒΗΟΓΟ B ΤΘΧΗΟΠΟΓΗΗβΟΚΟΜ ΟΤΗΟΠΙβΗΗΗ CnOCOSa CKJieHBaHHH Η3ΓΟ-τοβπΗβΜΜχ h cKJieHBaeMbix fleTaneft. 254146 2 B GB-PS 2 030 584. b eune HHeHOBbix mohomgpob npeBpanjaioT axpHJioBbie 3φηρω no-JIHOJIOB TOJIBKO C ΗββΟΠΒΠΙΗΜΗ KOJIHHeCTBaMH nOJIHTHOJla, ΠρΗΗβΜ 4>OTOCIIlHBaiOIUeňnojiHMepH3auneň Óojiee ýyHKUHOHaJibHoro axpHJiaTa βο3ηηκ3ιοτ nepacTBopHMbis no-JiHMepHbie ceTKH. THOJibHoe coeaHHeHHe snech tojibko ΗΜββτ 3anaqy yMeHbmuTb hh-rH6npoBaHne KHCJiopo,qa panHKanbHOň ποπΗΜβρΗ33ΗΗΗ. flajihnie 6buio yxe πρβπποχβΗΟκ CMecHM H3 ^HOKconaHMeTaKppuiaTOB h 2,2-6HC-p-(2-rmu5OKCH-3~-MeTaKpnjioKCH-προποκοΗ)φβΗΗΠ-nponaHa floCaBJíHTb ajiiKjbaTHqecKHe hhthojim. H b 3T0M cjiynae hhthoh cJiyxHT TOJibKO b KanecTBe ycKopHTejin φοτοοτΒβρτκπβΗΗΗ.
UeJIb Η3θ6ρβΤβΗΗΗ i
UeJIb Η3θ6ρβΤβΗΗΗ - flaTb BO3MO«HOCTb nOJiyqeHHH flOJirOBeUHblX, norOflOyCTOHWH-BblX, BblCOKOTOHHblX CKJieHBaHHň 6e3 HanpBJteHHH H C SoJIbUIHM BblXOflOM TOflHOň npo-«yKUHH ΠΡΗ nOMOnW CnOCOĎa CKJieHBaHHH, . 3φφβΚΤΗΒΗ0Γ0 B ΤβΧΗΟΠΟΓΗΗβΟΚΟΜ OTHO-meHHH.
HajioaceHHe· cymHOCTH Η3θ6ρβτβΗΗΗ; B ocHoey Η3θ6ρβτβΗΗΗ nojioaceHa 3aflaqa, co3naTb cnoco6 nojiyqeHHH οπτΗΗββκκχKJieeB 6e3 pacTBopHTeneň, OTBepMflaromnxcH Ha xojiony nyTeM Φοτοηηηηηηροβ3Ηημχοαηο- hjih flByxcTyneHqaTbix nponeccoB, kOTopue πρκ πρΗΜβκβΗΗΗ, coxpaHHH npea-nOHTHTejIbHbie CBOňCTBa HeCIflHTbtX THOJIbHbIX eHOBblX aflflHTHBHblX nOJIHMepOB flJIH on-THHecKHx yejieň HcnoJib3OB3HHH, xax xopomyio pa3beMHocTb h Majibie HanpHweHHH,TpeĎyiOT TOJIbKO ΚΟΡΟΤΚΗΧ ΒρβΜβΗ O6jiyqeHHH flJIH φοΤΟΗΗΗΗΗΗΡΟΒβΗΗΟΓΟ HaqaJia06pa30BaHHH ΠΟΠΗΜβρΟΒ. Πρκ HByxcTyneHqaTOM nppnecce οτΒβρκΗθΗΗΗ cKJieeHHbie οπτΗΗβοκΗβ ΗθτβπΗ b τβ-weHHe HOCTaToqHoro a jih κορρβΚΗΗΗ nojioateHHH ΒρβΜβΗΗ nocjie φοτοφΗκοβηκΗ hojek-Hbi 6biTb TepMHMecKH pasteMHbift. OKOHqaTejibHoe cKJieHBaHHe (nonHoe οτΒβρικΗβΗΗβ)flOJEKHO 6bITb HOCTHrHyTO BO BTOpOft CTynGHH.
HanpoTHB Toro πρκ OHHOCTyneHqaTOM nponecce οτΒβρ^βΗΗΗ KJieeBoe coenHHeHHeHHfl npenycMOTpeHHoň HejiH Hcnojib3OBaHHH b τβηβΗΗβ οίθηβ κοροτκοΓΟ ΒρβΜβΗΗ(no BO3M03KHOCTH B OSjíaCTH CeKyHfl) flOJEKHO 6blTb yJKe flOCTaTOHHO OTBepjKfleHO.3aaana cnoco6oM nojiyqeHHH KJieeB, b qacTHOCTH, hjih CKJienBaHHH onTHqecKHxHeTaneň, Ha ocHoee φοτοοτΒβρΗίΗβιοπιβΗΟΗ ΗΗβΗΟΒοή HHTHOJibHoň nojiHMepH3aHHOH—
Hoň CHCTeMbi cornacHO Η3θ6ρβτβΗΗΚ> pemaeTCH τβΜ, htó flHeHOByro· HHTHojibHyionOJIHMepH3aHHOHHy» ČHCTeMy ΒΜβΟΤβ C fíOJieě φyHK^HOHaJIbHbIMH 3nOKCHflaMH C MH“HHMaJibHo flByMH 3noKCHflHbiMH rpynnaMH h/hjih rHflpoKCHHKpmiaTaMH (MeTaKpuJiaTaMH')1C MHHHMajIbHO OflHOň φνΗΚΗΗΟΗΗΤΙΗΗΟή rHflpOKCHJIbHOň rpynriOH nOCpeflCTBOM H3BeCT“HbDC φΟΤΟΗΗΗΗΗΗΤΟρΟΒ ΠΟΗΒβΡΓβΙΟΤ nOJIHMSpH3aiIHH CBeTOM. B xanecTBe 6ojiee ^yHKHHOHajibHbix anoKCHflOB npeHMymecTBeHHo πρημθηηιοτ δΗβφβ-HOJI“A-flHrJIHflHflHJIOBblň· 3φΗρ HJIH 6ΗβφβΗΟΙΙ-Ρ-ΗΗΓηΗΗΗΗΗηθΒΜή 3φΗρ HJIH 3nOKCHflHbieCMOJIbl Ha OCHOBe Η33Β3ΗΗΜΧ δΗΟφβΗΟΗΟΒ HJIH 3ΗΗφ3ΤΗΗβΟΚΗβ 6HC (anOKCHflbl) , Πρβ“HMymecTBeHHO 3,4-3noKCH-HHKjioreKCHJiMeTHJi-3, 4-3noKCHHHKJioreKcaHKap6oKCHJiaTHJIH nSHTaSpHTpHT-TGTparJIHHHflHJIOBblň 3φΗΡ·
CjienyiomHe rHflpoKCHáKpHJiaTbi(MeTaKpHJiaTbi) ocoÓeHHO πρηγοηημ hjih onHOcTyneHqat· .·Toro nponecca OTBepJKHeHHn: - npOnyKT npHCOenHHeHHH aKpHJIOBOň KHCJIOTbl (MeTáKpHJIOBOň KHCJÍOTbl) K fíHClJe-HOJi-A-HHrnHHHHHJioBOMy 3φΗρν:
HO CH3 OH CH^C-C-O-CHrCH-CHi-0--G--O-CH rCH-CHl-O-C-C^CH2
OH CH3 OH 254146 “ προΛγκτ npucoeAHMeHHfl βκρκηοΒοϋ κη&amp;ποτμ (MetaKpanoso# Rhcjiotm) κ GHcýe-."HÓÍI-F-flHrjIHUH«HJIOBOMy BfcHpy!
. HO CH1»C-C-O-CH1-CH-CH 2-0- “CHl“ OH .
OHII I -o-ch2-ch-ch2-o~c-c-ch2 . OH ' ’ — npoayKTfaí npHCoesHHeBHH κ aro^aTHMBCKHM 6nc(3noKcnqaM), b uacTHocTH, προ-flyKT npHCOeflHHeHHH aKpHJIOBOň KHCJlOTbl (ΜβΤβΚρΜΠΟΒΟΛ KHCJlOTbl) K 3,4“3ΠΟΚΟΗ-HHKnoreKcnnMeTitn-3,4-9noKtmtHKnoreKcaHKap6oKciúiaŤ: H^C-HC-C-O-l^J kJ>*(O’C-CH-CH <2 0 ‘ f/ '/7' ? :/λ.· Α B KauecTBe MOHoýyHKBHOHanbHbtx raqpoKCHaxpiuiaTOB ocoCeMHO npuroaHbí: ΒΚρκη0Β0-(ΜβΤ3ΚρΗΛ0Βθ)-3-%Π0Ρ“2-ΓΗΠΡΟΚ0ΗΠρθΠΗΛ0ΒΜ# 3φΗρ! CH.-CH-C-O-CH^-CH-CHí-Cl ηII * i 1 o . OH' </< < ' _ j r . —aKpJUIOBO-(MeTaKpHJIOBo)-3-H30eyTOKCH-"2-THapOKCHnponHrtOBMft 3φΒρ _ ’ CHj I · ,. : CH,«CH-C-O-CH.-CH-CH,-O-CH. II z I »
.. 0 ’ OH B KauecTBě ,πητηοπι>ηογο coeAHiieHHŘ ocoCeHHo ioahtch cJioxKuň 3φκρ flHaHona cTHorjiHKoneBoň kmcjiotoA, xoTopuft b ochobhom 6ea sanaxa. 0 '·
" i ’ H
-C-^Vo-C-CH1SH θΐΗ5 HS-H2C-C-O-
HajIbHeňtnHMH npMrOAHtíMH AHTHOjlbHMMH COGJJHHBHHHMH HBJIHMTCH CnOMHbie 3φΗρυ THO**rnuKOjieBoň KHcnoTbi c TpHSTiuieHrjiHKOJieM: II ' ' HS-CH^-C-O-CH^-CH^-O-CH^-CH^-O-CH ^-CH^-O-C-CH^SH . - a TparJiHKonbflMTHon: HS-CH^-CH^-O-CH ^-CH^-O-CH^-CH^SH. B KaqecTBe AHeHOBbix coeflHHeHHň npe^nonTHTenbHO HčnonbsyWT: - fl«rnHKonb6HcannnjiKap6oHaTÍ λ-··". ‘ . .· o < Ό'.' <: H ii < ,HiC-JCH-CHa-O-C-O-(CHi>i-O-ÍCHíX-O-C-O-CH2-CH»CHÍ, , ~ H3o$TajieBOflHannmioBbiň 3φκρ: , \l,^C-O-CH2-CH“CH1Oc-O-CH^ ''../O.''··· *».· φοροΗ:
HjO v OH, 0 C-CH-Č-CH-C "" 3
HjC CH3 B KauecTBe φοτοοβΗοκβιϋιιηβτοροΒ ocoOeHHO npHH«Ma»TCH b cooópaxeHHe 6βΗ3θφβ-HOH, THOKCaHTOH HJIH ΤρΗφβΗΗΛφΟΟφΗΗ, B KaMeCTBe φΟΤΟΗΗΗΙξΗΒΤΟρΟΒ flJIH anOKCHfl- 254146 4
Hoň nojiHMepmaiíHH πρηγολημ flHapHJiňoflOHHeBbie cojih, b uacTHOCTH, TeTpaifrnyopo- 6opaT ftHTOjiHJiňoflOHHH, reKcatJxnyopoaHTHMOHaT hhtojihjihojiohhh , Γβκαβφ,πγοροφσοφβτ flHTOnHJIHOflOHHH HJIH ΓβΚΟβφ^ΟρΟβρΟβΗβΤ flHTOJIHJIHOflOHHH. J ·
CorJiaCHO Η3θ6ρβΤβΗΗΜ φοΤΟΟΤΒβρΧΑββΜωή B flByX CTyneHHX ΟΠΤΗΊΘΟΚΗΗ KJieň HMe-βτ COCTaB ΜΟΗΟΜβρΟΒ H HHHUHaTOpOB, ΠΟ3ΒΟΠΗΚ)ΠΙΗΗ aflflHTHBHyiO ΠΟΠΗΜβρΗ3 3ΡΚΠΟH nOJIHMepH3apHK) C pOCTOM penH H3 JKHflKOň CMeCH ΜΟΗΟΜβρΟΒ B flByX He3aBHCHMOflpyr ot flpyra ynpaBJíaeMbix φβ33χ peaKijHHJ BO-nepBMx b nojimpHcoeflHHeHHH Ρ,α-THOJia K flHeHOBOMy KOMHOHeHTy Η BO-BTOPMX B HHHHHHpOBaHHoň UHapHJIHOflOHHeBbiMH·cojihmh xaTHOHHOň nojiHMepH3aiiHH c pacxpbiTHeM pHxna anoKcnua.
Cnoco6 ΠΡΗ φΟΤΟΟΤΒβρΧΑβΙΟΠΙβΜεΗ OflHOKpaTHblM O6jiyqeHHeM ΟΠΤΗΗβΟΚΟΜ KJieiO HanpH“Mep BO3MOJKHO npOBOflHTh TaK, UTO K 3KBHMOJlHpHbIM CMeCHM H3 flHTHOJia H flUeHOBOrOcoe«HHeHHH «οδβΒππιοτ rHflpoKCHaKpHJiaTbi (MeTaxpHJiaTbi) corjiacHo Η3ο6ρετεΗΗΐο.IIpeflnoMTHTejibHO KOjmaecTBO Μοκετ cocTaBJwrb 20-60 eec.SJ οτηοοητθπβηο o6me-ΓΟ KOJIHMeCTBa flHTHOJlbHOňZflHeHOBOft nOÍIHMepH3apHOHHOň CHCTeMbí. npefllIOHTHTeJIbHOflOCaBHTb 0,5-1,5 Bec.x Ha3BaHHbIX ^OTOCeHCH6HJIH3aTOpOB (6θΗ3θφεΗΟΗ, THOKCaH-TOH HJIH ΤρΗφθΗΗΗφοεφΜΗ) . floOaBJíeHHeM COrJiaCHO H3O6peTeHM0 rHUpOKCHaxpHJiaTOBI^MeTaKpHJiaTOB) flocTHraeTCH xejiáeMaa ObiCTpan ΦοτοΦηκοηηηη, cmotph no no6aB“jieHHOMy xonnuecTBy, b TeueHHe 5-30 cex. ECJIH ΠΡΗ ΠρΗΜβΗβΗΗΗ φΟΤΟΟΤΒβρΜββΜίείίΟΪ THOJIbHOň-eHOBOň aXWHTHBHOň CHCTeMbícomacHO Η3θ6ρβτεΗΗκ> HeoOxoflHMO CTyneHMaToe φοτοοτΒβρχΛεΗΗβ, βμθοτο γηηροκ-CHaxpHJiaTOB (MeTaKpHJiaTOB) flOnOJIHHTeJIbHO HOOaBJIHIOT SnOKCHflbl C MHHHMaJIbHOflByMH anOKCHAHblMH TpynnaMH H 0,5-5 sec. Z φΟΤΟΗΗΗΗΗβΤΟρΟΒ flHapHJIHOflOHHeBblXcojieň oTHOcHTejibHO HcnojibaoBaHHoro KOJIHMeCTBa anoKcnaoB. Cnocofí b stom cny-uae bo3Mojkho npoBO«HTb Tax,, mto KJieeByw cMecb xax ο6μμηο noaaioT Me«ny cKnea-BaeMblMH OnTHneCKHMH fleTaJIHMH H' TOUHO KJCTHpyiOT B OnTHUeCKOM OTHOineHHH. B3T0M COCTOHHHH O6jiyUai0T ΟτφΗΠΙ>ΤρθΒ3ΗΗΗΜ CBeTOM pTyTHOň JiaMnbl BblCOKOTO flaB-neHHfl (>360 hm) b TeueHHe 1-2 mhh. B sto βρθμη ocymecTBjíHeTCH Φηκοβιιηη οπτη-uecKHX jneTaneft. IlocJie 3Toro onTHuecKHe neTanH 6e3 flonojiHHTejibHoro KpenneHHHmojkho noflBepraTb xpaHeHHio h TpaHcnopTy. OuihOouho cxneeHHbie onrauecKue ηβτβ-jih KpaTKOBpeMeHHbíM HaťpeBaHHeM flo 80-120°C οπητβ mojkho jierxo pa3beaHHHTbH OUHCTHTb OpraHHUeCKHMH paCTBOpHTeHHMH (χΠΟροφορΜΟΜ, βΐχβΤΟΗΟΜ) . 3aTeM O.HHοπητβ cnocoOHbí κ πρΗΜβΗβΗΗΐο. Ecjih He TpeSyeTCH KoppexpuH cxneeHHbix onTHuec-khx geTajieň, hx ηπη αοοτηκθηηη okoHuaTenbHoro oTsepitcfleHHH eme pa3 ofriryuaioTB ΤβΜβΗΗβ 5-10 MHHyT ΗβΟΤφΚΠΒΤρΟΒΗΗΗΜΜ CBeTOM pTyTHOň JiaMnbl· BblCOKOTO flaBJíe-hhh. nócJie 3Toro onTHuecKHe neTajiH cnocoóHbí κ πρΗΜβΗβΗΗΐο.
Bbino HaňfleHo, uto flHeHOBan flHTHOJibHan nonnMepn3aiiHOHHan CHCTeMa c nanbHeňmH-MH MOHOMepaMH, Oojiee φνΗΚΙΙΗΟΗΒίΙΒΗΗΜΗ SnOKCHflaMH HJIH THflpOKCHaKpHnaTaMH(MeTaKpHJiaTaMH ) C MHHHManbHO OflHOH φyHK^HOHaΠbHO^^ rHflpOKCHJIbHOň rpynnoň HJIHC anOKCHJiaMH H rHApOKCHaxpHJiaTaMH (μΘΤ3ΚΡΗΠ3Τ3ΜΗ ) BMeCTe, B KOMÓHHaiIHH CH3BecTHbiMH φοτοΗΗΗρΗΗτορΗΜΗ flaeT Kneň, cBH3biBaiomHň xoppinyio TexHonornuecKyioo6pa6aTbiBaeMOCTb c Bbtfs,aK>atftMaca CBoňcTBaMH npHMeHeHHa. TaxHM o6pa3OM hjih φο-TOHHHUHHpoBaHHoro nauana npouecca OTBepjKfléHHH b ojiho- hjih flByxcTyneHuaTOMcnocoBe cKneHBaHHH Tpe6yioTCH tojihko HeojKHflaHHO κοροτκΗβ BpeMeHa oSnyueHHH(xio oOnacTH ceKyHfl}. OmHČouHbie CKneHBaHHH npn «ByxcTyneHuaTOM cnocoOe ot-BepiKfleHHH 6e3 npočneM mojkho xoppHrHpoBaTb nocjie nepBoň cTyneHH OTBepaoieHHH(cTyneHb φΗΚΟβιΐΗΗ) .Bce-TaKH flOCTHraioT flůíiroBěUHbix, norofloycToňuHBbix, ynpy-γηχ cxjieHBaHHň .c MajiMM HanpaaceHHeM.
TeM caMbiM npn πομοπιη cnocoOa corjiacHo H3o6peTepno nonyuawT KJieň, κοτορκή HaOCHOB3HHH 3THX OTJIHUHbIX CBOftCTB npennouTHTejibHo MOJKHO o6pa6aTbiBaTb OCO6eH-ho b oĎJiacTH οπτΗκο-MexaHHuecKoň npoMbinuieHHOcTH.
KneH COTJiaCHO Η3θ6ρβΤΘΗΗΙΟ HBJIinOTCH OnTHUeCKH fipO3paUHbIMH nOJIHMepaMH H HMeiOTxopomyio npHJinnaeMOCTb Ha CTexne h MeTaJine. 254146 5 IIpHMepbl ΚΟΗΚρβΤΗΟΓΟ BbinOJIHeHHfl : Η3θ6ρβτβΗΗβ 6onee ποαρο6ηο noacHaeTca Ηίρκβ πρκ noMonw nerapex npHMepoBΚΟΗΚρβΤΗΟΓΟ ΒΜΠΟΠΗβΗΗΗ. ΠρΗΜβρ ΚΟΗΚρβΤΗΟΓΟ ΒΜΠΟΠΗβΗΗΗ 1: Jíněn cornacHO Η3θ6ρβτβΗΗΐο cneflywmHM oSpaaoM noflroTaBHHBajoT Η, πρημθηηιοτ flJiaCKJieHBaHHH οπτΗΗββκΗΧ fleTaneft: B CMecH H3 2,743 r flHrnHKonb6HcannHflKap6oHaTa, 1 ,823 r TPHrnHKonbflHTHona h6,8 ΜΓ 6βΗ3θφβΗΟΗβ paCTBOpHIOT 0,90 Γ npOflyKTa COeflHHeHHH aKpHnOBOft KHCHOTblK 6ΗβφβΗΟΗ-Α-ηΗΓΠΗμΗΑΗΠΟΒΟΜγ 3φΗργ. ΠθΤΟΜ CeCflBeTHblft. paCTBOp KaK o6bIHHOnoflaioT Mexmy CKneHBaeMbiMH onTHnecKHMH ΑβτβηηΜΗ h nofleepraioT oSnyneHuro ρτγτ-hoh naMrtbi BbicoKoro flaBJíeHHH (HBO-200). OHKcaflHH ocymecTBnneTCH b τβηβΗΗβΒρβΜβΗΗ ofíjiyneHHH 30 ββκ. Ποβηβ 3τογο οπτηηββκΗβ fleTajiH cnoco6Hbi κ πρΗΜβ-.ΗβΗΗΙΟ, ΠρΗΜβρ ΚΟΗΚρβΤΗΟΓΟ ΒΜΠΟηΗβΗΗΗ 2: Β CMecH Η3 2,743 γ nHrjiHKOJib6HcajinHJiKap6óHaTa, 4,125 r cnowHoro 3φΗρβ αηαηο*Jia C ΤΗΟΓΠΗΚΟΠβΒΟήKHCHOTOft η; 0,1 Γ 6βΗ3θφβΗΟΗβ paCTBOpHIOT 3,43 Γ aKpHJlOBO--3-XJIOp-2-rHflpOKCHnportHJIOBOrO ΟφΗρβ. BeCflBeTHblft, MaflOBH3KHft paCTBOp πρΗΜβΗΗ·lOT fljia CKneHBaHHH, KaK onHcano b npHMepe 1. ΒρβΜΗ oCnyneHHH ao φπκββΑΗΗ on-THnecKHX fleTaneft βοβτβΒ'ηηβτ 30-40 ββκ. ΠρΗΜβρ ΚΟΗΚρβΤΗΟΓΟ ΒΜΠΟηΗβΗΗΗ 3: Β CMecH Η3 2,743 r AHrnHKonb6HcajtnHnKap6oHaTa, 1,823 r TPHrnHKonbflHTHona h6,8 ΜΓ 6βΗ3θφβΗ0Η3 ΠΡΗ yMepeHHOM HarpeBaHHH paCTBOpHIOT 1,0 Γ 6ΗβφβΗΟΗ-Α-ΑΗ-ΓΠΗΑΗΑΗΠΟΒΟΓΟ 3φΗρβ Η 5 ΜΓ ΤβΤρβφ^θρθ6θρβΤΗ flHTOflHnňOflOHHH. PaCTBOp nOflaiOTMewfly CKneHBaeMbiMH οπτΗΗββκΗΜΗ ΑβτβπΗΜΗ η oSnynaioT εββτοΜ απηημ βοαημ365 ΗΜ (MeTajlJIHHeCKHH ΗΗΤβρφβρβΗΗΗΟΗΗΜή φΗΠϊιΤρ) pTyTHOň Π3ΜΠΜ BblCOKOrO flaB-ΠβΗΗΗ. Ποβπβ 60 ββκ ΟΠΤΗΗββΚΗβ fleTaJIH 33φΗΚβΗρ0Β3ΗΜ, ΠρΗ ΟΙΠΗΘΟΗΗΟΜ CKJieHBa-ΗΗΗ BO3MO3KHO ΤβρΜΗΗββΚΗή ρβ31>βΜ KpáTKOBpeMeHHblM Η3ΓρβΒΗΗΗβΜ flO 90° C. 0ΚΟΗ~naTenbHoe βκπβΗΒβΗΗβ ocymecTBJíneTCH ποβτορηημ ofinyneHKeM c ΗβοτφΗΠΒτροΒβΗΗΜΜCBeTOM pTyTHOft JiaMnbl BMCOKOrO ΑΗΒΠβΗΗΗ Β ΤβΗβΗΗβ 5 MHHyT. ΠθβΠβ 3ΤΟΓΟ ΟΠΤΗ“necKHe fleTann cnocoČHbí κ πρΗΜβΗβΗΗΐο. ΠρΗΜβρ ΚΟΗΚρβΤΗΟΓΟ ΒΜΠΟηΗβΗΗΗ 4ί Β CMecH Η3 2,76 γ φοροΗβ, 3,65 r TPHrnHKonbflHTHona η 0,9 r THOKcaHTOHa pac-TBOPHIOT 1 ,0 Γ 6ΗβφβΗΟΠ-Α-ΑΗΓΠΗΗΗΑΗΠ0ΒΟΓΟ 3φΗρβ Η 5 ΜΓ ΓβΚβ3φΐΐνθρθ3ΗΤΗΜΟΗ3Τ3AHTOJiHJiňoflOHHH. 3areM ποαχοαητ KaK onHcaHO Β πρΗΜβρβ 3. BpeMeHa o6jiyneHHHCOCTaBJIHIÓT 40 ββκ flnH φΗΚβΗΑΗΗ Η 5 MHHyT flHH. OKOHHaTéJIbHÓrO CKJieHBaHHH. iΦθρΜνΠ8 Η3θ6ρβΤβΗΗΗ! 1. Cnoco6 nonyneHjfH κηββΒ, b nacTHOCTH, flnn cKneHBaHHH οπτΗΗββκΗΧ fleTaneft,
Ha OCHOBe φΟΤΟΟΤΒβρΧΑβΚΜβήβη ΑΗβΗΟΒΟή flHTHOnbHOft ΠΟΑΗΜβρΗ3^(ΗΟΗΗθή CHCTeMbl,OTnHuaroiUHňc,H τβΜ, ητο «HeHOByra flHTHonbHyio nonHMepH3aflHOHHyio CHCTeMy ΒΜββτβc 6onee ^yHKflHOHanbHbíMH snoKCHflaMH c μηηημηπβηο flByMH βποκοηαημμη rpynnaMHη/ηΠΗ rHflpOKCHaKpHflaTaMH (ΜβΤ3ΚρΗηΒΤ3ΜΗ )C MHHHMaflbHÓ OflHOft φνΗΚΑΗΟΗβΠΒΗΟήfHflpOKCHflbHOft rpynnoft nOCpeflCTBOM HSBeCTHbIX φΟΤΟΗΗΗΑΗΒΤΟρΟΒ JIOflBepraiOT ΠΟΠΗ-MepH3aflHH CBeTOM. 2. CnocoC no π. 1, OTJiHnaiontHftcn τβΜ, hto b KanecTBe 6onee ΦνΗΚΑΗθΗ3π&amp;κωχanOKCHflOB ΠΡΗΜβΗΗΙΟΤ 6ΐΙθφβΗθη—A“flHrnHflHflHflOBblft 3φπρ ΗΠΗ δΗβφβΗΟΠ—F—flHmHflH“flHflOBblft 3φπρ ΗΠΗ 3ΠΗφ3ΤΗΗββΚΗβ 6HC <3nOKCHflbl) , npeHMymeCTBeHHO 3,4-3nOKCH-ΑΗΚΠΟΓβΚβΗΠΜβΤΗΠ-3,4-3nOKCHflHKnOreKCaH-Kap6OKCHJiaT ΗΠΗ ΠβΗΤΗ3ρΗΤρΗΤ”τβτρβ-rflHflHflHflOBblft 3φΗρ. 254146 6 3. Cnoco6 no π. 1 , OTJiHnaioiuHňCH τθμ, ητο β xanecTBe ΓΗπροκοΗβκρΗΠΗτοΒ (Mer-aKpWiaTOB) ΠρΗΜβΗΒΗΤΓ 3KPHJIOBO —(ΜβΤ3ΚρΗΠΟΒΟΓΟ )-3-ΧΠ0ρ-2-ΓΗΛρ0Κ0ΗΠΡ0ΠΗΠ0ΒΜή3φΗΡ HJIH aKpHJIOBO-(MeTaKpHnOBO)-3-H3O6yTOKCH-2-ruqpOKCHnpOnHJÍOBb!H 3φηρ HJ1HnpOflýKTbl npHCOeflHHeHHH aKpHJIOBOň KHCJIOTbl (MeTaKpHJlOBOň KHCJIOTbl) κ 6ηοφβ-HOJl-A-gHrjIHUHflHnOBOMy 3φκρν HJIH Κ 6HCφeHOJl-F-,^HΓJIH^HflHJIOBOMy ^φHpy HJIH κan^aTHuecKHM 6hc(anoKCHnaM) , npeHMymecTBemo κ 3,4-3noKCHHHKnoreKCHjiMeTHJi--3,4-3noKCHpHKnoreKcaH-Kap6oKcroiaTy. 4. Cnoco6 πο ππ. 1 η 3, oTJinnaioíunňcH τβΜ, ητο rHflpoKCHaKpHJiaTbi(MeTaKpHJiaTbi)floCaBjíHioT β KOHijeHTpaijHH 20-60 Bec.Z OTHOCHTéjIbHO o6mero KojiHaecTBa nneno-BOii flHTHOJIbHOÍÍ nOJIHMepH3aUHOHHOft CHCTeMbl. 5. Cnoco6 πο π. 1, OTJiHaaKwiťíCH τβΜ, ητο. b KaaecTBe Φοτοηηηιιη3τοροβ npn-ΜβΗΗΐοτ «HapitnfioflOHHeBbie cojih c KOMnJieKCHbíMH áttHOHaMH BF^, AsF^, SbF^, PFg Η B KaneCTBe φοΤΟΟεΗΟΗβΗΠΗββΤΟρΟΒ 6βΗ3θφβΗΟΗ, THOKCaHTOH HJIH ΤΡΗφβΗΗΠφΟΟφΗΗ.' 6. Cnoco6 πο ππ. 1 h 5, OTJiHnaroniHňca τβΜ* hto nHapHJiňonoHHeBbie cojih flOĎaBjía-WT B KOHyeHTpaUHH 0,5-5 Bec.% OTHOCHTéjIbHO HCnOJIb3OBaHHOrO KOJIHHeCTBa 3Π0Κ-CHJJOB. 7. Cnoco6 ΠΟ ΠΠ. 1 H 5, OTJIHHaHJIUHňca ΤβΜ, ΗΤΟ φθΤΟΟβΗΟΗ6ΗΙΙΗ3 3ΤθρΜ flO6aBJIHK>TB KOHijeHTpanHH 0-1,5 Bec.% OTHOCHTéjIbHO ofimero KOJiHaecTea «HenoBoň nHTHOjib-HOft nOJIHMepH3aHHOHHOň CHCTeMbl.
AHHOTaiUHH I Μ3θ6ρβτβΗΗβ othochtch κ cnocoSy nojiyaeHHH KJieeB, b h3cthocth, «jih cKJieHBa-hhh onTHHecKHX geTajieň, Ha ocHOBe flneHOBoň αητηοπβηοΑ nojiHMepH3apHOHHořiCHCTeMbl. ’ '
CneflyeT gaTb βο3μο;κηοοτβ nojiyaeHHa bmcokotohhmx, norofloycToňHHBbix cKjieHBa—hhh éea HanpaaceHHa h c 6οπβπμμ βμχοαομ roflHoó npoflyxHHH πρπ πομοπιη cnocoSaCKJieHBaHHH, 3φφέΚΤΗΒΗΟΓΟ Β ΤβΧΗΟΠΟΓΗΊβΟΚΟΜ ΟΤΗΟΙΠβΗΗΗ. nojiyaaeMbiň Kjieň, coxpanaa npeflnoHTHTenbHbie CBoňcTBa HecinHTbix THOJibHbix eHOBbixaflflHTHBHbIX nOJIHMepOB flJIH OnTHHeCKHX tjejieň flOJDKeH TpeSOBaTb TOJIbKO κοροτκκχΒρβΜβΗ oSjíyneHHH flJiH j φοτοΗΗΗΠΗΗροΒβΗΗΟΓΟ Háaajia nponecca OTBepMoeHHa. 4jih nojiyneHHH knea cofjiacHo H3odpeTeHHio UHeHOByro AHTHOjibHyte CMecb ΒΜβετβ c6onee φyHκ^noHaJIbHbIMH anoKCHflaMH η/ηπη rHflpoKCHaKpHJiaTaMH(MeTaxpHJiaTaMH)nOCpeflCTBÓM H3BeCTHbíX φΟΤΟΗΗΗΗΗβΤΟρΟΒ nOflBepraiOT nOJIHMepH3anHH CBeTOM. tlpHSHaHo H3o6pereHHeM no pe3yjibTaTaM 3KcnepTH3bi, ocymecTBJíeHHoň Be^OMCTBOMno flejiaM Η3θ6ρβτεΗΗβ h ππτβΗτοΒ fflP. 254146

Claims (7)

7 PŘBDMET VYNÁLEZU
1, Způsob výroby lepidel, zejména pro lepení optických sou-částí, na bázi fotoiniciovaného dien-ditiolového polymerač-ního systému, vyznačující se tím, že dien-ditiolový póly- v merační systém se zároveň s vícefunkčními epoxidy s nejménědvěma epoxidovými skupinami a/nebo hydroxyakryláty (meta-kryláty) s nejméně jednou funkční hydroxylovou skupinouv přítomnosti známých fotoiniciátorů podrobí polýmeracisvětlem.
2. Způsob podle bodu lj vyznačující se tím, že jako více-fuknční epoxid se použije bisfenol-A-diglycidileter nebobisfenol-P-diglycidileter nebo alifatické bisepoxidy, zej-ména 3,4-epoxicyklohexylmetyl-3,4-epoxicyklohexan-karboxylátnebo pentaerytril-tetraglycidileter·
3. Způsob podle bodu 1, vyznačující se tím, že jako hydro-xiakryláty/metakryláty se použije 3-chlor-2-hydroxipropyl-akrylát 4 nebo metakrylát nebo +3.-isobutosy-2-hydroxipro-pylakrylát nebo metakrylát , nebo adiční produkty kyselinyakrylové (kyseliny metakrylové) s bisfenol-A-diglycidil-eterem nebo k bis-fenol-P-diglycidileterem nebo s alifatic-kými bisepoxidy, zejména 3,4-epoxicyklohexylmetyl-3,4-epo-xicýklohexankarbóxylátem.
4· Způsob podle bodů 1 a 3, vyznačující se tím, že hydroxiakryláty (metakryláty) se přidávají v koncentraci 20 až60 hmot. % na celé množství dienového ditiolového polyme-račního systému. 254146 8
5. Způsob podle bodu 1, vyznačující se tím, že jako foto-iniciátoru se použije diaryljodoniové sole s komplexnímianionty BPj, AsFg, SbPg, PPg a jako fotoinzibilizátóruse použije benzofenon, tioxanton nebo trifenylfosfin.
6· Způsob podle bodů 1 a 5, vyznačující se tím, žediaryljodoniové soli se přidávají v koncentraci 0,5 až5 hmot· % na použitá množství epoxidu.
7· Způsob podle bodů 1 a 5» vyznačující se tím, že foto-senzibilizátory se přidávají v koncentraci 0 až 1,5 hmot.%, vztaženo na celá množství dien-diťíolováho polymerizač-ního systému. 254146
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EP1320561B1 (en) 2000-09-22 2010-03-17 PPG Industries Ohio, Inc. Curable polyurethanes, coatings prepared therefrom, and method of making the same
CN104321354B (zh) 2012-05-07 2017-03-08 莫赛纳实验室公司 用于制造含涂层产品以及复合物的方法和配方
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RU195584U1 (ru) * 2019-09-17 2020-01-31 Акционерное общество "Научно-производственное объединение "Государственный институт прикладной оптики" (АО "НПО ГИПО") Оптический компонент

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DE3436571A1 (de) 1985-06-13
HUT38386A (en) 1986-05-28

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